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At least 631 records · Page 35

Biogas Biocatalysis

Biogas derived from anaerobic digestion of waste streams such as biorefinery wastewater, animal, agricultural, and municipal solid waste, offers a versatile renewable energy source. Total domestic methane potential from landfill material, animal manure, wastewater, and organic waste, combined with biogas generated from AD of lignocellulosic biomass, is estimated to offer >4 quadrillion Btu potential energy. This energy could displace nearly half of current domestic natural gas consumption in the electric power sector and all consumption in the transportation sector. However, despite this promise of this feedstock, its gaseous state prevents facile integration with extant transportation and industrial infrastructure. Microbial conversion of biogas to liquid fuel and chemical intermediates offers valorization potential. However, biogas biocatalysis is currently limited by poor substrate gas-to-liquid mass transfer, low conversion efficiencies, and incomplete biogas utilization. To this end, the Biogas Biocatalysis AOP aims to develop a carbon- and energy-efficient biogas bioconversion process via techno-economic-informed strain and fermentation engineering strategies. Efforts here will improve both process economics and sustainability via process-intensified, carbon-efficient biogas bioconversion to value-added platform molecules, enabling bolt-on deployment for valorization of biogas derived from standalone AD infrastructure.

BASIC BIOLOGICAL SCIENCES,BIOMASS FUELS↗

High Power Density, Carbon Neutral Electrical Power Generation for Air Vehicles

The synergistic integration of a Solid Oxide Fuel Cell-Combustor (SOFC-C) with a turbogenerator (TG) will provide a very high fuel-to-electricity conversion efficiency while maintaining high power-to-weight ratio during high-altitude flight. The proposed SOFC-C-TG power generation technology exceeds the REEACH technical performance targets (TPT). This unique concept addresses many of the challenges faced in all electric propulsion-based aviation. The system has high part-load efficiency (more than 65% lower heating value (LHV)) during long cruise times, load following capability, high-power capacity at high altitudes adapting to low temperatures and pressures, rapid startup time of less than 30 minutes (proven with current SOFC technology), high power density (more than 3.2 kW/kg), efficient thermal management, and a foundation for a compact, efficient electrical storage and power generation system (ESPG). The SOFC-C concept achieves the technology targets by reducing the complexity of traditional fuel cell-gas turbine hybrid systems (FC-GT). The SOFC-C does not require heat exchangers and dramatically reduces the balance of plant increasing power density and performance in efficiency. The reduction in mass through elimination of heat exchangers, external reformer, and other components dramatically decreases the overall thermal dampening of the system which enables rapid startup and load following capability. Direct control of the cathode inlet temperature of the SOFC-C enables rapid warm-up of the SOFC tubes with the ability to reach operating temperature and full power in less than 30 minutes.

03 NATURAL GAS↗

Advancing Mass Timber Buildings: Novel Methods Improve Thermal Assessment and Material Use

For nearly a century, thermal demand calculations for buildings have relied on simplified models developed to match the technical constraints of their era. The first standards, introduced in Germany and Austria in 1929, established climate zones and material conductivity coefficients that, with only incremental updates, still underpin many current assessments. Yet, methods such as Hot box testing, originally designed for lightweight insulation, continue to be applied for mass timber buildings, overlooking thermodynamic characteristics confer real-world advantages. Recent research at Oak Ridge National Laboratory incorporates updated methodologies, aligned with ASHRAE Standard 55 (ASHRAE, 2023) accounting for factors such as thermal inertia, inner surface temperatures, emissivity, solar gains, and dynamic outdoor conditions. These factors better reflect observed heating and cooling loads and highlight opportunities for efficient use of materials in mass timber construction. This work provides a framework for designing comfortable, resilient, and resource-efficient buildings while aligning with performance expectations in energy codes.

Pickett, Robert [International Mass Timber Allianc↗

Molecular clouds in starburst galaxy nuclei

New CO observations of a complete sample of starburst galaxies are presented in order to determine the range of molecular gas masses and star-formation efficiencies that characterize these systems. The properties of the galaxies in the sample are given, and the H-alpha and R-band CCD images for six of the galaxies are shown. The novel feature of this study is that the galaxies in this study are infrared selected as opposed to optically selected. They exhibit levels of nuclear star formation activity which are comparable to the starburst galaxies M82 and NGC 253. A subset of galaxies with unusually narrow CO line widths, high star-formation efficiencies, and compact 10-micron distributions is revealed. It is proposed that, if gas distributions in these galaxies are also compact, as the narrow linewidths suggest, the high yields of massive stars per unit mass of molecular gas may be attributed to a star-formation mechanism which becomes more efficient as the gas density increases.

Young, Judith S.↗

A discharge flow-photoionization mass spectrometric study of the FO(X 2 Pi i) radical. Photoionization efficiency spectrum and ionization energy

Photoionization efficiency spectra of FO were measured over the wavelength range 80.0-100.0 nm and in the ionization threshold region, 94.0-100.0 nm, using a discharge flow-photoionization mass spectrometer apparatus coupled to a synchrotron radiation source. FO was generated by the reaction of F2P atoms with NO3 and via a F2O2 discharge. A value of 12.78 +/- 0.03 eV was obtained for the adiabatic ionization energy of FO from photoion thresholds which corresponds to FO(+)(X 3 Sigma -) from FO(X 2 Pi i). These results, which are the first to be obtained by direct Photo-ionization mass spectrometry (PIMS) measurements, corroborate those of a photoelectron spectroscopy (PES) study; however, the ionization energy determined here is free from interferences due to other species which complicated the PES measurement. A value of 109.5 +/- 8.0 kJ/mol for Delta f H 0 298(FO) is computed from the present value of IE(FO) and a previous appearance energy measurement, and a value for the proton affinity of FO is calculated to be 511.5 +/- 10.0 kJ/mol.

Zhang, Zhengyu↗

Actuator placement by degree of controllability including the effect of actuator mass

Various concepts of the degree of controllability (DOC) have been previously developed for the purpose of choosing actuator locations in the control of large flexible spacecraft. A perturbation technique is presented to efficiently account for the actuator mass in the computation of the fuel-optimal, time-optimal, and energy-optimal DOC definitions. Methods are developed for computing each of the three DOCs, when the mass of the actuator is nonnegligible. The energy-optimal DOC is employed to find optimal actuator locations for a large spacecraft under study by the NASA Langley Research Center. The mass of the actuator is seen to have a significant effect on the optimal actuator locations and is shown to spread the actuator locations more evenly for large mass actuators. Results indicate that when the actuator mass is large when compared to the structural mass it should be included in selecting actuator locations.

Longman, R. W.↗

Solar power satellite concepts and potential related space systems

Recent parametric studies of alternate SPS design concepts have shown that the concept appears technically feasible. The parametric studies were based on the use of advanced technology silicon solar cells for solar energy conversion. Solar array blanket unit masses of 0.31 to 0.46 kg/sq m were investigated. Conversion efficiencies of 15 to 17 percent air mass zero (AMO at 247 K) with a concentration ratio of two were considered. The systems were sized for a ground power output of 10 GW. To the level of detail studied, no design or operational problems were encountered that did not appear amenable to solution; however, the economic viability of the SPS concepts studied is obviously dependent upon a combination of technology advancement and/or the costs of competitive sources.

Redding, T. E.↗

Impact of Mass Wood Walls on Building Energy Use, Peak Demand, and Thermal Comfort

Thermal mass moderates indoor temperatures, allowing the heating, ventilation, and air conditioning (HVAC) system to operate more efficiently during peak hours. Cross-Laminated Timber (CLT) and other mass wood products provide thermal mass to the building envelope in a lighter and more environmentally friendly form than concrete. However, the influence of CLTs on heating and cooling energy, peak energy demand, and the indoor climate is not well-known. This project was formed to find the energy efficiency benefits of mass timber structures. The objectives were to (1) test the thermal performance of insulated mass wall structures in controlled laboratory conditions, (2) validate simulation models to expand performance to natural climatic conditions, (3) isolate the impact of the thermal properties of wood (thermal mass, thermal conductivity, moisture storage) on heating and cooling energy use and peak energy demand, and to optimize the performance. Currently, the designs used for CLT buildings have focused on structural and fire issues, and they do not consider the thermal mass benefits. Therefore, the thermal performance is not necessarily optimized.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Performance and Mass Modeling Subtleties in Closed-Brayton-Cycle Space Power Systems

A number of potential NASA missions could benefit from closed-Brayton-cycle (CBC) power conversion systems. The human and robotic mission power applications include spacecraft, surface base, and rover scenarios. Modeling of CBC subsystems allows system engineers, mission planners and project managers to make informed decisions regarding power conversion system characteristics and capabilities. To promote thorough modeling efforts, a critical review of CBC modeling techniques is presented. Analysis of critical modeling elements, component influences and cycle sensitivities is conducted. The analysis leads to quantitative results addressing projections on converter efficiency and overall power conversion system mass. Even moderate modeling errors are shown to easily over-predict converter efficiencies by 30 percent and underestimate mass estimates by 20 percent. Both static and dynamic modeling regimes are evaluated. Key considerations in determining model fidelity requirements are discussed. Conclusions and recommendations are presented that directly address ongoing modeling efforts in solar and nuclear space power systems.

Barrett, Michael J.↗

High-mass star-formation rates in M33

The H I, CO, and H-alpha data for M33 are analyzed to obtain high-mass star formation rates and efficiencies and to look for variations in these quantities within the inner disk of M33. Star formation rates and efficiencies are calculated using calibrated H-alpha data. The H-alpha emission in this region of the galaxy corresponds to high-mass and total star-formation rates of 0.007 and 0.04 solar mass/yr, respectively. These results agree reasonably well with the rates calculated from the 60 and 100-micron IRAS emission. The star formation rates obtained form FIR and H-alpha luminosities are compared with those obtained from optical photometry.

Wilson, Christine D.↗

JPL lithium doped solar cell development program

One of the most significant problems encountered in the use of silicon solar cells in space is the sensitivity of the device to electron and proton radiation exposure. The p-diffused-into-n-base solar cells were replaced with the more radiation tolerant n-diffused-into-p-base solar cells. Another advancement in achieving greater radiation tolerance was the discovery that the addition of lithium to n-base silicon resulted in what appeared to be annealing of radiation-induced defects. This phenomenon is being exploited to develop a high efficiency radiation resistant lithium-doped solar cell. Lithium-doped solar cells fabricated from oxygen-lean and oxygen-rich silicon were obtained with average initial efficiencies of 11.9% at air mass zero and 28 C, as compared to state-of-the-art n-p cells fabricated from 10 ohm cm silicon with average efficiencies of 11.3% under similar conditions. Lithium-doped cells demonstrated the ability to withstand three to five times the fluence of 1-MeV electrons before degrading to a power equivalent to state-of-the-art solar cells. The principal investigations are discussed with respect to fabrication of high efficiency radiation resistant lithium-doped cells, including starting material, p-n junction diffusion, lithium source introduction, and lithium diffusion.

Berman, P. A.↗

Thin-Film Photovoltaic Solar Array Parametric Assessment

This paper summarizes a study that had the objective to develop a model and parametrically determine the circumstances for which lightweight thin-film photovoltaic solar arrays would be more beneficial, in terms of mass and cost, than arrays using high-efficiency crystalline solar cells. Previous studies considering arrays with near-term thin-film technology for Earth orbiting applications are briefly reviewed. The present study uses a parametric approach that evaluated the performance of lightweight thin-film arrays with cell efficiencies ranging from 5 to 20 percent. The model developed for this study is described in some detail. Similar mass and cost trends for each array option were found across eight missions of various power levels in locations ranging from Venus to Jupiter. The results for one specific mission, a main belt asteroid tour, indicate that only moderate thin-film cell efficiency (approx. 12 percent) is necessary to match the mass of arrays using crystalline cells with much greater efficiency (35 percent multi-junction GaAs based and 20 percent thin-silicon). Regarding cost, a 12 percent efficient thin-film array is projected to cost about half is much as a 4-junction GaAs array. While efficiency improvements beyond 12 percent did not significantly further improve the mass and cost benefits for thin-film arrays, higher efficiency will be needed to mitigate the spacecraft-level impacts associated with large deployed array areas. A low-temperature approach to depositing thin-film cells on lightweight, flexible plastic substrates is briefly described. The paper concludes with the observation that with the characteristics assumed for this study, ultra-lightweight arrays using efficient, thin-film cells on flexible substrates may become a leading alternative for a wide variety of space missions.

Hoffman, David J.↗

On the use of the consistent mass matrix in flexible multibody systems

Two different methods are used in finite element structural analysis to define element mass distribution: consistent and lumped mass approximations. The lumped mass method is currently favored in multibody dynamics software packages because of its computational efficiency. This paper, however, presents a multibody dynamics formulation based on the consistent mass approach which should prove to be as computationally efficient as the lumped mass approach. It is shown that when component flexibility is modelled using modal coordinates, the equations of motion, as formulated by these two methods, are very similar in appearance, thereby facilitating their comparison. It is also shown, through simulation of a simple multibody system, that a system formulated with the lumped mass approximation will often require more finite elements and smaller integration step sizes than the corresponding consistent mass system.

Anthony, Tobin C.↗

EDEN: Exploring Disks Embedded in N-body Simulations of Milky Way–mass Halos from Symphony

We investigate the impact of galactic disks on the tidal stripping of cold dark matter subhalos within Milky Way (MW)-mass halos (M vir ∼ 10 12 M ⊙ ) using a new simulation suite, EDEN. By re-simulating 45 MW-mass zoomed-in halos from the N-body Symphony compilation with embedded disk potentials, which evolve according to star formation histories predicted by the UniverseMachine model, we self-consistently tie disk growth to halo accretion rate and significantly expand the range of disk masses and formation histories studied. We use the particle-tracking-based subhalo finder Symfind to enhance the robustness of subhalo tracking. We find that disks near the median disk-to-halo mass ratio of our sample (M *,Disk /M vir,host = 2%) reduce subhalo peak mass functions within 100 kpc by about 10% for peak masses above 10 8 M ⊙ . Heavier, MW/M31-like disks (M *,Disk /M vir,host ≳ 5%) lead to a reduction of more than 40%. Subhalo abundance suppression is more pronounced near halo centers, with particularly enhanced stripping for subhalos accreted over 8 Gyr ago on orbits with pericenters <100 kpc. Suppression is further amplified when disk mass is increased within fixed halo and disk assembly histories. In all cases, the suppression we measure should be interpreted as stripping below the mass resolution limit rather than complete subhalo disruption. This study reshapes our understanding of the MW’s impact on its satellites, suggesting it strips subhalos more efficiently than typical MW-mass galaxies due to its larger disk-to-halo mass ratio and earlier disk formation.

79 ASTRONOMY AND ASTROPHYSICS↗

High and Ultra-High Temperature Reaction Kinetics by Single Nanoparticle Mass Spectrometry

Methodology is presented for non-destructive, optically-detected single nanoparticle (NP) mass spectrometry, with the goal of extracting surface reaction kinetics for single NPs at high temperatures. Methods for determining the NP charge, mass, and temperature as a function of time are discussed, and the data are used to extract both the absolute kinetics for mass change, as well as the efficiencies of the surface processes that cause them. Factors that contribute to the uncertainties in absolute and relative mass determination, and in the resulting kinetic parameters, are discussed. The method allows the NP-to-NP variations in initial reactivity to be measured directly, along with the time evolution of reactivity resulting from NP structural/compositional changes that occur under reaction conditions. The strengths and limitations of single nanoparticle mass spectrometry as a high temperature surface kinetics tool are discussed in the context of sublimation and O2 oxidation kinetics experiments for single hafnium (Hf) NPs at temperatures ranging above 2400 K. The Hf oxidation kinetics are compared to analogous oxidation experiments for silicon, graphite, and carbon black NPs. In all four cases, the oxidation chemistry was dominated by processes that result in net mass loss, and the distinct mechanisms responsible are discussed. All four NPs also eventually passivated, i.e., the efficiencies for oxidative etching decreased by at least two orders of magnitude, relative to the initial efficiencies. Furthermore, the passivation mechanisms, which are quite different for carbon, compared to silicon or hafnium, are discussed. Carbon NP passivation is attributed to structural isomerization leading to fully coordinated, fullerene-like NP surfaces, while for silicon and hafnium, passivation results from delayed formation of an oxide layer, triggered by accumulation of oxygen in the NP sub-surface region.

36 MATERIALS SCIENCE↗

Erratum: Monoenergetic photon-induced fission cross-section ratio measurements for U 235 , U 238 , and Pu 239 from 9.0 to 17.0 MeV

In this erratum we report a correction to the previously published photofission cross-section ratio data. The actinide fission-chamber foils utilized in this work were extensively characterized during a new campaign using α- and γ-ray spectroscopy, and 2π alpha counting. These three techniques agreed, resulting in an improved accuracy of the fission-chamber foil masses used in the original experiment. The foil masses measured by α spectroscopy are detailed in Table I. All foils were counted on the same α spectrometer, using an identical geometry, which reduces the systematic uncertainty in the calculated mass ratios since the α spectrometer efficiency cancels out in the ratio. This results in a relative uncertainty on the mass ratio of 1.0% for 235 U/ 238 U, 0.62% for 239 Pu/ 235 U, and 1.1% for 239 Pu/ 238 U. The published cross-section ratio data are re-calculated to reflect the updated target masses and uncertainties. The new mass values cause a 2.40% decrease for the σ( 235 U(γ, f)/ 238 U(γ, f)) ratio, a 5.10% decrease for the σ( 235 U(γ, f)/ 239 Pu(γ, f)) ratio, and a 2.77% decrease for the σ( 238 U(γ, f)/ 239 Pu(γ, f)) ratio. The updated cross-section ratios are presented in Tables II, III, and IV, which are corrected versions of Tables III, IV, and V in Ref. [1]

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗