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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 631 records · Page 35
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Solid state photochemistry of polycarbonates

The quantum yield of photoFries rearrangement in a polycarbonate film has been analyzed as a function of temperature and humidity on the basis of previously reported (Koyler and Mann, 1977) experimental data. Results indicate that in the homogeneous amorphous phase, photoFries rearrangement is a concerted process proceeding either from the pi star reversed arrow n singlet, in which case it must be subject to considerable self quenching, or from a triplet, presumably the first triplet since the lifetime of higher triplets is expected to be very short in the solid phase. If the parent excited state is the first triplet, chain scission is possibly an independent process, probably occurring from the pi star reversed arrow n singlet. Evidence of chain scission on photodegradation in the solid state includes loss of C-O and C-C bond intensities revealed in the Fourier transform infrared spectra, gel permeation chromotography elution profiles of degraded film samples dissolved in CHCl3, and a decrease in tensile strength and T sub g as photodegradation proceeds. Chain scission is apparently inhibited as photoFries products accumulate.

Gupta, A.↗
NASA NTRS1980

Characterization of PMR-15 polyimide composition in thermo-oxidatively exposed graphite fiber composites

The contributions of individual resin components to total resin weight loss in 600 F air aged Celion 6000/PMR-15 polyimide composites were determined from the overall resin weight loss in the composite by chemically separating the PMR-15 matrix resin into its monomeric components. The individual resin components were also analyzed by spectroscopic techniques in order to elucidate curing and degradation mechanisms of the PMR-15 matrix resin. The isothermal weight loss of the individual resin components during prolonged 600 F thermo-oxidative aging of the composite was correlated to the changes observed in the Fourier Transform infrared spectra and Fourier Transform nuclear magnetic resonance spectra of the individual resin components. The correlation was used to identify the molecular site of the thermo-oxidative changes in PMR-15 polyimide matrix resin during 600 F curing the prolonged 600 F thermo-oxidative aging.

Alston, W. B.↗
NASA NTRS1979

Unidentified infrared spectral features

It is noted that the infrared spectra between 2 and 13 microns of a variety of objects have become available in the past few years. Attention is given to the fact that these spectra have shown many objects to have up to six emission features that are still unidentified. It is reported that other objects show absorptions due to ice, carbon monoxide, silicates, and two unidentified features. Discussion covers the observational characteristics of the unidentified features together with possible identifications.

Willner, S. P.↗
NASA NTRS1980

The infrared spectrum of matrix isolated hydrogen and deuterium

The induced infrared spectra of H2 and D2, trapped in matrices of Ar, Kr, N2, CO, have been investigated. It is found that in Ar and Kr, the pure rotation spectrum is always readily observable. Portions of the fundamental region, however, are induced by impurities, while the entire spectrum is impurity induced in N2 matrices. These results are discussed in light of a recent Raman study of this system, and in comparison with several single crystal studies. Effective rotational and vibrational constants for matrix isolated H2 are also given.

Warren, J. A.↗
NASA NTRS1980

The helium abundance of Jupiter from Voyager

Full disk measurements recorded 31 days before the Voyager 1 encounter with Jupiter by the radiometer of the infrared instrument, IRIS, indicate a geometric albedo of 0.274 + or - 0.013. Combining this measurement with the Pioneer derived phase integral of 1.25 and our error estimate of 0.1 yields a Jovian Bond albedo of 0.343 + or - 0.032. Infrared spectra recorded at the same time by the Michelson interferometer, along with a model extrapolation to low wave numbers not covered by the instrument, yield a thermal emission of (1.359 + or - 0.014) .001 W cm to the (-2) power. As in the case of the albedo measurement, the quoted errors in the emission measurement reflect estimates of systematic effects and are uncertain while the random component is negligible. From these measurements the internal heat flux of Jupiter is estimated to be (5.444 + or - 0.425) .0001 W cm to the (-2) power, and the energy balance defined as the ratio of emitted thermal to absorbed solar energy is 1.668 + or - 0.085.

Gautier, D.↗
NASA NTRS1981

Infrared observations of the Saturnian system from Voyager 1

Atmospheric chemistry analyses of Saturn based on Voyager 1 infrared spectral and radiometric data are presented, including characteristics of the planet's rings and of Titan and other satellites. Infrared spectra of Saturn indicate the presence of H2, CH4, NH3, PH3, C2H2, and C2H6, with the possibility of C3H4 and C3H8. The atmospheric thermal structure of the planet shows hemispheric asymmetries that are consistent with seasonally varying insolation response, with an extensive small-scale latitudinal structure. Atmospheric chemistries of Titan, and optical and thermal characteristics for the rings of Saturn, are also given.

Hanel, R.↗
NASA NTRS1981

Matrix spectroscopic studies of chlorine atom-ozone reaction products

A spectroscopic study is presented of the matrix-isolated products of the direct combination reaction of chlorine atoms with ozone and of the microwave discharge reaction of chlorine and oxygen. Infrared spectra in the wavenumber range 2000 to 200 per cm were recorded for reaction products trapped by the condensation of a matrix of solid argon. Evidence for the formation of the ClO radical as well as the ClOO and ClClO radicals during the direct chlorine-ozone reaction is obtained, however no evidence is found for the presence of asymmetric ClO3 under conditions thought favorable for its formation. The ClO molecule is also observed following the microwave discharge reaction of chlorine and oxygen in argon in the isotopic forms (Cl-35)(O-16), (Cl-37)(O-16), (Cl-35)(O-18), and (Cl-37)(O-18). It is noted that the vibrational frequency for the (Cl-35)(O-16) radical at 849.2 per cm is blue-shifted 5 per cm above its gas-phase fundamental.

Carter, R. O., III↗
NASA NTRS1982

Radiative transfer and remote sensing

Radiative transfer, the basic theoretical tool for the quantitative interpretation of planetary infrared spectra, is discussed. The function it plays in linking the remotely sensed data to the properties of the atmosphere (composition, thermal structure, dynamics, etc.), is inferred. A brief overview of the remote sensing problem as it pertains to the interpretation of planetary spectra is presented. The presentation is tutorial rather than exhaustive.

Conrath, B. J.↗
NASA NTRS1982

Rayleigh, Raman and particulate scattering

Analysis of the visible and near infrared spectra of planetary atmospheres and the multiple scattering of photons within the atmosphere are discussed. Photons detected within the spectral region are solar photons which were scattered by the gas and particles in the planetary atmosphere. An example is given for the incident and emitted fluxes for a hypothetical planet with an effective temperature of 100 K. The absorption spectrum of the planetary atmosphere is discussed in terms of the various scattering processes photons undergo within the atmosphere. Three different physical processes are considered. Rayleigh scattering and Raman scattering by the gas molecules, and scattering by any cloud or dust aerosol particles in the atmosphere. The physics of each of these processes is examined.

Cochran, W. D.↗
NASA NTRS1982

Long-pathlength absorption spectroscopy of CH4

Infrared spectra of methane and ammonia are taken. The methane data base accumulated is described. The spectral region from 4,000 to 6,500 cm is covered at moderate resolution (0.15 cm), working at three temperatures (118, 191, and 272K), and with the (pressure - pathlength) product ranging over a factor of a thousand. Methane spectra broadened by hydrogen and helium have also been taken. Normalized spectra are stored on magnetic tapes, at a resolution slightly better than 0.25 cm.

Silvaggio, P.↗
NASA NTRS1981

Spectroscopic detection of stratospheric hydrogen cyanide

A number of features have been identified as absorption lines of hydrogen cyanide in infrared spectra of stratospheric absorption obtained from a high-altitude aircraft. Column amounts of stratospheric hydrogen cyanide have been derived from spectra recorded on eight flights. The average vertical column amount above 12 kilometers is 7.1 + or - 0.8 x 10 to the 14th molecules per square centimeter, corresponding to an average mixing ratio of 170 parts per trillion by volume.

Coffey, M. T.↗
NASA NTRS1981

Albedo, internal heat, and energy balance of Jupiter - Preliminary results of the Voyager infrared investigation

Full disk measurements recorded by the 0.4-1.7 micron radiometer on Voyager 1 indicate a geometric albedo of 0.274 + or - 0.013. This measurement and the Pioneer-based phase integral of 1.25 yield a Jovian Bond albedo of 0.343 + or - 0.032. Infrared spectra yield a thermal emission of 1.359 + or - 0.014 x .001 W/sq cm, which corresponds to an equivalent blackbody temperature of 124.4 + or - 0.3 K. In addition, the internal heat flux of Jupiter is estimated to be 5.444 + or - 0.425 x .0001 W/sq cm, and the energy balance defined as the ratio of emitted thermal to absorbed solar energy is 1.668 + or - 0.085.

Hanel, R. A.↗
NASA NTRS1981

4-8 micron spectrophotometry of OH 0739-14

Spectrophotometry of the dust-embedded late-type star OH 0739-14 shows an absorption feature at 6.0 microns characteristic of H2O ice at temperatures significantly lower than 150 K, confirming the identification of H2O ice in the circumstellar shell in this source. The differences in the infrared spectra of HO 0739-14 and embedded molecular cloud sources are attributed to the different cloud lifetimes and temperature regimes in which the molecules are formed. A lower limit to the mass loss rate of 0.0001 solar mass per year is derived, based on the column density of ice and the size and the expansion velocity of the circumstellar cloud.

Soifer, B. T.↗
NASA NTRS1981

Analysis of infrared emission from thin adsorbates

Fuel and lubricant deposits on solid surfaces, though often of similar visual appearance, differ in composition, depending on the nature of the deposit formers and the circumstances of deposition. To help establish these relations an Infrared Emission Fourier Polarization Microspectrophotometer was constructed to record infrared spectra from the deposits on their original support. By focussing on small aggregates with a reflecting microscope objective and by discriminating against the randomly polarized blackbody radiation with a rotating polarizing filter phase-locked to an amplifier, excellent Fourier emission spectra of polarized bands could be obtained. In many instances, the microscope objective was adequate without the polarizer. The analysis was calibrated against a very thin film of polyethylene terephthalate attached to a highly reflective aluminum mirror on the sample positioner.

Lauer, J. L.↗
NASA NTRS1982

Remote sensing studies of lunar dark-halo impact craters - Preliminary results and implications for early volcanism

A summary of the nature and origin of lunar dark-halo craters is presented. New remote sensing data for dark-haloed impact craters were obtained and interpreted. A variety of spectral, thermal, radar, and photogeologic data are presented which confirm the hypothesis that Copernicus H crater excavated mare basalt from beneath lighter deposits emplaced by the Copernicus impact event. Multispectral imagery suggests that analogous impact re-exposure of basaltic material on the ejecta blankets of other large Copernican and Eratosthenian craters resulted in the formation of other dark-halo craters. Preliminary analyses of near-infrared spectra of dark-haloed impact craters in the Schickard-Schiller region are consistent with the hypothesis that basaltic material was excavated from beneath light plains. These light plains may have been emplaced as a result of the Orientale impact event. Additional evidence is presented which suggests that both pre- and post-Orientale volcanic activity was more prevalent in this region than has previously been recognized.

Hawke, B. R.↗
NASA NTRS1982

Forced torsional properties of PMR composites with varying nadic ester concentrations and processing histories

PMR polyimide resin was prepared from 4,4'-methylenedianiline, the dimethyl ester of 3,3',4,4'-benzophenonetetracarboxylic acid and the monomethyl ester of 5-norbornene-2,3-dicarboxylic acid (NE). The NE group serves as a chain terminator and crosslinking site. PMR/Celion 6000 composites were fabricated from resins having varying NE concentrations using two molding processes, and the laminates characterized in forced torsion. Glass transition temperatures (T(g)) of 360-390 C were observed in the crosslinked resins, as compared with the literature value of 284 C reported for the uncrosslinked system. T(g) did not decrease with decreasing NE concentrations over the range from 2.0 to 1.25 moles. Stoichiometry, within the range studied, showed little influence on shear properties; however, a 25% variation in matrix shear modulus with processing was observed. The G(12) values determined in forced torsion were in excellent agreement with those reported from tensile tests of + or - 45 deg laminates. A branching and possible secondary crosslink mechanism is proposed based on dynamic mechanical behavior and infrared spectra of the composites.

Hurwitz, F. I.↗
NASA NTRS1983

High pressure cosmochemistry applied to major planetary interiors: Experimental studies

The infrared spectra of H2O ice VII and D2O ice VII were studied and techniques were developed for measuring adiabats of phases of NH3-H2O to 5 GPa. A mixing system for pressurized fluids was constructed in which liquid solutions of definite compositions can be prepared and loaded reliably into diamond cells in a project which seeks to determine the properties and boundaries of several high pressure phases of the H2-He-H2O-NH3-CH4 system. These data are needed to constrain theoretical models of the interiors of the major planets.

Nicol, M. F.↗
NASA NTRS1982

Infrared photometry of periodic comets Encke, Chernykh, Kearns-Kwee, Stephan-Oterma, and Tuttle

Nearly simultaneous photometry of the reflected and thermal infrared spectra of periodic comets Encke, Chernykh, Kearns-Kwee, Stephan-Oterma, and Tuttle are presented. The 10-micron silicate emission feature has been detected for the first time in periodic comets and was observed in three of these objects. The albedo of the dust particles in the comae of these comets is calculated and compared to that of Comet Kohoutek. The peculiar behavior of the dust in Comet Encke is discussed.

Campins, H.↗