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At least 631 records · Page 35

Distorted reflector antenna performance prediction technique

The application of a 3-D curve-fit technique to the electromagnetic analysis of reflector antennas is presented. the reflector antennas are described by the coordinates of an irregular distribution of measured points on the reflector surface. The reflector antenna analysis method used to calculate radiation patterns is geometric-optics with aperture-integration since an efficient and accurate computer code was readily available for modification.

Bailey, M. C.↗

Size and Stoichiometry Effects on the Reactivity of MoCy Nanoparticles Towards Ethylene

Molybdenum carbides are promising catalysts alternative to Pt-group metals for the hydrogenation of unsaturated hydrocarbons. Nanostructuring has been shown to be an efficient way to boost the catalytic activity of these materials with MoCy nanoparticles (NPs) exhibiting a good performance when encapsulated inside zeolites or dispersed on inert supports such as carbon or gold. In this work, we focus on a systematic DFT study of the interaction of MoCy NPs with ethylene (C 2 H 4 ), as a general and simple approach for examining binding and activation of C≡C bonds. Models for 14 NPs, with a Mo/C ratio in the 0.67 to 2.00 range, have been built following a cascade procedure. Several chemical descriptors, including the adsorption energy, structural NPs distortion, C≡C deformation, and C 2 H 4 attachment energy have been analyzed along with a meticulous geometric and electronic characterization of bare NPs and C2H4 binding. The present results show that 1:1 stoichiometric Mo 6 C 6 , Mo 12 C 12 , and Mo 24 C 24 , and the non-stochiometric Mo 4 C 6 , Mo 8 C 12 (MetCar), and Mo 14 C 13 (Nanocube) are excellent systems for the binding and activation of ethylene, exhibiting a much bigger reactivity than a bulk δ-MoC(001) surface with a similar Mo:C ratio. In addition, C 2 H 4 binding on the NPs with a Mo/C < 1.08 is advantageous since, apart from a rather large adsorption energy, implies low energy values for NPs deformation (from 0.00 to 0.31 eV), C≡C distortion (from 0.30 to 0.52 eV), and C 2 H 4 attachment (from -2.12 to -2.58 eV). These theoretical results point to the ideal MoCy size and composition for C 2 H 4 binding, providing a background for further experimental studies aimed at the preparation of MoCy NPs as hydrogenation catalysts.

36 MATERIALS SCIENCE↗

Surface enrichment dictates block copolymer orientation

Orientation of block copolymer (BCP) morphology in thin films is critical to applications as nanostructured coatings. Despite being well-studied, the ability to control BCP orientation across all possible block constituents remains challenging. Here, in this study, we deploy coarse-grained molecular dynamics simulations to study diblock copolymer ordering in thin films, focusing on chain makeup, substrate surface energy, and surface tension disparity between the two constituent blocks. We explore the multi-dimensional parameter space of ordering using a machine-learning approach, where an autonomous loop using a Gaussian process (GP) control algorithm iteratively selects high-value simulations to compute. The GP kernel was engineered to capture known symmetries. The trained GP model serves as both a complete map of system response, and a robust means of extracting material knowledge. We demonstrate that the vertical orientation of BCP phases depends on several counter-balancing energetic contributions, including entropic and enthalpic material enrichment at interfaces, distortion of morphological objects through the film depth, and of course interfacial energies. BCP lamellae are found more resistant to these effects, and thus more robustly form vertical orientations across a broad range of conditions; while BCP cylinders are found to be highly sensitive to surface tension disparity.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Starspots as the cause of the intrinsic light variations in RS Canum Venaticorum type stars

A starspot model is proposed to interpret the light curves of three RS CVn type binary systems. Two of the systems are RS CVn and SZ Psc, which are detached, while the third system, RT Lac, is semidetached. Solar activity and the surface activity of the RS CVn type stars are compared. It is found that the spot model permits the detailed fitting of both the out-of-eclipse complications and the distorted shapes of the secondary eclipses in the light curves of these stars.

Eaton, J. A.↗

Incidence angle effects on convected gust airfoil noise

An analysis is developed which predicts the influence of airfoil mean loading on noise generation due to convected gusts. The theory is based on a linearization of the exact inviscid equations about a nonuniform compressible mean flow and the solution is developed using singular perturbation techniques. The case of a flat plate airfoil, at incidence angle alpha, interacting with three-dimensional disturbances is analyzed. It is found that in the vicinity of the airfoil leading and trailing edges, local regions are present which scale on the disturbance wavelength, with the noise generation concentrated in these regions. Away from the airfoil edges, the mean flow variation is found to be slow compared to the disturbance wavelength and no significant noise generation occurs. The mean flow variation near the leading edge generates additional noise by distorting the convected gust. The cumulative effect of the airfoil mean loading in the trailing edge region produces a 0(1) phase shift between the disturbances on the upper and lower surfaces of the airfoil. A corresponding 0(1) decrease, compared to the alpha = 0 case, is found in the noise generated at the trailing edge.

Kerschen, E. J.↗

An analysis of curvature effects for the control of wall-bounded shear flows

The Reynolds stress transport equations are used to predict the effects of simultaneous and sequential combinations of distortions on turbulent boundary layers. The equations are written in general orthogonal curvilinear coordinates, with the curvature terms expressed in terms of the principal radii of curvature of the respective coordinate surfaces. Results are obtained for the cases of two-dimensional and three-dimensional flows in the limit where production and pressure-strain redistribution dominate over diffusion effects.

Gatski, T. B.↗

Multicolor surface photometry of powerful radio galaxies. I - Observations and data reduction

The first of a series of papers which explore the optical morphology, photometric properties, and colors of powerful radio galaxies is presented. This paper reports the observations and data reduction process. The surface photometry techniques used in the analysis are described and the calibration of the results is given. The resulting images reveal that a significant fraction of powerful radio galaxies are morphologically distorted and that many of these galaxies have unusual colors. Results for individual objects are discussed.

Smith, Eric P.↗

Attitude stability of LDEF: Refinement of results from the silver pinhole camera

A measurement was previously described of the angular offset and attitude stability of the LDEF spacecraft using a simple pinhole camera device in the UAH experiment A0114. This device uses a silver surface to record the impact zone of atmospheric atomic oxygen passing through a small pinhole on the front surface of the satellite. The shape and size of this zone are well defined if the satellite velocity and gas temperature are known. The circular symmetry of the zone would be distorted by oscillation of the LDEF about its stable attitude, or by the effect of the co-rotation of the Earth's atmosphere for cases of satellites in nonequatorial orbits. The observed ellipticity of 1.05 with the major axis in the yaw direction is equivalent to an oscillation of + or - 0.2 deg about the stable attitude. The uncertainty in that measurement was estimated at about 0.1 deg. A refined analysis based on summing distributions of flux versus incidence angle for a large number of orbital positions, and including a co-rotating atmosphere, indicates that the combined distributions produce a result consistent with the measured exposed spot. It is suggested that, within the precision of the measurements, no actual oscillation of the LDEF is required to produce the results. Thus, the LDEF may have maintained a stable attitude to better than 0.1 deg, even under conditions of maximum aerodynamic perturbation when the silver oxygen record was made. This error is some two orders of magnitude lower than the predicted uncertainty in yaw oscillation and may indicate that the predict methodologies are too conservative.

Peters, P. N.↗

Modeling and Prediction of the Noise from Non-Axisymmetric Jets

The new source model was combined with the original sound propagation model developed for rectangular jets to produce a new version of the rectangular jet noise prediction code. This code was validated using a set of rectangular nozzles whose geometries were specified by NASA. Nozzles of aspect ratios two, four and eight were studied at jet exit Mach numbers of 0.5, 0.7 and 0.9, for a total of nine cases. Reynolds-averaged Navier-Stokes solutions for these jets were provided to the contactor for use as input to the code. Quantitative comparisons of the predicted azimuthal and polar directivity of the acoustic spectrum were made with experimental data provided by NASA. The results of these comparisons, along with a documentation of the propagation and source models, were reported in a journal article publication (Ref. 4). The complete set of computer codes and computational modules that make up the prediction scheme, along with a user's guide describing their use and example test cases, was provided to NASA as a deliverable of this task. The use of conformal mapping, along with simplified modeling of the mean flow field, for noise propagation modeling was explored for other nozzle geometries, to support the task milestone of developing methods which are applicable to other geometries and flow conditions of interest to NASA. A model to represent twin round jets using this approach was formulated and implemented. A general approach to solving the equations governing sound propagation in a locally parallel nonaxisymmetric jet was developed and implemented, in aid of the tasks and milestones charged with selecting more exact numerical methods for modeling sound propagation, and developing methods that have application to other nozzle geometries. The method is based on expansion of both the mean-flowdependent coefficients in the governing equation and the Green's function in series of orthogonal functions. The method was coded and tested on two analytically prescribed mean flows which were meant to represent noise reduction concepts being considered by NASA. Testing (Ref. 5) showed that the method was feasible for the types of mean flows of interest in jet noise applications. Subsequently, this method was further developed to allow use of mean flow profiles obtained from a Reynolds-averaged Navier-Stokes (RANS) solution of the flow. Preliminary testing of the generalized code was among the last tasks completed under this contract. The stringent noise-reduction goals of NASA's Fundamental Aeronautics Program suggest that, in addition to potentially complex exhaust nozzle geometries, next generation aircraft will also involve tighter integration of the engine with the airframe. Therefore, noise generated and propagated by jet flows in the vicinity of solid surfaces is expected to be quite significant, and reduced-order noise prediction tools will be needed that can deal with such geometries. One important source of noise is that generated by the interaction of a turbulent jet with the edge of a solid surface (edge noise). Such noise is generated, for example, by the passing of the engine exhaust over a shielding surface, such as a wing. Work under this task supported an effort to develop a RANS-based prediction code for edge noise based on an extension of the classical Rapid Distortion Theory (RDT) to transversely sheared base flows (Refs. 6 and 7). The RDT-based theoretical analysis was applied to the generic problem of a turbulent jet interacting with the trailing edge of a flat plate. A code was written to evaluate the formula derived for the spectrum of the noise produced by this interaction and results were compared with data taken at NASA Glenn for a variety of jet/plate configurations and flow conditions (Ref. 8). A longer-term goal of this task was to work toward the development of a high-fidelity model of sound propagation in spatially developing non-axisymmetric jets using direct numerical methods for solving the relevant equations. Working with NASA Glenn Acoustics Branch personnel, numerical methods and boundary conditions appropriate for use in a high-resolution calculation of the full equations governing sound propagation in a steady base flow were identified. Computer codes were then written (by NASA) and tested (by OAI) for an increasingly complex set of flow conditions to validate the methods. The NASA-supplied codes were ported to the High-End Computing resources of the NASA Advanced Supercomputing facility for testing and validation against analytical (where possible) and independent numerical solutions. The cases which were completed during the course of this contract were solutions of the two-dimensional linearized Euler equations with no mean flow, a uniform mean flow and a nonuniform mean flow representative of a parallel flow jet.

Leib, Stewart J.↗

Supertwisted spirals of layered materials enabled by growth on non-Euclidean surfaces

Using curves to make twists The growth of layered materials on flat substrates usually occurs in stacked layers, although defects or a lattice mismatch can induce strains that distort the shape of subsequent layers. However, these effects are usually small and can be uncontrolled. Zhao et al. now demonstrate the possibility of synthesizing multilayers of two-dimensional materials with certain twists between the layers induced by the presence of screw dislocations in combination with curved substrate surfaces. Different twist angles are achieved by varying the amount of nonplanarity and the character (conical or hyperbolic) of the surface. Science , this issue p. 442

Science & Technology - Other Topics↗

Application of distorted models in developing scaled structural models

In the design and development of dynamically similar structural models a distorted model of the panel is used. The panel thickness is made larger than that dictated by geometric scaling, and the mass of the panel is decreased by adding mass to the surface of the panel to counteract the additional stiffness obtained by the thickness increase.

White, R. W.↗

The rotationally modulated Zeeman spectrum at nearly 10 to the 9th Gauss of the white dwarf PG 1031 + 234

Detailed analyses are performed of high-quality, phase-resolved CCD spectroscopy of the absorption-line spectrum throughout its rotation period of the new white dwarf PG 1031 + 234. The spectral variations are discussed and compared with new theoretical calculations of the behavior of hydrogen in strong magnetic fields. This analysis is then extended through a modeling procedure which produces a synthetic magnetically distorted spectrum for a star of arbitrary field strength and structure. The results confirm that PG 1031 + 234 possesses the strongest field yet detected on a white dwarf, with regions on the surface spanning the range of about 200 to nearly 1000 MG. The spectroscopic data reflect a field pattern containing a slightly offset global component of polar field strength of about 500 MG together with a localized magnetic 'spot' whose central field approaches 2000 MG.

Latter, William B.↗

High performance zinc anode for battery applications

An improved zinc anode for use in a high density rechargeable alkaline battery is disclosed. A process for making the zinc electrode comprises electrolytic loading of the zinc active material from a slightly acidic zinc nitrate solution into a substrate of nickel, copper or silver. The substrate comprises a sintered plaque having very fine pores, a high surface area, and 80-85 percent total initial porosity. The residual porosity after zinc loading is approximately 25-30%. The electrode of the present invention exhibits reduced zinc mobility, shape change and distortion, and demonstrates reduced dendrite buildup cycling of the battery. The disclosed battery is useful for applications requiring high energy density and multiple charge capability.

Casey, John E., Jr.↗

Electronic surface reconstruction of TiO 2 nanocrystals revealed by resonant inelastic x-ray scattering

The identification of lattice multiphases in TiO 2 nanocrystals is studied by high resolution transmission electron microscope and electron diffraction patterns. Based on the spectroscopic analysis using soft x-ray absorption and resonant inelastic soft x-ray scattering, it is believed that the oxygen vacancies at the interface exhibit structural distortion of the TiO$^{8-}_6$ cluster around the defect site as for the multiphase lattice. We elucidate that the extra 3d electrons nearby induce the inelastic scattering features with the excitation energy dependence owing to different energy relaxation processes, a characteristic of the electron-phonon coupling or the nature of the electron-hole pair at the intermediate state. The manifold dd excitations driven by the strong interaction between Ti-3d and O-2p electrons are noticeably rich, coexisting on both Ti and O sites. Finally, this sophisticated experiment can advance the perspective of nanocomposite TiO 2 for various interactions of surface Ti 3+ in applications of future devices.

36 MATERIALS SCIENCE↗

Progress of Coating Stress Compensation of Silicon Mirrors for Lynx X-ray Telescope Mission Concept Using Thermal Oxide Patterning Method

A thermal oxide patterning method has proven to be effective for correcting coating-stress-induced distortion on flat silicon wafers. We report progress on developing this method for correcting curved silicon mirrors distorted by front-side iridium coatings. Owing to the difference in geometry, a finite element model has been established to calculate the appropriate duty cycle maps in thermal oxide hexagon patterns used for compensation. In addition, a photolithographic process, along with three-dimensional printed equipment, has been developed for creating patterns precisely on the back side of curved mirrors. The developed method has been used to recover the original surface shape of two silicon mirrors which are 100-mm long, 0.5-mm thick, having 312-mm radius of curvature, and 30 deg in azimuthal span (Wolter-I geometry). These mirrors’ front sides are sputter-coated by 20-nm iridium layers with ∼-70 N∕m integrated stress. Measurement results show that the developed method can mitigate coating-induced distortion by a factor of ∼5 in RMS height and ∼4 in RMS slope error, corresponding to ∼0.5 arc sec RMS slope error. Residual errors after correction are dominated by midfrequency ripples created during the annealing process, which will be resolved in the future. The presented method is precise and inexpensive and a potential candidate for resolving the coating stress issue for Lynx optics in the future.

x-ray↗

Circuit enhances vertical resolution in raster scanning systems

Circuit enhances vertical resolution in electron beam, raster scanning systems exhibiting aperture distortion in the vertical direction. A sensitized area /image/ produces a video output when the scan beam nears it, which causes vertical elongation in the reconstructed images of all sensitized areas on the surface.

Alsovsky, W. H.↗

Summary of flight performance of the Skylab Earth Resources Experiment Package /EREP/

A group of six remote sensor systems (sensing visible, infrared, and microwave radiation) known as the Earth Resources Experiment Package (EREP) was flown on the NASA Skylab spacecraft to furnish data to numerous investigators in the earth sciences and in technology assessment. Inflight sensor performance in three categories (functional, geometric, and radiometric) was evaluated using: (1) ground measurements of surface, atmospheric, and illumination parameters; (2) ground deployment and operation of microwave receivers and transponders to monitor and excite the active EREP sensors; (3) measurement of surface and atmospheric parameters by instrumented aircraft on underflights of Skylab passes; and (4) analysis of the actual flight data. This resulted in identification and correction of anomalous sensor operation, quantization of geometric distortions or aberrations, improvement or confirmation of calibrations, and determination of sensitivity, accuracy, and stability of the sensors.

Potter, A. E.↗

Wave phenomena in a high Reynolds number compressible boundary layer

Growth of unstable disturbances in a high Reynolds number compressible boundary layer is numerically simulated. Localized periodic surface heating and cooling as a means of active control of these disturbances is studied. It is shown that compressibility in itself stabilizes the flow but at a lower Mach number, significant nonlinear distortions are produced. Phase cancellation is shown to be an effective mechanism for active boundary layer control.

Bayliss, A.↗