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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 631 records · Page 35
All sourcesNASA NTRSDOE OSTI
NASA NTRS1945

Effect of Maximum Cruise-power Operation at Ultra-lean Mixture and Increased Spark Advance on the Mechanical Condition of Cylinder Components

A continuous 50-hour test was conducted to determine the effect of maximum cruise-power operation at ultra-lean fuel-air mixture and increased spark advance on the mechanical conditions of cylinder components. The test was conducted on a nine-cylinder air-cooled radial engine at the following conditions:brake horsepower, 750; engine speed, 1900 rpm; brake mean effective pressure, 172 pounds per square inch; fuel-air ratio, 0.052; spark advance, 30 deg B.T.C.; and maximum rear-spark-plug-bushing temperature, 400 F. In addition to the data on corrosion and wear, data are presented and briefly discussed on the effect of engine operation at the conditions of this test on economy, knock, preignition, and mixture distribution. Cylinder, piston, and piston-ring wear was small and all cylinder component were in good condition at the conclusion of the 50-hour test except that all exhaust-valve guides were bellmouthed beyond the Army's specified limit and one exhaust-valve face was lightly burned. It is improbable that the light burning in one spot of the valve face would have progressed further because the burn was filled with a hard deposit so that the valve face formed an unbroken seal and the mating seat showed no evidence of burning. The bellmouthing of the exhaust-valve guides is believed to have been a result of the heavy carbon and lead-oxide deposits, which were present on the head end of the guided length of the exhaust-valve stem. Engine operational the conditions of this test was shown to result In a fuel saving of 16.8 percent on a cooled-power basis as compared with operation at the conditions recommended for this engine by the Army Air Forces for the same power.

ENGINE CYLINDERS-WEAR↗
DOE OSTI2014

Systematic prediction of high-pressure melting curves of transition metals

The pressure effects on melting temperatures of transition metals have been studied based on the combination of the modified Lindemann criterion with statistical moment method in quantum statistical mechanics. Numerical calculations have been performed for five transition metals including Cu, Pd, Pt, Ni, and Mn up to pressure 100 GPa. Our results are in good and reasonable agreements with available experimental data. This approach gives us a relatively simple method for qualitatively calculating high-pressure melting temperature. Moreover, it can be used to verify future experimental and theoretical works. This research proposes the potential of the combination of statistical moment method and the modified Lindemann criterion on predicting high-pressure melting of materials.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Magnetic Precursor of the Pressure-Induced Superconductivity in Fe-Ladder Compounds

We studied the pressure effects on the antiferromagentic orders in iron-based ladder compounds CsFe$_2$Se$_3$ and BaFe$_2$S$_3$ using single crytal neutron diffraction technique. With identical crystal structure and similar magnetic structures, the two compounds exhibit highly contrasting magnetic behaviors under moderate external pressures. In CsFe$_2$Se$_3$ the ladders are brought much closer to each other by pressure, but the stripe-type of magnetic order shows no observable change. Furthermore, the stripe order in BaFe$_2$S$_3$, undergoes a quantum phase transition where an abrupt increase of $N\acute{e}el$ temperature by more than 50$\%$ occurs at about 1 GPa, accompanied by a jump in ordered moment. Finally, with its spin structure unchanged, BaFe$_2$S$_3$ enters an enhanced magnetic phase that bears the characteristics of an orbital selective Mott phase, which is the true herald for superconductivity emerging at higher pressures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Unraveling Emergent Quantum States in Magnetic Topological Insulators using High Pressure Neutron Scattering

This proposal aims to uncover novel quantum phenomena under high pressure and understand the pressure effects on the atomic electronic interactions in magnetic topological materials. This program supports a combined neutron scattering and materials discovery of novel magnetic materials that display the coexistence of magnetism plus other physical phenomena such as a non-trivial electronic band topology under high pressure. The goal of this project is to close a long-standing knowledge gap in quantum materials research by developing a high-pressure neutron scattering (HP-NS) toolbox to systematically determine the magnetic structures and electronic interactions present at high pressure.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2018

Modeling The Effects of Shock Pressure and Pore Morphology on Hot Spot Mechanisms in HMX

Here, we investigate the effects of shock pressure and pore morphology on the formation and growth of hot spots in HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine). Both non-reactive and reactive ALE3D simulations are used in these studies. Our non-reactive simulations show a viscous-dominated pore collapse mode at lower shock pressures (2–10 GPa) with shear band formation and a hydrodynamic-dominated mode at higher shock pressures (20-40 GPa) due to bulk melting. When normalized by bulk shock heating, viscous-dominated pore collapse modes are more efficient at generating hot spots. Pore morphology influences the post-collapse temperature distributions and reaction rate for a fixed pore area and shock pressure. We find that multiple surface pores at the binder-grain interface tend to react the fastest. Due to their upstream location in the HMX grain, the surface pores collapse sooner than interior pores; thus, the extent of reaction will generally favor these morphologies because they have more time to grow. In general, multiple smaller hot spots tend to react faster than a single larger hot spot because they accelerate one another's burning. The rank order of morphology effects, however, is not the same for non-reactive and reactive simulations. For example, while multiple surface pores produce the highest reaction rates they do not produce the highest (non-reactive) hot spot temperatures. In conclusion, our numerical studies provide insights on hot spot mechanisms in lieu of direct measurements and can be used to develop advanced shock initiation models.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

The Effect of Spark-Plug Heat Dispersal Range and Exhaust Valve Opening Timing on Cold-Start Emissions and Cycle-to-Cycle Variability

The partnership for advancing combustion engines (PACE) is a US Department of Energy consortium involving multiple national laboratories and includes a goal of addressing key efficiency and emission barriers in light-duty engines fueled with a market-representative E10 gasoline. A major pillar of the initiative is the generation of detailed experimental data and modeling capabilities to understand and predict cold-start behavior. Cold-start, as defined by the time between first engine crank and three-way catalyst light-off, is responsible for a large percentage of NOx, unburned hydrocarbon and particulate matter emissions in light-duty engines. Minimizing emissions during cold-start is a trade-off between achieving faster light-off of the three-way catalyst and engine out emissions during that period. In this study, gaseous and soot emissions were measured at a distance representative of the three-way catalyst position downstream of the engine at a 2 bar net indicated mean effective pressure (NIMEP) steady-state operating condition representative of cold-start. The test matrix included sweeps of ignition timing 15 degrees-before to 10 degrees-after top dead center firing (TDCf) across three different spark-plug heat dispersal ranges (HR). Additionally, the effect of varying exhaust valve opening (EVO) timing on combustion stability and emissions was also studied. Results show that the spark plug HR affects the coefficient of variation (COV) of NIMEP under all cold-start conditions, while the impact on emissions was found to be minimal. At very retarded spark timings, colder spark plugs required higher air and fuel flow to maintain the desired 2bar NIMEP load, but the fraction of fuel energy going into the exhaust was found to be similar for all spark plugs. Finally, retarding exhaust valve timings showed a simultaneous reduction in emissions while increasing the fraction of fuel energy being fed into the exhaust. However, engine COV was also observed to increase with retarded exhaust timings.

42 ENGINEERING↗
DOE OSTI2018

Effect of Wear on Surface Crack Propagation in Rail–Wheel Wet Contact

The interaction between wear and rolling contact fatigue in wet contact was investigated by means of experiments on a two-disk test bench. Specimens of various railway wheel steels were coupled with specimens of the same rail steel, subjected to rolling and sliding wet contact with varying sliding/rolling ratio. Some tests with a dry rolling–sliding contact phase preceding wet contact were carried out as well (dry–wet tests). The pressurization of the fluid entrapped in the surface cracks was the cause of a rapid and severe damage in the dry–wet tests, due to the nucleation of surface cracks by ratcheting in the dry phase, which subsequently propagate in the wet phase. In the wet tests, the fluid pressurization effect was much mitigated due to the absence of initial surface cracks; the specimens subjected to higher sliding/rolling ratio showed the best performance against rolling contact fatigue, due to the effect of wear in reducing the length of surface cracks. A model for assessing the interaction between wear and rolling contact fatigue was proposed, based on the correction of the classical Paris law for crack propagation by taking into account the effect of wear on crack length reduction. The application of the model to the experimental tests allowed finding a correlation between the model predictions and the occurrence of fatigue failure.

36 MATERIALS SCIENCE↗
NASA NTRS1995

Unusual locations of Earth's bow shock on September 24 - 25, 1987: Mach number effects

International Sun Earth Explorer 1 (ISEE 1) and Interplanetary Monitoring Platform 8 (IMP 8) data are used to identify 19 crossings of Earth's bow shock during a 30-hour period following 0000 UT on September 24, 1987. Apparent standoff distances for the shock are calculated for each crossing using two methods and the spacecraft location; one method assumes the average shock shape, while the other assumes a ram pressure-dependent shock shape. The shock's apparent standoff distance, normally approximately 14 R(sub E), is shown to increase from near 10 R(sub E) initially to near 19 R(sub E) during an 8-hour period, followed by an excursion to near 35 R(sub E) (where two IMP 8 shock crossings occur) and an eventual return to values smaller than 19 R(sub E). The Alfven M(sub A) and fast magnetosonic M(sub ms). Mach numbers remain above 2 and the number density above 4/cu cm for almost the entire period. Ram pressure effects produce the initial near-Earth shock location, whereas expansions and contractions of the bow shock due to low Mach number effects account, qualitatively and semiquantitatively, for the timing and existence of almost all the remaining ISEE crossings and both IMP 8 crossings. Significant quantitative differences exist between the apparent standoff distances for the shock crossings and those predicted using the observed plasma parameters and the standard model based on Spreiter et al.'s (1966) gasdynamic equation. These differences can be explained in terms of either a different dependence of the standoff distance on Mach number at low M(sub A) and M(sub ms), or variations in shock shape with M(sub A) and M(sub ms) (becoming increasingly "puffed up" with decreasing M(sub A) and M(sub ms), as expected theoretically), or by a combination of both effects.

Cairns, Iver H.↗
DOE OSTI2020

Pressure-Induced Dimerization of C 60 at Room Temperature as Revealed by an In Situ Spectroscopy Study Using an Infrared Laser

Using in situ high-pressure Raman spectroscopy and X-ray diffraction, the polymerization and structure evaluation of C 60 were studied up to 16 GPa at room temperature. The use of an 830 nm laser successfully eliminated the photo-polymerization of C 60 , which has interfered with the pressure effect in previous studies when a laser with a shorter wavelength was used as excitation. It was found that face-centered cubic (fcc) structured C 60 transformed into simple cubic (sc) C 60 due to the hint of free rotation for the C 60 at 0.3 GPa. The pressure-induced dimerization of C 60 was found to occur at about 3.2 GPa at room temperature. Our results suggest the benefit and importance of the choice of the infrared laser as the excitation laser.

36 MATERIALS SCIENCE↗
NASA NTRS1973

Rates and mechanisms of the atomic oxygen reaction with nickel at elevated temperatures

The oxidation of nickel by atomic oxygen at pressure from 1 to 45 N/sq m between 1050 and 1250 K was investigated. In these ranges, the oxidation was found to follow the parobolic rate law, viz., K sub p = 0.0000114 exp(-13410/T) g squared/cm4/sec for films of greater than 1 micron thickness and was pressure independent. The activation enthalpy for the oxidation reaction was 112 + or - 11 kj/mole (27 + or - 3 kcal/mole). Of a number of possible mechanisms and defect structures considered, it was shown that the most likely was a saturated surface defect model for atomic oxidation, based on reaction activation enthalpies, impurity effects, pressure independence, and magnitudes of rates. A model judged somewhat less likely was one having doubly ionized cationic defects rate controlling in both atomic and molecular oxygen. From comparisons of the appropriate processes, the following enthalpy values were derived: enthalpy of activation (Ni diffusion in Ni0) = 110 + or - 30 kj/mole and standard enthalpy change for reaction formation (doubly ionized cation vacancies in Ni0 from atomic oxygen)= -9 + or - 25 kj/mole.

Christian, J. D.↗
DOE OSTI2024

Evaluation of the Performance and Exhaust Emissions of a 4 Cylinder CI Engine Operating With Dimethyl Ether (DME) and Propane Blends

In response to stringent emissions regulations and the need for higher efficiency engines, the utilization of DME and propane fuel blends in compression ignition (CI) engines has gained interest in the automotive industry. In this study, a range of DME-propane blends are explored in a CI combustion strategy at high injection pressures. A GT-Power model of a 2.2 L Hyundai CI engine was developed to facilitate evaluation of the impacts of variations of DME and propane blends at a light and medium engine speed-torque-load operating condition; specifically at 1500 rpm, 50 Nm and 2.84 bar brake mean effective pressure (BMEP); and 2000 rpm, 150 Nm, 8.53 bar BMEP speed-torque-load combination. Here, the GT-Power model was validated using Computational Fluid Dynamics (CFD) simulations. The results indicate that high diesel-like efficiencies can be achieved with a 100% DME mass substitution and up to 50% propane-DME blends could be implemented without a significant penalty on engine performance indicators. Significant brake specific nitrogen oxides (BSNOx) reductions were also observed along with reductions in carbon dioxide (CO2) and soot when leveraging these fuel blends.

computational fluid dynamics↗
NASA NTRSDate not supplied

TPSAS-NF1676L-30044-DND

The Clouds and the Earth's Radiant Energy System (CERES) project now has over 17 years accurately observed top-of-the-atmosphere (TOA) flux record for climate monitoring and diagnostic studies. The CERES FluxByCldTyp dataset, which contains cloud properties and radiative fluxes for 42 cloud types sorted by cloud top pressure and cloud optical depth, is used to investigate the clouds and their associated TOA (top-of-the-atmosphere) fluxes changes over the tropical area during ENSO events during the observed period. Unlike past studies, this study shows the impact of ENSO on cloud properties like optical depth, cloud top effective pressure and temperature and TOA LW and SW fluxes for each sub cloud type. The study reveals the detailed contributions from different cloud types for radiative characteristics during different regimes of ENSOs. This is especially important for very small net TOA radiative balance due to the cancellation of the fluxes from different cloud types. The dataset serves as a more stringent validation of climate models for cloud properties and radiative fluxes.

Sun, Moguo↗
NASA NTRSDate not supplied

ENSO Tropical Cloud and TOA radiative signatures from the CERES observation

The Clouds and the Earth's Radiant Energy System (CERES) project now has over 15 years accurately observed top-of-the-atmosphere (TOA) flux record for climate monitoring and diagnostic studies. The CERES flux-by-cloud-type dataset, which contains cloud properties and radiative fluxes for 42 cloud types sorted by cloud top pressure and cloud optical depth, is used to investigate the clouds and their associated TOA (top-of-the-atmosphere) fluxes changes over the tropical area during ENSO events during the observed period. Unlike past studies, this study shows the impact of ENSO on cloud properties like optical depth, cloud top effective pressure and temperature and TOA LW and SW fluxes for each sub cloud type. The study reveals the detailed contributions from different cloud types for radiative characteristics during different phases of ENSO. This is especially important for very small net TOA radiative balance due to the cancellation of the fluxes from different cloud types. To further demonstrate the usefulness of this dataset, NCAR Community Atmosphere Model (CAM) is used to simulate the cloud and radiative changes during the period. The model cloud properties are converted to MODIS like cloud properties using modified MODIS simulator. The dataset serves as a more stringent validation of the model for cloud properties and radiative fluxes.

Moguo Sun↗
DOE OSTI2014

Dependence on pressure of the refractive indices of wurtzite ZnO, GaN, and AlN

We have measured both the ordinary and extraordinary refractive index of m-plane cuts of wurtzite ZnO, GaN, and AlN single crystals at room temperature and as a function of hydrostatic pressure up to 8 GPa. For that purpose we have developed an alternative optical interference method, called bisected-beam method, which leads, in general, to high contrast interference fringes. Its main feature, however, is to be particularly suitable for high pressure experiments with the diamond anvil cell, when the refractive index of the sample is low and similar to that of diamond and/or the pressure transmitting medium, as is the case here. For all three wide-gap materials we observe a monotonous decrease of the ordinary and extraordinary refractive indices with increasing pressure, being most pronounced for GaN, less marked for ZnO, and the smallest for AlN. The frequency dependence of the refractive indices was extrapolated to zero energy using a critical-point-plus-Lorentz-oscillator model of the ordinary and extraordinary dielectric function. In this way, we determined the variation with pressure of the electronic part (no-phonon contribution) of the static dielectric constant epsilon(infinity). Its volume derivative, r = d ln epsilon(infinity)/d ln V, serves as single scaling coefficient for comparison with experimental and/or theoretical results for other semiconductors, regarding the pressure effects on the dielectric properties. We have obtained an ordinary/extraordinary average value (r) over bar of 0.49(15) for ZnO, 1.22(9) for GaN, and 0.32(4) for AlN. With the values for the ordinary and extraordinary case being within experimental uncertainty, there is thus no apparent change in dielectric anisotropy under pressure for these wurtzite semiconductors. Results are discussed in terms of the pressure-dependent electronic band structure of the materials.

Goni, AR↗
DOE OSTI2022

Modeling the hydrodynamic impact on the tool influence function during hemispherical subaperture optical polishing

To fabricate high-precision and accurate optics relative to the optical design surface, a high level of deterministic control of material removal (i.e., the tool influence function, TIF) during subaperture tool polishing is required. In this study, a detailed analysis of the pressure distribution, which is a key component of the TIF, has been performed using finite element analysis to couple together solid mechanics and fluid dynamics. Modeling experimental parameters of recently published work reveals that, when considering tool deformation, which in turn influences the fluid film thickness between the tool and workpiece, the effective pressure profile has a flat-top distribution. This flat-top pressure profile differs from the parabolic pressure distributions predicted by Hertzian mechanics. Furthermore, the shear contribution is shown here to be a key contributor to material removal, inducing the removal at the periphery of the contact edge and even outside the generally accepted contact area. Finally, the simulated fluid velocities provide evidence of mixed-mode contact polishing, supporting recent experimental findings that also suggest that onset of hydroplaning contributions lead to material removal drop-off.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Superconductivity and electron-phonon interaction in Sr x Bi 2 Se 3 under pressure

Pressure-induced superconductivity has been widely explored and observed in Bi 2 Se 3 -based topological materials to hunt for topological superconductors. Although their triggered superconductivity has a close connection to their pressure-induced structural phase transitions, the quest for the electron pairing mechanism of these superconducting semiconductors in both their initial rhombohedral and high-pressure phases remains unknown. In this work, we present a systematic study of the pressure effect on superconducting properties and lattice dynamics using a combination of electrical transport, Raman-scattering, and synchrotron x-ray diffraction measurements using diamond anvil cells. One key finding is our observation of a cooperative connection between the strength of the electron–phonon interaction (EPI) generated by optical branches and the pressure-tunable superconductivity in rhombohedral Sr x Bi 2 Se 3 crystal. The underlying suppression mechanism of the T c by pressure is ascribed to the weakening of the electrons' interaction with the optical phonon modes in the rhombohedral phase. In the intermediate monoclinic phase, the T c value underwent a sharp increase with carrier density accumulation accompanying the concurrent enhanced EPI. This is intuitively unusual since it is expected that the EPI shall be weakened by inducing more conducting carriers in a normal metal. In the tetragonal phase, the superconductivity is interpreted within BCS theory, since it is fully metallized and obeys the adiabatic Born–Oppenheimer approximation well. Our findings are important to fully understand unconventional superconductivity and the unusual pairing mechanism in the layered rhombohedral Bi 2 Se 3 -based superconductors.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1923

Performance of Maybach 300-horsepower airplane engine

This report contains the results of a test made upon a Maybach Engine in the altitude chamber of the Bureau of Standards, where controlled conditions of temperature and pressure can be made the same as those of the desired altitude. The results of this test lead to the following conclusions: from the standpoint of thermal efficiency the full-load performance of the engine is excellent at densities corresponding to altitudes up to and including 15,000 feet. The brake mean effective pressure is rather low even at wide-open throttle. This tends to give a high weight per horsepower, in as much as the weight of many engine parts is governed by the size rather than the power of the engine. At part load the thermal efficiency of the engine is low. Judged on a basis of performance the engine's chief claim to interest would appear to lie in the carburetor design, which is largely responsible excellent full-load efficiency and for its poor part-load efficiency.

Sparrow, S W↗
DOE OSTI2018

Effect of Holding Pressure on Microstructure and Mechanical Properties of A356 Aluminum Alloy

In this study, the effect of holding pressure on microstructure and mechanical properties of low-pressure die cast A356 aluminum alloy was investigated. The results showed that the application of high holding pressure (300 kPa) generated castings with denser structure and superior mechanical properties. By increasing the holding pressure up to 300 kPa, the size of secondary dendrite arm spacing greatly reduced by 22.7% at the cooling rate of 1°C/s and decreased by 12.8% at 10°C/s. The Feret’s diameter and aspect ratio of eutectic silicon particles decreased by 8.4 and 5.1% at the cooling rate of 1°C/s and decreased by 9.3 and 6.4% at 10°C/s, respectively. Meanwhile, the density of A356 aluminum alloy increased to 2.678 g/cm{sup 3} and the area fraction of porosity decreased to 0.035%. Thus, tensile properties of A356 aluminum alloy obtained at high holding pressure were enhanced, especially the ductility. All these could be associated with the better filling capability and faster cooling rate caused by high holding pressure. In the analytical range of experimental conditions, the correlation of mechanical properties with process parameters was established by statistical models to predict the ultimate tensile strength and elongation of low-pressure die cast A356 aluminum alloy.

36 MATERIALS SCIENCE↗