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At least 631 records · Page 35

Structure and Site Evolution of Framework Ni Species in MIL-127 MOFs for Propylene Oligomerization Catalysis

A mixed-valence oxotrimer metal–organic framework (MOF), Ni-MIL-127, with a fully coordinated nickel atom and two iron atoms in the inorganic node, generates a missing linker defect upon thermal treatment in helium (>473 K) to engender an open coordination site on nickel which catalyzes propylene oligomerization devoid of any cocatalysts or initiators. This catalyst is stable for ~20 h on stream at 500 kPa and 473 K, unprecedented for this chemistry. The number of missing linkers on synthesized and activated Ni-MIL-127 MOFs is quantified using temperature-programmed oxidation, 1 H nuclear magnetic resonance spectroscopy, and X-ray absorption spectroscopy to be ~0.7 missing linkers per nickel; thus, a majority of Ni species in the MOF framework catalyze propylene oligomerization. In situ NO titrations under reaction conditions enumerate ~62% of the nickel atoms as catalytically relevant to validate the defect density upon thermal treatment. Propylene oligomerization rates on Ni-MIL-127 measured at steady state have activation energies of 55–67 kJ mol –1 from 448 to 493 K and are first-order in propylene pressures from 5 to 550 kPa. Density functional theory calculations on cluster models of Ni-MIL-127 are employed to validate the plausibility of the missing linker defect and the Cossee–Arlman mechanism for propylene oligomerization through comparisons between apparent activation energies from steady-state kinetics and computation. Here this study illustrates how MOF precatalysts engender defective Ni species which exhibit reactivity and stability characteristics that are distinct and can be engineered to improve catalytic activity for olefin oligomerization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Development of molecular cluster models to probe pyrite surface reactivity

Abstract The recent discovery that anaerobic methanogens can reductively dissolve pyrite and utilize dissolution products as a source of iron and sulfur to meet their biosynthetic demands for these elements prompted the development of atomic‐scale nanoparticle models, as maquettes of reactive surface sites, for describing the fundamental redox steps that take place at the mineral surface during reduction. The given report describes our computational approach for modeling n (FeS 2 ) nanoparticles originated from mineral bulk structure. These maquettes contain a comprehensive set of coordinatively unsaturated Fe (II) sites that are connected via a range of persulfide (S 2 2− ) ligation. In addition to the specific maquettes with n = 8, 18, and 32 FeS 2 units, we established guidelines for obtaining low‐energy structures by considering the pattern of ionic, covalent, and magnetic interactions among the metal and ligand sites. The developed models serve as computational nano‐reactors that can be used to describe the reductive dissolution mechanism of pyrite to better understand the reactive sites on the mineral, where microbial extracellular electron‐transfer reactions can occur.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Photoluminescence, photophysics, and photochemistry of the V B - defect in hexagonal boron nitride

Extensive photochemical and spectroscopic properties of the V B - defect in hexagonal boron nitride are calculated, concluding that the observed photoemission associated with recently observed optically detected magnetic resonance is most likely of (1) 3 E'' → (1) 3 A' 2 origin. Rapid intersystem crossing from the defect's triplet to singlet manifolds explains the observed short excited-state lifetime and very low quantum yield. New experimental results reveal smaller intrinsic spectral bandwidths than previously recognized, interpreted in terms of spectral narrowing and zero-phonon-line shifting induced by the Jahn-Teller effect. Different types of computational methods are applied to map out the complex triplet and singlet defect manifolds, including the doubly ionized formulation of the equation-of-motion coupled-cluster theory that is designed to deal with the open-shell nature of defect states, and mixed quantum-mechanics/molecular-mechanics schemes enabling 5763-atom simulations. Finally, two other energetically feasible spectral assignments from among the singlet and triplet manifolds are considered, but ruled out based on inappropriate photochemical properties.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Increased Defect Resistance and Ordering in MnBi 2 (Se 1– x Te x ) 4 via Accurate Diffusion Monte Carlo

Stabilizing materials and controlling defect formation remain key challenges in materials science, particularly for theory, where small energy differences must be resolved for accurate predictions. Here, we applied state-of-the-art theoretical methods to topological materials, focusing on MnBi 2 Te 4 (MBT), which is a promising intrinsic magnetic topological insulator. Antisite defects in MBT alter its electronic structure and magnetism, degrading topological properties and causing experimental inconsistencies. Using diffusion Monte Carlo and density functional theory, we investigated the thermodynamic stability and defect formation in MBT, MnBi 2 Se 4 (MBS), and MnBi 2 (Se 1–x Te x ) 4 . We found that MnBi 2 Se 2 Te 2 can be stable at finite temperatures, with higher defect formation energies due to stronger Mn–Se bonding and reduced internal strain. Se preferentially substitutes Te near Mn instead of Te in the outer layer, encouraging long-range ordering when incorporated. For MnBi 2 (Se 1–x Te x ) 4 , cluster expansion phase diagrams revealed solid solution behavior when x <0.5 and phase separation for larger x. MBT and MBS are topological insulators; therefore, the MnBi 2 (Se 1–x Te x ) 4 family could offer tunable topological behavior and improved stability.

MnBi2Te4↗

Cluster in the Auroral Acceleration Region

Due to a fortuitous evolution of the Cluster orbit, the Cluster spacecraft penetrated for the first time in its mission the heart of Earth's auroral acceleration region (AAR) in December 2009 and January 2010. During this time a special AAR campaign was carried out by the various Cluster instrument teams with special support from ESA and NASA facilities. We present some of the first multi-spacecraft observations of the waves, particles and fields made during that campaign. The Cluster spacecraft configuration during these AAR passages was such that it allowed us to explore the differences in the signatures of waves, particles, and fields on the various spacecraft in ways not possible with single spacecraft. For example, one spacecraft was more poleward than the other three (C2), one was at higher altitude (C1), and one of them (0) followed another (C4) through the AAR on approximately the same track but delayed by three minutes. Their separations were generally on the order of a few thousand km or less and occasionally two of them were lying along the same magnetic field line. We will show some of the first analyses of the data obtained during the AAR campaign, where upward and downward current regions, and the waves specifically associated with those regions, as well as the auroral cavities, were observed similarly and differently on the various spacecraft, helping us to explore the spatial, as well as the temporal, aspects of processes occurring in the AAR.

Pickett, Jolene S.↗

Coherence lengths of upstream ULF waves - Dual ISEE observations

We have used high time resolution simultaneous magnetic field data from the dual ISEE spacecraft to study the coherence lengths of upstream ULF waves. We examine the cross-correlation between ISEE 1 and 2 observations for different spacecraft separations and determine the coherence lengths for upstream 30-second waves, 3-second waves, and one-Hz waves. We find that the observed coherence lengths are consistent with those estimated from the bandwidth of the spectral peak and that these lengths vary markedly from less than 100 km to over 1 R(E). In order to study all these wave phenomena, a multiple spacecraft mission such as the upcoming ESA Cluster mission would need to be capable of assuming a wide variety of possible separations.

Le, G.↗

Crater Flux Transfer Events: Highroad to the X Line?

We examine Cluster observations of a so-called magnetosphere crater FTE, employing data from five instruments (FGM, CIS, EDI, EFW, and WHISPER), some at the highest resolution. The aim of doing this is to deepen our understanding of the reconnection nature of these events by applying recent advances in the theory of collisionless reconnection and in detailed observational work. Our data support the hypothesis of a stratified structure with regions which we show to be spatial structures. We support the bulge-like topology of the core region (R3) made up of plasma jetting transverse to reconnected field lines. We document encounters with a magnetic separatrix as a thin layer embedded in the region (R2) just outside the bulge, where the speed of the protons flowing approximately parallel to the field maximizes: (1) short (fraction of a sec) bursts of enhanced electric field strengths (up to approximately 30 mV/m) and (2) electrons flowing against the field toward the X line at approximately the same time as the bursts of intense electric fields. R2 also contains a density decrease concomitant with an enhanced magnetic field strength. At its interface with the core region, R3, electric field activity ceases abruptly. The accelerated plasma flow profile has a catenary shape consisting of beams parallel to the field in R2 close to the R2/R3 boundary and slower jets moving across the magnetic field within the bulge region. We detail commonalities our observations of crater FTEs have with reconnection structures in other scenarios. We suggest that in view of these properties and their frequency of occurrence, crater FTEs are ideal places to study processes at the separatrices, key regions in magnetic reconnection. This is a good preparation for the MMS mission.

Farrugia, C. J.↗

Cluster Observations of Multiple Dipolarization Fronts

We present Cluster observations of a series of dipolarization fronts (DF 1 to 6) at the central current sheet in Earth's magnetotail. The velocities of fast earthward flow following behind each DF 1.3 are comparable to the Alfven velocity, indicating that the flow bursts might have been generated by bursty reconnection that occurred tailward of the spacecraft. Based on multispacecraft timing analysis, DF normals are found to propagate mainly earthward at 160.335 km/s with a thickness of 900-1500 km, which corresponds to the ion inertial length or gyroradius scale. Each DF is followed by significant fluctuations in the x and y components of the magnetic field whose peaks are found 1.2 min after the DF passage. These (B(sub x), B(sub y)) fluctuations propagate dawnward (mainly) and earthward. Strongly enhanced field-aligned beams are observed coincidently with (B(sub x), B(sub y)) fluctuations, while an enhancement of cross-tail currents is associated with the DFs. From the observed pressure imbalance and flux tube entropy changes between the two regions separated by the DF, we speculate that interchange instability destabilizes the DFs and causes the deformation of the midtail magnetic topology. This process generates significant field-aligned currents and might power the auroral brightening in the ionosphere. However, this event is associated with neither the main substorm auroral breakup nor the poleward expansion, which might indicate that the observed multiple DFs have been dissipated before they reach the inner plasma sheet boundary.

Hwang, K.-J.↗

Chain Dynamics in Magnetorheological Suspensions

Magnetorheological (MR) suspensions are composed of colloidal particles which acquire dipole moments when subjected to an external magnetic field. At sufficient field strengths and concentrations, the dipolar particles rapidly aggregate to form long chains. Subsequent lateral cross-linking of the dipolar chains is responsible for a rapid liquid-to-solid-like rheological transition. The unique, magnetically-activated rheological properties of MR suspensions make them ideal for interfacing mechanical systems to electronic controls. Additionally, the ability to experimentally probe colloidal suspensions interacting through tunable anisotropic potentials is of fundamental interest. Our current experimental work has focused on understanding the fluctuations of dipolar chains. It has been proposed by Halsey and Toor (HT) that the strong Landau-Peierls thermal fluctuations of dipolar chains could be responsible for long-range attractions between chains. Such interactions will govern the long-time relaxation of MR suspensions. We have synthesized monodisperse neutrally buoyant MR suspensions by density matching stabilized ferrofluid emulsion droplets with D2O. This allows us to probe the dynamics of the dipolar chains using light scattering without gravitational, interfacial, and polydispersity effects to resolve the short-wavelength dynamics of the dipolar chains. We used diffusing wave spectroscopy to measure these dynamics. The particle displacements at short times that show an independence to the field strength, but at long times exhibit a constrained, sub-diffusive motion that slows as the dipole strength is increased. The experiments are in good qualitative agreement with Brownian dynamics simulations of dipolar chains. Although there have been several important and detailed studies of the structure and interactions in MR suspensions, there has not been conclusive evidence that supports or contradicts the HT model prediction that long-range interactions exist between fluctuating chains of dipolar particles. Resolving this issue would contribute greatly to the understanding of these interesting and important materials. We have begun to test the predictions of the HT model by both examining the dynamics of individual chains and by measuring the forces between dipolar chains directly to accurately and quantitatively assess the interactions that they experience. To do so, we employ optical trapping techniques and video-microscopy to manipulate and observe our samples on the microscopic level. With these techniques, it is possible to observe chains that are fluctuating freely in three-dimensions, independent of interfacial effects. More importantly, we are able to controllably observe the interactions of two chains at various separations to measure the force-distance profile. The techniques also allow us to study the mechanical properties of individual chains and chain clusters. Our work to this point has focused on reversibly-formed dipolar chains due to field induced dipoles where the combination of this chaining, the dipolar forces, and the hydrodynamic interactions that dictate the rheology of the suspensions. One can envision, however, many situations where optical, electronic, or rheological behavior may be optimized with magneto-responsive anisotropic particles. Chains of polarizable particles may have the best properties as they can coil and flex in the absence of a field and stiffen and orient when a field is applied. We have recently demonstrated a synthesis of stable, permanent paramagnetic chains by both covalently and physically linking paramagnetic colloidal particles. The method employed allows us to create monodisperse chains of controlled length. We observed the stability, field-alignment, and rigidity of this new class of materials. The chains may exhibit unique rheological properties in an applied magnetic field over isotropic suspensions of paramagnetic particles. They are also useful rheological models as bead-spring systems. These chains form the basis for our current experiments with optical traps.

Gast, A. P.↗

Self-sustaining sound in collisionless, high- β plasma

Using analytical theory and hybrid-kinetic numerical simulations, we demonstrate that, in a collisionless plasma, long-wavelength ion-acoustic waves (IAWs) with amplitudes $δn/n_0≳2/β$ (where $β\gg1$ is the ratio of thermal to magnetic pressure) generate sufficient pressure anisotropy to destabilize the plasma to firehose and mirror instabilities. These kinetic instabilities grow rapidly to reduce the pressure anisotropy by pitch-angle scattering and trapping particles, respectively, thereby impeding the maintenance of Landau resonances that enable such waves’ otherwise potent collisionless damping. The result is wave dynamics that evince a weakly collisional plasma: the ion distribution function is near-Maxwellian, the field-parallel flow of heat resembles its Braginskii form (except in regions where large-amplitude magnetic mirrors strongly suppress particle transport), and the relations between various thermodynamic quantities are more ‘fluid-like’ than kinetic. A nonlinear fluctuation–dissipation relation for self-sustaining IAWs is obtained by solving a plasma-kinetic Langevin problem, which demonstrates suppressed damping, enhanced fluctuation levels and weakly collisional thermodynamics when IAWs with $δn/n_0≳2/β$ are stochastically driven. We investigate how our results depend upon the scale separation between the wavelength of the IAW and the Larmor radius of the ions, and discuss briefly their implications for our understanding of turbulence and transport in the solar wind and the intracluster medium of galaxy clusters.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Conventional single-gap $s-$wave superconductivity and hidden peak effect in single crystals of Mo$_8$Ga$_{41}$ superconductor

London and Campbell penetration depths were measured in single crystals of the endohedral gallide cluster superconductor, Mo _8 8 Ga _41 41 . The full temperature range superfluid density, \rho_s(T) ρ s ( T ) , is consistent with the clean isotropic s- s − wave weak-coupling BCS theory without any signs of the second gap or strong coupling. The temperature dependence of the Campbell length is hysteretic between zero-field cooling (ZFC) and field-cooling (FC) protocols, indicating an anharmonic vortex pinning potential. The field dependence of the effective critical current density, j_{c}(H) j c ( H ) , reveals an unusual result. While in the ZFC protocol, j_{c}(H) j c ( H ) is monotonically suppressed by the magnetic field, it exhibits a profound “hidden” peak effect in the FC protocol, that is, without a vortex density gradient. We suggest a possible novel mechanism for such a peak effect, which involves both static and dynamic aspects of vortex pinning.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The response of the near earth magnetotail to substorm activity

The large scale structure of the current sheet in the terrestrial magnetotail is often represented as the superposition of a constant northward-oriented magnetic field component (B(sub z)) and a component along the Earth-Sun direction (B(sub x)) that varies with distance from the center of the sheet (z(sub o) in GSM) as in a Hams neutral sheet. The latter implies that B(sub x) = B(sub Lx) tanh((z - z(sub o))/h) where B(sub Lx) is the magnitude of the B(sub x) component in the northern lobe. Correspondingly, the cross-tail current should be approximated by J(sub y) = (B(sub Lx)/h) sech(sup 2)((z - z(sub o))/h). Using data from the fluxgate magnetometer (FGM) on the Cluster I1 spacecraft tetrad, we have used measured fields and currents to ask if this model represents the large-scale properties of the system. During very quiet crossings of the plasmasheet, we find that the model gives a reasonable estimate of the trend of the average current and field distributions, but during disturbed intervals, the best fit fails to represent the data. If, however, the parameters z(sub o) and h of the model are taken as variable functions of time, the fits can be reasonably good. The temporal variation of the fit parameter h that characterizes the thickness of the current sheet can be interpreted in terms of thinning during the growth phase of a substorm and thickening following the expansion phase. Ground signatures that give insight into the local time of substorm onset can be used to interpret the response of the plasmasheet to substorm related changes of the global system. During a substorm, the field magnitude in the central plasmasheet fluctuates at the period of Pi2 pulsations.

Kivelson, M. G.↗

Detailed Characterization of Vitrinite-Rich Subbituminous and Bituminous Coals for Utilization in Carbon Fiber Precursor Production

Chemical structures of candidate coals (one subbituminous coal from the Powder River Basin and three bituminous Eastern US coals) were examined for potential low-cost carbon fiber precursor production. Here, the structural evaluation examined the carbon skeleton ( 13 C nuclear magnetic resonance (NMR) and high-resolution transmission electron microscopy (HRTEM)), the heteroatom functionality (X-ray photoelectron spectroscopy (XPS) Fourier transform infrared spectroscopy (FTIR) and NMR), the structural ordering and distribution of PAH sizes (HRTEM), and an estimation of the molecular weight distribution (laser desorption ionization mass spectrometry, LDIMS). The molecular compositional distributions were also evaluated for a mixed solvent extract (atmospheric pressure photoionization, 21 T Fourier transform ion cyclotron resonance mass spectrometry, FT-ICR MS). Significant structural differences existed between the subbituminous and bituminous coals, as expected with coalification (with the bituminous coals having a higher carbon content, lower oxygen content, higher aromaticity values, larger cluster sizes, and so forth). While the bituminous coals were similar in structure (close in rank with Blue Gem being hvAb and the rest being hvBb), structural differences were still evident. Specifically, structural similarities were evident for the average properties of Herrin and Springfield coals: same rank, similar moisture, and volatile matter yields, along with similar aromaticity and carbon and hydrogen content. However, significant structural differences were observed at the molecular level by 21 T FT-ICR MS, which showed that the Springfield coal was structurally more complex. Specifically, 21740, 16931, 30190, and 12982 unique elemental compositions were identified for the Monarch, Herrin, Springfield, and Blue Gem coals, further illustrating the complexity of the coal.

01 COAL, LIGNITE, AND PEAT↗

Cluster Observations of Multiple Dipolarization Fronts

We present Cluster observations of a series of dipolarization fronts (DF 1 to 6) at the central current sheet in Earth's magnetotail. The velocities of fast earthward flow following behind each DF 1-3, are comparable to the Alfven velocity, indicating that the flow bursts might have been generated by bursty reconnection that occurred tailward of the spacecraft. Based on multi-spacecraft timing analysis, DF normals are found to propagate mainly earthward at $160-335$ km/s with a thickness of 900-1500 km, which corresponds to the ion inertial length or gyroradius scale. Each DF is followed by significant fluctuations in the $x$ and $y$ components of the magnetic field whose peaks are found 1-2 minutes after the DF passage. These $(B_{x},B_{y} )$-fluctuations propagate dawnward (mainly) and earthward. Strongly enhanced field-aligned beams are observed coincidently with $(B_{x},B_{y})$ fluctuations, while an enhancement of cross-tail currents is associated with the DFs. From the observed pressure imbalance and flux-tube entropy changes between the two regions separated by the DF, we speculate that interchange instability destabilizes the DFs and causes the deformation of the mid-tail magnetic topology. This process generates significant field-aligned currents, and might power the auroral brightening in the ionosphere. However, this event is neither associated with the main substorm auroral breakup nor the poleward expansion, which might indicate that the observed multiple DFs have been dissipated before they reach the inner plasma sheet boundary.

Hwang, Kyoung-Joo↗

Electronic structure of strongly correlated systems: recent developments in multiconfiguration pair-density functional theory and multiconfiguration nonclassical-energy functional theory

Strong electron correlation plays an important role in transition-metal and heavy-metal chemistry, magnetic molecules, bond breaking, biradicals, excited states, and many functional materials, but it provides a significant challenge for modern electronic structure theory. The treatment of strongly correlated systems usually requires a multireference method to adequately describe spin densities and near-degeneracy correlation. However, quantitative computation of dynamic correlation with multireference wave functions is often difficult or impractical. Multiconfiguration pair-density functional theory (MC-PDFT) provides a way to blend multiconfiguration wave function theory and density functional theory to quantitatively treat both near-degeneracy correlation and dynamic correlation in strongly correlated systems; it is more affordable than multireference perturbation theory, multireference configuration interaction, or multireference coupled cluster theory and more accurate for many properties than Kohn–Sham density functional theory. This perspective article provides a brief introduction to strongly correlated systems and previously reviewed progress on MC-PDFT followed by a discussion of several recent developments and applications of MC-PDFT and related methods, including localized-active-space MC-PDFT, generalized active-space MC-PDFT, density-matrix-renormalization-group MC-PDFT, hybrid MC-PDFT, multistate MC-PDFT, spin–orbit coupling, analytic gradients, and dipole moments. We also review the more recently introduced multiconfiguration nonclassical-energy functional theory (MC-NEFT), which is like MC-PDFT but allows for other ingredients in the nonclassical-energy functional. We discuss two new kinds of MC-NEFT methods, namely multiconfiguration density coherence functional theory and machine-learned functionals.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

ROSAT observations of six millisecond pulsars

We present ROSAT observations toward six known millisecond radio pulsars. These observations yielded upper limits to the X-ray flux in the ROSAT band (0.1-2.4 keV) for five pulsars and a possible association of an X-ray source with PSR B1821-24, in the globular cluster M28. At the 99.9% confidence level, the source is pulsed at the expected radio pulsar frequency. We compare our results with predicted X-ray luminosities by Seward & Wang Oegelman. The X-ray luminosities of PSRs B1257+12 and J0437-4715, millisecond pulsars with similar periods and spin-down rates, are found to differ by more than a factor of 25. X-ray emission from radio pulsars has been ascribed to a thermal component arising from a surface hot spot and a power-law magnetospheric component (Halpern & Ruderman). In the context of this model and these observations, we argue that the orientation of the magnetic and rotation axes with respect to the line of sight is very different for PSR J0437-4715 compared to PSR B1257+12. Finally, we suggest that the beaming factor for X-ray emission is independent of the pulsar period, unlike that for radio emission; if so, most millisecond pulsars are visible in the radio but no at X-ray energies.

Danner, R.↗

To Boldly Go: America's Next Era in Space. The Plasma Universe

Dr. France Cordova, NASA's Chief Scientist, chaired this, the eighth seminar in the Administrator's Seminar Series. She introduced the NASA Administrator, Daniel S. Goldin, who, in turn, introduced the subject of plasma. Plasma, an ionized gas, is a function of temperature and density. We ve learned that, at Jupiter, the radiation is dense. But, Goldin asked, what else do we know? Dr. Cordova then introduced Dr. James Van Allen, for whom the Van Allen radiation belt was named. Dr. Van Allen, a member of the University of Iowa faculty, discussed the growing interest in practical applications of space physics, including radiation fields and particles, plasmas and ionospheres. He listed a hierarchy of magnetic fields, beginning at the top, as pulsars, the Sun, planets, interplanetary medium, and interstellar medium. He pointed out that we have investigated eight of the nine known planets,. He listed three basic energy sources as 1) kinetic energy from flowing plasma such as constitutional solar wind or interstellar wind; 2) rotational energy of the planet, and 3) orbital energy of satellites. He believes there are seven sources of energetic particles and five potential places where particles may go. The next speaker, Dr. Ian Axford of New Zealand, has been associated with the Max Planck Institut fuer Aeronomie and plasma physics. He has studied solar and galactic winds and clusters of galaxies of which there are several thousand. He believes that the solar wind temperature is in the millions of degrees. The final speaker was Dr. Roger Blanford of the California Institute of Technology. He classified extreme plasmas as lab plasmas and cosmic plasmas. Cosmic plasmas are from supernovae remnants. These have supplied us with heavy elements and may come via a shock front of 10(sup 15) electron volts. To understand the physics of plasma, one must learn about x-rays, the maximum energy of acceleration by supernova remnants, particle acceleration and composition of cosmic rays, maximum acceleration, and how fast protons are heated by ions. He asked questions about where high energy cosmic rays are made, what accelerates electrons, radiates gamma rays, makes electronpositron plasma, and finally noted that pulsars are good time keepers, but we need a better understanding of their mechanism and of plasmas, both cosmic and ground-based. In the discussion period, Goldin asked if NASA should put up an x-ray interferometer. The answer was no; gamma rays are of greater interest just now. Goldin also asked what the assembled scientists would like to see for a future mission? They expressed an interest in learning more about the origin of galaxies, cosmic rays, solar systems, planets, the existence of life "out there", gamma ray sources, the nature of gamma ray bursts, and the flow of gases around black holes. The discussion concluded with a suggestion that NASA should communicate to the general public more information regarding actual technological trials and tribulations involved in getting an experiment to work. The speakers thought that this would help non-scientists to better appreciate what it is that NASA does in connection with the benefits that are achieved.

Source record↗

A Deep Imaging Survey of NGC 6475 and a Deep Survey of the Young Open Cluster Alpha Persei

We have published three papers directly related to the x-ray data (see below), and one other paper directly related to the optical photometry obtained in connection to the ROSAT data analysis (also listed below). In addition, we have used the x-ray data in combination with the optical photometry and with high resolution optical spectra that we have obtained (to derive spectroscopic rotational velocities) to address questions related to the dependence of coronal activity on the rotation rate, mass, and other characteristics of the target stars. The overall goal of our ROSAT projects has been to determine the time evolution of coronal activity in low mass stars, and from that behavior place constraints on the physical processes involved in generating coronal activity. NGC 6475 and Alpha Persei are important parts of that process. We are now beginning to address how these data constrain theoretical models of angular momentum evolution and dynamo magnetic field generation (see paper by Stauffer et al. and Krishnamurthi et al. listed below in the "related papers" section). We are still working on two papers pertaining to this grant (rotational velocities and chromospheric activity of Alpha Persei x-ray sources and rotational velocities and lithium abundances of NGC 6475 sources), but we will publish those papers using funds from other grants.

Stauffer, John R.↗