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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 631 records · Page 35
All sourcesNASA NTRSDOE OSTI
NASA NTRS2019

Advances in Low-Cost Manufacturing and Folding of Solar Sail Membranes

Solar sail membranes must have a high area-to-mass ratio and high solid volume fraction when stowed. In order to meet mission requirements, current solar sail projects, such as NASA’s Near Earth Asteroid Scout, require metallized sail membranes with thicknesses on the order of 2-3 μm. These very thin membranes do not retain creases like thicker membranes, solar panels, or paper models. For Cubesat-class spacecraft, volume, rather than mass, is often the driving requirement for deployable structural elements. These two factors make it both difficult and highly desirable to characterize the practical differences between solar sail membrane packaging methods with laboratory demonstrations. This paper presents lessons gathered from lab work with solar sail membranes at a 10-meter scale.

Stohlman, Olive R.↗
NASA NTRSDate not supplied

Advances in Low-Cost Manufacturing and Folding of Solar Sail Membrane

Solar sail membranes must have a high area-to-mass ratio and high solid volume fraction when stowed. In order to meet mission requirements, current solar sail projects, such as the NASA Near Earth Asteroid Scout and Advanced Composite Solar Sail System, require metallized sail membranes with thicknesses on the order of 2-3 μm. These very thin membranes do not retain creases like thicker membranes, solar panels, or paper models. For CubeSat-class spacecraft, volume, rather than mass, is often the driving requirement for deployable structural elements. These two factors make it both difficult and highly desirable to characterize the practical differences between various membrane designs and packaging methods with laboratory demonstrations. This paper presents lessons gathered from lab work on solar sail membranes at a 9-meter scale. Among other results, laboratory deployment of a full-scale sail quadrant revealed important differences between seaming methods.

Olive R Stohlman↗
NASA NTRSDate not supplied

Unleashing the Power of Anaerobic–Phototrophic Membrane Bioreactors for Sustainable Bioregenerative Life Support

Using the core ideals of bioregenerative life support, an anaerobic–phototrophic membrane bioreactor (APMBR) has been designed and operated at NASA’s Kennedy Space Center to treat complex wastewaters with the goal of closing water and nutrient cycles on early planetary bases. The system combined the previously operated anaerobic membrane bioreactor and the phototrophic membrane bioreactor that have been detailed in presentations at previous ICES conferences. This newly combined system is able to treat complex wastewater with completely automated controls on a small footprint. The treatment of wastes in this APMBR is as follows: (1) the waste enters the anaerobic subsystem, where solids are hydrolyzed and carbon is removed via anaerobic digestion, (2) an ultrafiltration membrane is used to separate the solids and the recovered water, (3) the effluent from the anaerobic subsystem is fed to the phototrophic subsystem on command, (4) the algae–bacteria consortium aids in nitrification in the recovered water, and (5) an ultrafiltration membrane is used to separate the algae and the final recovered water. The recovered water from the APMBR is rich in nutrients, making it a sustainable source of fertilizer for downstream hydroponic systems. This conference paper will detail the design and operation of the APMBR as a bioregenerative alternative to physical–chemical systems or bag and storage systems. In this paper, data will be presented on subsystem water quality, membrane performance, and effluent quality. Overall, the APMBR has the ability to treat wastewater using a combination of biological and filtration technologies that allow for higher removal efficiencies, low consumable use, and small footprint.

Jason A. Fischer↗
DOE OSTI2021

Superhydrophobic coated micro-porous carbon foam membrane and method for solar-thermal driven desalination

A solar membrane distillation apparatus includes a housing comprising a light transmitting wall. A solar distillation membrane is positioned in the housing to receive solar radiation transmitted through the light transmitting wall. The solar distillation membrane includes a porous graphitic foam and a coating of a hydrophobic composition on the surface and pores of the graphitic foam. A water chamber within the housing is provided for retaining water adjacent to the solar distillation membrane. A vapor chamber is provided for collecting water vapor distilling through the solar distillation membrane. A condenser is provided for condensing distilled water vapor from the vapor chamber into liquid water. A separation membrane and a method of solar distillation are also disclosed.

Jang, Gyoung Gug↗
DOE OSTI2021

Durable graphene oxide membranes

Embodiments described herein relate generally to durable graphene oxide membranes for fluid filtration. For example, the graphene oxide membranes can be durable under high temperatures non-neutral pH, and/or high pressures. One aspect of the present disclosure relates to a filtration apparatus comprising: a support substrate, and a graphene oxide membrane disposed on the support substrate. The graphene oxide membrane has a first lactose rejection rate of at least 50% with a first 1 wt % lactose solution at room temperature. The graphene oxide membrane has a second lactose rejection rate of at least 50% with a second 1 wt % lactose solution at room temperature after the graphene oxide membrane is contacted with a solution that is at least 80° C. for a period of time.

Frayne, Stephen↗
DOE OSTI2022

Optimizing the Fabrication of Electrospun Nanofibrous Membrane Using Fractional Factorial Design

Electrospinning, a simple and easily tunable technique that utilizes the force balance between the electrostatic force and the solution surface tension to fabricate membranes out of 1D nanostructured fibers, has garnered much interest especially from the nanotechnology community. Depending on the morphology of the fibers, electrospun membrane has found its way in a wide range of applications, such as oil-water separation, desalination, tissue engineering, and batteries. During an electrospinning process, many factors can affect the morphology of the products, such as viscosity of the solution, voltage supply, discharge distance, feed rate of the solution, and electrospinning time. In this work, we investigated the impacts of the most important parameters on the morphology of electrospun fibrous membrane based on the fractional factorial design. We evaluated the electrospun fibrous membrane morphology using scanning electron microscopy (SEM) and capillary flow porometry. Poly (vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) was chosen for the current study due to its interesting and versatile functionalities including superior hydrophobicity, high free volume, and piezoelectricity. This work provides valuable insight for the fabrication of electrospun membranes, especially for tailoring membrane properties in accordance with any targeted applications.

Zhao, Yajing↗
DOE OSTI2022

Ion-imbibed membranes based on proton conducting aromatic polyether type copolymers and their application in redox flow batteries

The present invention relates to a class of polymer ion imbibed membranes for electrolyte flow batteries. The membranes are a conducting aromatic polyether type copolymer bearing nitrogen heterocycles groups, especially pyridine type. While the membranes can be used in acid, basic, and neutral electrolytes, the nitrogen heterocycles in the membrane interact with acid in the electrolyte to form a proton transport network, so as to keep the proton transport performance of the membrane. The membrane has excellent mechanical stability and thermostability as well as tunable porosity.

Paloumbis, George↗
DOE OSTI2022

Composite membranes for separation of gases

Membranes, methods of making the membranes, and methods of using the membranes are described herein. The membranes can comprise a gas permeable support layer, an inorganic layer disposed on the support, the inorganic layer comprising a plurality of discreet nanoparticles having an average particle size of less than 1 micron, and a selective polymer layer disposed on the inorganic layer, the selective polymer layer comprising a selective polymer having a CO2:N2 selectivity of at least 10 at 57° C. In some embodiments, the membrane can be selectively permeable to an acidic gas. The membranes can be used, for example, to separate gaseous mixtures, such as flue gas.

Ho, W. S. Winston↗
DOE OSTI2022

System and method of water purification utilizing an ionomer membrane

A water purification system utilizes an ionomer membrane and mild vacuum to draw water from source water through the membrane. A water source may be salt water or a contaminated water source. The water drawn through the membrane passes across the condenser chamber to a condenser surface where it is condensed into purified water. The condenser surface may be metal or any other suitable surface and may be flat or pleated. In addition, the condenser surface may be maintained at a lower temperature than the water on the water source side of the membrane. The ionomer membrane may be configured in a cartridge, a pleated or flat plate configuration. A latent heat loop may be configured to carry the latent heat of vaporization from the condenser back to the water source side of the ionomer membrane. The source water may be heated by a solar water heater.

Bahar, Bamdad↗
DOE OSTI2022

Durable graphene oxide membranes

Embodiments described herein relate generally to durable graphene oxide membranes for fluid filtration. For example, the graphene oxide membranes can be durable under high temperatures non-neutral pH, and/or high pressures. One aspect of the present disclosure relates to a filtration apparatus comprising: a support substrate, and a graphene oxide membrane disposed on the support substrate. The graphene oxide membrane has a first lactose rejection rate of at least 50% with a first 1 wt % lactose solution at room temperature. The graphene oxide membrane has a second lactose rejection rate of at least 50% with a second 1 wt % lactose solution at room temperature after the graphene oxide membrane is contacted with a solution that is at least 80° C. for a period of time.

Frayne, Stephen↗
DOE OSTI2023

Membranes for gas separation

Membranes, methods of making the membranes, and methods of using the membranes are described herein. The membranes can comprise a support layer, and a selective polymer layer disposed on the support layer. The selective polymer layer can comprise a selective polymer matrix and carbon nanotubes dispersed within the selective polymer matrix. The carbon nanotubes can comprise multi-walled carbon nanotubes wrapped in a hydrophilic polymer, such as polyvinylpyrrolidone or a copolymer thereof, such as poly(1-vinylpyrrolidone-co-vinyl acetate). The membranes can exhibit selective permeability to gases. As such, the membranes can be for the selective removal of carbon dioxide and/or hydrogen sulfide from hydrogen and/or nitrogen.

Ho, W. S. Winston↗
DOE OSTI2024

CFD modeling of high-flux plate-and-frame membrane modules for industrial carbon capture

In this work, we explore the use of CO2-selective flat sheet membranes for capturing CO2 from point sources. We employ Computational Fluid Dynamics (CFD) models to design high-flux plate-and-frame membrane modules to achieve uniform flow distribution among membrane elements, minimize dead-end zones, and ease the common concentration polarization issue for gas separation membranes. The goal is to drive membrane technology improvements by providing better module designs for given membrane properties and operating conditions.

Dosso, Cheick↗
DOE OSTI2024

Filtration membranes

Polymeric membranes are modified via SIS to promote membrane resilience, prolong membrane lifetime, and mitigate fouling. Modified membranes include an inorganic material within an outer portion of the modified membrane and a polymeric core that remains unmodified by the inorganic material. The polymer may be removed leaving an inorganic material patterned from an initial unmodified polymeric membrane.

Source record↗
DOE OSTI2024

Membranes for gas separation

Membranes, methods of making the membranes, and methods of using the membranes are described herein. The membranes can comprise a support layer, and a selective polymer layer disposed on the support layer. In some cases, the support layer can comprise a gas permeable polymer and hydrophilic additive dispersed within the gas permeable polymer. In some cases, the selective polymer layer can comprise a selective polymer matrix and carbon nanotubes dispersed within the selective polymer matrix. The membranes can exhibit selective permeability to gases. As such, the membranes can be for the selective removal of carbon dioxide and/or hydrogen sulfide from hydrogen and/or nitrogen.

Ho, W. S. Winston↗
DOE OSTI2023

Appealing sheath-core spun high-performance composite carbon molecular sieve membranes

Carbon molecular sieve (CMS) membranes are attractive candidates to meet requirements for challenging gas separations. The added ability to maintain such intrinsic properties in an asymmetric morphology with a structure that we term a “Pseudo Wheel+Hub & Spoke” asymmetric form offers new opportunities. For CMS membrane, specifically, the structure provides both selective layer support and low flow resistance even for high feed pressures and fluxes in CO 2 removal from natural gas. Further, this capability is unavailable to even rigid glassy polymers due to the much higher modulus of CMS materials. Combining precursor asymmetric hollow fiber formation and optimized pyrolysis creates a defect free CMS proof-of-concept membrane for this application. Facile formation of the sheath-core spun precursor with a 6FDA-DAM sheath and Matrimid® core also avoids the need to seal defects before or after the carbonization of the precursors. The composite CMS membrane shows CO 2 /CH 4 (50 : 50) mixed gas feed with an attractive CO 2 /CH 4 selectivity of 64.3 and CO 2 permeance of 232 GPU at 35 °C. A key additional benefit of the approach is reduction in use of the more costly high performance 6FDA-DAM in a composite sheath-core CMS membrane with the “Pseudo Wheel+Hub & Spoke” structure.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Improved CO 2 utilization efficiency using membrane carbonation in outdoor raceways

Membrane carbonation, the delivery of CO 2 by diffusion through non-porous hollow fiber membranes, was successfully integrated into outdoor raceways (5.6 m 2 , 900 L) and operated continuously for up to 45 days. Biomass productivity associated with membrane carbonation was similar to using traditional sparging, but the average carbon utilization efficiencies for membrane carbonation was 3-fold higher than for sparging when 100% CO 2 was delivered to both systems. Here, when the pH setpoint was 8.5, growth on ammonium bicarbonate using membrane carbonation achieved a carbon utilization efficiency of 106 ± 45% due to uptake of some carbon from bicarbonate. Using nitrate as the N source had a 78 ± 55% carbon utilization efficiency, due to dissolved inorganic carbon accumulation as the medium alkalinity increased. Lowering the pH setpoint to 8.0 created a carbon-rich environment that decreased the carbon utilization efficiency to 51 ± 27% due to CO 2 off-gassing, but it still was 3-fold higher than with sparging.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Polybenzimidazole-derived carbon molecular sieve hollow fiber membranes with tailored oxygen selective transport

Polymer membrane carbonization is a promising strategy to obtain carbon molecular sieve (CMS) membrane materials with tailorable cavity size distributions for high gas selectivities beyond that attained from traditional polymer membrane materials. Despite their already demonstrated exceptional separation performance characteristics for several gas separation applications (e.g. CO 2 /CH 4 and H 2 /CO 2 ), further development of CMS membranes having high O 2 /N 2 perm-selectivity for energy-efficient high-purity O 2 production has proven challenging. Herein, we explore CMS hollow fiber membranes (HFMs) derived from highly rigid and tightly-packed polybenzimidazole (PBI) materials. Nearly defect-free PBI-derived CMS HFMs were fabricated and evaluated for O 2 /N 2 separation performance for the first time. The micro-structural and O 2 selective gas separation characteristics of PBI-CMS HFMs pyrolyzed at different pyrolysis conditions were intensively studied. With rigorous carbonization protocol optimization, we obtained highly O 2 permselective PBI-CMS HFMs having O 2 /N 2 selectivities approaching 14, enabling high purity O 2 production. The PBI-CMS HFM O 2 /N 2 separation performance dependence on operating conditions (e.g. temperature and feed pressure) are reported.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Impact of hydrophobic pendant phenyl groups on transport and co-transport of methanol and acetate in PEGDA-SPMAK cation exchange membranes

CO 2 reduction cells are innovative devices that reduce CO 2 into valuable chemicals (i.e. methanol (MeOH) and acetate (OAc – )) on the cathode. A major challenge with such devices is to develop ion exchange membranes that allow ion-selective transport (i.e., protons for cation exchange membranes, CEM) and suppress the crossover of CO 2 reduction products. To design such membranes, it is important to understand multi-solute transport behavior of these solutes. Previously, our group reported acetate diffusivities in co-transport with MeOH increase in sulfonated CEMs, where we speculated charge screening of the electrostatic interactions by co-diffusing MeOH has an impact. Here, crosslinked membranes fabricated by photopolymerization of poly(ethylene glycol) diacrylate (PEGDA), 3-sulfopropyl methacrylate potassium (SPMAK, SO 3 – -containing ionomer), and a phenyl-containing comonomer either phenoxyethyl acrylate (PEA) or poly(ethylene glycol) phenyl ether acrylate (PEGPEA)) are investigated. We observe OAc – diffusivities to both (1) PEGDA-SPMAK and (2) PEGDA-PEGPEA increase in co-diffusion with MeOH and those to (3) PEGDA-SPMAK/PEGPEA decrease. To rationalize this emergent co-transport behavior, we speculate (1) electrostatic interactions are interfered with by co-diffusing MeOH, (2) chain mobility (segmental dynamics) increases in the presence of MeOH and (3) for films with both hydrophobic (PEGPEA) and hydrophilic (SPMAK) comonomers chain mobility (segmental dynamics) decrease due to interactions between the comonomer sidechains depressing overall solute diffusivities. Finally, while further investigations are needed, this work contributes to improving our fundamental understanding of the relationships between polymer film chemistry, solute chemistry, and emergent cotransport behavior observed and described in this work (and others) towards enabling the design of improved membrane materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗