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At least 631 records · Page 35

Forced convection heat transfer to air/water vapor mixtures

Heat transfer coefficients were measured using both dry and humid air in the same forced convection cooling scheme and were compared using appropriate nondimensional parameters (Nusselt, Prandtl and Reynolds numbers). A forced convection scheme with a complex flow field, two dimensional arrays of circular jets with crossflow, was utilized with humidity ratios (mass ratio of water vapor to air) up to 0.23. The dynamic viscosity, thermal conductivity and specific heat of air, steam and air/steam mixtures are examined. Methods for determining gaseous mixture properties from the properties of their pure components are reviewed as well as methods for determining these properties with good confidence. The need for more experimentally determined property data for humid air is discussed. It is concluded that dimensionless forms of forced convection heat transfer data and empirical correlations based on measurements with dry air may be applied to conditions involving humid air with the same confidence as for the dry air case itself, provided that the thermophysical properties of the humid air mixtures are known with the same confidence as their dry air counterparts.

Richards, D. R.↗

Environmental tests of metallization systems for terrestrial photovoltaic cells

Seven different solar cell metallization systems were subjected to temperature cycling tests and humidity tests. Temperature cycling excursions were -50 deg C to 150 deg C per cycle. Humidity conditions were 70 deg C at 98% relative humidity. The seven metallization systems were: Ti/Ag, Ti/Pd/Ag, Ti/Pd/Cu, Ni/Cu, Pd/Ni/Solder, Cr/Pd/Ag, and thick film Ag. All metallization systems showed a slight to moderate decrease in cell efficiencies after subjection to 1000 temperature cycles. Six of the seven metallization systems also evidenced slight increases in cell efficiencies after moderate numbers of cycles, generally less than 100 cycles. The copper based systems showed the largest decrease in cell efficiencies after temperature cycling. All metallization systems showed moderate to large decreases in cell efficiencies after 123 days of humidity exposure. The copper based systems again showed the largest decrease in cell efficiencies after humidity exposure. Graphs of the environmental exposures versus cell efficiencies are presented for each metallization system, as well as environmental exposures versus fill factors or series resistance.

Alexander, P., Jr.↗

Physics of greenhouse effect and convection in warm oceans

Sea surface temperature (SST) in roughly 50% of the tropical Pacific Ocean is warm enough (SST greater than 300 K) to permit deep convection. This paper examines the effects of deep convection on the climatological mean vertical distributions of water vapor and its greenhouse effect over such warm oceans. The study, which uses a combination of satellite radiation budget observations, atmospheric soundings deployed from ships, and radiation model calculations, also examines the link between SST, vertical distribution of water vapor, and its greenhouse effect in the tropical oceans. Since the focus of the study is on the radiative effects of water vapor, the radiation model calculations do not include the effects of clouds. The data are grouped into nonconvective and convective categories using SST as an index for convective activity. On average, convective regions are more humid, trap significantly more longwave radiation, and emit more radiation to the sea surface. The greenhouse effect in regions of convection operates as per classical ideas, that is, as the SST increases, the atmosphere traps the excess longwave energy emitted by the surface and reradiates it locally back to the ocean surface. The important departure from the classical picture is that the net (up minus down) fluxes at the surface and at the top of the atmosphere decrease with an increase in SST; that is, the surface and the surface-troposphere column lose the ability to radiate the excess energy to space. The cause of this super greenhouse effect at the surface is the rapid increase in the lower-troposphere humidity with SST; that of the column is due to a combination of increase in humidity in the entire column and increase in the lapse rate within the lower troposphere. The increase in the vertical distribution of humidity far exceeds that which can be attributed to the temperature dependence of saturation vapor pressure; that is, the tropospheric relative humidity is larger in convective regions. The positive coupling between SST and the radiative warming of the surface by the water vapor greenhouse effect is also shown to exist on interannual time scales.

Inamdar, A. K.↗

Effect of stratification and geometrical spreading on sonic boom rise time

The purpose of our investigation is to determine the effect of unsteadiness (not associated with turbulence) on rise time. The unsteadiness considered here is due to (1) geometrical spreading, (2) stratification, which includes variation in density, temperature, and relative humidity, and (3) N shaped waveform. A very general Burgers equation, which includes all these effects, is the propagation model for our study. The equation is solved by a new computational algorithm in which all the calculations are done in the time domain. The present paper is a progress report in which some of the factors contributing to unsteadiness are studied, namely geometrical spreading and variation in relative humidity. The work of Pierce and Kang, which motivated our study, is first reviewed. We proceed with a discussion of the Burgers equation model and the algorithm for solving the equation. Some comparison tests to establish the validity of the algorithm are presented. The algorithm is then used to determine the distance required for a steady-state shock, on encountering an abrupt change in relative humidity, to reach a new steady state based on the new humidity. It is found that the transition distance for plane shocks of amplitude 70 Pa is about 4 km when the change in relative humidity is 10 percent. Shocks of amplitude 140 Pa require less distance. The effect of spherical and cylindrical spreading is also considered. We demonstrate that a spreading shock wave never reaches steady state and that its rise time will be less than the equivalent steady state shock. Finally we show that an N wave has a slightly shorter rise time than a step shock of the same amplitude.

Cleveland, Robin O.↗

Friction and Wear Properties of As-deposited and Carbon Ion-implanted Diamond Films

Recent work on the friction and wear properties of as-deposited and carbon ion-implanted diamond films was reviewed. Diamond films were produced by the microwave plasma chemical vapor deposition (CVD) technique. Diamond films with various grain sizes and surface roughnesses were implanted with carbon ions at 60 ke V ion energy, resulting in a dose of 1.2310(exp 17) carbon ions/cm(exp 2). Various analytical techniques, including Raman spectroscopy, proton recoil analysis, Rutherford backscattering, transmission and scanning electron microscopy, x-ray photoelectron spectroscopy, and x-ray diffraction, were utilized to characterize the diamond films. Sliding friction experiments were conducted with a polished natural diamond pin in contact with diamond films in the three environments: humid air (40 percent relative humidity), dry nitrogen (less than 1 percent relative humidity), and ultrahigh vacuum (10(exp -7) Pa). The CVD diamond films indeed have friction and were properties similar to those of natural diamond in the three environments. The as-deposited, fine-grain diamond films can be effectively used as self-lubricating, wear-resistant coatings that have low coefficients of friction (0.02 to 0.04) and low wear rates (10(exp -7) to 10(exp -8)mm(exp 3)/N-m) in both humid air and dry nitrogen. However, they have high coefficients of friction (1.5 to 1.7) and a high wear rate (10(exp -4)mm(exp 3/N-m) in ultrahigh vacuum. The carbon ion implanation produced a thin surficial layer (less than 0.1 micron thick) of amorphous, nondiamond carbon on the diamond films. In humid air and dry nitrogen, the ion-implanted, fine- and coarse-grain diamond films have a low coefficient of friction (around 0.1) and a low wear rate (10(exp -7)mm(exp 3/N-m). Even in ultrahigh vacuum, the presence of the nondiamond carbon layer reduced the coefficient of friction of fine-grain diamond films to 0.1 or lower and the wear rate to 10(exp -6)mm(exp 3)/N-m. Thus, the carbon ion-implanted, fine-grain diamond films can be effectively used as wear-resistant, self-lubricating coatings not only in air and dry nitrogen, but also in ultrahigh vacuum. The wear mechanism of diamond films is that of small fragments chipping off the surface. The size of wear particles is related to the extent of wear rates.

Miyoshi, Kazuhisa↗

Validation of clear-sky fluxes for tropical oceans from the Earth Radiation Budget Experiment

The existence and magnitude of a systematic bias in the clear-sky longwave fluxes from the Earth Radiation Budget Experiment (ERBE) is investigated. The bias is apparently introduced because the ERBE method for scene identification does not account for large zonal gradients in longwave absorption by water vapor. The ERBE fluxes are compared to fluxes calculated with a radiative transfer model from ship radiosonde measurements. The comparison is based upon an analysis of 5 yr of coincident satellite and radiosonde observations for equatorial ocean regions. The differences between the ERBE and model fluxes are examined as functions of sea surface temperature (SST) and relative humidity. The authors use height-mean relative humidity bar-RH as an index of atmospheric moisture. The average offset between and model ERBE fluxes ranges between +2 and +6 W/sq m for SSTs above 295 K, and the gradients with respect to SST are nearly identical. However, the difference between the model and ERBE depends significantly on the tropospheric relative humidity. ERBE fluxes exceed model fluxes for bar-RH above 70%, and the maximum offset of +9 to +12 W/sq m is consistent with previous estimates. There are also indications that the clear-sky fluxes for bar-RH below 25% may be underestimated by about 10-15 W/sq m. Since extreme values of height-mean humidity are relatively infrequent, the net bias introduced in the ERBE monthly mean clear-sky fluxes is generally less than the systematic error in estimates introduced in the ERBE monthly mean clear-sky fluxes is generally less than the systematic error in estimates of the instantaneous fluxes. These findings support earlier work on the coupling between SST and the atmospheric greenhouse effect, in particular the existence of a super greenhouse effect for oceans warmer than 300 K. Recent reports of much larger systematic differences are not supported by this analysis. The results indicate that comparison of general circulation model (GCM) and ERBE clear-sky longwave fluxes will depend explicitly on atmospheric humidity.

Collins, W. D.↗

Friction and Wear Properties of As-Deposited and Carbon Ion-Implanted Diamond Films

Recent work on the friction and wear properties of as-deposited and carbon ion-implanted diamond films was reviewed. Diamond films were produced by the microwave plasma chemical vapor deposition (CVD) technique. Diamond films with various grain sizes and surface roughnesses were implanted with carbon ions at 60 keV ion energy, resulting in a dose of 1.2 x 10(exp 17) carbon ions per cm(exp 2). Various analytical techniques, including Raman spectroscopy, proton recoil analysis, Rutherford backscattering, transmission and scanning electron microscopy, X-ray photoelectron spectroscopy, and X-ray diffraction, were utilized to characterize the diamond films. Sliding friction experiments were conducted with a polished natural diamond pin in contact with diamond films in the three environments: humid air (40% relative humidity), dry nitrogen (less than 1 percent relative humidity), and ultrahigh vacuum (10(exp -7) Pa). The CVD diamond films indeed have friction and wear properties similar to those of natural diamond in the three environments. The as-deposited, fine-grain diamond films can be effectively used as self-lubricating, wear-resistant coatings that have low coefficients of friction (0.02 to 0.04) and low wear rates (10(exp -7) to lO(exp -8) mm(exp 3) N(exp -1) m(exp -1)) in both humid air and dry nitrogen. However, they have high coefficients of friction (1.5 to 1.7) and a high wear rate (10(exp -4) mm(exp 7) N(exp -1) m(exp -1)) in ultrahigh vacuum. The carbon ion implantation produced a thin surficial layer (less than 0.1 micron thick) of amorphous, non-diamond carbon on the diamond films. In humid air and dry nitrogen, the ion-implanted, fine and coarse-grain diamond films have a low coefficient of friction (around 0.1) and a low wear rate (10(exp -7) mm(exp 3) N(exp -1) m(exp-1)). Even in ultrahigh vacuum, the presence of the non-diamond carbon layer reduced the coefficient of friction of fine-grain diamond films to 0.1 or lower and the wear rate to 10(exp -6) mm(exp 3) N(exp -1) m(exp -1). Thus, the carbon ion-implanted, fine-grain diamond films can be effectively used as wear-resistant, self-lubricating coatings not only in air and dry nitrogen, but also in ultrahigh vacuum.

Miyoshi, Kazuhisa↗

How Dry is the Tropical Free Troposphere? Implications for Global Warming Theory

The humidity of the free troposphere is being increasingly scrutinized in climate research due to its central role in global warming theory through positive water vapor feedback. This feedback is the primary source of global warming in general circulation models (GCMs). Because the loss of infrared energy to space increases nonlinearly with decreases in relative humidity, the vast dry zones in the Tropics are of particular interest. These dry zones are nearly devoid of radiosonde stations, and most of those stations have, until recently, ignored the low humidity information from the sondes. This results in substantial uncertainty in GCM tuning and validation based on sonde data. While satellite infrared radiometers are now beginning to reveal some information about the aridity of the tropical free troposphere, the authors show that the latest microwave humidity sounder data suggests even drier conditions than have been previously reported. This underscores the importance of understanding how these low humidity levels are controlled in order to tune and validate GCMs, and to predict the magnitude of water vapor feedback and thus the magnitude of global warming.

Spencer, Roy W.↗

Sliding Wear and Fretting Wear of DLC-Based, Functionally Graded Nanocomposite Coatings

Improving the tribological functionality of diamondlike carbon (DLC) films--developing, good wear resistance, low friction, and high load-carrying capacity-was the aim of this investigation. Nanocomposite coatings consisting of an amorphous DLC (a-DLC) top layer and a functionally graded titanium-titanium carbon-diamondlike carbon (Ti-Ti(sub x) C(sub y)-DLC) underlayer were produced on AISI 440C stainless steel substrates by the hybrid technique of magnetron sputtering and pulsed-laser deposition. The resultant DLC films were characterized by Raman spectroscopy, scanning electron microscopy, and surface profilometry. Two types of wear experiment were conducted in this investioation: sliding friction experiments and fretting wear experiments. Unidirectional ball-on-disk sliding friction experiments were conducted to examine the wear behavior of an a-DLC/Ti-Ti(sub x) C(sub y)-DLC-coated AISI 440C stainless steel disk in sliding contact with a 6-mm-diameter AISI 440C stainless steel ball in ultrahigh vacuum, dry nitrogen, and humid air. Although the wear rates for both the coating and ball were low in all three environments, the humid air and dry nitrogen caused mild wear with burnishing, in the a-DLC top layer, and the ultrahigh vacuum caused relatively severe wear with brittle fracture in both the a-DLC top layer and the Ti-Ti(sub x) C(sub y)-DLC underlayer. For reference, amorphous hydrogenated carbon (H-DLC) films produced on a-DLC/Ti-Ti(sub x) C(sub y)-DLC nanocomposite coatings by using an ion beam were also examined in the same manner. The H-DLC films markedly reduced friction even in ultrahigh vacuum without sacrificing wear resistance. The H-DLC films behaved much like the a-DLC/Ti-Ti(sub x) C(sub y)-DLC nanocomposite coating in dry nitrogen and humid air, presenting low friction and low wear. Fretting wear experiments were conducted in humid air (approximately 50% relative humidity) at a frequency of 80 Hz and an amplitude of 75 micron on an a-DLC/Ti-Ti(sub x) C(sub y)-DLC-coated AISI 440C disk and on a titanium-6 wt % aluminum-4 wt% vanadium (Ti-6Al-4V) flat, both in contact with a 9.4-mm-diameter, hemispherical Ti-6Al-4V pin. The resistance to fretting wear and damage of the a-DLC/Ti-6Al-4V materials pair was superior to that of the Ti-6Al-4V/Ti-6AI-4V materials pair.

Miyoshi, K.↗

Electrochemical Measurement of Atmospheric Corrosion

Corrosion of Shuttle thruster components in atmospheres containing high concentrations of nitrogen tetroxide (NTO) and water is an important issue in ground operations of bipropellant systems in humid locations. Measurements of the corrosivities of NTO-containing atmospheres and the responses of different materials to these atmospheres have been accomplished using an electrochemical sensor. The sensor is composed of alternating aluminum/titanium strips separated by thin insulating layers. Under high humidity conditions a thin film of water covers the surface of the sensor. Added NTO vapor reacts with the water film to form a conductive medium and establishes a galvanic cell. The current from this cell can be integrated with respect to time and related to the corrosion activity. The surface layer formed from humid air/NTO reacts in the same way as an aqueous solution of nitric acid. Nitric acid is generally considered an important agent in NTO corrosion situations. The aluminum/titanium sensor is unresponsive to dry air, responds slightly to humid air (> 75% RH), and responds strongly to the combination of humid air and NTO. The sensor response is a power function (n = 2) of the NTO concentration. The sensor does not respond to NTO in dry air. The response of other materials in this type of sensor is related to position of the material in a galvanic series in aqueous nitric acid. The concept and operation of this electrochemical corrosion measurement is being applied to other corrosive atmospheric contaminants such as hydrogen chloride, hydrogen fluoride, sulfur dioxide, and acidic aerosols.

DeArmond, Anna H.↗

Friction and Wear Properties of Selected Solid Lubricating Films

To evaluate commercially developed solid film lubricants for aerospace bearing applications, we investigated the friction and wear behavior of bonded molybdenum disulfide (MoS2), magnetron-sputtered MoS2 and ion-plated silver films in sliding contact with 6-mm-diameter American Iron and Steel Institute (AISI) 440 C stainless steel balls. Unidirectional sliding friction experiments were conducted with a load of 5.9 N (600 g), a mean Herizian contact pressure of 0.79 GPa maximum 1.19 GPa), and a sliding velocity of 0.2 m/s at room temperature in three environments: ultrahigh vacuum (7x10 (exp -7Pa)), humid air (approx. 20 percent humidity), and dry nitrogen (less than 1 percent humidity). The resultant films were characterized by scanning electron microscopy, energy-dispersive x-ray spectroscopy, and surface profilometry. Marked differences in friction and wear resulted front the environmental conditions and the film materials. The main criteria for judging the performance were coefficient of friction and wear rate, which had to be less than 0.3 and on the order of 10 (exp -6mm exp 3/Nm or less), respectively. The bonded MoS2 and magnetron-sputtered MoS2 films met the criteria in all three environments. Also, the wear rates of the counterpart AISI 440 C stainless steel balls met that criterion in all three environments. The ion-plated silver films met the criteria only in ultrahigh vacuum. In ultrahigh vacuum the bonded MoS2 films were superior. In humid air the bonded MoS2 films had higher coefficient of friction and shorter wear life than did the magnetron-sputtered MoS2 films. The ion-plated silver films had a high coefficient of friction in humid air but relatively low coefficients of friction in the nonoxidative environments. Adhesion and plastic deformation played important roles in all three environments. All sliding involved adhesive transfer of materials.

Miyoshi, Kazuhisa↗

Reliable, Low-Cost, Low-Weight, Non-Hermetic Coating for MCM Applications

Through an Air Force Research Laboratory sponsored STM program, reliable, low-cost, low-weight, non-hermetic coatings for multi-chip-module(MCK applications were developed. Using the combination of Sandia Laboratory ATC-01 test chips, AvanTeco's moisture sensor chips(MSC's), and silicon slices, we have shown that organic and organic/inorganic overcoatings are reliable and practical non-hermetic moisture and oxidation barriers. The use of the MSC and unpassivated ATC-01 test chips provided rapid test results and comparison of moisture barrier quality of the overcoatings. The organic coatings studied were Parylene and Cyclotene. The inorganic coatings were Al2O3 and SiO2. The choice of coating(s) is dependent on the environment that the device(s) will be exposed to. We have defined four(4) classes of environments: Class I(moderate temperature/moderate humidity). Class H(high temperature/moderate humidity). Class III(moderate temperature/high humidity). Class IV(high temperature/high humidity). By subjecting the components to adhesion, FTIR, temperature-humidity(TH), pressure cooker(PCT), and electrical tests, we have determined that it is possible to reduce failures 50-70% for organic/inorganic coated components compared to organic coated components. All materials and equipment used are readily available commercially or are standard in most semiconductor fabrication lines. It is estimated that production cost for the developed technology would range from $1-10/module, compared to $20-200 for hermetically sealed packages.

Jones, Eric W.↗

Evaluation of Selected Solid Lubricating Films

An investigation was conducted to examine the friction and wear properties of bonded molybdenum disulfide (MoS2), magnetron-sputtered MoS2, ion-plated silver, ion-plated lead, magnetron-sputtered diamondlike carbon (MS DLC), and plasma-assisted, chemical-vapor-deposited DLC (PACVD DLC) films in sliding contact with 6-mm-diameter AISI 440C stainless steel balls. Unidirectional ball-on-disk sliding friction experiments were conducted with a load of 5.9 N and a sliding velocity of 0.2 m/s at room temperature in three environments: ultrahigh vacuum (vacuum pressure, 7 x 10(exp -7) Pa), humid air (relative humidity, approx. 20 percent), and dry nitrogen (relative humidity, less than 1 percent). The main criteria for judging the performance of the solid lubricating films were coefficient of friction and wear rate, which had to be less than 0.3 and on the order of 10(exp -6) cubic mm/N(dot)m or less, respectively. The bonded MoS2 and magnetron-sputtered MoS2 films met the criteria in all three environments. The ion-plated lead and silver films met the criteria only in ultrahigh vacuum but failed in humid air and in dry nitrogen. The MS DLC and PACVD DLC films met the requirements in humid air and dry nitrogen but failed in ultrahigh vacuum.

Miyoshi, Kazuhisa↗

Durability Evaluation of Selected Solid Lubricating Films

An investigation was conducted to examine the coefficients of friction, wear rates, and durability of bonded molybdenum disulfide (MoS2), magnetron-sputtered MoS2, ion-plated silver, ion-plated lead, magnetron-sputtered diamondlike carbon (MS DLC), and plasma-assisted, chemical-vapor-deposited DLC (PACVD DLC) films in sliding contact with 6-mm-diameter AISI 440C stainless steel balls. Unidirectional ball-on-disk sliding friction experiments were conducted with a load of 5.9 N and a sliding velocity of 0.2 m/s at room temperature in three environments: ultrahigh vacuum (vacuum pressure, 7 x 10(exp -7) Pa), humid air (relative humidity, approx. 20 percent), and dry nitrogen (relative humidity, less than 1 percent). The main criteria for judging the performance of the solid lubricating films were coefficient of friction and wear rate, which had to be less than 0.3 and on the order of 10(exp -6) cu mm/N.m or less, respectively. The bonded MoS2 and magnetron-sputtered MoS2 films met the criteria in all three environments. The ion-plated lead and silver films met the criteria only in ultrahigh vacuum but failed in humid air and in dry nitrogen. The MS DLC and PACVD DLC films met the requirements in humid air and dry nitrogen but failed in ultrahigh vacuum.

Miyoshi, Kazuhisa↗

The Sensitivity of West African Squall Line Water Budgets to Land Cover

This study used a two-dimensional coupled land/atmosphere (cloud-resolving) model to investigate the influence of land cover on the water budgets of squall lines in the Sahel. Study simulations used the same initial sounding and one of three different land covers, a sparsely vegetated semi-desert, a grassy savanna, and a dense evergreen broadleaf forest. All simulations began at midnight and ran for 24 hours to capture a full diurnal cycle. In the morning, the latent heat flux, boundary layer mixing ratio, and moist static energy in the boundary layer exhibited notable variations among the three land covers. The broadleaf forest had the highest latent heat flux, the shallowest, moistest, slowest growing boundary layer, and significantly more moist static energy per unit area than the savanna and semi-desert. Although all simulations produced squall lines by early afternoon, the broadleaf forest had the most intense, longest-lived squall lines with 29% more rainfall than the savanna and 37% more than the semi-desert. The sensitivity of the results to vegetation density, initial sounding humidity, and grid resolution was also assessed. There were greater differences in rainfall among land cover types than among simulations of the same land cover with varying amounts of vegetation. Small changes in humidity were equivalent in effect to large changes in land cover, producing large changes in the condensate and rainfall. Decreasing the humidity had a greater effect on rainfall volume than increasing the humidity. Reducing the grid resolution from 1.5 km to 0.5 km decreased the temperature and humidity of the cold pools and increased the rain volume.

Mohr, Karen I.↗

Evaporation/SST Sensitivity Over the Tropical Oceans During ENSO Events as Estimated from the da Silva, Young, Levitus Surface Marine Data Set

The da Silva, Young and Levitus Surface Marine Atlas, based on observations from the Comprehensive Ocean Atmosphere Data Set (COADS) Release 1, has been used to investigate the relationship between evaporation and sea-surface temperature (SST) over the global oceans. For the period 1950 to 1987 SST, surface latent heat flux, and other related variables have been filtered to minimize data uncertainties and to focus upon interannual variations associated with warm (El Nino) and cold (La Nina) ENSO events. Compositing procedures have enabled identification of systematic variations in latent heat fluxes accompanying these events and the relationship to spatial anomalies in ocean surface wind speed and humidity. The evaporation response associated with ENSO sea surface temperature (SST) variability is systematic in nature and composed of offsetting contributions from the surface wind and humidity variations. During warm events exceeding 1.0 S.D. delta SST, increases in the surface humidity deficit, delta(qs-qa), between the surface and 2m height dominate regions of positive SST anomalies and lead to increases in evaporation of almost 2 Wm (exp -2) at deltaSST = 0.23 K. Despite the increases in specific humidity, relative humidity decreases slightly in regions of elevated SSTs. For the most part, variations in wind speed are consistent with previous investigations. Weakening of the equatorial easterlies (and generation of westerlies) between 160 degrees E and 140 degrees W dominates during the early phases of warm events. Elevated wind speeds in adjacent subtropical regions and in the eastern equatorial Pacific subsequently develop too. The net contribution of these winds, which reflect adjustments in Hadley and Walker circulation components is toward reduced evaporation. Results for cold periods are approximately similar, but opposite in sign to warm events, though evidence of different temporal evolution is noted.

Robertson, F. R.↗

Tropical Ocean Evaporation/SST Sensitivity and It's Link to Water and Energy Budget Variations During ENSO

The continuing debate over feedback mechanisms governing tropical sea surface temperatures (SSTs) and tropical climate in general has highlighted the diversity of potential checks and balances within the climate system. Competing feedbacks due to changes in surface evaporation, water vapor, and cloud long- and shortwave radiative properties each may serve critical roles in stabilizing or destabilizing the climate system. It is also intriguing that even those climate variations having origins internal to the climate system - changes in ocean heat transport for example, apparently require complementary equilibrating effects by changes in atmospheric energy fluxes. Perhaps the best observational evidence of this is the relatively invariant nature of tropically averaged net radiation exiting the top-of-atmosphere (TOA) as measured by broadband satellite sensors over the past two decades. Thus, analyzing how these feedback mechanisms are operating within the context of current interannual variability may offer considerable insight for anticipating future climate change. In this paper we focus primarily on interannual variations of ocean evaporative fluxes and their significance for coupled water and energy cycles within the tropical climate system. In particular, we use both the da Silva estimates of surface fluxes (based on the Comprehensive Ocean Atmosphere Data Set, COADS) and numerical simulations from several global climate models to examine evaporation sensitivity to perturbations in SST associated with warm and cold ENSO events. The specific questions we address are as follows: (1) What recurring patterns of surface wind and humidity anomalies are present during ENSO and how do they combine to yield systematic evaporation anomalies?, (2) What is the resulting tropical ocean mean evaporation-SST sensitivity associated with this climate perturbation?, and (3) What role does this evaporation play in tropical heat and water balance over tropical oceanic regions? We use the da Silva ocean flux data to identify composite structure of departures of latent heat flux from climatology. We also show how these patterns arise out of associated wind and humidity anomaly distributions. Our preliminary work shows that evaporation sensitivity estimates from the da Silva / COADS data, computed for the tropical oceans (30 degrees N/S) are in the neighborhood of 5 to 6 W/square m K. Model estimates are also quite close to this figure. This rate is only slightly less than a rate corresponding to constant relative humidity; however, substantial regional departures from constant relative humidity are present. These patterns are robust and we relate the associated wind and humidity fluctuations noted in previous investigations to the derived evaporation anomalies. Finally, these results are interpreted with other data from the Earth radiation Budget Experiment (ERBE), Global Precipitation Climatology Project (GPCP) and NASA's Surface Radiation Budget (SRB) data set to characterize the tropical energetics of ENSO-related climate variability.

Robertson, Franklin R.↗

Auto Emission Testing

The photos show automobile engines being tested for nitrous oxide emissions, as required by the Environmental Protection Agency (EPA), at the Research and Engineering Division of Ford Motor Company, Dearborn. Michigan. NASA technical information helped the company develop a means of calculating emissions test results. Nitrous oxide emission readings vary with relative humidity in the test facility. EPA uses a standard humidity measurement, but the agency allows manufacturers to test under different humidity conditions, then apply a correction factor to adjust the results to the EPA standard. NASA's Dryden Flight Research Center developed analytic equations which provide a simple, computer-programmable method of correcting for humidity variations. A Ford engineer read a NASA Tech Brief describing the Dryden development and requested more detailed information in the form of a technical support package, which NASA routinely supplies to industry on request. Ford's Emissions Test Laboratory now uses the Dryden equations for humidity-adjusted emissions data reported to EPA.

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