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At least 631 records · Page 35

Premixed Atmosphere and Convection Influences on Flame Inhibition and Combustion (Pacific)

Flame spread over flat solid fuel beds is a useful paradigm for studying the behavior of more complex two-phase nonpremixed flames. For practical applications, two of the most important elements of flame spreading are the effects of (1) the ambient atmosphere (e.g. pressure and composition) and (2) the flow environment on the spread rate and extinction conditions. Concerning (1), studies of flame spread in vitiated air and non-standard atmospheres such as those found in undersea vessels and spacecraft are particularly important for the assessment of fire hazards in these environments as well as determination of the effectiveness of fire suppressants. Concerning (2), the flow environment may vary widely even when no forced flow is present because of buoyancy effects. Consequently, the goal of this work is to employ microgravity (micro g) experiments to extend previous studies of the effects of ambient atmosphere and the flow environment on flame spread through the use of microgravity (micro g) experiments. Because of the considerable differences between upward (concurrent-flow) and downward (opposed-flow) flame spread at 1g (Williams, 1976, Fernandez-Pello, 1984), in this work both upward and downward 1g spread are tested. Two types of changes to the oxidizing atmosphere are considered in this work. One is the addition of sub-flammability-limit concentrations of a gaseous fuel ('partially premixed' atmospheres). This is of interest because in fires in enclosures, combustion may occur under poorly ventilated conditions, so that oxygen is partially depleted from the air and is replaced by combustible gases such as fuel vapors, H2 or CO. Subsequent fire spread over the solid fuel could occur under conditions of varying oxygen and gaseous fuel content. The potential significance of flame spread under vitiated or partially premixed conditions has been noted previously (Beyler, 1984). The second change is the diluent type, which affects the radiative properties of the mixture as well as the Lewis number (Le) of the reactants in the atmosphere, which for oxygen is defined as the thermal diffusivity of the bulk mixture divided by the mass diffusivity of oxygen into the bulk mixture. Understanding the effect of diluent type is desirable because in some undersea and spaceborne habitations, it is desirable to use diluent gases other than nitrogen. Prior experiments have shown that both radiation (Bhattacharjee and Altenkirch, 1993) and Lewis number (Zhang et al, 1992) effects are important in flame spreading problems.

Honda, Linton K.↗

Exploration of Anomalous Gravity Effects by rf-Pumped Magnetized High-T(c) Superconducting Oxides

A number of anomalous gravitational effects have been reported in the scientific literature during recent years, but there has been no independent confirmation with regard to any of these claims. Therefore, the NASA Marshall Space Flight Center, in response to the propulsion challenges specified by NASA's Breakthrough Propulsion Physics (BPP) program, proposed to explore the possibility of observing anomalous gravitation behavior through the manipulation of Josephson junction effects in magnetized high-Tc superconducting oxides. The technical goal was to critically test this revolutionary physical claim and provide a rigorous, independent, empirical confirmation (or refutation) of anomalous effects related to the manipulation of gravity by radio frequency (rf)-pumped magnetized type-2 superconductors. Because the current empirical evidence for gravity modification is anecdotal, our objective was to design, construct, and meticulously implement a discriminating experiment, which would put these observations on a more firm footing within the scientific community. Our approach is unique in that we advocate the construction of an extremely sensitive torsion balance with which to measure gravity modification effects by rf-pumped type-2 superconductor test masses. This paper reviews the anecdotal evidence for anomalous gravity effects, describes the design and development of a simplified torsion balance experiment for empirically investigating these claims, and presents the results of preliminary experiments.

Robertson, Tony↗

A comparison of imaging methods for use in an array biosensor

An array biosensor has been developed which uses an actively-cooled, charge-coupled device (CCD) imager. In an effort to save money and space, a complementary metal-oxide semiconductor (CMOS) camera and photodiode were tested as replacements for the cooled CCD imager. Different concentrations of CY5 fluorescent dye in glycerol were imaged using the three different detection systems with the same imaging optics. Signal discrimination above noise was compared for each of the three systems.

Evaluation Studies↗

Effect of Surface Impulsive Thermal Loads on Fatigue Behavior of Constant Volume Propulsion Engine Combustor Materials

The development of advanced high performance constant-volume-combustion-cycle engines (CVCCE) requires robust design of the engine components that are capable of enduring harsh combustion environments under high frequency thermal and mechanical fatigue conditions. In this study, a simulated engine test rig has been established to evaluate thermal fatigue behavior of a candidate engine combustor material, Haynes 188, under superimposed CO2 laser surface impulsive thermal loads (30 to 100 Hz) in conjunction with the mechanical fatigue loads (10 Hz). The mechanical high cycle fatigue (HCF) testing of some laser pre-exposed specimens has also been conducted under a frequency of 100 Hz to determine the laser surface damage effect. The test results have indicated that material surface oxidation and creep-enhanced fatigue is an important mechanism for the surface crack initiation and propagation under the simulated CVCCE engine conditions.

Zhu, Dongming↗

An Improved Retrieval of Tropospheric Nitrogen Dioxide from GOME

We present a retrieval of tropospheric nitrogen dioxide (NO2) columns from the Global Ozone Monitoring Experiment (GOME) satellite instrument that improves in several ways over previous retrievals, especially in the accounting of Rayleigh and cloud scattering. Slant columns, which are directly fitted without low-pass filtering or spectral smoothing, are corrected for an artificial offset likely induced by spectral structure on the diffuser plate of the GOME instrument. The stratospheric column is determined from NO2 columns over the remote Pacific Ocean to minimize contamination from tropospheric NO2. The air mass factor (AMF) used to convert slant columns to vertical columns is calculated from the integral of the relative vertical NO2 distribution from a global 3-D model of tropospheric chemistry driven by assimilated meteorological data (Global Earth Observing System (GEOS)-CHEM), weighted by altitude dependent scattering weights computed with a radiative transfer model (Linearized Discrete Ordinate Radiative Transfer), using local surface albedos determined from GOME observations at NO2 wavelengths. The AMF calculation accounts for cloud scattering using cloud fraction, cloud top pressure, and cloud optical thickness from a cloud retrieval algorithm (GOME Cloud Retrieval Algorithm). Over continental regions with high surface emissions, clouds decrease the AMT by 20- 30% relative to clear sky. GOME is almost twice as sensitive to tropospheric NO2 columns over ocean than over land. Comparison of the retrieved tropospheric NO2 columns for July 1996 with GEOS-CHEM values tests both the retrieval and the nitrogen oxide radical (NOx) emissions inventories used in GEOS-CHEM. Retrieved tropospheric NO2 columns over the United States, where NOx emissions are particularly well known, are within 18% of GEOS-CHEM columns and are strongly spatially correlated (r = 0.78, n = 288, p less than 0.005). Retrieved columns show more NO2 than GEOS-CHEM columns over the Transvaal region of South Africa and industrial regions of the northeast United States and Europe. They are lower over Houston, India, eastern Asia, and the biomass burning region of central Africa, possibly because of biases from absorbing aerosols.

Martin, Randall V.↗

Depth Measurements Using Alpha Particles and Upsettable SRAMs

A custom designed SRAM was used to measure the thickness of integrated circuit over layers and the epi-layer thickness using alpha particles and a test SRAM. The over layer consists of oxide, nitride, metal, and junction regions.

upsettable SRAMs↗

Comparison of Four Strong Acids on the Precipitation Potential of Gypsum in Brines During Distillation of Pretreated, Augmented Urine

Two batches of nominally pretreated and augmented urine were prepared with the baseline pretreatment formulation of sulfuric acid and chromium trioxide. The urine was augmented with inorganic salts and organic compounds in order to simulate a urinary ionic concentrations representing the upper 95 percentile on orbit. Three strong mineral acids: phosphoric, hydrochloric, and nitric acid, were substituted for the sulfuric acid for comparison to the baseline sulfuric acid pretreatment formulation. Three concentrations of oxidizer in the pretreatment formulation were also tested. Pretreated urine was distilled to 85% water recovery to determine the effect of each acid and its conjugate base on the precipitation of minerals during distillation. The brines were analyzed for calcium and sulfate ion, total, volatile, and fixed suspended solids. Test results verified that substitution of phosphoric, hydrochloric, or nitric acids for sulfuric acid would prevent the precipitation of gypsum up to 85% recovery from pretreated urine representing the upper 95 percentile calcium concentration on orbit.

Muirhead, Dean↗

Peregrine 100-km Sounding Rocket Project

The Peregrine Sounding Rocket Program is a joint basic research program of NASA Ames Research Center, NASA Wallops, Stanford University, and the Space Propulsion Group, Inc. (SPG). The goal is to determine the applicability of this technology to a small launch system. The approach is to design, build, and fly a stable, efficient liquefying fuel hybrid rocket vehicle to an altitude of 100 km. The program was kicked off in October of 2006 and has seen considerable progress in the subsequent 18 months. This research group began studying liquifying hybrid rocket fuel technology more than a decade ago. The overall goal of the research was to gain a better understanding of the fundamental physics of the liquid layer entrainment process responsible for the large increase in regression rate observed in these fuels, and to demonstrate the effect of increased regression rate on hybrid rocket motor performance. At the time of this reporting, more than 400 motor tests were conducted with a variety of oxidizers (N2O, GOx, LOx) at ever increasing scales with thrust levels from 5 to over 15,000 pounds (22 N to over 66 kN) in order to move this technology from the laboratory to practical applications. The Peregrine program is the natural next step in this development. A number of small sounding rockets with diameters of 3, 4, and 6 in. (7.6, 10.2, and 15.2 cm) have been flown, but Peregrine at a diameter of 15 in. (38.1 cm) and 14,000-lb (62.3-kN) thrust is by far the largest system ever attempted and will be one of the largest hybrids ever flown. Successful Peregrine flights will set the stage for a wide range of applications of this technology.

Zilliac, Gregory↗

Influence of Catalysis and Oxidation on Slug Calorimeter Measurements in Arc Jets

Arc jet tests play a critical role in the characterization and certification of thermal protection materials and systems (TPS). The results from these arc jet tests feed directly into computational models of material response and aerothermodynamics to predict the performance of the TPS in flight. Thus the precise knowledge of the plasma environment to which the test material is subjected, is invaluable. As one of the environmental parameters, the heat flux is commonly measured. The measured heat flux is used to determine the plasma enthalpy through analytical or computational models. At NASA Ames Research Center (ARC), slug calorimeters of a geometrically similar body to the test article are routinely used to determine the heat flux. A slug calorimeter is a thermal capacitance-type calorimeter that uses the temperature rise in a thermally insulated slug to determine the heat transfer rate, see Figure 1(left). Current best practices for measuring the heat flux with a slug calorimeter are described in ASTM E457 - 96. Both the calorimeter body and slug are made of Oxygen Free High Conductivity Copper, and are cleaned before each run.

Nawaz, Anuscheh↗

Development of a Two-Stage Mars Ascent Vehicle Using In-Situ Propellant Production

Mars Sample Return (MSR) and Mars In-Situ Resource Utilization (ISRU) present two main challenges for the advancement of Mars science. MSR would demonstrate Mars lift-off capability, while ISRU would test the ability to produce fuel and oxidizer using Martian resources, a crucial step for future human missions. A two-stage Mars Ascent Vehicle (MAV) concept was developed to support sample return as well as in-situ propellant production. The MAV would be powered by a solid rocket first stage and a LOX-propane second stage. A liquid second-stage provides higher orbit insertion reliability than a solid second stage as well as a degree of complexity eventually required for manned missions. Propane in particular offers comparable performance to methane without requiring cryogenic storage. The total MAV mass would be 119.9 kg to carry an 11 kg payload to orbit. The feasibility of in-situ fuel and oxidizer production was also examined. Two potential schemes were evaluated for production capability, size and power requirements. The schemes examined utilize CO2 and water as starting blocks to produce LOX and a propane blend. The infrastructure required to fuel and launch the MAV was also explored.

Paxton, Laurel↗

Metallic Environmentally Resistant Coating Rapid Innovation Initiative Under Extreme Space Environments

Mission concepts such as JPL’s Endurance-A campaign will utilize rovers such as Astrolab’s FLEX concept to explore the lunar surface. For these types of systems, lightweight alloys such as aluminum (Al) and titanium (Ti) are often specified to minimize mass while maintaining structural integrity [1,2,3]. Such alloys, however, exhibit poor tribological response in the form of high friction and wear, especially in extreme space environments and with the additional presence of lunar regolith. This shortens the lifetimes of these systems which have a requirement to traverse 1,00km/year [2,3]. The MERCRII project is ad-dressing the technology need of this and future rover missions by developing advanced wear- and radiation-resistant coatings for lightweight parts to extend the lifetime and sustainability of both lunar and Martian assets. The MERCRII project focuses on the technology taxonomies of exploration destination systems, mission infrastructure, and sustainability and supportability to explore both new and existing coating technologies, including material formulations and application methods. Several material formulations were considered for their wear resistance and fracture toughness and the following were chosen for Phase I testing: Nickle Titani-um (NiTi), Aluminum Oxide (AlO), and Ti64 with hBN at two and ten vol percent (Ti-2vol%hBN and Ti-10vol%hBN).

S. Rengifo↗

Wall-Jet Evolution During Plume-Surface Interaction Using PLIF Imaging

Planar laser-induced fluorescence (PLIF) flow visualization was used to examine the spatial evolution for the wall-jet formed by an impinging supersonic jet in a large-scale vacuum environment. This canonical configuration is representative of the plume-surface interaction induced by a rocket exhaust plume impinging on the planetary surface at lunar-relevant and Martian-relevant environments. PLIF flow visualization of the very low-density environment (as low as ~0.006% of standard atmospheric density) was performed using seeded nitric oxide in a nitrogen flow at three test conditions. Two conditions are representative of the lunar environment, and one is representative of the Martian environment. The combined images from two simultaneous PLIF views were used to construct a 2D slice of the flowfield spanning approximately 150 mm in height (determined by the laser sheet) and 500 mm in width (determined by the camera views). The three test conditions showed different behavior for the wall-jet, largely due to the different levels of lifting above the surface and the appearance of a physical process similar to a Kelvin–Helmholtz instability for the Martian-relevant case, which appeared to create a dramatic expansion of the wall-jet height with increased radial distance.

PSI↗

Wall-Jet Evolution During Plume-Surface Interaction Using PLIF Imaging

Planar laser-induced fluorescence (PLIF) flow visualization was used to examine the spatial evolution for the wall-jet formed by an impinging supersonic jet in a large-scale vacuum environment. This canonical configuration is representative of the plume-surface interaction induced by a rocket exhaust plume impinging on the planetary surface at lunar-relevant and Martian-relevant environments. PLIF flow visualization of the very low-density environment (as low as ~0.006% of standard atmospheric density) was performed using seeded nitric oxide in a nitrogen flow at three test conditions. Two conditions are representative of the lunar environment, and one is representative of the Martian environment. The combined images from two simultaneous PLIF views were used to construct a 2D slice of the flowfield spanning approximately 150 mm in height (determined by the laser sheet) and 500 mm in width (determined by the camera views). The three test conditions showed different behavior for the wall-jet, largely due to the different levels of lifting above the surface and the appearance of a physical process similar to a Kelvin–Helmholtz instability for the Martian-relevant case, which appeared to create a dramatic expansion of the wall-jet height with increased radial distance.

PSI↗

Effect of Pressure on Piloted Ignition Delay of PMMA

In order to reduce the risk of decompression sickness associated with spacewalks, NASA is considering designing the next generation of exploration vehicles and habitats with a different cabin environment than used previously. The proposed environment uses a total cabin pressure of 52.7 to 58.6 kPa with an oxygen concentration of 30 to 34% by volume and was chosen with material flammability in mind. Because materials may burn differently under these conditions and there is little information on how this new environment affects the flammability of the materials onboard, it is important to conduct material flammability experiments at the intended exploration atmosphere. One method to evaluate material flammability is by its ease of ignition. To this end, piloted ignition delay tests were conducted in the Forced Ignition and Spread Test (FIST) apparatus subject to this new environment. In these tests, polymethylmethacylate (PMMA) was exposed to a range of oxidizer flow velocities and externally applied heat fluxes. The ultimate goal is to determine the individual effect of pressure and the combined effect of pressure and oxygen concentration on the ignition delay. Tests were conducted for a baseline case of normal pressure and oxygen concentration, low pressure (58.6 kPa) with normal oxygen (21%). Future work will focus on low pressure with 32% oxygen concentration (space exploration atmosphere - SEA) conditions. It was found that reducing the pressure while keeping the oxygen concentration at 21% reduced the ignition time by 17% on average. It was also noted that the critical heat flux for ignition decreases in low-pressure conditions. Because tests conducted in standard atmospheric conditions will underpredict the flammability of materials intended for use on spacecraft, fire safety onboard at exploration atmospheres may be compromised.

McAllister, Sara↗

Investigation of characteristics of feed system instabilities

The relationship between the structural and feed system natural frequencies in structure-propulsion system coupled longitudinal oscillations (pogo) is investigated. The feed system frequencies are usually very dependent upon the compressibility (compliance) of cavitation bubbles that exist to some extent in all operating turbopumps. This document includes: a complete review of cavitation mechanisms; development of a turbopump cavitation compliance model; an accumulation and analysis of all available cavitation compliance test data; and a correlation of empirical-analytical results. The analytical model is based on the analysis of flow relative to a set of cascaded blades, having any described shape, and assumes phase changes occur under conditions of isentropic equilibrium. Analytical cavitation compliance predictions for the J-2 LOX, F-1 LOX, H-1 LOX and LR87 oxidizer turbopump inducers do not compare favorably with test data. The model predicts much less cavitation than is derived from the test data. This implies that mechanisms other than blade cavitation contribute significantly to the total amount of turbopump cavitation.

Vaage, R. D.↗

Nonleaking battery terminals.

Three different terminals were designed for usage in a 40 ampere/hour silver zinc battery which has a 45% KOH by weight electrolyte in a plastic battery case. Life tests, including thermal cycling, electrical charge and discharge for up to three years duration, were conducted on these three different terminal designs. Tests for creep rate and tensile strength were conducted on the polyphenylene oxide plastic battery cases. Some cases were unused and others containing KOH electrolyte were placed on life tests. The design and testing of nonleaking battery terminals for use with a KOH electrolyte in a plastic case are considered.

Snider, W. E.↗

Formation of Oxides in the Interior of Friction Stir Welds

In friction stir welding (FSWing) the actual solid state joining takes place between the faying surfaces which form the weld seam. Thus the seam trace is often investigated for clues when the strength of the weld is reduced. Aluminum and its alloys are known to form a native, protective oxide on the surface. If these native surface oxides are not sufficiently broken up during the FSW process, they are reported to remain in the FSW interior and weaken the bond strength. This type of weld defect has been referred to as a lazy "S", lazy "Z", joint line defect, kissing bond, or residual oxide defect. Usually these defects are mitigated by modification of the process parameters, such as increased tool rotation rate, which causes a finer breakup of the native oxide particles. This study proposes that there may be an alternative mechanism for formation of oxides found within the weld nugget. As the oxidation rate increases at elevated temperatures above 400ºC, it may be possible for enhanced oxidation to occur on the interior surfaces during the FSW process from entrained air entering the seam gap. Normally, FSWs of aluminum alloys are made without a purge gas and it is unknown how process parameters and initial fit up could affect a potential air path into the interior during the processing. In addition, variations in FSW parameters, such as the tool rotation, are known to have a strong influence on the FSW temperature which may affect the oxidation rate if internal surfaces are exposed to entrained air. A series of FSWs were made in 3 different thickness panels of AA2219 (0.95, 1.27 and 1.56 cm) at 2 different weld pitches. As the thickness of the panels increased, there was an increased tendency for a gap to form in advance of the weld tool. If sufficient air is able to enter the workpiece gap prior to consolidation, the weld temperature can increase the oxidation rate on the interior surfaces. These oxidation rates would also be accelerated in areas of localized liquation. Metallographs from the weld panels showed indications of liquation at the grain boundaries. In FSWs of thicker panels, these regions of liquation were found to be heavily oxidized. The quality of the FSWs was evaluated from tensile testing at room temperature. As the panel thickness increased, a slight decrease in tensile strength was observed which was attributed to the presence of oxides. No oxide formation was observed in the thinner workpieces, although there were indications of localized liquation at the grain boundaries. Results from this study will assist in a better understand of the mechanisms of oxide formation in FSW interiors and provide methodology for minimizing their occurrence.

Schneider, Judy↗