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At least 631 records · Page 35

K-Shell Photoabsorption and Photoionisation of Trace Elements I. Isoelectronic Sequences With Electron Number 3< or = N < or = 11

Context. With the recent launching of the Hitomi X-ray space observatory, K lines and edges of chemical elements with low cosmic abundances, namely F, Na, P, Cl, K, Sc, Ti, V, Cr, Mn, Co, Cu and Zn, can be resolved and used to determine important properties of supernova remnants, galaxy clusters and accreting black holes and neutron stars.Aims. The second stage of the present ongoing project involves the computation of the accurate photoabsorption and photoionisation cross sections required to interpret the X-ray spectra of such trace elements.Methods. Depending on target complexity and computer tractability, ground-state cross sections are computed either with the close-coupling Breit-Pauli R-matrix method or with the autostructure atomic structure code in the isolated-resonance approximation. The intermediate-coupling scheme is used whenever possible. In order to determine a realistic K-edge behaviour for each species, both radiative and Auger dampings are taken into account, the latter being included in the R-matrix formalism by means of an optical potential.Results. Photoabsorption and total and partial photoionisation cross sections are reported for isoelectronic sequences with electron numbers 3< or = N< or = 11. The Na sequence (N=11) is used to estimate the contributions from configurations with a 2s hole (i.e. [2s]) and those containing 3d orbitals, which will be crucial when considering sequences with N 11.Conclusions. It is found that the [2s/u] configurations must be included in the target representations of species with N> 11 as they contribute significantly to the monotonic background of the cross section between the L and K edges. Configurations with 3d orbitals are important in rendering an accurate L edge, but they can be practically neglected in the K-edge region.

atomic data / X-rays: general↗

Tropopause Laminar Cirrus and Its Role in the Lower Stratosphere Total Water Budget

Laminar cirrus are thin, extensive, isolated layers of ice clouds frequently observed in the tropical tropopause layer. Widespread laminar cirrus significantly affects tropical tropopause layer total water and thermal budget. In this study, we extract laminar cirrus from the Cloud‐Aerosol Lidar with Orthogonal Polarization Level 1 attenuated total backscatter images for January 2009, in order to characterize statistical properties of laminar cirrus cloud length, base, thickness, optical depth, and layer partial ice water path. These characteristics are used to develop an algorithm identifying laminar cirrus automatically from the Cloud‐Aerosol Lidar with Orthogonal Polarization Level 2 layer product for 2008–2017. The nearly 10‐year records reveal that tropopause laminar cirrus occurrence (30–40% of total cirrus) is strongly anticorrelated with the tropopause temperatures in that colder tropopause in frequent (super)saturation during boreal winter favors in situ formation of clouds. Interannually, anomalously warmer troposphere temperature (ΔT), easterly shear of the quasi‐biennial oscillation, and stronger upwelling branch of the Brewer‐Dobson circulation enhance laminar cirrus formation via cooling of the tropopause. The tropopause laminar cirrus carries ~0.05 mg/m(exp 3) (~0.5 ppmv) of ice water content during boreal winter and <0.01 mg/m(exp 3) during summer, which is anticorrelated with the seasonal variations of water vapor (H2O) observed by the Microwave Lime Sounder, indicating a temperature‐regulated partition between vapor and ice. Interannually, in cirrus‐rich region 1 ppmv decrease in H2O corresponds to 0.2–0.3 ppmv increase in ice water content. Frequently situated in (super)saturated air, tropopause laminar cirrus are likely to survive multiple lifecycles of the sublimation‐deposition processes, and may contribute up to 10% to the total water budget in the lower stratosphere. Satellites constantly observe thin, isolated, extensive layer of cirrus around the tropopause. The so‐called “laminar” cirrus occurrence and their ice amount are strongly regulated by temperature, such that colder temperatures favor more frequent (super)saturation, which results in more frequent laminar cirrus with more ice amount and therefore less water vapor. In this study we analyze laminar cirrus and water vapor from the Cloud‐Aerosol Lidar with Orthogonal Polarization and Microwave Lime Sounder observations, and hypothesize that laminar cirrus could act as an important transient water storage and contribute to the total water budget in the lower stratosphere.

Tao Wang↗

Photographic Equipment Test System (PETS)

The Photographic Equipment Test System is presented. The device is a mobile optical system designed for evaluating performance of various sensors in a laboratory, in a vacuum chamber or on a flight line. The carriage is designed to allow elevation as well as azimuth control of the direction of the light from the collimator. The pneumatic tires provide an effective vibration isolation system. A target/illumination system is mounted on a motor driven linear slide, and focusing and exposure control can be operated remotely from the small electronics control console.

Source record↗

High-resolution optical imaging of the 'Frosty Leo' nebula

High-resolution optical images have been obtained of IRAS 09371 + 1212 (the 'Frosty Leo' nebula). The images were taken with the Dominion Astrophysical Observatory/Canada-France-Hawaii Telescope (DAO/CFHT) High-Resolution Camera using broadband V and I filters and with an intermediate-band H-alpha filter. The red filters, particularly H-alpha show that the bipolar nebula is surrounded by a nearly spherical envelope of material approximately 30 sec in diameter. The high-resolution images allow a detailed study of changes in the nebular morphology with wavelength. The ansae remain stationary with wavelength, whereas the positions of the lobes and the position angle of the disk change with wavelength from the optical to the near infrared. These results suggest that the ejection process is colliminated by the disk, which has been processing with time. The possibility that the Frosty Leo nebula is not a post-asymptotic giant branch (AGB) star but a pre-main-sequence object formed in isolation from interstellar clouds is discussed.

Langill, Philip P.↗

Meteorites, Microfossils and Exobiology

The discovery of evidence for biogenic activity and possible microfossils in a Martian meteorite may have initiated a paradigm shift regarding the existence of extraterrestrial microbial life. Terrestrial extremophiles that live in deep granite and hydrothermal vents and nanofossils in volcanic tuffs have altered the premise that microbial life and microfossils are inconsistent with volcanic activity and igneous rocks. Evidence for biogenic activity and microfossils in meteorites can no longer be dismissed solely because the meteoritic rock matrix is not sedimentary. Meteorite impact-ejection and comets provide mechanisms for planetary cross-contamination of biogenic chemicals, microfossils, and living microorganisms. Hence, previously dismissed evidence for complex indigenous biochemicals and possible microfossils in carbonaceous chondrites must be re-examined. Many similar, unidentifiable, biological-like microstructures have been found in different carbonaceous chondrites and the prevailing terrestrial contaminant model is considered suspect. This paper reports the discovery of microfossils indigenous to the Murchison meteorite. These forms were found in-situ in freshly broken, interior surfaces of the meteorite. Environmental Scanning Electron Microscope (ESEM) and optical microscopy images indicate that a population of different biological-like forms are represented. Energy Dispersive Spectroscopy reveals these forms have high carbon content overlaying an elemental distribution similar to the matrix. Efforts at identification with terrestrial microfossils and microorganisms were negative. Some forms strongly resemble bodies previously isolated in the Orgueil meteorite and considered microfossils by prior researchers. The Murchison forms are interpreted to represent an indigenous population of the preserved and altered carbonized remains (microfossils) of microorganisms that lived in the parent body of this meteorite at diverse times during the past 4.5 billion years (Gy).

Hoover, Richard B.↗

Optical Communications Link to Airborne Transceiver

An optical link from Earth to an aircraft demonstrates the ability to establish a link from a ground platform to a transceiver moving overhead. An airplane has a challenging disturbance environment including airframe vibrations and occasional abrupt changes in attitude during flight. These disturbances make it difficult to maintain pointing lock in an optical transceiver in an airplane. Acquisition can also be challenging. In the case of the aircraft link, the ground station initially has no precise knowledge of the aircraft s location. An airborne pointing system has been designed, built, and demonstrated using direct-drive brushless DC motors for passive isolation of pointing disturbances and for high-bandwidth control feedback. The airborne transceiver uses a GPS-INS system to determine the aircraft s position and attitude, and to then illuminate the ground station initially for acquisition. The ground transceiver participates in link-pointing acquisition by first using a wide-field camera to detect initial illumination from the airborne beacon, and to perform coarse pointing. It then transfers control to a high-precision pointing detector. Using this scheme, live video was successfully streamed from the ground to the aircraft at 270 Mb/s while simultaneously downlinking a 50 kb/s data stream from the aircraft to the ground.

Regehr, Martin W.↗

36 Hz integral linewidth laser based on a photonic integrated 4.0 m coil resonator

Laser stabilization sits at the heart of many precision scientific experiments and applications, including quantum information science, metrology, and atomic timekeeping. Many of these systems narrow the laser linewidth and stabilize the carrier by use of Pound–Drever–Hall (PDH) locking to a table-scale, ultrahigh quality factor (Q), vacuum spaced Fabry–Perot reference cavity. Integrating these cavities to bring characteristics of PDH stabilization to the chip scale is critical to reducing their size, cost, and weight, and enabling a wide range of portable and system-on-chip applications. We report a significant advance in integrated laser linewidth narrowing, stabilization, and noise reduction by use of a photonic integrated 4.0 m long coil resonator to stabilize a semiconductor laser. We achieve a 36 Hz 1 / π <#comment/> -integral linewidth, Allan deviation of 1.8 × <#comment/> 10 − <#comment/> 13 at 10 ms measurement time, and a 2.3 kHz/s drift—to the best of our knowledge, the lowest integral linewidth and highest stability demonstrated for an integrated waveguide reference cavity. This performance represents over an order of magnitude improvement in integral linewidth and frequency noise over previous integrated waveguide PDH stabilized reference cavities and bulk-optic and integrated injection locked approaches, and over two orders of magnitude improvement in frequency and phase noise than integrated injection locked approaches. Two different wavelength coil designs are demonstrated, stabilizing lasers at 1550 nm and 1319 nm. The resonator is bus-coupled to a 4.0 m long coil, with a 49 MHz free spectral range, mode volume of 1.0 × <#comment/> 10 10 µ <#comment/> m 3 , and 142 million intrinsic Q , fabricated in a CMOS compatible, ultralow loss silicon nitride waveguide platform. Our measurements and simulations show that the thermorefractive noise floor for this particular cavity is reached for frequencies down to 20 Hz in an ambient environment with simple passive vibration isolation and without vacuum or thermal isolation. The thermorefractive noise limited performance is estimated to yield an 8 Hz 1 / π <#comment/> -integral linewidth and Allan deviation of 5 × <#comment/> 10 − <#comment/> 14 at 10 ms, opening a stability regime that heretofore has been available only in fundamentally non-integrated systems. These results demonstrate the potential to bring the characteristics of laboratory-scale stabilized lasers to the integrated, wafer-scale compatible chip scale, and are of interest for a number of applications in quantum technologies and atomic, molecular, and optical physics, and with further developments below 10 Hz linewidth, can be highly relevant to ultralow noise microwave generation.

Liu, Kaikai (ORCID:0000000213609646)↗

A Compact Topological Microwave Isolator

A central goal of topological photonics has been to develop compact isolators using protected, non-reciprocal edge states. Furthermore, a recent demonstration of a ferrite-based microwave isolator leverages the magnon-induced topological photonic bandgap to achieve over 100 dB of isolation in a device smaller than a single free-space wavelength.

Magneto-optics↗

Expanded Analogs of Three‐Dimensional Lead‐Halide Hybrid Perovskites

Abstract Replacing the Pb−X octahedral building unit of A I PbX 3 perovskites (X=halide) with a pair of edge‐sharing Pb−X octahedra affords the expanded perovskite analogs: A II Pb 2 X 6 . We report seven members of this new family of materials. In 3D hybrid perovskites, orbitals from the organic molecules do not participate in the band edges. In contrast, the more spacious inorganic sublattice of the expanded analogs accommodates larger pyrazinium‐based cations with low‐lying π* orbitals that form the conduction band, substantially decreasing the band gap of the expanded lattice. The molecular nature of the conduction band allows us to electronically dope the materials by reducing the organic molecules. By synthesizing derivatives with A II =pyridinium and ammonium, we can isolate the contributions of the pyrazinium‐based orbitals in the band gap transition of A II Pb 2 X 6 . The organic‐molecule‐based conduction band and the inorganic‐ion‐based valence band provide an unusual electronic platform with localized states for electrons and more disperse bands for holes upon optical or thermal excitation.

Umeyama, Daiki↗

Benchmarking Microscale Ductility Measurements (Final Report of the Project DE-NE0008799)

Conventional macroscale experimentation is generally considered to be straightforward with few limitations. Conversely, micro/nanoscale experimentation presents numerous challenges in loading device design, sample preparation and handling, as well as accurate understanding of grain size and local texture effects on recorded measurements. Despite these challenges, nanopillar compression, MEMs based micro-tension, and nanoindentation approaches have been able to provide fundamental contributions to the understanding of material behavior at small lengthscales. However, the overarching shortcoming of these micro/nanoscale experimentation approaches, is the inability to directly translate measurements evaluated at the nm and µm length scales (e.g., hardness) to macroscale tensile material behavior (i.e., elastic modulus, yield strength, and ductility). The objectives of the proposed study are, 1) to establish best practices for obtaining tensile microscale ductility measurements, and 2) to validate methodologies to for comparing microscale ductility measurements to macroscale ductility measurements. In order to achieve these objectives, a multi-lengthscale, multi-temperature testing protocol and simulation framework are executed first on copper as a model material to validate the following approach, and second on reactor grade Zircaloy-2. Experiments are conducted on specimens extracted from the same test piece to ensure nominally identical grain size and texture from specimens to specimen. Motivated by the need to isolate the contribution of size-effects on obtained mechanical property measurements, specimens are manufactured with thicknesses at the micro- (1-10 µm), meso- (10-100's µm), and macroscales (sub-sized ASTM E8). In-situ full-field deformation techniques (scanning electron microscopy (SEM) grid methods and optical DIC) are incorporated into testing at each specimen length-scale to capture plasticity localization and evolution. Experimental testing for all specimens is conducted at both room temperature and elevated temperatures to probe the role of thermal activation on plastic deformation accommodation processes. Simulation efforts focus on examining the mechanical behavior of microscale specimens using a finite element approach with explicitly resolved grain morphologies, and an embedded crystal plasticity model. The cost-efficient implementation method allows for the modeling of a statistically significant number of both real (i.e., digital twin) and generated microstructures to obtain an understanding of the interrelationships between specimen microstructure and geometric variables (grain size, texture, specimen geometry, etc.) on microscale mechanical behavior.

36 MATERIALS SCIENCE↗

Laboratory verification optical signal coupling. IMBLMS phase B.4, appendix C, section 12

The design of optical couplers is described for use in the IMBLMS hardwire mode. One coupler transmits data from the bio-belt to the central data system and the other coupler transmits audio frequencies in the opposite direction, from the central data system to the bio-belt. The objective is to isolate the ground system at the body worn bio-belt electronics and the main ground at the central data system, or biomedical and behavioral station. The safety of the subject wearing the bio-belt measuring electronics is the purpose in isolating the wearer from the main system ground.

Source record↗

Mass and energy balance of the cold Io torus

A new model of the cold Io torus is described. Ions and energy are injected into the system by independent processes so that the mass balance is isolated from the energy balance. The primary source of energy is local ionization and acceleration of hot pickup ions resulting from charge exchange between thermal ions and an extended cloud of Iogenic sulfur and oxygen atoms. The primary energy loss mechanism of the plasma is collisionally excited line emission at optical wavelengths. The primary ion source is radial diffusion inward from the hot torus on a time scale of 140-710 days. The primary ion loss mechanism is a novel two-step enhanced recombination mechanism involving charge exchange between thermal ions and an extended cloud of neutral SO2 molecules, followed by rapid dissociative recombination of the resultant molecular ion. The model provides a self-consistent solution which reconciles a number of diverse observations with known physical processes.

Moreno, M. A.↗

Reusable Rack Interface Controller Common Software for Various Science Research Racks on the International Space Station

The purpose of the EXPRESS (Expedite the PRocessing of Experiments to Space Station) rack project is to provide a set of predefined interfaces for scientific payloads which allow rapid integration into a payload rack on International Space Station (ISS). VxWorks' was selected as the operating system for the rack and payload resource controller, primarily based on the proliferation of VME (Versa Module Eurocard) products. These products provide needed flexibility for future hardware upgrades to meet everchanging science research rack configuration requirements. On the International Space Station, there are multiple science research rack configurations, including: 1) Human Research Facility (HRF); 2) EXPRESS ARIS (Active Rack Isolation System); 3) WORF (Window Observational Research Facility); and 4) HHR (Habitat Holding Rack). The RIC (Rack Interface Controller) connects payloads to the ISS bus architecture for data transfer between the payload and ground control. The RIC is a general purpose embedded computer which supports multiple communication protocols, including fiber optic communication buses, Ethernet buses, EIA-422, Mil-Std-1553 buses, SMPTE (Society Motion Picture Television Engineers)-170M video, and audio interfaces to payloads and the ISS. As a cost saving and software reliability strategy, the Boeing Payload Software Organization developed reusable common software where appropriate. These reusable modules included a set of low-level driver software interfaces to 1553B. RS232, RS422, Ethernet buses, HRDL (High Rate Data Link), video switch functionality, telemetry processing, and executive software hosted on the FUC computer. These drivers formed the basis for software development of the HRF, EXPRESS, EXPRESS ARIS, WORF, and HHR RIC executable modules. The reusable RIC common software has provided extensive benefits, including: 1) Significant reduction in development flow time; 2) Minimal rework and maintenance; 3) Improved reliability; and 4) Overall reduction in software life cycle cost. Due to the limited number of crew hours available on ISS for science research, operational efficiency is a critical customer concern. The current method of upgrading RIC software is a time consuming process; thus, an improved methodology for uploading RIC software is currently under evaluation.

Lu, George C.↗

Ultraviolet, optical, and infrared observations of the high-latitude molecular cloud toward HD 210121

Low-resolution UV spectra of the B3 V star HD 210121, located behind the high-latitude molecular cloud DBB 80, yield an extinction curve exhibiting a far-UV rise that is among the steepest known. The apparently simple line of sight affords an excellent opportunity for investigating the absorption and emission characteristics of a single, isolated interstellar cloud characterized by extreme UV extinction. The low ratios of the IRAS bands with respect to I(100 microns) suggest that the radiation field incident on the cloud is lower than the average interstellar field, with further attenuation of the field within the cloud. The apparent relative enhancement of I(12 microns) compared with models of dust emission, and the extremely steep far-UV extinction together are consistent with the presence of an enhanced population of very small grains; the normal calcium depletion suggests that there has been little wholesale grain destruction. The steep far-UV extinction may help to explain the relatively high abundances of CO and CN. The disagreement in density for this cloud inferred from C2 absorption versus that inferred from CO emission may be due in part to clumping in the gas sample by the radio beams.

Welty, Daniel E.↗

Cyclic(alkyl)(amino)carbene ruthenium complexes for Z -stereoselective (asymmetric) olefin metathesis

The first Z-stereoselective catechodithiolate ruthenium complexes containing cyclic(alkyl)(amino)carbene ligands are reported. Isolated in nearly quantitative yields or in situ generated, these catalysts demonstrated remarkable Z selectivity (Z/E ratio up to >98/2) in ring-opening metathesis polymerization (ROMP), ring-opening-cross metathesis (ROCM) and cross-metathesis (CM). Thanks to the efficient chiral HPLC resolution of racemic CAAC-complex precursors, optically pure dithiolated complexes were also synthesized allowing to produce enantioenriched Z-ROCM products in >99/1 Z/E with good levels of enantioselectivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Metrology of Large Parts

As discussed in the first chapter of this book, there are many different methods to measure a part using optical technology. Chapter 2 discussed the use of machine vision to measure macroscopic features such as length and position, which was extended to the use of interferometry as a linear measurement tool in chapter 3, and laser or other trackers to find the relation of key points on large parts in chapter 4. This chapter looks at measuring large parts to optical tolerances in the sub-micron range using interferometry, ranging, and optical tools discussed in the previous chapters. The purpose of this chapter is not to discuss specific metrology tools (such as interferometers or gauges), but to describe a systems engineering approach to testing large parts. Issues such as material warpage and temperature drifts that may be insignificant when measuring a part to micron levels under a microscope, as will be discussed in later chapters, can prove to be very important when making the same measurement over a larger part. In this chapter, we will define a set of guiding principles for successfully overcoming these challenges and illustrate the application of these principles with real world examples. While these examples are drawn from specific large optical testing applications, they inform the problems associated with testing any large part to optical tolerances. Manufacturing today relies on micrometer level part performance. Fields such as energy and transportation are demanding higher tolerances to provide increased efficiencies and fuel savings. By looking at how the optics industry approaches sub-micrometer metrology, one can gain a better understanding of the metrology challenges for any larger part specified to micrometer tolerances. Testing large parts, whether optical components or precision structures, to optical tolerances is just like testing small parts, only harder. Identical with what one does for small parts, a metrologist tests large parts and optics in particular to quantify their mechanical properties (such as dimensions, mass, etc); their optical prescription or design (i.e. radius of curvature, conic constant, vertex location, size); and their full part shape. And, just as with small parts, a metrologist accomplishes these tests using distance measuring instruments such as tape measures, inside micrometers, coordinate measuring machines, distance measuring interferometers; angle measuring instruments such as theodolites, autocollimators; and surface measuring instruments including interferometers, stylus profilers, interference microscopes, photogrammetric cameras, or other tools. However, while the methodology may be similar, it is more difficult to test a large object for the simple reason that most metrologists do not have the necessary intuition. The skills used to test small parts or optics in a laboratory do not extrapolate to testing large parts in an industrial setting any more than a backyard gardener might successfully operate a farm. But first, what is a large part? A simple definition might be the part's size or diameter. For optics and diffuse surface parts alike, the driving constraint is ability to illuminate the part's surface. For reflective convex mirrors, large is typically anything greater than 1 meter. But, for refractive optics, flats or convex mirrors, large is typically greater than 0.5 meter. While a size definition is simple, it may be less than universal. A more nuanced definition might be that a large part is any component which cannot be easily tested in a standard laboratory environment, on a standard vibration isolated table using standard laboratory infrastructure. A micro-switch or a precision lens might be easily measured to nanometer levels under a microscope in a lab, but a power turbine spline or a larger telescope mirror will not fit under that microscope and may not even fit on the table.

Stahl, H. Philip↗

Atmospheric correction of AVIRIS data of Monterey Bay contaminated by thin cirrus clouds

Point source measurements (e.g. sun photometer data, weather station observations) are often used to constrain radiative transfer models such as MODTRAN/LOWTRAN7 when atmospherically correcting AVIRIS imagery. The basic assumption is that the atmosphere is horizontally homogeneous throughout the entire area. If the target area of interest is isolated a distance away from the point measurement position, the calculated visibility and atmospheric profiles may not be characteristic of the atmosphere over the target. AVIRIS scenes are often rejected when cloud cover exceeds 10%. However, if the cloud cover is determined to be primarily cirrus rather than cumulus, in-water optical properties may still be extracted over open ocean. High altitude cirrus clouds are non-absorbing at 744 nm. If the optical properties of the AVIRIS scene can be determined from the 744 nm band itself, the atmospheric conditions during the overflight may be deduced.

Vandenbosch, Jeannette↗