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At least 631 records · Page 35

Biomass Pyrolysis to Hydrocarbon Fuels in the Petroleum Refining Context: Cooperative Research and Development Final Report, CRADA Number CRD-12-500

This work focuses on developing a thermochemical route to produce biofuels from agricultural wastes such as sugar cane bagasse, wood chips or corn stover; more specifically it intends to develop the biomass pyrolysis route, which produces bio-oils. Production of bio-oils by pyrolysis is a commercial technology. However, bio-oils are currently not being used for liquid fuels production. Although bio-oils can be produced by high-pressure liquefaction, pyrolysis is a less expensive technology. Nevertheless, bio-oils cannot be used directly as a transportation fuel without upgrading, since they are generally unstable, viscous, and acidic. Thus NREL and Petrobras intend to use their combined expertise to develop a two-step route to biofuels production: in the first step, a stable bio-oil is produced by NREL biomass pyrolysis technology, while in the second step it is upgraded by using two distinct catalytic processes under development by Petrobras. The first process converts bio-oil into gasoline, LPG, and fuel oil using the catalytic cracking process, while the second one, converts bio-oil into synthesis gas. Syngas gasification catalysts provided by both NREL and Petrobras will be tested. The work includes experiments at both sites to produce bio-oil and then biofuels, life-cycle analysis of each route, personnel training and development of analytical methods with a duration time of two years.

09 BIOMASS FUELS↗

Achieving Tier 4 Emissions in Biomass Cookstoves

Previous literature on top-lit updraft (TLUD) gasifier cookstoves suggested that these stoves have the potential to be the lowest emitting biomass cookstove. However, the previous literature also demonstrated a high degree of variability in TLUD emissions and performance, and a lack of general understanding of the TLUD combustion process. The objective of this study was to improve understanding of the combustion process in TLUD cookstoves. In a TLUD, biomass is gasified and the resulting producer gas is burned in a secondary flame located just above the fuel bed. The goal of this project is to enable the design of a more robust TLUD that consistently meets Tier 4 performance targets through a better understanding of the underlying combustion physics. The project featured a combined modeling, experimental and product design/development effort comprised of four different activities: Development of a model of the gasification process in the biomass fuel bed; Development of a CFD model of the secondary combustion zone; Experiments with a modular TLUD test bed to provide information on how stove design, fuel properties, and operating mode influence performance and provide data needed to validate the fuel bed model; Planar laser-induced fluorescence (PLIF) experiments with a two-dimensional optical test bed to provide insight into the flame dynamics in the secondary combustion zone and data to validate the CFD model; Design, development and field testing of a market ready TLUD prototype. Over 180 tests of 40 different configurations of the modular TLUD test bed were performed to demonstrate how stove design, fuel properties and operating mode influences performance, and the conditions under which Tier 4 emissions are obtainable. Images of OH and acetone PLIF were collected at 10 kHz with the optical test bed. The modeling and experimental results informed the design of a TLUD prototype that met Tier 3 to Tier 4 specifications in emissions and Tier 2 in efficiency. The final prototype was field tested in India.

09 BIOMASS FUELS↗

Reliable SOFC Systems

The goal of this U.S. Department of Energy (DOE) sponsored project was to advance the reliability, robustness and endurance of low-cost SOFC technology suitable for ultimate deployment in ≥100 MWe Integrated Gasification Fuel Cell (IGFC) or Natural Gas Fuel Cell (NGFC) systems capable of ≥97% CO2 capture. The ultimate SOFC program goals are ≤ 0.2% per 1000 hours power degradation over a 5-plus year stack life, high-volume (≥ 250 MW/year) stack production cost of ≤$225/kWsystem net AC, and “power block” (exclusive of fuel supply, contaminant removal, and CO2 capture subsystems) capital cost of ≤ 900/kWsystem net AC (in year 2011). To progress towards the ultimate program goals, the specific objectives of this project were to achieve an SOFC stack power degradation rate of ≤1.5% per 1000 hours in a 100 kW (125 kW Peak) Modular Power Block (MPB) stand-alone power system under thermally self-sustained normal operating conditions and to verify the prospects for high volume SOFC stack production cost below the DOE target of ≤ 225/kW. This final technical report summarizes the progress made during the project period of 36 months. Significant progress was made in the areas of cell and stack technology development, Modular Power Block (MPB) development, sub-MW MPB system development, and MW-class SOFC System Development and Costing. The work focused on areas necessary for comprehensive development of an SOFC fuel cell system, including, active cell improvement, contaminant resistance, process engineering, and development of non-repeat module components. Additionally, several custom built balance-of-plant components were designed and fabricated to support the fuel cell system. SOFC cell and stack development focused on improving cell performance and durability. Enhancements were achieved in areas of electrode stability and impurity tolerance. Additionally, several quality control techniques and tools were developed to ensure predictable and repeatable fabrication of SOFC stacks. Module development continued previous development efforts to achieve footprint reduction and higher efficiency by incorporating balance-of-plant functional equipment into the fuel cell containment module. Several improvements were made to prior design. Control and instrumentation hardware was integrated within the module for serviceability and size reduction. The design efforts culminated in a complete SOFC power plant system. The designed plant was constructed and tested at FCE. Stack and system costs were updated, reflecting advances made in this program.

20 FOSSIL-FUELED POWER PLANTS↗

Evolving Robust and Reconfigurable Multi-objective Controllers for Advanced Power Systems

Motivation: To meet the ever-increasing power requirements of our society, as well as minimize emissions and environmental impact, the efficiency, reliability, performance, and robustness of power plants need to improve significantly. As a consequence, research on all aspects of power plants, ranging from combustion, gasification, turbines, fuel cells, gas cleaning and separation and carbon dioxide separation and capture is being conducted. But it is not sufficient to simply provide advances in any (or all) of these areas. Advances in each of these areas increases the complexity of every component of a power system, and their integration creates fundamentally new problems in the areas of modeling, sensing, optimization and control.

20 FOSSIL-FUELED POWER PLANTS↗

Lignite-plus-Biomass to Synthetic Jet Fuel with CO2 Capture and Storage: Design, Cost, and Greenhouse Gas Emissions Analysis for a Near-Term First-of-a-Kind Demonstration Project and Prospective Future Commercial Plants

We report on a 30-month design study for a first-of-a-kind (FOAK) demonstration plant that would be built at a site near Meridian, Mississippi, to coprocess lignite coal and woody biomass into jet fuel. The design uses an oxygen-blown TRIG™ gasifier developed by KBR and Southern Company. Fischer-Tropsch conversion of the syngas produces synthetic paraffinic kerosene (SPK) as the primary product, plus naphtha. Other co-products include electricity sold to the grid and CO 2 sold for use in enhanced oil recovery (EOR). Previous studies have identified coprocessing of various coals and biomass with CO 2 capture as promising options for cost-competitive production of low net lifecycle greenhouse gas (GHG) emissions synthetic fuels. The effort reported here goes beyond earlier studies in the level of detail in process design and cost estimation with the aim of improving the understanding of the economic prospects for lignite and woody biomass coprocessing systems. Key objectives in the design of the FOAK lignite/biomass-to-jet (LBJ) plant were to achieve net lifecycle GHG emissions for the SPK that are less than for conventional petroleum-derived jet fuel and to make process design and equipment selections such that the plant could be built and operated in the near term, e.g., before 2025. The process design was developed by researchers at Princeton University and the University of Queensland and validated by engineers at the WorleyParsons Group (WP). Commercial vendors provided design and cost estimates for several major plant components. Bare-erected capital costs and operating and maintenance costs were estimated by WP. The primary objective in building and operating the FOAK plant would be to demonstrate the technical viability of the LBJ concept as an essential first step toward launching commercial-scale plants in the longer term. With this in mind, the project team developed a set of principles to help guide the process design: the total plant cost should be less than 2 billion USD (to limit investment risk); the level of input biomass should be both proportionally significant to reflect biomass/lignite co-gasification and sufficient to achieve GHG emissions goals; process design decisions and vendor/equipment selections should prioritize the likelihood of technical success over minimizing the cost of jet fuel production. The resulting FOAK plant design capacity is 1,551 metric t/d (45.5% moisture) lignite and 556 t/d (43.3% moisture) biomass, for a total input of 295 MW HHV , of which 25% is biomass. The design output is 1,252 actual barrels per day of liquids, of which 80% is SPK (62.3 MW LHV ) and 20% is naphtha (13.9 MW LHV ). It exports 15 MW e of electricity after satisfying a 38 MW e onsite auxiliary load. Additional products are 1,326 t/d of pressurized pipeline-quality CO 2 and 49 t/day of sulfuric acid (93 wt% H 2 SO 4 ). With thinnings from sustainably-managed southern pine plantations as the biomass, and with captured CO 2 stored underground via EOR, the net lifecycle emissions for the SPK product are estimated to be about one-quarter of those for petroleum-derived jet fuel. The bare-erected cost (BEC) estimated by WP for this plant is 588 million USD (2015). The authors’ best estimate of total plant cost (TPC) is 1,230 million USD, arrived at by assuming engineering, procurement and construction management services (20% of BEC), process 5 contingencies (35% of BEC), and project contingencies (35% of the sum of all other costs, i.e., 35% of 1.55xBEC). Not surprisingly, an annual discounted cash flow (DCF) analysis determined that it would be impossible to generate a positive net present value (NPV) over a wide range in key input assumptions. An SPK production cost subsidy of nearly 400/bbl USD over a 20-year plant life would be required to achieve zero NPV under a baseline set of assumptions (including 3% real weighted average cost of capital and a levelized crude oil price of 80/bbl USD). Alternatively, a capital grant in excess of the TPC value would also achieve zero NPV. The poor financial results reflect the small scale of the plant, the design principle to prioritize technical success, the levels of contingencies appropriate for the relatively early stage of project development, and the first-of-a-kind nature of the plant. Technology innovations, learning via construction and operating experience, alternative plant configurations, and larger scale should improve economics of future plants. To help understand these prospects, a preliminary analysis of N th -of-a-kind (NOAK) plants was developed, but with the limitation that plants would use only equipment components that for the most part are already commercial today: consideration of advanced, not-yet-commercial technologies and of R&D-driven improvements in existing technologies were beyond the scope of this analysis. The analysis found that a variety of NOAK plant designs that coprocess lignite and woody biomass to make jet fuel are unlikely to be economically competitive without subsidy even in the presence of a high future carbon tax or equivalent greenhouse gas mitigation policy. This conclusion applies to process configurations and input biomass/lignite ratios that result in net GHG emissions as high as those for petroleum-derived jet fuel and as low as zero. In contrast, encouraging results were found for plants processing only biomass. The economics of these “BECCS” plants (biomass energy with CCS) improve dramatically with the strength of carbon mitigation policies because of their strongly negative net GHG emissions. These findings do not imply that coal/biomass coprocessing strategies for making synfuels with CCS are not economically promising – only that, in the case of lignite, much more than a 25% biomass coprocessing rate would be needed. However, our analysis shows that all such systems are unlikely to be economic in the absence of a strong carbon mitigation policy. Future R&D driven technological innovations could modify this conclusion. Among other R&D priorities, an emphasis on better understanding and reducing plant auxiliary loads is warranted.

09 BIOMASS FUELS↗

AOI [3]: Smart Refractory Sensor Systems for Wireless Monitoring of Temperature, Health, and Degradation of Slagging Gasifiers

The objective of the work was to develop refractory “smart bricks”, which would contain embedded temperature, strain/stress, and spallation sensors throughout the volume of highchromia (-Cr 2 O 3 ) refractory brick. The proposed work included work to interconnect the sensors to the reactor exterior, where the sensor signals may be processed by low-power electronics and transmitted wirelessly to a central processing hub. The data processing and wireless transmitter hardware was specifically designed to be isolated (with low power consumption) and to be adaptable to future implementation of energy-harvesting strategies for extended life. Finally, the collected data was incorporated into a model to estimate refractory degradation, a technique that could help monitor the health of the refractory in real-time. The long-term goal of this program was to demonstrate high-temperature, wireless sensor arrays for in situ three-dimensional (3-D) refractory monitoring or mapping for slagging gasification systems. The research was in collaboration with HarbisonWalker International (HWI) Technology Center in West Mifflin, PA. HWI is a leading developer and manufacturer of ceramic refractory products for high-temperature applications. The work completed focused on the following areas: 1) Investigation of the chemical stability, microstructural evolution, grain growth kinetics, degree of homogeneity (quantitative image analysis), and electrical properties of refractory oxide-silicide composites at temperatures between 750-1450ºC; 2) Fabrication of silicide-alumina composite and oxide thermocouples and thermistor preforms and the development of techniques to embed them into high-chromia refractory bricks to form “smart bricks”; 3) Utilization of commercial off-the-shelf discrete components to prototype circuits for interfacing between smart brick sensors and the wireless sensor network. The prototypes were then used to design an integrated circuit for thermistor, thermocouple, and capacitive-based smart brick sensor interfacing; 4) Interfacing of the smart bricks with embedded sensors with wireless motes thus yielding a complete signal chain. This end-to-end data collection system was tested on a furnace heated to 1350°C; 5) Development of a slag penetration model and a nonlinear unknown input filter for the data from the embedded sensors for estimating temperature and extent of slag penetration.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Engineering Design of Advanced H 2 – CO 2 Pd and Pd/Alloy Composite Membrane Separations and Process Intensification

The integrated gasification combined cycle (IGCC) process is a way to co-produce synthesis gas, electricity, hydrogen, fuels and chemicals from coal and coal/biomass-mix in an environmentally responsible manner. The production of hydrogen via the water-gas shift (WGS) reaction is a key part of this process. Pd and Pd/Alloy-based catalytic membrane reactors used in the WGS process could significantly improve the efficiency of the IGCC process with a great potential for process intensification. Membrane reactors enable reaction, separation and product concentration to take place in a single unit operation, leading to conversion levels beyond thermodynamic equilibrium due to the continuous removal of H 2 . Worcester Polytechnic Institute (WPI) has developed composite Pd and Pd/alloy composite hydrogen separation membranes with high H 2 flux, excellent selectivity and long-term durability for this membrane reactor process. WPI membranes used in a natural gas reforming operation were stable for over 6,000 hours (>8 months) at 500°C and 40 bar. Under the DOE Hydrogen Pathway Program (DE-FC-26-07NT43058) Pd membranes prepared by WPI exceed the DOE 2015 targets for H 2 flux, selectivity and stability. Furthermore, the scalability of the WPI technology has been shown to be relatively easy, and composite Pd/Cu and Pd/Au alloy membranes have been shown to be sulfur resistant and permeance recoverable.

42 ENGINEERING↗

Cost and Performance Baseline for Fossil Energy Plants Supplement: Sensitivity to CO 2 Capture Rate in Coal-Fired Power Plants

The cost and performance of various plants designed to meet a range of carbon dioxide (CO 2 ) emissions are evaluated in this report by varying the CO 2 capture rate. The base cases for these designs are the supercritical (SC) pulverized coal (PC) plant from the National Energy Technology Laboratory’s (NETL) report “Cost and Performance Baseline for Fossil Energy Plants, Volume 1a: Bituminous Coal (PC) and Natural Gas to Electricity, Revision 3” and the General Electric Energy (GEE) integrated gasification combined cycle (IGCC) plant in NETL’s report, “Cost and Performance Baseline for Fossil Energy Plants, Volume 1b: Bituminous Coal (IGCC) to Electricity, Revision 2 – Year Dollar Update.” The chosen SC PC plants were based on the Case B12B, differing only in the addition of a bypass flow path that allows for an appropriate portion of the flue gas stream exiting the desulfurization step to be directed towards the stack, which reduces the amount CO 2 captured in the Cansolv process. The chosen IGCC plants were based on the Case B5B, differing by bypassing (either partially or entirely) the water gas shift reactors and thereby reducing the amount of CO 2 captured in the Selexol process. The major components of the underlying CO 2 capture technology in the plants were preserved with minimal modifications to the overall processes. The SC PC cases include up-to-date cost and performance information from recent vendor quotes whereas the IGCC performance and cost are based upon the older quotes used for the Revision 2 report, with standard adjustments made to update the costs to 2011 dollars.

01 COAL, LIGNITE, AND PEAT↗

Pilot Scale Operation and Testing of Syngas Chemical Looping For Hydrogen Production

The Syngas Chemical looping (SCL) process provides efficient and economic means to utilize the abundant fossil reserve of coal. The main problem associated with coal utilization is the CO 2 emissions resulting from its combustion. Even though CO 2 regulation or carbon tax is currently not in place, its enforcement is expected in the near future. Such a greenhouse gas emission control, if adopted in current power plant systems, will drive the efficiency down and increase the cost of electricity, due to the energy and capital-intensive nature of current CO 2 separation techniques. This highlights the need to develop technologies that present a solution to the rising cost of electricity in the future. The integrated gasification combined cycle (IGCC) presents an improvement to the above predicament, but it is capital intensive due to the extensive unit operations involved. The efficiency for a CO 2 capture incorporated IGCC system is around ~32%, resulting in approximately 45% increase in cost of electricity. This is definitely a better path to traverse than the conventional pulverized coal (PC) power plants as it has improved economics and efficiencies accompanied by product flexibility. The SCL process advances the benefits even further when integrated with the IGCC process. The SCL process removes the expensive WGS system and CO 2 separation columns, thereby saving on capital and operational expenses. This integration results in a 12 – 21% increase in efficiency accompanied by a reduction in cost of electricity by 15 – 28%, over conventional IGCC systems. Therefore, SCL process provides the best route to harness the energy from coal. The overall project objective was to construct and operate a syngas chemical looping pilot scale test unit at the NCCC. The project scope of work was divided into 3 phases. In Phase I, cold flow model studies using a 1:1 scale acrylic test unit constructed at Particulate Solids Research, Inc. (PSRI) was successfully completed confirming robust solid flow control is achievable in the non-mechanical system design. In Phase II, the high pressure, high temperature, chemical looping reactor was successfully designed with all necessary equipment and safety instrumentation/controls specified to allow for fabrication, site construction, and assembly to commence in Phase III. In Phase III, the SCL pilot plant was successfully assembled and all necessary functional checks and pre-startup safety reviews completed. During unit commission over the course of 200 hours of testing, operational issues were observed with premix burner used for system startup. With the grants awarded by the National Energy Laboratory (NETL) and the Ohio Development Services Agency (ODSA) under awards DE-FE0023915 and D-14-18, the SCL pilot unit underwent three auxiliary equipment modifications to resolve all of the startup operational issues encountered. The unit was successfully demonstrated with 300+hr continuous operation. Key results obtained include high syngas conversion of 97.95% with 16.03% oxygen carrier conversion in the moving bed reducer and >99% purity H 2 produced from the moving bed oxidizer.

01 COAL, LIGNITE, AND PEAT↗

Improving Energy Efficiency of Air Separation via Hollow Fiber Sorbents

This report summarizes the work performed under the Department of Energy’s National Energy Technology Laboratory (DOE-NETL) Advanced Energy Systems Program award number DE-FE0026163 Improving Energy Efficiency of Air Separation via Hollow Fiber Sorbents. The overall objective of the project was to develop technology to produce oxygen for use in coal gasification processes at a significantly lower cost than that of the commercial state-of-the-art technology. The focus of the project was development and optimization of hollow fiber sorbents for use in a pressure swing adsorption (PSA) process for producing oxygen from air. The key technical advancement under this program was the development of a hollow fiber sorbent capable of producing oxygen in a PSA process. PSAs produce oxygen by using a beaded zeolite material (typically lithium exchanged zeolites or LiX) that selectively adsorb nitrogen over oxygen. For a fiber to adsorb nitrogen, LiX needed to be integrated into a polymer fiber and then activated at over 350C to remove residual moisture. After screening multiple materials and process techniques, Matrimid/LiX hollow fibers were produced that were able to withstand the activation and had crystalline nitrogen capacity close to pure LiX crystals. The fibers were dual layer fibers with a barrier layer isolating the hollow bore from the LiX embedded layer. The barrier layer was formed from an Ultem® based solution. The hollow bore was intended for encapsulating phase change materials to ensure isothermal PSA operation. Modeling work from the project suggested that the benefits of this additional complexity were marginal, thus the team fabricated non-hollow fibers comprised of Matrimid and LiX. The Matrimid/LiX fibers were loaded into a module and tested on a bench scale PSA unit. The fibers were able to separate oxygen from air, but the purity and recovery were lower than expected and lower than traditional beaded LiX zeolites, although modeling results suggested that the bed sizes for fiber sorbents could be half the size of a beaded LiX bed. Additional work will be needed to understand the shortfall and to produce fiber sorbent modules with performance equal to the targets set for this program. In addition to producing fibers, modeling work was carried out at both the fiber level and process level to guide both fiber sorbent development and to determine the optimal process conditions for a PSA using fiber sorbents. A 2D hollow fiber model was developed in gPROMS Model Builder. This model was based on literature data for mass transfer and other parameters. This model used a basic single bed PSA process to determine important fiber properties and process conditions for achieving high oxygen recovery. The preliminary 2D fiber model was a valuable tool, however, for step-out technologies, such as a PSA process with fiber sorbents, intelligent optimization and plant control was needed to effectively determine minimum power designs. Therefore, a gPROMS Process Builder-based optimization tool was developed with an “Automated Cycle Optimizer” model that was able to determine optimal cycle conditions for a fiber sorbent PSA. The results from the optimizer were used in the final power analysis. Flow sheet analysis and techno-economic analysis (TEA) was carried out to determine a lower power solution versus the baseline case. The original project scope suggested that the fiber sorbent PSA could be used to debottleneck a cryogenic air separation plant (cryo-ASU) with the combined plant having lower power than a standalone cryo-ASU. However, early flowsheet analysis showed that the PSA/cryo-ASU concept would not lead to a lower power solution. However, further flowsheet analysis suggested that an oxygen PSA combined with a nitrogen PSA could have lower power versus state-of-the-art air separation technology. Work concluded with the TEA showing a fiber sorbent oxygen PSA combined with an advanced nitrogen PSA could be up to 8% lower power versus the base case cryo-ASU. Overall, there is significant potential remaining for the zeolite hollow fiber sorbent concept, and this project successfully identified -- and ultimately remedied -- many technical challenges associated with scale-up.

01 COAL, LIGNITE, AND PEAT↗

SOFC NG and Coal plant with CCUS

Coal integrated gasification solid oxide fuel cell (SOFC) and natural gas (NG) solid fuel cell power plants with and without carbon capture. To access the model referenced in the report, please visit https://www.netl.doe.gov/energy-analysis/details?id=85E9192F-26A2-4A05-914B-9AB64C68538D

01 COAL, LIGNITE, AND PEAT↗

Cost and Performance Baseline for Fossil Energy Plants - Volume 4: Coal-to-Liquids via Fischer-Tropsch Synthesis

This report establishes performance and cost data for coal-to-liquids systems, specifically by means of gasification and Fischer-Tropsch reaction. The analyses were performed on a consistent technical and economic basis to assess the design and financial performance of a commercial-scale coal-to-Fischer-Tropsch liquids facility. The cost and performance data were compiled from published reports, information obtained from vendor quotes and users of the technology, and data from designing and building utility and refining projects.

01 COAL, LIGNITE, AND PEAT↗

Abstract for CRADA between the National Energy Technology Laboratory, Ohio State University, Lawrence Berkeley National Laboratory, and Sandia National Laboratories (AGMT-0804)

This CRADA will enable cooperation between Ohio State University (OSU) and a collective led by the National Energy Technology Laboratory (NETL), with the goal of facilitating the accelerated commercialization of OSU’s iron-based chemical looping process through advanced modeling and state-of-the-art optimization techniques. OSU will provide data for model development and validation, while NETL and collaborators through the Institute for the Design of Advanced Energy Systems (IDAES) will develop advanced high-fidelity optimization-based system models. The project will use data collected primarily from OSU’s bench scale and sub pilot scale facilities and will be supplemented by data collected from the open literature. Models representative of chemical looping combustion or gasification using either coal or natural gas as fuel are considered in scope. Specific tasks will include 1) development of physical property sub-models, 2) development of steady-state and dynamic 1 st principles models of the novel gas solid contactor technologies being developed by OSU, and 3) superstructure and parametric optimization of a full chemical looping process by leveraging the large-scale optimization capabilities being developed by IDAES. This collaboration will provide a greater fundamental understanding of the OSU chemical looping process, will help to improve the overall process economics, and will thus enable a greater probability of commercial success. It will provide IDAES with the opportunity to validate, demonstrate, and further develop its toolset through a real-world practical demonstration.

01 COAL, LIGNITE, AND PEAT↗

Scale-Up of Coal-Based Supercritical CO 2 cycle technology

The Allam Cycle is a transformational technology that enables a step change in the performance, efficiency, and cost of electricity for electrical generating units by using supercritical CO 2 (sCO 2 ) as the working fluid in the turbine for power generation. The objectives of this Phase I effort were to select a host site for a large pilot system through a process of down selection, develop a conceptual design, and conduct a pre-front-end engineering design (pre-FEED) study for a sCO 2 cycle pilot plant that uses domestic coal reserves as the primary feedstock, thereby furthering technology development of the coal-based Allam Cycle. The project was divided into four main tasks: 1) Project Management and Planning; 2) Conceptual Pilot Plant Definition and Host Site Selection; 3) Preliminary Design, Cost, and Schedule Development; and 4) Commitments and Environmental Information Volume (EIV). All project management activities occurred in Task 1. Host site selection was conducted in Task 2, while conceptual design and pre-FEED activities took place under Task 3. Task 4 enhanced the project by securing commitments for the next phase of the program and completing an initial EIV. The Great Plains Synfuels Plant (GPSP) has been selected as the host site for the large-scale pilot, and its owner, Dakota Gasification Company (DGC), is a committed partner. GPSP was compared to two other host site candidates during Phase I: the existing natural gas Allam Cycle facility in La Porte, Texas, and the Energy & Environmental Research Center’s (EERC) high-bay demonstration facility in Grand Forks, North Dakota. Costs for hosting the pilot plant were estimated for each facility, and those costs are shown in Table ES-1. Based on these estimates, the DGC site was clearly shown to be the lowest cost option and was selected as the host site for the project.

01 COAL, LIGNITE, AND PEAT↗

Thermal Analysis of Mixed Matrix Membranes Involved in Gas Separation

Idaho National Laboratory is developing a mixed matrix membrane that can separate oxygen from air. The enriched oxygen stream is intended to be used in gasification systems and coal combustion. This study evaluated the thermal properties of polymer membranes that were cast from different solvents and contained various concentrations of nanodiamonds, where the polymer-nanodiamond composites acted as the selective layer. Measuring these properties helped to understand the membrane formation process to yield membranes that give reproducible performance. Thermomechanical Analysis determined that nanodiamonds cause a physical effect on the membrane when exposed to heating. Thermogravimetric Analysis and Differential Scanning Calorimetry determined residual solvent in the membrane after formation. Residual solvent tended to decrease the performance of membranes. From this work, we developed a method of forming solvent-free polysulfone membrane composites containing nanodiamond particles that gave reproducible permeability and selectivity data.

25 ENERGY STORAGE↗

Cost and Performance Baseline for Fossil Energy Plants Supplement: Sensitivity to CO 2 Capture Rate In Coal-Fired Power Plants

The cost and performance of various plants designed to meet a range of carbon dioxide (CO 2 ) emission limits are evaluated in this report by varying the CO 2 capture rate. The base cases for these designs are the supercritical (SC) pulverized coal (PC) plant and the General Electric Power (GEP) integrated gasification combined cycle (IGCC) plant from the Department of Energy (DOE) National Energy Technology Laboratory (NETL) report “Cost and Performance Baseline for Fossil Energy Plants, Volume 1: Bituminous Coal and Natural Gas to Electricity, Revision 4” (“Bituminous Baseline”).

20 FOSSIL-FUELED POWER PLANTS↗

Understanding Transient Combustion Phenomena in Low-NO x Gas Turbines

The goal of this work was to understand, quantify, and eventually predict combustion instability during operational transients in low-NO x gas turbine combustors. Transient operation is defined as a mode where one or more key operating parameters, including equivalence ratio, fuel composition, or fuel splitting between nozzles in a combustor, are varying in time. The timescale over which this variation occurs will be referred to as the transient timescale, the magnitude of the change in the transient parameter will be referred to as the transient amplitude, and the direction of the variation will be referred to as the transient direction. Transients occur regularly in power generation gas turbine operation. For example, load-following gas turbines vary load to meet power demands while accounting for variation in unsteady grid contributors like wind and solar power. Operators achieve this by varying equivalence ratio and fuel splitting inside the combustors to produce more or less power. Another example of transient operation is during fuel-switching operations, a particular issue for turbines operating with syngas fuels in a co-generation facility. In this case, the composition of the fuel stream may vary in time either as a result of fluctuations in the pipeline, or in the case of a co-generation plant, variations in feedstock or gasification processes. This fluctuation in fuel composition can have significant implications for combustion processes, particularly with high-hydrogen fuels. A small number of studies have investigated transient behavior in gas turbine combustors, particularly in the context of flame blow-off; here, investigators have typically focused on issues of transient amplitude, though without the depth and physics-based experimental design that is proposed in this program. To our knowledge, there have been no studies that have quantified the impact of the transient timescale on combustion. The work helped us understand the impact of several types of transients on combustion stability. Both static and dynamic combustion stability will be considered. The transients will be quantified using their amplitude, direction, and timescale, and we will consider transients in equivalence ratio, fuel composition, and fuel splitting. There were two main objectives of this work: 1. Provide a fundamental understanding of combustion stability during transient operation using data obtained from a number of high-speed diagnostic techniques on experimental configurations that capture important gas turbine combustor features and operating conditions. This goal was met in conjunction with our industrial partner, GE Global Research, with whom we worked closely throughout the program. 2. Develop a stability prediction framework that will allow for the prediction, and possible control, of instabilities as a function of the transient amplitude, direction, and timescale. This input/output model should be physics-based and allow for screening of operating conditions and prediction of unstable behavior at the end of a transient by monitoring combustor health and precursor signals during operation.

03 NATURAL GAS↗