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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 631 records · Page 35

Stormwater Pollution Prevention Plan for the TA-03-22 Power and Steam Plant, Los Alamos National Laboratory, Revision 3 Final, January 2018

The TA-03-22 Power and Steam Plant (PSP) is part of LANL’s Utilities and Institutional (UI) Facilities Operations Directorate (FOD) with day-to-day management provided by UI facility and operations personnel; which has established a Stormwater Pollution Prevention Team (PPT) whose members are responsible for assisting the facility manager in developing and revising the facility’s SWPPP as well as maintaining control measures and taking corrective actions when required. All PPT members will have access to either a hard copy or an electronic version of this SWPPP.

54 ENVIRONMENTAL SCIENCES↗

Steam Oxidation, Burst and Critical Heat Flux Testing of FeCrAl Cladding in the Severe Accident Test Station

Since August 2011, Oak Ridge National Laboratory (ORNL) has been evaluating the steam oxidation resistance of a wide range of materials to identify a potential accident tolerant fuel (ATF) cladding [1-14]. The primary goal of an ATF cladding is to enhance safety margins in light water reactors (LWR) during beyond design basis accident scenarios (such as the nuclear accident at Fukushima Daiichi in March 2011) without requiring changes to the reactor design or fuel enrichment, or significantly affecting reactor economics during normal operation.

36 MATERIALS SCIENCE↗

Tensile Strength and Steam Oxidation Resistance of ODS FeCrAl Sheet and Tubes

ORNL is developing advanced low-Cr oxide dispersion strengthened (ODS) FeCrAlY alloys for accident tolerant fuel cladding, and this report describes the fabrication and characterization of a new ODS FeCrAlYZr (CrAZY) tube. This CrAZY tube was produced by successive steps of pilgering and annealing, in collaboration with a Japanese tube manufacturer. Very fine, elongated sub-grain structure in the as-received tube was consistent with the fine sub-grain structure observed for CrAZY foils fabricated by cold rolling at ORNL and led to very high tensile strength at room temperature. The elongated grain structure along the pilgering direction resulted in lower ductility in the hoop direction compared to the ductility along the tube. Similar anisotropic tensile behavior was also observed for the CrAZY foil with very limited ductility perpendicular to the rolling direction. The foil and tube were heat treated in the 850- 1100ºC range to reduce the residual stress. Recrystallization was observed at temperature as low as 900ºC, with an increasing number of recrystallized grains with increasing temperature. Exposure for 1h at 900ºC resulted in a significant improvement of the foil and tube, with a moderate decrease of strength. Atom probe tomographic analysis revealed the presence of many nano oxide precipitates but also areas with fewer precipitates due to the relatively high extrusion temperature (1100ºC). Finally, the CrAZY tube showed good oxidation resistance in steam at temperature up to 1400ºC.

36 MATERIALS SCIENCE↗

ICME for Creep of Ni-Base Superalloys in Advanced Ultra-Supercritical Steam Turbines

The goal of this project contains three major aspects: (1) critical assessment of existing experimental data, (2) critical assessment of existing modeling capabilities and (3) development of new modeling capabilities that are critical but currently missing in predicting long-term creep behavior of Ni-base superalloys used in advanced ultra- supercritical (A-USC) steam turbines for coal-fired power plants. The project uses advanced materials informatics to datamine the experimental data, uncertainty quantification tools to rigorously assess existing creep-life models, and integration of phase-field and FFT-based crystal plasticity to develop a multi-scale, physics-based, microstructure-sensitive creep model.

20 FOSSIL-FUELED POWER PLANTS↗

High Temperature Steam Electrolysis Process Performance and Cost Estimates

Technology readiness levels (TRLs) of electrolysis systems have dramatically increased in recent years as the interest in clean hydrogen production and decarbonization of transportation, industrial and other sectors increases across the globe. This is especially true of high temperature steam electrolysis (HTSE) / solid oxide electrolysis cell (SOEC) systems which show promise of much higher system efficiencies than other more developed electrolysis technologies. This possibility of higher efficiencies of HTSE / SOEC systems has been previously assumed to be theoretically possible but in recent years it has become less theoretical and more realistic as an increasing amount of suppliers complete lab and pilot tests showing very promising results. Research in the areas of manufacturing techniques, material selection, electrode and electrolyte compositions, and balance of plant size and integration continues at a fast pace as an increasing number of suppliers both internationally and domestically become involved. The advantages of HTSE become more pronounced when HTSE is coupled with nuclear power plants (NPPs). This is because thermal energy produced by the nuclear reactor can be used in a series of heat transfer loops and heat exchangers to vaporize HTSE feedwater, which drastically improves the economics of the process. Idaho National Laboratory (INL) has been very involved in the research and modeling of HTSE systems for a number of years, in collaboration with other national laboratories, academia, and industry stakeholders both on the hydrogen production as well as the hydrogen demand side. The modeling completed over the years on a large variety of projects has led to a wealth of knowledge at INL including in the area of the technoeconomic assessment (TEA) of HTSE systems. TEAs include process modeling of the HTSE systems to calculate system energy requirements and equipment sizing, followed by estimation of capital and operating costs to enable calculation of the levelized cost of hydrogen (LCOH). The TEA work performed has produced incremental improvements and tuning of the methods, assumptions, models, and results of the analyses as well as providing some opportunities for validating these results. The purpose of this document is to record the current baseline HTSE analyses led by INL to show the current status of assumptions and costs of these systems. Given the rapid development of this technology, the variety of suppliers entering the space, and the increasing attention government and industry are giving to such systems, this document may be updated on a periodic basis with updated analysis and assumptions. This document compiles various analyses results and approaches completed over a period of years into a single document to be used as a baseline going forward. It represents what the INL HTSE analysis group assumes to be the internal best estimate of the current operation, costs, and landscape of the HTSE industry state of the art capability for current SOEC technology in an Nth-of-a-Kind (NOAK) plant, which in this study is defined as existence of the manufacturing capacity to support previous deployment of N = 100 count of 25 MWe modular HTSE blocks (with modular equipment component cost reductions specified as following a 95% learning curve). That said, This is a public document and as such so no proprietary data was used or included in this report. There may be HTSE suppliers that have performance specifications, and cost estimates, and test data that differ from the analysis presented in this document. This document is meant to be a best conservative estimate of the technology and not an absolute reference.

08 HYDROGEN↗

Engineering Design of a Linde-BASF Advanced Post-Combustion CO 2 Capture Technology at a Linde Steam Methane Reforming H 2 Plant

Linde carried out an initial engineering design study for a Linde-BASF advanced post combustion CO 2 capture technology to be installed at a commercial-scale steam methane reforming (SMR) hydrogen plant located in the US Gulf Coast. This pre-FEED equivalent study included following: (1) basic design, including specific project scope definition and design basis, (2) basic engineering, including development of process flow diagrams and heat & material balances, (3) inside the battery limit (ISBL) equipment and systems specification, (4) balance of plant outside the battery limit (OSBL) equipment and systems specifications, (5) technology maturation plan, (6) hazard and operability (HAZOP) review, (7) environmental, health and safety (EH&S) assessment and environmental permitting analysis, (8) constructability review, (9) ISBL and OSBL EPC cost estimation, and (10) commercial-scale techno-economic analysis including capital expenditures (CAPEX) and operating expenditures (OPEX) and CO 2 capture cost estimates.

08 HYDROGEN↗

Steam Methane Reforming (SMR) operations

Hydrogen production through conventional steam methane reforming. To access the model referenced in the report, please visit https://www.netl.doe.gov/energy-analysis/details?id=bbb35592-8589-4187-be70-f6a2466762b4

08 HYDROGEN↗

Stable Catalysts for Combined Dry and Steam Reforming of Methane and Carbon Dioxide

The specific aim of this project is to develop a comprehensive understanding of cheaper and more stable methane and carbon dioxide reforming catalysts with an optimal introduction of steam to reduce carbon deposits that typically prevent the catalytic systems from transferring to commercial implementation. The work was proposed as a two-year project with the end goal of to show a reliable catalyst system run for at least 400 hours at temperatures less than 800 °C with less than 5% loss of activity of the catalyst and a carbon monoxide to hydrogen product ratio of at least 1:1. The project went for one-year and met the end of year milestone by developing two strategies (use of a cerium co-catalyst and introducing 5% water) that reduced the carbon deposition rates by at least 20% relative to the baseline 10% NiMgAlO methane reforming of CO 2 at < 800 °C in order to shown technical feasibility of the concept.

36 MATERIALS SCIENCE↗

Engineering Study of Svante’s Solid Sorbent Post-Combustion CO 2 Capture Technology at a Linde Steam Methane Reforming H 2 Plant

An initial engineering design study was performed for an advanced post combustion CO 2 capture (PCC) technology to be installed at a commercial-scale steam methane reforming (SMR) hydrogen plant located in the US Gulf Coast. The PCC process integrated the VeloxoTherm™ structured adsorbent technology from Svante for the CO 2 separation and CO 2 compression and purification and balance of plant systems provided by Linde. This pre-FEED equivalent study included following: (1) design basis, (2) basic engineering, including development of process flow diagrams and heat & material balances, (3) inside the battery limit (ISBL) equipment and systems specification, (4) balance of plant outside the battery limit (OSBL) equipment and systems specifications, (5) technology maturation plan, (6) hazard identification (HAZID) review, (7) environmental, health and safety (EH&S) assessment and environmental permitting analysis, (8) constructability review, (9) ISBL and OSBL EPC cost estimation, and (10) commercial-scale techno-economic analysis including capital expenditures (CAPEX) and operating expenditures (OPEX) and CO 2 capture cost estimates.

03 NATURAL GAS↗

Carbon Capture on Air Liquide United States Gulf Coast Steam Methane Reformer using the Cryocap TM Flue Gases Process

The objective of this DOE-funded project is to execute and complete a Front-End Engineering and Design (FEED) study for a commercial-scale carbon capture project for Air Liquide’s Steam Methane Reformer (SMR) located at La Porte, near Houston, Texas. The Host Site is one of Air Liquide’s largest SMR assets, and supplies hydrogen to the Air Liquide Gulf Coast Hydrogen System, which serves refiners and petrochemical manufacturers through an existing H2 pipeline spanning roughly 200 miles from Port Arthur, TX to Bay City, TX. The Host Site produces up to 116.5 million standard cubic feet per day (MMSCFD) of gaseous hydrogen and emits approximately 950 ktpy CO 2 at the nameplate capacity. The evolving importance of decarbonized H2 for both existing customers and new markets, as well as the availability and intent of prominent third-party partners to transport and sequester captured CO 2 in locally abundant geological sites for 45Q credits, make the AL US Gulf Coast SMR an ideal site for the proposed FEED study. The envisioned carbon capture system is based on Air Liquide’s proprietary Cryocap™ Flue Gas (FG) process. The integration of the Cryocap™ FG technology to the existing SMR would enable the capture of 900 ktpy of CO 2 , with a net carbon capture rate of >95% and with minimum impact on the levelized cost of hydrogen produced at 99.97% purity.

03 NATURAL GAS↗

Role of Tartaric Acid in Chemical, Mechanical and Self-Healing Behaviors of a Calcium-Aluminate Cement Blend with Fly Ash F under Steam and Alkali Carbonate Environments at 270 °C

Tartaric acid (TA) changes short-term mechanical behavior and phase composition of sodium-metasilicate activated calcium-aluminate cement blend with fly ash, type F, when used as a set control additive to allow sufficient pumping time for underground well placement. The present work focuses on TA effect on self-healing properties of the blend under steam or alkali carbonate environments at 270 °C applicable to geothermal wells. Compressive strength recoveries and cracks sealing were examined to evaluate self-healing of the cement after repeated crush tests followed by two consecutive healing periods of 10 and 5 days at 270 °C. Optical and scanning electron microscopes, X-ray diffraction, Fourier Transform infrared and EDX measurements along with thermal gravimetric analyses were used to identify phases participating in the healing processes. Samples with 1% mass fraction of TA by weight of blend demonstrated improved strength recoveries and crack plugging properties, especially in alkali carbonate environment. This effect was attributed to silicon-rich (C,N)-A-S-H amorphous phase predominant in TA-modified samples, high-temperature stable zeolite phases along with the formation of tobermorite-type crystals in the presence of tartaric acid.

15 GEOTHERMAL ENERGY↗

Reaction of steam with molybdenum is studied

Comprehensive report studies the reaction of flowing steam with refractory metals /in particular molybdenum/, in the temperature range of 1100 degrees C. The reaction products are hydrogen gas and molybdenum oxide vapor.

Kilpatrick, M.↗