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At least 631 records · Page 35
All sourcesNASA NTRSDOE OSTI
NASA NTRS1972

Surface properties of thermionic electrodes

A quasi-equilibrium model which provides semiquantitative predictions of the oxygen reaction with refractory metals was developed at high temperature and low pressure. Extensive experimental data was obtained on adsorption and work function properties for a wide variety of adsorbates (Cs, K, Na, I, Br, Cl, and O) on several refractory metals (W, Ta, Mo, and Re). Conclusions and recommendations for research on alkali metal adsorption, oxygen adsorption, and adsorption of cesium - oxygen mixtures are included.

Stickney, R. E.↗
NASA NTRS1972

Purfication kinetics of beryllium during vacuum induction melting

The kinetics of evaporation in binary alloys were quantitatively treated. The formalism so developed works well for several systems studied. The kinetics of purification of beryllium was studied through evaporation data actually acquired during vacuum induction melting. Normal evaporation equations are shown to be generally valid and useful for understanding the kinetics of beryllium purification. The normal evaporation analysis has been extended to cover cases of limited liquid diffusion. It was shown that under steady-state evaporation, the solute concentration near the surface may be up to six orders of magnitude different from the bulk concentration. Corrections for limited liquid diffusion are definitely needed for the highly evaporative solute elements, such as Zn, Mg, and Na, for which the computed evaporation times are improved by five orders of magnitude. The commonly observed logarithmic relation between evaporation time and final concentration further supports the validity of the normal evaporation equations.

Mukherjee, J. L.↗
NASA NTRS1973

High field superconductivity in alkali metal intercalates of MoS2

In the search for better high temperature, high critical field superconductors, a class of materials was found which have layered structures and can be intercalated with various elements and compounds. Since a large number of compounds can be formed, intercalation provides a method of control of superconducting properties. They also provide the possible medium for excitonic superconductivity. Results of magnetic field studies are presented on alkali metal (Na, K, Rb, and Cs) intercalated MoS2 (2H polymorph).

Woollam, J. A.↗
NASA NTRS1972

The moon as a high temperature condensate

The accretion during condensation mechanism is used to explain the differences in composition of the terrestrial planets and the moon. Many of the properties of the moon, including the enrichment in Ca, Al, Ti, U, Th, Ba, Sr and the REE and the depletion in Fe, Rb, K, Na and other volatiles can be understood if the moon represents a high temperature condensate from the solar nebula. Thermodynamic calculations show that Ca, Al and Ti rich compounds condense first in a cooling nebula. The high temperature mineralogy is gehlenite, spinel perovskite, Ca-Al-rich pyroxenes and anorthite. The model is consistent with extensive early melting, shallow melting at 3 A.E. and with presently high speed internal temperatures. It is predicted that the outer 250 km is rich in plagioclase and FeO. The low iron content of the interior in this model raises the interior temperatures estimated from electrical conductivity by some 800 C. The lunar crust is 80 percent gabbroic anorthosite, 20 percent basalt and is about 250-270 km thick. The lunar mantle is probably composed of spinel, merwinite and diopside with a density of 3.4 g/cu cm.

Anderson, D. L.↗
NASA NTRS1973

Nighttime ion composition measurements at the geomagnetic equator

Two ion composition profiles, representative of the nighttime equatorial ionosphere between 90 km and 300 km, are presented. These profiles were obtained by two rocket-borne ion mass spectrometers on a single night for solar zenith angles of 112 deg and 165 deg. For both flights, the principal ion above 200 km is O(+). The downward drift of the atomic ions O(+) and N(+), coinciding with the postsunset lowering of the F2 peak, is observed through an enhancement of the density of O(+) at altitudes above 200 km and N(+) above 240 km. Below the drift region, O(+) and N(+) are observed in concentrations larger than expected. The NO(+) altitude distribution retains its shape throughout the night, and below 210 km, is the principal ion. The behavior of O2(+) can be explained by the O(+), electron density and theoretical neutral nitric oxide concentrations. Light metallic ions, including Mg(+), Na(+), and possibly Si(+), are observed to altitudes approaching 300 km and are affected by vertical drift.

Goldberg, R. A.↗
NASA NTRS1973

Structural and spectral studies of sunspots

The work is reported in the multicolor photometry of umbral cores, and the residual intensity midway between the Na D1 and D2 lines. The photelectric magnetometer observations, the generation of umbral flashes and penumbral running waves, and the work on sunspot interior modes with Alfen wave emission are discussed.

Wyller, A. A.↗
NASA NTRS1972

Chemistry and particle track studies of Apollo 14 glasses.

The abundance and the composition of Apollo 14 glasses have been studied. Glass particles were analyzed for Si, Ti, Al, Fe, Mn, Mg, Na, and K by electron microprobe analysis. The refractive indices of 26 particles were determined by the oil immersion method. Track analyses have been carried out in order to determine the uranium content and the radiation history of glass particles. The proper identification of galactic and solar flare nuclei tracks makes it possible to estimated residence times of the glass particles in the top layer of the lunar soil.

Glass, B. P.↗
NASA NTRS1973

Alkali metal intercalates of molybdenum disulfide.

Study of some of the physicochemical properties of compounds obtained by subjecting natural molybdenite and single crystals of molybdenum disulfide grown by chemical vapor transport to intercalation with the alkali group of metals (Li, Na, K, Rb, and Cs) by means of the liquid ammonia technique. Reported data and results include: (1) the intercalation of the entire alkali metal group, (2) stoichiometries and X-ray data on all of the compounds, and (3) superconductivity data for all the intercalation compounds.

Somoano, R. B.↗
NASA NTRS1972

Cosmogeneic radionuclides in the Havero meteorite.

An 87-gram sample of the Havero ureilite has been analyzed by nondestructive gamma-ray spectrometry. The results of the measurements, in dpm/kg at time of fall, are: Na-22, 71 plus or minus 3; Al-26, 43 plus or minus 3; Sc-46, 3.4 plus or minus 2.1; Mn-54, 35 plus or minus 6; Co-60, less than or equal to 0.7, 2 sigma limit. Havero has 77 plus or minus 14% of the Al-26 activity calculated for its chemical composition. When averaged with previously reported analyses of Goalpara and Novo Urei, ureilites as a class have 74 plus or minus 7% of their expected Al-26 activity. The depletion in Al-26 could be the coincidental result of identical 'shielding' effects in three meteorites of apparently very different preatmospheric sizes. Alternatively, ureilites may have been exposed to a lower cosmic-ray flux than that experienced by most chondrites, probably the result of characteristically different orbits.

Cressy, P. J., Jr.↗
NASA NTRS1973

Metallic ions in the equatorial ionosphere.

Four positive ion composition measurements of the equatorial E region at Thumba, India, are presented. During the day, the major ions between 90 and 125 km are NO+ and O2+. The relative concentrations are similar to those observed at midlatitudes but exhibit unusual structural behavior with altitude. A metallic ion layer centered at 92 km is found to contain Mg+, Fe+, Ca+, K+, Al+, Na+, and possibly Si+ ions. The layer is explained in terms of a similarly shaped altitude distribution of neutral atoms that are photoionized and charge exchanged with NO+ and O2+. Three-body reactions form molecular metallic ions that are rapidly lost by dissociative ion-electron recombination.

Aikin, A. C.↗
NASA NTRS1973

Ouabain-sensitive component of brown fat thermogenesis.

The study discussed was undertaken to quantify the amount of energy utilized by the ouabain-sensitive Na(+)-K(+) membrane pump during the norepinephrine-induced thermogenesis of brown adipose tissue. The data obtained indicate that the observed inhibition of the catecholamine-induced increase in brown fat thermogenesis by ouabain does not reflect an inhibition of cyclic AMP synthesis.

Horwitz, B. A.↗
NASA NTRS1973

The moon as a high temperature condensate.

The accretion during condensation mechanism, if it occurs during the early over-luminous stage of the sun, can explain the differences in composition of the terrestrial planets and the moon. An important factor is the variation of pressure and temperature with distance from the sun, and in the case of the moon and captured satellites of other planets, with distance from the median plane. Current estimates of the temperature and pressure in the solar nebula suggest that condensation will not be complete in the vicinity of the terrestrial planets, and that depending on location, iron, magnesium silicates and the volatiles will be at least partially held in the gaseous phase and subject to separation from the dust by solar wind and magnetic effects associated with the transfer of angular momentum just before the sun joins the Main Sequence. Many of the properties of the moon, including the 'enrichment' in Ca, Al, Ti, U, Th, Ba, Sr and the REE and the 'depletion' in Fe, Rb, K, Na and other volatiles can be understood if the moon represents a high temperature condensate from the solar nebula.

Anderson, D. L.↗
NASA NTRS1974

Ion composition and drift observations in the nighttime equatorial ionosphere

The first in situ measurements of ion composition in the nighttime equatorial E and F region ionospheres (90-300 km) are presented and discussed. These profiles were obtained by two rocket-borne ion mass spectrometers launched from Thumba, India on March 9-10, 1970 at solar zenith angles of 112 deg and 165 deg. Ionosonde data established that the composition was measured at times bounding a period of F region downward drift. During this period the ions O(+) and N(+) were enhanced by one to three orders of magnitude between 220 and 300 km. Below the drift region (200 km), O(+) ceased to be the major ionic constituent, but the concentrations of O(+) and N(+) remained larger than predicted from known radiation sources and loss processes. Here also, both the O2(+) and NO(+) profiles retained nearly the same shape and magnitude throughout the night in agreement with theories assuming scattered UV radiation to be the maintaining source. Light metallic ions including Mg(+), Na(+) and possibly Si(+) were observed to altitude approaching 300 km, while the heavier ions Ca(+) and K(+) were seen in reduced quantity to 200 km. All metal ion profiles exhibited changes which can be ascribed to vertical drifting.

Goldberg, R. A.↗
NASA NTRS1973

Coordinated observations of chemical releases from the ground and from aircraft at high latitudes

The ground observations of the Na-Li trail released from a Nike-Apache rocket obtained by the Geophysical Institute are discussed. By using the nominal trajectory for a 60 pound payload and the particular rocket, a best fit trajectory was determined based on the Ester Dome photographic data, launch time and earth-sun geometrical shadow height. From these calculations, the height of obvious features along the trail were determined and their velocity estimated. A clockwise rotation of the velocity vector with increasing height was observed. Velocities deduced at various altitudes were then compared to meter radar data also obtained during this period. The comparisons of these two neutral wind measurements techniques are satisfactory.

Romick, G. J.↗
NASA NTRS1973

Gamma ray spectrometer experiment, NaI(Tl) detector crystal activation

Preliminary results are presented of data on the extent of the cosmic ray-induced activity obtained by a sodium iodide thallium-activated crystal flown onboard the Apollo 17 command module. Qualitative identification is reported for the following: Na-24, I-123, I-124, I-125, I-126, and Xe-127.

Trombka, J. I.↗
NASA NTRS1974

Cometary coma ions

For comets whose nuclei are composed of water ice conglomerates it is shown that the ion H3O(+) can predominate to distances of 5000 km in the subsolar direction. Beyond this distance H2O(+) is the most important ion. The crossover point is a sensitive function of the rate of evaporation from the nucleus. The presence of ammonia or metals such as sodium, in concentrations greater than 0.1% H2O, can lead to NH4(+) and Na(+) ions.

Aikin, A. C.↗
NASA NTRS1974

Investigation of laser dynamics, modulation and control by means of intra-cavity time varying perturbation

Projects aimed at the generation of tunable visible, infrared, and ultraviolet light, and on the control of this light by means of novel mode-locking and modulation techniques are discussed. During this period the following projects have been active: (1) studies of transient mode-locking of the Nd:YAG laser and the application of short optical pulses; (2) experimental investigations of the Na-Xe excimer laser system; (3) further development of techniques for vacuum ultraviolet holography; and (4) theoretical and initial experimental studies of a new device which should prove very useful for both infrared up-conversion and generation of tunable UV radiation - a two-photon resonantly pumped frequency converter.

Harris, S. E.↗
NASA NTRS1974

Scanner observations of selected cool stars

Photoelectric spectral scans at 30-A resolution of 9 dwarfs, 10 giants and 6 supergiants with spectral types GO to M5 were presented. All stars were observed every 4 A from wavelength 3300 to wavelength 7000. Absorption features at this resolution coincide with: strong atomic lines of Fe 1,11, Ca 1,11, Mg 1, and Na 1; vibrational bands of the electronic transitions of TiO, MgH, CaH, SiH, AlH, Cn, Ch, C2, OH, and NH. The dependence of the wavelength 3740 Fe 1 blend and the wavelength 3440 depression on temperature is discussed.

Fay, T. D., Jr.↗