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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 631 records · Page 35
All sourcesNASA NTRSDOE OSTI
NASA NTRS1998

Fabrication and Atomic Force Microscopy Characterization of Molecular Composites of Fullerenes in Aerogel Matrix for Optical Limiting

An optical limiter is a device which exhibits a decrease in the transmittance in a material with an increase in intensity of light. Sol-gel techniques offer many advantages in the fabrication of materials. These materials possess many desirable properties for nonlinear optical (NLO) device applications which include transparency, high thermal and chemical stabilities, very low refractive index and dielectric constants. C60 shows a higher excited state absorption cross section than the ground state absorption cross section over the complete visible spectrum, and the spectrum of the excited state absorption of C60 has the same general shape as the ground state absorption. This fact suggests that fullerenes are ideal optical limiting materials. Aerogels are fabricated by sol-gel processing. One of the key issues is the dispersion of fullerenes into small and uniform pores of silica aerogel host matrices. The aerogel network was characterized by Raman spectroscopy. Atomic force microscopy is a technique with many advantages to characterize the aerogel materials. The morphology of the cleaved surface for a C60/aerogel sample shows that there are long paralleled shaped stripes with 20-30 nm in width and about 500 nm in length on the cleaved surface. The cleaved surface also was etched by 5% HF solution for one minutes, and it became smoother after HF etching. The main feature in on the surface is the spherical particles with the size of few nanometers, and no aggregated fullerenes appear. The fullerenes are well dispersed in the aerogel matrices.

Lu, W. J .↗
DOE OSTI2023

Laser heating of ferroelectric cubes for tunable electromagnetic properties in metamaterials

In this experimental study, we demonstrate the feasibility of a thermally tunable, resonant dielectric microwave metasurface based on sub-wavelength Mie resonances of ferroelectric dielectric cubes (Calcium titanate, CaTiO 3 ) in which the temperature of the meta-atoms can be locally and dynamically controlled by heating with an optical laser beam over a large range of temperatures and, consequently, values of the dielectric constant of the cube and corresponding resonance frequency of the meta-atoms. Further, this avoids any interference of otherwise necessary heating elements or power supply wires with the propagation of the microwave signal and can be made spatially addressable. The concept scales at least to the THz domain. This contactless approach opens up an alternative avenue to tunability and active control of metamaterials.

36 MATERIALS SCIENCE↗
NASA NTRS1984

Structure of the Uranian rings. I - Square-well model and particle-size constraints

A least squares fitting is added to the diffraction model for the Uranian rings and the model is then used to determine the relative optical depths of the rings at visible and near-IR wavelengths. Light transmission is assumed constant on a scale of a few radial km in the rings. The amount of starlight passing through the rings is calculated from occultations with account taken of a monolayer ring, diffraction effects, and multiple ring layers. A diffracted occultation profile is generated with consideration given to the angular diameter of the star, the impulse response of the detector, and atmospheric aberrations. Calculation procedures which remove noise are outlined and results are compared with the observational data base. The wavelength dependence of optical depth is formulated. It is shown that occultation data do not support the presence of a large fraction of submicron particles. No optical depth variations are projected for 0.88-2.2 microns wavelengths. Unchopped data are needed to verify the model predictions.

Elliot, J. L.↗
NASA NTRS1983

Ultraviolet response of film candidates for the solar optical telescope photometric filtergraph

Measurements of UV response between 2000 and 3000 A of Kodak films 2415, Aerocon II 3412, and SO-415 are reported. The short wavelength cutoff of the response of all films studied lies near 2100 A, occurring as a gentle falloff starting near 2500 A. The sensitivity of the films appears to remain roughly constant from 2500 to 3000 A. Estimates of UV Gamma for 2415 and the effect of hard UV on the optics in the experiment are also discussed.

Morgan, J. A.↗
NASA NTRS1986

Limits to size for terrestrial telescopes - Two-stage optics

A wave front corrector inserted at the image of a surface producing an error can remove the wave front error over a reasonable field of view. The relationship of magnitude of error, constants of a given configuration, and the residual wave front error is explored. Results are presented of the production of a sample wave front error surface by diamond turning with the Large Optical Diamond Turning Machine (LODTM). The cost consequences of this new ability to upgrade a submillimeter-quality telescope to a high-acuity optical telescope are shown.

Meinel, Marjorie P.↗
NASA NTRS1991

Opacity effects on the radiative losses of coronal loops

This paper presents calculations of radiative losses, which include the effects of geometry and optical depth, that can be used to improve the energy losses in many flux-tube calculations for loops with constant and variable cross sections. The results include the non-LTE ionization state of hydrogen and helium, thus allowing the determination of the ionization energy in the gas and the relative importance of collisional and radiative processes. These calculations show that optical depth effects are important under solar conditions in the temperature range of 8000-40,000 K.

Kuin, N. P. M.↗
DOE OSTI2020

Experimental demonstration of broadband solar absorption beyond the lambertian limit in certain thin silicon photonic crystals

The tantalizing possibility of 31% solar-to-electric power conversion efficiency in thin film crystalline silicon solar cell architectures relies essentially on solar absorption well beyond the Lambertian light trapping limit (Bhattacharya and John in Nat Sci Rep 9:12482, 2019). Up to now, no solar cell architecture has exhibited above-Lambertian solar absorption, integrated over the broad solar spectrum. In this work, we experimentally demonstrate two types of photonic crystal (PhC) solar cells architectures that exceed Lambertian light absorption, integrated over the entire 300–1,200 nm wavelength band. These measurements confirm theoretically predicted wave-interference-based optical resonances associated with long lifetime, slow-light modes and parallel-to-interface refraction. These phenomena are beyond the realm of ray optics. Using two types of 10-μm thick PhC’s, first an Inverted Pyramid PhC with lattice constant a= 2,500 nm and second a Teepee PhC with a = 1,200 nm, we observe solar absorption well beyond the Lambertian limit over λ = 950–1,200 nm. Our absorption measurements correspond to the maximum-achievable-photocurrent-density (MAPD), under AM1.5G illumination at 4-degree incident angle, 41.29 and 41.52 mA/cm2 for the Inverted Pyramid and Teepee PhC, respectively, in agreement with wave-optics, numerical simulations. Both of these values exceed the MAPD (= 39.63 mA/cm2) corresponding to the Lambertian limit for a 10-μm thick silicon for solar absorption over the 300–1,200 nm band.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Accessing Transient Isomers in the Photoreaction of Metastable‐State Photoacid

The photoreaction of a metastable‐state photoacid (mPAH) generally involves multiple isomers with various connected pathways of photoinduced structural changes during a single reaction cycle. However, only a limited number of isomers have been identified experimentally so far owing to the inherent complexity in combination with the presence of various competing electronic and vibrational processes, as well as the constantly varying interactions between mPAH isomers and solvent molecules. Here, in this work, an optical spectroscopic study on a benzimidazole‐based mPAH, a novel photoacid using benzimidazole as the structural moiety with the active proton, is reported. Through measurements of linear absorption and steady‐state fluorescence in neat solvents and binary mixtures, a pronounced effect of neat water and its binary mixture with glycerol is discovered on the photoreaction of this benzimidazole‐mPAH, manifested by the remarkably distinct spectral responses to irradiation from that observed for an organic solution under identical conditions. Measurements of time‐ and frequency‐resolved fluorescence emission further enable to access transient isomers and the associated spectral characteristics from other competing electronic excited‐state relaxation processes. Spectral deconvolution analysis and time‐dependent density functional theory calculations are applied to separate distinct spectral components and access their potential origin.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Optical neural engine for solving scientific partial differential equations

Abstract Solving partial differential equations (PDEs) is the cornerstone of scientific research and development. Data-driven machine learning (ML) approaches are emerging to accelerate time-consuming and computation-intensive numerical simulations of PDEs. Although optical systems offer high-throughput and energy-efficient ML hardware, their demonstration for solving PDEs is limited. Here, we present an optical neural engine (ONE) architecture combining diffractive optical neural networks for Fourier space processing and optical crossbar structures for real space processing to solve time-dependent and time-independent PDEs in diverse disciplines, including Darcy flow equation, the magnetostatic Poisson’s equation in demagnetization, the Navier-Stokes equation in incompressible fluid, Maxwell’s equations in nanophotonic metasurfaces, and coupled PDEs in a multiphysics system. We numerically and experimentally demonstrate the capability of the ONE architecture, which not only leverages the advantages of high-performance dual-space processing for outperforming traditional PDE solvers and being comparable with state-of-the-art ML models but also can be implemented using optical computing hardware with unique features of low-energy and highly parallel constant-time processing irrespective of model scales and real-time reconfigurability for tackling multiple tasks with the same architecture. The demonstrated architecture offers a versatile and powerful platform for large-scale scientific and engineering computations.

Tang, Yingheng (ORCID:0009000153622546)↗
DOE OSTI2023

Electronic properties and optical spectra of donor–acceptor conjugated organic polymers

Organic semiconductors based on conjugated donor-acceptor (D–A) polymers are a unique platform for electronic, spintronic, and energy-harvesting devices. Understanding the electronic structure of D–A polymers with a small band gap is essential for developing next-generation technologies. Here, we investigate the electronic structure and optical spectra of cyclopentadithiophene-based closed/open-shell D–A polymers using density functional theory and the Bethe–Salpeter equation based on G 0 W 0 approximation. We explored the role of different acceptor units and chemical substitutions on the structural changes and, more importantly, electronic, optical, and dielectric behavior. We found that the computed first exciton peak of the polymers agreed well with the available experimentally measured optical gap. Furthermore, D–A polymers with open-shell character display higher dielectric constant than the closed-shell polymers. We show that the exceptional performance of polycyclopentadithiophene-thiophenylthiadiazoloquinoxaline (PCPDT-TTQ) as a scalable n-type material for Faradaic supercapacitors can be partly ascribed to its elevated dielectric constant. Consequently, these D–A polymers, characterized by their high dielectric constants, exhibit significant potential for various applications, including energy storage, organic electronics, and the production of dielectric films.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Eye-Safe 1.5 and 2.0 Micron Laser Power Conversion Using Metamorphic InGaAs Photovoltaic Devices

Laser power transmission at 1.5 and 2.0 microns are considered eye-safe up to 0.1 W/cm2 irradiance. Further, the atmospheric bands at these two wavelengths may provide the highest optical transmission through the atmosphere in hazy conditions. By slowly changing the lattice-constant of InGaAs with a Compositionally Graded Buffer (CGB), we have fabricated InGaAs photovoltaic (PV) devices over a wide range of bandgaps useful for multijunction concentrating photovoltaic devices, thermophotovoltaic devices, and Laser Power Converters (LPC). Here, we have demonstrated monochromatic power conversion of 1.5-micron light with an eye-safe efficiency of 39.8% at 0.1 W/cm2 with InGaAs devices lattice-matched to InP with an Antireflection Coating (ARC). We have also demonstrated 30.2% and 24.5% eye-safe LPC efficiency of metamorphic InGaAs devices grown on GaAs substrates using GaInP and AlGaAsP CGBs, respectively. Finally, we have demonstrated metamorphic InGaAs devices grown on InP and GaAs substrates that are estimated to have eye-safe LPC efficiencies at 2.0 microns of 27.4% and 20.9% respectively. The efficiencies of all these LPC devices continues to increase up to about 30-70 times the eye-safe irradiance.

eye-safe↗
NASA NTRS1967

Foil radiometer accessory improves measurements

The responsiveness of a foil radiometer is increased and its time constant is simultaneously decreased by isolating the foil in a controlled environment. Using an optical system, it is coupled to the media to be measured, and the resulting concentration of energy permits the thermocouple junction temperature to respond quickly.

Schumacher, P. E.↗
NASA NTRS1972

Light scattering from an inhomogeneous fluid.

The methods of geometric optics are used to obtain the irradiance and spectral distribution of light scattered by fluctuations in an inhomogeneous fluid. The optical properties of the fluid are assumed to be described by a local dielectric constant that varies monotonically in one direction.

Miller, B. N.↗
NASA NTRS1974

Dually-mode-locked ND: YAG laser

Mode-locking is stabilized effectively by conventional loss-modulator and phase-modulator, mode-locking elements placed in laser cavity in optical series with one another. Resulting dually-mode-locked system provides pulses with constant phase relative to mode-lock drive signal without presence of relaxation oscillation noise.

Osmundson, J.↗
NASA NTRS1993

The galaxy velocity field and CDM models

It is generally accepted that some kind of non-baryonic dark matter accounts for most of the mass density of the universe. Considering such a component has become, in the last decade, a key ingredient in current theories of structure formation. In particular, the Cold Dark Matter (CDM) scenario has proven to be quite successful in explaining most of the observed properties of galaxies and of their large-scale distribution. The standard CDM model is characterized by a primordial Zel'dovich spectrum, of random-phase adiabatic perturbations in a universe with density parameter omega sub 0 = 1 and vanishing cosmological constant. This poster paper presents an analysis of observational data on peculiar motion of optical galaxies in comparison to the predictions of CDM models where the assumptions of the standard scenario: omega sub 0 = 1, n = 1, and bias parameter b = 1 are relaxed. In particular, CDM models with 0 less than n less than 1 and 0.4 less than omega sub 0 less than 1 are considered.

Tormen, Giuseppe↗
NASA NTRS1993

GCM simulations of volcanic aerosol forcing. I - Climate changes induced by steady-state perturbations

The response of the climate system to a temporally and spatially constant amount of volcanic particles is simulated using a general circulation model (GCM). The optical depth of the aerosols is chosen so as to produce approximately the same amount of forcing as results from doubling the present CO2 content of the atmosphere and from the boundary conditions associated with the peak of the last ice age. The climate changes produced by long-term volcanic aerosol forcing are obtained by differencing this simulation and one made for the present climate with no volcanic aerosol forcing. The simulations indicate that a significant cooling of the troposphere and surface can occur at times of closely spaced multiple sulfur-rich volcanic explosions that span time scales of decades to centuries. The steady-state climate response to volcanic forcing includes a large expansion of sea ice, especially in the Southern Hemisphere; a resultant large increase in surface and planetary albedo at high latitudes; and sizable changes in the annually and zonally averaged air temperature.

Pollack, James B.↗
NASA NTRS1995

Polyimides Made From 3,5-Diaminobenzotrifluoride

Polyimides synthesized from 3,5-diaminobenzotrifluoride (DABTF). One monomer of major importance in preparing these high-temperature polymers is 1,3-phenylenediamine (mPDA). Fluorinated polyimides exhibit characteristics potentially attractive for aerospace and electronic applications. Includes optical transparency, solubility in common polar solvents, enhanced thermo-oxidative stability, low dielectric constants, and high glass-transition temperatures. Polyimides also used to form free-standing films, coatings, and moldings.

St. Clair, Terry L.↗
NASA NTRS2002

Problems in Assessment of the UV Penetration into Natural Waters from Space-based Measurements

Satellite instruments currently provide global maps of surface UV (ultraviolet) irradiance by combining backscattered radiance data with radiative transfer models. The models are often limited by uncertainties in physical input parameters of the atmosphere and surface. Global mapping of the underwater UV irradiance creates further challenges for the models. The uncertainties in physical input parameters become more serious because of the presence of absorbing and scattering quantities caused by biological processes within the oceans. In this paper we summarize the problems encountered in the assessment of the underwater UV irradiance from space-based measurements, and propose approaches to resolve the problems. We have developed a radiative transfer scheme for computation of the UV irradiance in the atmosphere-ocean system. The scheme makes use of input parameters derived from satellite instruments such as TOMS (Total Ozone Mapping Spectrometer) and SeaWiFS (Sea-viewing Wide Field-of-view Sensor). The major problem in assessment of the surface UV irradiance is to accurately quantify the effects of clouds. Unlike the standard TOMS UV algorithm, we use the cloud fraction products available from SeaWiFS and MODIS (Moderate Resolution Imaging Spectrometer) to calculate instantaneous surface flux at the ocean surface. Daily UV doses can be calculated by assuming a model of constant cloudiness throughout the day. Both SeaWiFS and MODIS provide some estimates of seawater optical properties in the visible. To calculate the underwater UV flux the seawater optical properties must be extrapolated down to shorter wavelengths. Currently, the problem of accurate extrapolation of visible data down to the UV spectral range is not solved completely, and there are few available measurements. The major difficulty is insufficient correlation between photosynthetic and photoprotective pigments of phytoplankton absorbing in the visible and UV respectively. We propose to empirically parameterize seawater absorption in the UV on a basis of available data sets of bio-optical measurements from a variety of ocean waters. Another problem is the lack of reliable data on pure seawater absorption in the UV. Laboratory measurements of the UV absorption of both pure water and pure seawater are required.

Vasilkov, Alexander P.↗