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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 631 records · Page 35
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Water Formation Reaction under Interfacial Confinement: Al0.25Si0.75O2 on O-Ru(0001)

Confined nanosized spaces at the interface between a metal and a seemingly inert material, such as a silicate, have recently been shown to influence the chemistry at the metal surface. In prior work, we observed that a bilayer (BL) silica on Ru(0001) can change the reaction pathway of the water formation reaction (WFR) near room temperature when compared to the bare metal. In this work, we looked at the effect of doping the silicate with Al, resulting in a stoichiometry of Al0.25Si0.75O2. We investigated the kinetics of WFR at elevated H2 pressures and various temperatures under interfacial confinement using ambient pressure X-ray photoelectron spectroscopy. The apparent activation energy was lower than that on bare Ru(0001) but higher than that on the BL-silica/Ru(0001). The apparent reaction order with respect to H2 was also determined. The increased residence time of water at the surface, resulting from the presence of the BL-aluminosilicate (and its subsequent electrostatic stabilization), favors the so-called disproportionation reaction pathway (*H2O + *O ↔ 2 *OH), but with a higher energy barrier than for pure BL-silica.

36 MATERIALS SCIENCE↗
DOE OSTI2022

PetroFit: A Python Package for Computing Petrosian Radii and Fitting Galaxy Light Profiles

PetroFit is an open-source Python package based on Astropy and Photutils that can calculate Petrosian profiles and fit galaxy images. It offers end-to-end tools for making accurate photometric measurements, estimating morphological properties, and fitting 2D models to galaxy images. Petrosian metric radii can be used for model parameter estimation and aperture photometry to provide accurate total fluxes. Correction tools are provided for improving Petrosian radii estimates affected by galaxy morphology. PetroFit also provides tools for sampling Astropy-based models (including custom profiles and multicomponent models) onto image grids and enables point-spread function convolution to account for the effects of seeing. These capabilities provide a robust means of modeling and fitting galaxy light profiles. We have made the PetroFit package publicly available on GitHub (PetroFit/petrofit) and PyPi (pip install petrofit).

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

$\scriptsize\mathrm{{SQuIGG\overrightarrow{L}E}}$: Studying Quenching in Intermediate- z Galaxies—Gas, $\scriptsize\mathrm{{Angu\overrightarrow{L}ar}}$ Momentum, and Evolution

We describe the Studying Quenching in Intermediate-z Galaxies: Gas, $\scriptsize\mathrm{\rm{angu}}\overrightarrow{L}{\rm{ar}}$ momentum, and Evolution ($\scriptsize\mathrm{{SQuIGG\overrightarrow{L}E}}$) survey of intermediate-redshift post-starburst galaxies. We leverage the large sky coverage of the Sloan Digital Sky Survey to select ~1300 recently quenched galaxies at 0.5 < z ≤ 0.9 based on their unique spectral shapes. These bright, intermediate-redshift galaxies are ideal laboratories to study the physics responsible for the rapid quenching of star formation: they are distant enough to be useful analogs for high-redshift quenching galaxies, but low enough redshift that multiwavelength follow-up observations are feasible with modest telescope investments. We use the Prospector code to infer the stellar population properties and nonparametric star formation histories (SFHs) of all galaxies in the sample. We find that $\scriptsize\mathrm{{SQuIGG\overrightarrow{L}E}}$ galaxies are both very massive (M * ~ 10 11.25 M ⊙ ) and quenched, with inferred star formation rates ≲1 M ⊙ yr -1 , more than an order of magnitude below the star-forming main sequence. The best-fit SFHs confirm that these galaxies recently quenched a major burst of star formation: >75% of $\scriptsize\mathrm{{SQuIGG\overrightarrow{L}E}}$ galaxies formed at least a quarter of their total stellar mass in the recent burst, which ended just ~200 Myr before observation. We find that $\scriptsize\mathrm{{SQuIGG\overrightarrow{L}E}}$ galaxies are on average younger and more burst-dominated than most other z ≲ 1 post-starburst galaxy samples. This large sample of bright post-starburst galaxies at intermediate redshift opens a wide range of studies into the quenching process. In particular, the full $\scriptsize\mathrm{{SQuIGG\overrightarrow{L}E}}$ survey will investigate the molecular gas reservoirs, morphologies, kinematics, resolved stellar populations, active galactic nucleus incidence, and infrared properties of this unique sample of galaxies in order to place definitive constraints on the quenching process.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

ESCARGOT: Mapping Vertical Phase Spiral Characteristics Throughout the Real and Simulated Milky Way

Abstract The recent discovery of a spiral pattern in the vertical kinematic structure in the solar neighborhood provides a prime opportunity to study nonequilibrium dynamics in the Milky Way from local stellar kinematics. Furthermore, results from simulations indicate that even in a limited volume, differences in stellar orbital histories allow us to trace variations in the initial perturbation across large regions of the disk. We present ESCARGOT , a novel algorithm for studying these variations in both simulated and observed data sets. ESCARGOT automatically extracts key quantities from the structure of a given phase spiral, including the time since perturbation and the perturbation mode. We test ESCARGOT on simulated data and show that it is capable of accurately recovering information about the time since the perturbation occurred as well as subtle differences in phase spiral morphology due to stellar locations in the disk at the time of perturbation. We apply ESCARGOT to kinematic data from data release 3 of the Gaia mission in bins of guiding radius. We show that similar structural differences in morphology occur in the Gaia phase spirals as a function of stellar orbital history. These results indicate that the phase spirals are the product of a complex dynamical response in the disk with large-scale coupling between different regions of phase space.

Darragh-Ford, Elise (ORCID:0000000288005652)↗
DOE OSTI2024

Geophysical Observations of the 2023 September 24 OSIRIS-REx Sample Return Capsule Reentry

Sample return capsules (SRCs) entering Earth's atmosphere at hypervelocity from interplanetary space are a valuable resource for studying meteor phenomena. The 2023 September 24 arrival of the Origins, Spectral Interpretation, Resource Identification, and Security-Regolith Explorer SRC provided an unprecedented chance for geophysical observations of a well-characterized source with known parameters, including timing and trajectory. A collaborative effort involving researchers from 16 institutions executed a carefully planned geophysical observational campaign at strategically chosen locations, deploying over 400 ground-based sensors encompassing infrasound, seismic, distributed acoustic sensing, and Global Positioning System technologies. Additionally, balloons equipped with infrasound sensors were launched to capture signals at higher altitudes. This campaign (the largest of its kind so far) yielded a wealth of invaluable data anticipated to fuel scientific inquiry for years to come. The success of the observational campaign is evidenced by the near-universal detection of signals across instruments, both proximal and distal. This paper presents a comprehensive overview of the collective scientific effort, field deployment, and preliminary findings. The early findings have the potential to inform future space missions and terrestrial campaigns, contributing to our understanding of meteoroid interactions with planetary atmospheres. Furthermore, the data set collected during this campaign will improve entry and propagation models and augment the study of atmospheric dynamics and shock phenomena generated by meteoroids and similar sources.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2025

Potential absence of observed π2 linear-chain structures in 14O via 10C(α,α) resonances scattering

Background: The preference for light nuclear systems to coagulate into -particle clusters has been well-studied. The possibility of a linear chain configuration of -particles would allow for a new way to study this phenomenon. Purpose: A rotational band of states in C has been claimed showing a linear chain structure. The mirror system, O, has been studied here to examine how this linear chain structure is affected by replacing the valence neutrons with protons. Method: A beam of C was incident into a chamber filled with He:CO gas with the tracks recorded inside the TexAT Time Projection Chamber and the recoil -particles detected by a silicon detector array to measure the cross section. Results: The experimental cross section was compared with previous studies and fit using R-Matrix theory with the previously-observed O states being transformed to the C using mirror symmetry. The measured cross section does not replicate the claimed states, with the predicted cross section exceeding that observed at several energies and angles. Conclusion: A series of possibilities are highlighted with the most likely being that the originally-seen C states did not constitute a rotational band with a potentially incorrect spin assignment due to the limitations of the angular correlation method with non-zero spin particles. The work highlights the difficulties in measuring broad resonances corresponding to a linear chain state in a high level density.

Bishop, J.↗
DOE OSTI2023

Oxidation of NiCr and NiCrMo Alloys at Low Temperatures

Oxidation of Ni-Cr and Ni-Cr-Mo was studied in operando with near ambient pressure x-ray photoelectron spectroscopy in the Cabrera-Mott regime. The oxidation temperature was 200 °C - a severely diffusion limited regime. The near-surface alloy is Cr-enriched after reduction of natives oxide in vacuum, and especially so for Ni-15Cr-6Mo. Mo-cations are integrated in the oxide and Mo(VI) dominates at the surface. The surface chemistry driven promotion of chromia by Mo predicted by theory is negated by the limited surface diffusion of reactants. Furthermore, pre-oxidation processing is proposed to control the oxide properties for use of Ni-Cr superalloys at low temperatures.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Non-linear hydrologic organization

We revisit three variants of the well-known Stommel diagrams that have been used to summarize knowledge of characteristic scales in time and space of some important hydrologic phenomena and modified these diagrams focusing on spatiotemporal scaling analyses of the underlying hydrologic processes. In the present paper we focus on soil formation, vegetation growth, and drainage network organization. We use existing scaling relationships for vegetation growth and soil formation, both of which refer to the same fundamental length and timescales defining flow rates at the pore scale but different powers of the power law relating time and space. The principle of a hierarchical organization of optimal subsurface flow paths could underlie both root lateral spread (RLS) of vegetation and drainage basin organization. To assess the applicability of scaling, and to extend the Stommel diagrams, data for soil depth, vegetation root lateral spread, and drainage basin length have been accessed. The new data considered here include timescales out to 150 Myr that correspond to depths of up to 240 m and horizontal length scales up to 6400 km and probe the limits of drainage basin development in time, depth, and horizontal extent.

58 GEOSCIENCES↗
DOE OSTI2026

Assessment of Energy Technology Options for the Island of Molokai, Hawaii: Analysis of Floating Solar, Pumped Storage Hydropower, and Backup Energy Systems [Slides]

This presentation summarizes analysis done by researchers at the National Laboratory of the Rockies and Pacific Northwest National Laboratory to evaluate the potential for and explore project concepts of electricity generation and storage additions on the island of Molokai, Hawaii, as identified in the Community Energy Resilience Action Plan (CERAP) by the Molokai Clean Energy Hui (MCEH), Sustainable Molokai, and the Hawaii Natural Energy Institute (HNEI). These electricity generation and storage additions include distributed photovoltaics (PV), battery energy storage, and generators for critical facilities on the island that can provide backup energy to the facilities during grid disruptions and outages, a floating PV (FPV) system on Kualapuu Reservoir, and pumped storage hydropower (PSH) systems scaled to act as a significant or primary source of energy storage on the Molokai grid. This presentation accompanies the full technical report published under the same title.

14 SOLAR ENERGY↗
DOE OSTI2026

Advanced-Research-on-Integrated-Energy-Systems-Based Analysis to Support Resilient System Upgrades: Energy to Communities Energyshed In-Depth Partnership with Molokai, Hawaii

The Molokai, Hawaii, Energy to Communities (E2C) Energyshed project represents a collaborative effort between the National Laboratory of the Rockies, Shake Energy Collaborative, the Molokai Clean Energy Hui, Sustainable Molokai, and Ho'ahu Energy Cooperative Molokai to advance Molokai's Community Energy Resilience Action Plan (CERAP). Supported by Hawaiian Electric Company and the Hawaii State Energy Office, the initiative aims to develop a community-defined portfolio of renewable energy solutions that enhance energy resilience while aligning with the Hawaiian Electric Integrated Grid Plan (IGP) and Molokai's energy goals. Phase 1 focused on technical analyses and community engagement to co-design feasible energy scenarios. Challenges such as grid upgrades, storage sizing, and inverter ride-through standards were addressed to align technical and operational requirements with community preferences. The project equips Molokai with actionable data and insights to implement energy initiatives while ensuring resilient and culturally informed solutions. Future efforts aim to finalize project designs, secure interconnection agreements, and deploy energy projects that reflect community priorities and technical feasibility.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2026

Assessment of Energy Technology Options for the Island of Molokai, Hawaii: Analysis of Floating Solar, Pumped Storage Hydropower, and Backup Energy Systems

This report documents analysis done by researchers at the National Laboratory of the Rockies and Pacific Northwest National Laboratory to evaluate the potential for and explore project concepts of electricity generation and storage additions on the island of Molokai, Hawaii, as identified in the Community Energy Resilience Action Plan (CERAP) by the Molokai Clean Energy Hui (MCEH), Sustainable Molokai, and the Hawaii Natural Energy Institute (HNEI). These electricity generation and storage additions include distributed photovoltaics (PV), battery energy storage, and generators for critical facilities on the island that can provide backup energy to the facilities during grid disruptions and outages, a floating PV (FPV) system on Kualapuu Reservoir, and pumped storage hydropower (PSH) systems scaled to act as a significant or primary source of energy storage on the Molokai grid.

13 HYDRO ENERGY↗
DOE OSTI2020

Casein kinase 1 dynamics underlie substrate selectivity and the PER2 circadian phosphoswitch

Post-translational control of PERIOD stability by Casein Kinase 1δ and ε (CK1) plays a key regulatory role in metazoan circadian rhythms. Despite the deep evolutionary conservation of CK1 in eukaryotes, little is known about its regulation and the factors that influence substrate selectivity on functionally antagonistic sites in PERIOD that directly control circadian period. Here we describe a molecular switch involving a highly conserved anion binding site in CK1. This switch controls conformation of the kinase activation loop and determines which sites on mammalian PER2 are preferentially phosphorylated, thereby directly regulating PER2 stability. Integrated experimental and computational studies shed light on the allosteric linkage between two anion binding sites that dynamically regulate kinase activity. We show that period-altering kinase mutations from humans to Drosophila differentially modulate this activation loop switch to elicit predictable changes in PER2 stability, providing a foundation to understand and further manipulate CK1 regulation of circadian rhythms.

59 BASIC BIOLOGICAL SCIENCES↗