Using of X-ray imaging and CT methods for locating life in complex mineralogical and lithic environments
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topography life detection↗
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Rheological Model for a Heterogeneous Lower Crust with a Quartzo-Feldspathic Mineralogy
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Landers-Big Bear Earthquake earthquake rheology se↗
Primary Mineralogical and Chemical Characteristics of the Major K/T and Late Eocene Impact Deposits
Three well-characterized, distal impact deposits at the WT boundary and in upper Eocene sediments serve as a baseline for understanding other proposed impact deposits. All contain abundant spherules, evidence of shock metamorphism, and the largest have significant extraterrestrial components (ETCs). The K/T and the Eocene cpx-spherule (cpxS) deposits are global - likely from the events that produced the 180 km Chicxulub and 100 km Popigai craters. The Eocene North American microtektite (NAM) deposit is regional and likely from the event that produced the 45 km Chesapeake Bay crater. These deposits all contain abundant spherules formed from both shock-melted target and mixtures of target and projectile in the ejecta plume. Spherules constitute most of the mass of the distal ejecta. K/T spherules in regional deposits around the Gulf of Mexico are from low-velocity, target-rich ejecta. These can be a few mm in size and form deposits 10s of cm thick. Globally deposited KIT spherules from the plume (typically a few hundred micron size) are both target- and projectile-rich. When well preserved, the global deposits are 3 mm thick. Eocene cpxS deposits are similar to distal K/T with both target- and projectile-rich varieties (Le., glassy microtektite, and cpx spherules). They are smaller on average than WT spherules, concentrated in the 125-250 micron and smaller fractions. They are invariably bioturbated, but the initial deposit was probably less than 1 mm thick. The NAM are composed entirely of target-rich glass. They are similar in size to the cpxS. Size is an important criterion for distal ejecta because droplet size in the impact plume is proportional to the energy of the impact. Both the JUT and cpxS deposits are characterized by well-defined ETCs, commonly measured by Ir. The total Ir deposited is about 55 ng per square cm in WT sediments, and about 11 ng for the cpxS layer. This 5/1 proportion in Ir is generally consistent with the approx.1.8/1 ratio in crater diameters. The NAM have no significant ETC. This may be a function of the smaller impact. It indicates there was no significant projectile-rich plume deposit.
Kyte, Frank T.↗
An East to West Mineralogical Trend in Mars Exploration Rover Spirit Moessbauer Spectra of Home Plate
Home Plate is a light-toned plateau approx.90 m in diameter within the Inner Basin of the Columbia Hills in Gusev crater on Mars. It is the most extensive exposure of layered bedrock encountered by Spirit to date, and it is composed of clastic rocks of moderately altered alkali basalt composition, enriched in some highly volatile elements. Textural observations suggest an explosive origin and geochemical observations favor volcanism, probably a hydrovolcanic explosion [1]. Since it first arrived at Home Plate on sol 744, Spirit has circumnavigated the plateau (Fig. 1) and is now, since sol 1410, resting at its Winter Haven 3 location at the north end of Home Plate. Results: The MER Moessbauer spectrometers determine Fe oxidation states, identify Fe-bearing mineral phases and quantify the distribution of Fe among oxidation states and mineral phases [2]. Moessbauer spectra of Home Plate bedrock were obtained in five different locations from nine different targets (Fig. 1): Barnhill Ace, Posey Manager, and James Cool Papa Bell Stars at the northwest side of Home Plate; Pesapallo, June Emerson, and Elizabeth Emery on the east side; Texas Chili on the south side; Pecan Pie on the west side; and Chanute on the north side.
Schroder, C.↗
Chemostratigraphy and Fe Mineralogy of the Victoria Crater Duck Bay Section: Opportunity APXS and Moessbauer Results
Meridiani Planum is a vast plain of approximately horizontally bedded sedimentary rocks composed of mixed and reworked basaltic and evaporitic sands containing secondary, diagenetic minerals [e.g., 1-5]. Because bedding planes are subparallel to topography, investigation of contiguous stratigraphy requires examining exposures in impact craters. Early in the mission (sols 130-317), Opportunity was commanded to do detailed study of exposed outcrops in Endurance crater, including the contiguous Karatepe section at the point of ingress. Just over 1000 sols later and roughly 7 km to the south, the rover is being commanded to do a similar study of the Duck Bay section of Victoria crater. Here we report on the preliminary results from the Alpha Particle X-ray Spectrometer (APXS) and Moessbauer instruments.
Mittlefehldt, D. W.↗
The Rio Tinto Basin, Spain: Mineralogy, Sedimentary Geobiology, and Implications for Interpretation of Outcrop Rocks at Meridiani Planum, Mars
Exploration by the NASA rover Opportunity has revealed sulfate- and hematite-rich sedimentary rocks exposed in craters and other surface features of Meridiani Planum, Mars. Modern, Holocene, and Plio-Pleistocene deposits of the Rio Tinto, southwestern Spain, provide at least a partial environmental analog to Meridiani Planum rocks, facilitating our understanding of Meridiani mineral precipitation and diagenesis, while informing considerations of martian astrobiology. Oxidation, thought to be biologically mediated, of pyritic ore bodies by groundwaters in the source area of the Rio Tinto generates headwaters enriched in sulfuric acid and ferric iron. Seasonal evaporation of river water drives precipitation of hydronium jarosite and schwertmannite, while (Mg,Al,Fe(sup 3+))-copiapite, coquimbite, gypsum, and other sulfate minerals precipitate nearby as efflorescences where locally variable source waters are brought to the surface by capillary action. During the wet season, hydrolysis of sulfate salts results in the precipitation of nanophase goethite. Holocene and Plio-Pleistocene terraces show increasing goethite crystallinity and then replacement of goethite with hematite through time. Hematite in Meridiani spherules also formed during diagenesis, although whether these replaced precursor goethite or precipitated directly from groundwaters is not known. The retention of jarosite and other soluble sulfate salts suggests that water limited the diagenesis of Meridiani rocks. Diverse prokaryotic and eukaryotic microorganisms inhabit acidic and seasonally dry Rio Tinto environments. Organic matter does not persist in Rio Tinto sediments, but biosignatures imparted to sedimentary rocks as macroscopic textures of coated microbial streamers, surface blisters formed by biogenic gas, and microfossils preserved as casts and molds in iron oxides help to shape strategies for astrobiological investigation of Meridiani outcrops.
Fernandez-Remolar, David C.↗
Optical Design of a Compact Imaging Spectrometer for Planetary Mineralogy
We present the design of a compact, wide-angle pushbroom imaging spectrometer suitable for exploration of solar system bodies from low orbit. The spectrometer is based on a single detector array with a broadband response that covers the range 400 to 3000 nm and provides a spectral sampling of 10 nm. The telescope has a 24-deg field of view with 600 spatially resolved elements (detector pixels). A specially designed convex diffraction grating permits optimization of the signal-to-noise ratio through the entire spectral band. Tolerances and design parameters permit the achievement of high uniformity of response through field and wavelength. The spectrometer performance is evaluated in terms of predicted spectral and spatial response functions and from the point of view of minimizing their variation through field and wavelength. The design serves as an example for illustrating the design principles specific to this type of system.
space optics↗
NEOCAM: Near Earth Object Chemical Analysis Mission: Bridging the Gulf between Telescopic Observations and the Chemical and Mineralogical Compositions of Asteroids or Diogenes A: Diagnostic Observation of the Geology of Near Earth Spectrally-Classified Asteroids
Studies of meteorites have yielded a wealth of scientific information based on highly detailed chemical and isotopic studies possible only in sophisticated terrestrial laboratories. Telescopic studies have revealed an enormous (greater than 10(exp 5)) number of physical objects ranging in size from a few tens of meters to several hundred kilometers, orbiting not only in the traditional asteroid belt between Mars and Jupiter but also throughout the inner solar system. Many of the largest asteroids are classed into taxonomic groups based on their observed spectral properties and are designated as C, D. X, S or V types (as well as a wide range in sub-types). These objects are certainly the sources far the meteorites in our laboratories, but which asteroids are the sources for which meteorites? Spectral classes are nominally correlated to the chemical composition and physical characteristics of the asteroid itself based on studies of the spectral changes induced in meteorites due to exposure to a simulated space environment. While laboratory studies have produced some notable successes (e.g. the identification of the asteroid Vesta as the source of the H, E and D meteorite classes), it is unlikely that we have samples of each asteroidal spectral type in our meteorite collection. The correlation of spectral type and composition for many objects will therefore remain uncertain until we can return samples of specific asteroid types to Earth for analyses. The best candidates for sample return are asteroids that already come close to the Earth. Asteroids in orbit near 1 A.U. have been classified into three groups (Aten, Apollo & Amor) based on their orbital characteristics. These Near Earth Objects (NEOs) contain representatives of virtually all spectral types and sub-types of the asteroid population identified to date. Because of their close proximity to Earth, NEOs are prime targets for asteroid missions such as the NEAR-Shoemaker NASA Discovery Mission to Eros and the Japanese Hyabusa Mission to Itokawa. Also due to their close proximity to Earth, NEOs constitute the most likely set of celestial objects that will impact us in the relatively near future.
Nuth, Joseph A.↗
Spitzer IRS (8-30 micron) Spectra of Basaltic Asteroids 1459 Magnya and 956 Elisa: Mineralogy and Thermal Properties
We report preliminary results from Spitzer IRS (Infrared Spectrograph) spectroscopy of 956 Elisa, 1459 Magnya, and other small basaltic asteroids with the Spitzer IRS. Program targets include members of the dynamical family of the unique large differentiated asteroid 4 Vesta ("Vestoids"), several outer-main-belt basaltic asteroids whose orbits exclude them from originating on 4 Vesta, and the basaltic near-Earth asteroid 4055 Magellan. The preliminary thermal model (STM) fit to the 5--35 micron spectrum of 956 Elisa gives a radius of 5.4 +/- 0.3 km and a subsolar- point temperature of 282.2 +/- 0.5 K. This temperature corresponds to eta approximately equals 1.06 +/- 0.02, which is substantially higher than the eta approximately equals 0.756 characteristic of large main-belt asteroids. Unlike 4 Vesta and other large asteroids, therefore, 956 Elisa has significant thermal inertia in its surface layer. The wavelength of the Christiansen feature (emissivity maximum near 9 micron), the positions and shapes of the narrow maxima (10 micron, 11 micron) within the broad 9--14 micron silicate band, and the 19--20 micron minimum are consistent with features found in the laboratory spectra of diogenites and of low-Ca pyroxenes of similar composition (Wo<5, En50-En75).
Lim, Lucy F.↗
Mineralogy of Antarctica Dry Valley Soils: Implications for Pedogenic Processes on Mars
The Antarctic Dry Valleys (ADVs) located in the Transantarctic Mountains are the coldest and driest locations on Earth. The mean annual air temperature is -20 C or less and the ADVs receive 100mm or less of precipitation annually in the form of snow. The cold and dry climate in the ADVs is one of the best terrestrial analogs for the climatic conditions on Mars [2]. The soils in the ADVs have been categorized into three soil moisture zones: subxerous, xerous and ultraxerous. The subxerous zone is a coastal region in which soils have ice-cemented permafrost relatively close to the surface. Moisture is available in relatively large amounts and soil temperatures are above freezing throughout the soil profile (above ice permafrost) in summer months. The xerous zone, the most widespread of the three zones, is an inland region with a climate midway between the subxerous and ultraxerous. The soils from this zone have dry permafrost at moderate depths (30-75cm) but have sufficient water in the upper soil horizons to allow leaching of soluble materials. The ultraxerous zone is a high elevation zone, where both temperature and precipitation amounts are very low resulting in dry permafrost throughout the soil profile. The three moisture regime regions are similar to the three microclimatic zones (coastal thaw, inland mixed, stable upland) defined by Marchant and Head.
Quinn, J. E.↗
Morphology and Distribution of Volcanic Vents in the Orientale Basin from Chandrayaan-1 Moon Mineralogy Mapper (M3) Data
One of the most fundamental questions in the geological and thermal evolution of the Moon is the nature and history of mantle melting and its relationship to the formation and evolution of lunar multi-ringed basins. Mare volcanic deposits provide evidence for the nature, magnitude and composition of mantle melting as a function of space and time [1]. Many argue that mantle partial melts are derived from depths well below the influence of multiringed basin impact events [1], while others postulate that the formation of these basins can cause mantle perturbations that are more directly linked to the generation ascent and eruption of mare basalts [2,3]. In any case, longer-term basin evolution will considerably influence the state and orientation of stress in the lithosphere, and the location of mare volcanic vents in basins as a function of time [4]. Thus, the location, nature and ages of volcanic vents and deposits in relation to multi-ringed impact basins provides evidence for the role that these basins played in the generation of volcanism or in the influence of the basins on surface volcanic eruption and deposit concentration. Unfortunately, most lunar multi-ringed impact basins have been eroded by impacts or filled with lunar mare deposits [5-8], with estimates of the thickness of mare fill extending up to more than six km in the central part of some basins [9-11]. The interior of most basins (e.g., Crisium, Serenitatis, Imbrium, Humorum) are almost completely covered and obscured. Although much is known about the lava filling of multi-ringed basins, and particularly the most recent deposits [5-8], little is known about initial stages of mare volcanism and its relationship to the impact event. One multi-ringed basin, Orientale, offers substantial clues to the relationships of basin interiors and mare basalt volcanism.
Head, James↗
The Mineralogy of Circumstellar Silicates Preserved in Cometary Dust
Interplanetary dust particles (IDPs) contain a record of the building blocks of the solar system including presolar grains, molecular cloud material, and materials formed in the early solar nebula. Cometary IDPs have remained relatively unaltered since their accretion because of the lack of parent body thermal and aqueous alteration. We are using coordinated transmission electron microscope (TEM) and ion microprobe studies to establish the origins of the various components within cometary IDPs. Of particular interest is the nature and abundance of presolar silicates in these particles because astronomical observations suggest that crystalline and amorphous silicates are the dominant grain types produced in young main sequence stars and evolved O-rich stars. Five circumstellar grains have been identified including three amorphous silicate grains and two polycrystalline aggregates. All of these grains are between 0.2 and 0.5 micrometers in size. The isotopic compositions of all five presolar silicate grains fall within the range of presolar oxides and silicates, having large (17)O-enrichments and normal (18)O/(16)O ratios (Group 1 grains from AGB and RG stars). The amorphous silicates are chemically heterogeneous and contain nanophase FeNi metal and FeS grains in a Mg-silicate matrix. Two of the amorphous silicate grains are aggregates with subgrains showing variable Mg/Si ratios in chemical maps. The polycrystalline grains show annealed textures (equilibrium grains boundaries, uniform Mg/Fe ratios), and consist of 50-100 nm enstatite and pyrrhotite grains with lesser forsterite. One of the polycrystalline aggregates contains a subgrain of diopside. The polycrystalline aggregates form by subsolidus annealing of amorphous precursors. The bulk compositions of the five grains span a wide range in Mg/Si ratios from 0.4 to 1.2 (avg. 0.86). The average Fe/Si (0.40) and S/Si (0.21) ratios show a much narrower range of values and are approximately 50% of their solar abundances. The latter observation may indicate a decoupling of the silicate and sulfide components in grains that condense in stellar outflows. The amorphous silicate grains described here were not extensively affected by irradiation, sputtering, or thermal processing and may represent relatively pristine circumstellar grains. They are strong candidates for the "dirty silicates" in astronomical observations of circumstellar dust shells. The polycrystalline grains were originally amorphous silicate grains that were likely annealed in the early solar nebula but the processing was not sufficient to erase their anomalous oxygen isotopic compositions.
Keller, L. P.↗
Definitive Mineralogy from the Mars Science Laboratory Chemin Instrument
The Mars Science Laboratory (MSL) rover will land in Gale Crater on Mars in August 2012. The planned landing site is an alluvial fan near the base of the crater's central mound. Orbital remote sensing of this 5 km high mound indicates the presence of hydrated sulfates, interstratified with smectite and hematite-bearing layers. Minerals formed in an aqueous environment are of particular interest given that water is a fundamental ingredient of living systems and that MSL's prime science objective is to investigate martian habitability.
Yen, A. S.↗
The Spatial Distribution of Organic Matter and Mineralogical Relationships in Carbonaceous Chondrites
Organic matter present within primitive carbonaceous meteorites represents the complex conglomeration of species formed in a variety of physically and temporally distinct environments including circumstellar space, the interstellar medium, the Solar Nebula & Jovian sub-nebulae and asteroids. In each case, multiple chemical pathways would have been available for the synthesis of organic molecules. Consequently these meteorites constitute a unique record of organic chemical evolution in the Universe and one of the biggest challenges in organic cosmochemistry has been in deciphering this record. While bulk chemical analysis has provided a detailed description of the range and diversity of organic species present in carbonaceous chondrites, there is virtually no hard experimental data as to how these species are spatially distributed and their relationship to the host mineral matrix, (with one exception). The distribution of organic phases is nevertheless critical to understanding parent body processes. The CM and CI chondrites all display evidence of low temperature (< 350K) interaction with aqueous fluids, which based on O isotope data, flowed along thermal gradients within the respective parent bodies. This pervasive aqueous alteration may have led to aqueous geochromatographic separation of organics and synthesis of new organics coupled to aqueous mineral alteration. To address such issues we have applied the technique of microprobe two-step laser desorption / photoionization mass spectrometry (L2MS) to map in situ the spatial distribution of a broad range of organic species at the micron scale in the freshly exposed matrices of the Bells, Tagish Lake and Murchison (CM2) carbonaceous chondrites.
Clemett, S. J.↗
Overview of Vesta Mineralogy Diversity
4 Vesta is known to have a surface of basaltic material through visible/near-infrared reflectance spectroscopy (1). Vesta s spectrum has strong absorption features centered near 0.9 and 1.9 m, indicative of Fe-bearing pyroxenes. The spectra of HED (howardite, eucrite and diogenite) meteorites have similar features (1). This led to the hypothesis that Vesta was the parent body of the HED clan (2,3) and the discovery of a dynamical Vesta family of asteroids (Vestoids) provides a further link between Vesta and HEDs (4). Data from the Dawn VIR (Visible InfraRed mapping Spectrometer) (5) characterize and map the mineral distribution on Vesta, strengthen the Vesta - HED linkage and provide new insights into Vesta s formation and evolution.
DeSanctis, M. C.↗
Vesta Mineralogy after Dawn Global Observations
The Dawn mission has completed its mapping phases at Vesta and millions of spectra have been acquired by the Visible and InfraRed Mapping Spectrometer, VIR(1). VIR characterizes and maps the mineral distribution on Vesta -strengthening the Vesta HED linkage- and provides new insights into Vesta s formation and evolution(2,3). VIR spectra are dominated by pyroxene absorptions near 0.9 and 2.0 m and large thermal emission beyond 3.5 m. Although almost all surface materials exhibit howardite-like spectra, some large regions can be interpreted to be richer in eucritic (basaltic) material and others richer in diogenititic (Mg-orthopyroxenitic) material. The Rheasilvia basin contains Mg-pyroxene-rich terrains for example. Vesta' s surface shows considerable diversity at local scales. Many bright and dark areas(3,4) are associated with various geological features and show remarkably different morphology. Moreover, VIR detected statistically significant, but weak, variations at 2.8 m that have been interpreted as indicating the presence of OH-bearing phases on the surface(5). The OH distribution is uneven with large regions lacking this absorption feature. Associations of 2.8 m band with morphological structures indicate complex process responsible for OH. Vesta exhibits large spectral variations that often correlate with geological structures, indicating a complex geological and evolutionary history, more similar to that of the terrestrial planets than to other asteroids visited by spacecrafts.
ChristinaDeSanctis, Maria↗
Analysis of Organic Molecules Extracted from Mars Analogues and Influence of Their Mineralogy Using N-Methyl-N-(tert-butyldimethylsilyl)Trifluoroacetamide Derivatization Coupled with Gas Chromatography Mass Spectrometry in Preparation for the Sample Analysis at Mars Derivatization Experiment on the Mars Science Laboratory Mission
The search for complex organic molecules on Mars, including important biomolecules such as amino acids and carboxylic acids will require a chemical extraction and derivatization step to transform these organic compounds into species that are sufficiently volatile to be detected by gas chromatography mass spectrometry (GCMS). We have developed, a one-pot extraction and chemical derivatization protocol using N-methyl-N-(tert-butyldimethylsilyl)trifluoroacetamide (MTBSTFA) and dimethylformamide (DMF) for the Sample Analysis at Mars (SAM) experiment on the Mars Science Laboratory (MSL). The temperature and duration the derivatization reaction, pre-concentration of chemical derivatives, and gas chromatographic separation parameters have been optimized under SAM instrument design constraints. MTBSTFA/DMF extraction and derivatization at 300 C for several minutes of a variety of terrestrial Mars analogue materials facilitated the detection of amino acids and carboxylic acids in a surface soil sample collected from the Atacama Desert and a carbonate-rich stromatolite sample from Svalbard. However, the rapid reaction of MTBSTFA with water in several analogue materials that contained high abundances of hydrated minerals and the possible deactivation of derivatized compounds by iron oxides, as detected by XRD/XRF using the CheMin field unit Terra, proved to be highly problematic for the direct extraction of organics using MTBSTFA, The combination of pyrolysis and two different chemical derivatization methods employed by SAM should enable a wide range of organic compounds to be detected by GCMS if present on Mars,
Stalport, F.↗
Mineralogy of Meteorite Groups: An Update
Twenty minerals that were not included in the most recent list of meteoritic minerals have been reported as occurring in meteorites. Extraterrestrial anhydrous Ca phosphate should be called menillite, not whitlockite.
Rubin, Alan E.↗