Long Lived InSitu Solar System Explorer (LLISSE): Development Status
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Sandia National Laboratories in collaboration with the National Renewable Energy Laboratory outline a framework for developing a solar fuels roadmap based on novel concepts for hybridizing gas-splitting thermochemical cycle s with high-temperature electro chemical steps. We call this concept SoHyTEC, a Solar Hybrid Thermochemical-Electrochemical Cycle. The strategy focuses on transforming purely thermochemical cycles that split water (H 2 O) and carbon dioxide (CO 2 ) to produce hydrogen (H 2 ) and carbon monoxide (CO) , respectively, the fundamental chemical building blocks for diverse fuels and chemicals , by substituting thermochemical reactions with high-temperature electrochemical steps. By invoking high-temperature electrochemistry, the energy required to complete the gas-splitting cycle is divided into a thermal component (process temperature) and an electrical component (applied voltage). These components, sourced from solar energy, are independently variable knobs to maximize overall process efficiency. Furthermore, a small applied voltage can reduce cycle process temperature by hundreds of degrees , opening the door to cost-effective solar concentrators and practical receiver/reactor de signs. Using the SoHyTEC concept as a backdrop, we outline a framework that advocates developing methods for automating information gathering, critically evaluating thermochemical cycles for adapting into SoHyTEC, establishing requirements based on thermodynamic analysis, and developing a model-based approach to benchmarking a SoHyTEC system against a baseline concentrating solar thermal integrated electrolysis plant. We feel these framework elements are a necessary precursor to creating a robust and adaptive technology development roadmap for producing solar fuels using SoHyTEC. In one example, we introduce high-temperature electrochemistry as a method to manipulate a fully stoichiometric two-step metal oxide cycle that circumvents costly separation processes and ultra-high cycle temperatures. We also identify and group water-splitting chemistries that are conceptually amenable to hybridization.
Summarized report on development and testing of hot-air flat-plate solar collector includes structural details, coating selection, and spacing between coating and glass plate. Report gives complete performance specifications and extensive certifications test report.
The National Renewable Energy Laboratory (NREL) led a collaborative effort to develop the Solar Automated Permit Processing Plus (SolarAPP+), a no-cost solar permitting software solution to address residential solar photovoltaic (PV) permitting resource constraints and streamline solar adoption processes among authorities having jurisdiction (AHJs). The SolarAPP+ is an online portal that automates permit plan review, enabling an instant permit approval process for code-compliant residential PV systems. Based on national model building, electrical, and fire codes, the SolarAPP+ automatically performs a compliance check of permit inputs against code requirements and produces an inspection checklist that can be used to verify installation practices, workmanship, and adherence to the approved design. NREL conducted a two-phase pilot with five participating AHJs and 16 solar contractors, spanning from November 2020 through December 2021, evaluating the ability of SolarAPP+ to deliver instant permits and its impact on four critical areas within each AHJ: permit review timelines; solar adoption timelines; AHJ time saved; and inspection results. The pilot confirmed that SolarAPP+ reduced permit review times to less than one day, reduced solar adoption timelines by an average of 12 days, saved an estimated 2,067 staff hours, and had comparable inspection results to those found in traditional permitting. The pilot further identified key lessons for improving SolarAPP+, including ways to streamline SolarAPP+ adoption, development of training resources, and expansion of supported products.
Despite the rapid development of perovskite solar cells (PSCs) toward commercialization, the toxic lead (Pb) ions in PSCs pose a potential threat to the environment, health and safety. Managing Pb via recycling represents a promising approach to mitigating its toxicity. However, managing Pb from commonly used organic solvents has been challenging due to the lack of suitable Pb adsorbents. Here, we report a new adsorbent for both separation and recovery of Pb from PSC pollutants. The synthesized iron-incorporated hydroxyapatite possesses a strongly negatively charged surface that improves electrostatic interaction through surface-charge delocalization, thus leading to enhanced Pb adsorption. Finally, we demonstrate the feasibility of a complete Pb management process, including the purification of Pb-containing non-aqueous solvents below 15 parts per 10 9 , a level compliant with the standards of the US Environmental Protection Agency, as well as recycling of 99.97% of Pb ions by forming lead iodide.
We develop an effective strategy to obtain polymer solar cells with high power conversion efficiency (17%) and remarkable mechanical robustness, by design of polymer donors with aliphatic flexible spacer incorporated into a rigid backbone.
Design, and development of solar wind spectrometer for Apollo lunar surface experiment package
Research and development on silicon solar cell with improved efficiency
The design and development of two solar radiation simulators with an intensity variation ranging from 0.01 to greater than 100 solar constants under vacuum conditions are discussed. The characteristics of the simulators are presented in terms of spectral content, beam uniformity, and stability. Preliminary thermal radiative property data obtained at high temperatures are reported. The general operating characteristics of the simulator are automatic starting, control of both positive and negative electrodes, and uninterrupted operation for periods in excess of 24 hours.
The developments in space solar power technology are reviewed, with the emphasis on solar power output improvement as the goal of further efforts. It is contended that the biggest pay-off should be expected not from cost cutting in solar cell fabrication but from versatile improvement of solar cell designs to a feasible maximum.
The development and application of a variable composition solar cell computer analysis program is discussed. The basic device equations are derived and results of the computer analysis of several Al(x)Ga(1-x)As and GaAs(1-x)P(x) solar cell structures are presented along with a discussion of the effects of interface states and various composition and doping profiles on maximum solar cell efficiency. Interface states are found to be responsible for a severe reduction in the efficiency of GaAs(1-x)P(x) cells, but do not significantly affect the behavior of Al(x)Ga(1-x)As cells. The depth of the p-n junction below the wide bandgap window layer is a critical factor in determining the loss of minority carriers to interface recombination at the heterojunction.
The development and application of a graded bandgap solar cell computer analysis program is discussed. The basic device equations as used in the computer analysis are discussed and the techniques used to model material parameter variations are described. Finally, the results of the computer analysis of several Al(x)Ga(1-x)As and GaAs(1-x)P(x) solar cell structures are presented along with a discussion of the effects of interface states and various composition profiles on maximum solar cell efficiency.
Significant new developments in InP solar cell research are reviewed. Recent accomplishments include monolithic multibandgap two junction cells (three and two terminal) using InP as the top cell and lattice matched GaInAs and GaInAsP as the bottom, low bandgap component. Concentrator cells include the three terminal multibandgap cell and n + p cell using an InP substrate. The review also includes small scale production of ITO/InP cells and results for n + p InP and ITO/InP cells in space on board the LIPS 3 satellite.
The compact soft X-ray/EUV/FUV multilayer coated telescopes developed for solar chromosphere, corona, and corona/solar-wind interface studies permit the use of conventional (Cassegrain, Herschelian, etc.) configurations. The multilayer coatings also allow a narrow-wavelength band to be selected for imaging. NASA's Multi-Spectral Solar Telescope Array is composed of 17 of these compact telescopes; attention is given to their ability to obtain temperature-diagnostic information concerning the solar plasma.
Significant new developments in InP solar cell research are reviewed. Recent accomplishments include monolithic multibandgap two junction cells (three and two terminal) using InP as the top cell and lattice matched GaInAs and GaInAsP as the bottom, low bandgap, component. Concentrator cells include the three terminal multibandgap cell and an n + p cell using an InP substrate. The review also includes small scale production of ITO/InP cells and results for n+p InP and ITO/InP cells in space on board the LIPS 3 satellite.
The NASA Marshall Space Flight Center (MSFC) developed the Solar Cruiser mission concept to mature solar sail technology for use in future Heliophysics missions, as well as missions of interest across a broad user community (e.g., space weather and Earth polar observatories). Solar Cruiser will serve as a pathfinder for missions that observe the solar environment from unique vantage points such as a high inclination solar mission opening a fundamentally new range of observational capabilities for the Heliophysics Program and for space weather monitoring. Sustained observations away from the Sun-Earth line (SEL) present unique opportunities for answering the outstanding science questions of Heliophysics, improving space-weather monitoring and prediction, and revealing new information about our Sun and solar system. Propellantless solar sails can be used to create artificial equilibria and maintain indefinite station-keeping at locations sunward of L1 along the SEL, or at any desired offset from the SEL leading or trailing the Earth in its orbit. They can change the heliocentric inclination of a spacecraft from the ecliptic to as high as solar polar, stopping and remaining at any intermediate inclination orbit in between. Sails can be used to hover over the Earth’s poles, using solar photon pressure to offset the Earth’s gravitational attraction, creating functional equivalents of geostationary earth orbits. The Solar Cruiser mission would fly a small spacecraft with a large (>1,600 square meter) solar sail containing embedded reflectivity control devices (RCDs) and photovoltaic cells. The mission concept includes successful deployment of the solar sail, validation of all sail subsystems, controlled station-keeping inside of the Sun-Earth L1 point, attitude control of the sail with the RCDs (including spinning and de-spinning), demonstration of pointing performance for science imaging, and an increase in heliocentric inclination (out of the ecliptic). To demonstrate the requisite sail technology, the Solar Cruiser project will design, fabricate, deploy, and fly the Solar Sail Propulsion Element (SSPE). The SSPE incorporates the following three systems: • The Solar Sail System (SSS) provides the large propulsive surface required for acceleration and smaller reflectivity-changing surfaces for roll control. • The Active Mass Translator System (AMT) provides SSPE motion with respect to the sailcraft bus for pitch and yaw control. • The Solar Sail Attitude Determination and Control System (SSADCS) consists of embedded software to 1) provide autonomous sailcraft attitude estimation, attitude pointing control, and reaction wheel momentum management following sail deployment and 2) execute the uplinked inertial attitude pointing commands to maintain the desired sailcraft trajectory. The plans for maturing each of these technology systems to TRL 5 and beyond are described herein.