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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 631 records · Page 35

Recovery of High Value Anode Materials for a Closed Loop Li-ion Battery Recycling Process (Final Report)

Battery Resourcers’ goal with this Small Business Innovative Research Phase 1 project was to produce high quality and high purity graphite generated from its Li-ion battery recycling technology. Battery Resourcers’ technology recovers cathode material from a broad spectrum of Li-ion battery regardless of size, shape or chemistry. In Battery Resourcers existing model, the graphite is recovered to be used as a reductant and therefore the battery materials cost or recycling cost is not lowered by the recovery of the graphite. Currently, Battery Resourcers is piloting its lithium ion battery recycling process and the recovered LiNi 0.33 Mn 0.33 Co 0.33 O 2 (NMC111) or LiNi 0.6 Mn 0.2 Co 0.2 O 2 (NMC111) cathode materials have shown that they can outperform existing commercial NMC111 cathode materials while being produced at a projected lower cost. Battery Resourcers and its subcontractor WPI have demonstrated the same success with the recovered graphite for anode materials. The success of this award will enable Battery Resourcers offer lowest cost anode materials while reducing the carbon footprint of the battery industry. This will potentially lower the cost of EV by lowering the upfront cost of the battery and the end of life disposal costs. The technical objectives of this Phase 1 research project are to purify the recovered graphite from Battery Resourcers leaching process and demonstrate it is viable to be used in new electric vehicle lithium ion batteries. This project demonstrated that Battery Resourcers can recover graphite with less than 2% impurities. To separate the graphite from other materials Battery Resourcers will employed new filtering techniques and chemical processing methods.

25 ENERGY STORAGE↗

A novel poplar biomass germplasm resource for functional genomics and breeding. Final report addendum

In this report, we report and update activities associated with co-PI Groover. This report is an addendum to the full report detailing genomic objectives associated with the project, submitted by PI Luca Comai and co-PI Isabelle Henry. The Groover lab is leading the efforts to produce and replicate poplar irradiation and control hybrids genotypes, and phenotype the hybrids. These efforts are coordinated with Comai and Henry to ensure the most promising hybrids are included for field and greenhouse-based studies, and to link the genomic and phenotypic analyses.

09 BIOMASS FUELS↗

ION Engineering Commercial Carbon Capture Design & Costing (C3DC) (Final Report)

ION Engineering LLC (ION) has coupled its proven, solvent-based CO 2 capture technology with an exceptionally qualified design and engineering team to complete a pre FEED for a 300-megawatt equivalent commercial-scale CO 2 capture plant for Gerald Gentleman Station’s (GGS) Generation Unit 2 (GGS2). The remarkable team was comprised of ION, Nebraska Public Power District (NPPD), Sargent & Lundy (S&L) with continued support from Koch Modular Process Systems (KMPS), and Siemens. The overall objective of the project was to provide the engineering design and cost estimate at an American Association of Cost Engineers (AACE) Class 3 estimate, resulting in accuracy ranges of -20 to +30% for the capital cost estimate. The project team was successful in completing this objective and was able to overcome the challenges that were presented during the process. A conservative interest rate of 7.0% with a financing term of 20 years was used based on interest rates utilized by S&L for this level of study. The resulting annualization factor is multiplied by the total EPC cost to calculate an annualized capital expenditure. It is estimated that the carbon capture facility treating a 300 MWe slipstream will capture 1.9 million tonnes per year of CO 2 at a capacity factor of 85%. The resulting cost of capture for the CO 2 island was determined to be $\$$36.55/tonne. Utilizing an interest rate of 4.5%, supported by historical rates for previous large capital projects in the power industry, reduces the cost of capture to $32.52/tonne. These cost of capture numbers continue to further ION’s case for commercial deployment of ION’s solvent technology.

20 FOSSIL-FUELED POWER PLANTS↗

Holistic Measurement Driven Resilience: Combining Operational Fault and Failure Measurements and Fault Injection for Quantifying Fault Detection, Propagation and Impact. Final report

For HPC systems to date, application resilience to faults and failures has been accomplished by the brute- force method of checkpoint/restart, which allows an application to make forward progress in the face of system and application faults, errors, and failures independent of root cause or end result. It has remained the primary resilience mechanism because we lack a way to identify faults and anticipate consequences early enough to take meaningful mitigating action. However, checkpoint/restart implementations put a tremendous burden on system resources and on the applications themselves and is becoming less feasible at scale. Because we have not yet operated at scales at which checkpoint/restart fails to provide forward progress, despite increasing costs, vendors have had little motivation to provide the instrumentation necessary for early identification of faults and failures. However, as we move from petascale to exascale, component mean time to failure (MTTF) will render the existing techniques ineffectual and/or too expensive. Furthermore, fault recovery mechanisms such as failover and/or error correction introduce performance inconsistency. Instrumentation allowing early indication of problems and tools to enable use of such information by systems, operating systems, and applications offer an alternative, more scalable and less costly solution. In the HMDR project, we built on our experience and expertise developed and accumulated over years of research on design, monitoring, measurement, and assessment of resilient computing systems. Analysis of field data on the current and past generations of extreme-scale systems revealed several challenges that, if not addressed in increasingly larger and more complex systems, may hinder the effectiveness of future exascale computing systems. Specifically, i) file systems and interconnects in current-generation large-scale systems already operate at the margins of resiliency, including consistent performance, and may not scale to larger deployments; ii) automated, software-based failover mechanisms are frequently inadequate and can introduce wider failures, such that failures during recovery may lead to system/application failures, including system-wide outages; and iii) silent data corruption represents a critical fault mode and will require efficient detection mechanisms if next-generation applications are to take full advantage of exascale hardware. To address the above challenges, we assembled a team of world-renowned experts in resilient extreme- scale computing from the University of Illinois (Electrical and Computer Engineering, Computer Science, and NCSA), SNL, LANL, NERSC, and Cray. Our team includes representatives from centers that house many of the largest HPC resources in the world, both today and over the coming years. The team has a unique track record of research in i) system and application failure characterization based on the analysis of field data, ii) data-driven design of fault/error detection mechanisms, and iii) experimental characterization of system/application resiliency. The team includes system owners/operators who provide continuous data collection and access and ensure installation of appropriate analysis tools.

97 MATHEMATICS AND COMPUTING↗

Binder Jet Tooling for Automotive Lighting Industry. CRADA Final Report

The goal of this collaborative project between Oak Ridge National Laboratory’s (ORNL) Manufacturing Demonstration Facility (MDF) and Grote Industries, LLC was to develop additively manufactured tooling to produce lighting products in a production environment. The project explored the use of metal powder bed systems to rapidly manufacture moderately sized injection molding tools (less than 8” x 8” x 2”) for automotive lamps. The team designed the mold (male and female), manufactured the mold using the binder jet process, experimented with finishing processes, manufactured parts using the molds, and monitored the wear on the mold to predict life.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

FY19 FES Theory Performance Target (Final Report)

Understanding the relevant turbulent transport mechanisms at the edge of a high-performance tokamak is essential for predicting and optimizing the H-mode pedestal structure in future burning plasma devices. Global electromagnetic gyrokinetic simulations will be performed based on representative experimental pedestal scenarios in order to clarify which instabilities are most important for each of the particle and heat transport channels. Edge transport modeling will be performed in order to estimate and bound the particle and heat sources—e.g., the ionization density source and the atomic energy loss channels due to ionization, charge exchange, and radiation. Comparisons will be made with data from the DIII-D, JET, C-Mod and NSTX or MAST experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

FY2018 Fusion Theory and Simulation Milestone on Plasma Materials Interaction (PMI) (Final Report)

The interaction of the boundary plasma with the material surfaces in magnetically confined plasmas is among the most critical problems in fusion energy science. In FY2018, perform high performance computing simulations with coupled boundary plasma physics and materials surface models to predict the fuel recycling and tritium retention of the ITER divertor for D-T burning plasma conditions, accounting for erosion, re-deposition and impurity transport in the plasma boundary, and an initial evaluation of the influence of material deposition on the recycling and retention.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

A Modular Heat Engine for the Direct Conversion of Natural Gas to Hydrogen and Power using Hydrogen Turbines (Phase I Final Report)

This report describes a novel, modular heat engine comprising of a one-step hydrogen production from natural gas with in-situ CO 2 separation which is amenable for re-use or sequestration. Combining with a hydrogen turbine subsystem, a distributed or central power generation system is conceived. An added hydrogen storage subsystem enables load-following capability. The techno-economics of the overall system compared favorably against current state-of-the-art natural gas combined cycle plants with post-combustion CO 2 capture.

01 COAL, LIGNITE, AND PEAT↗

High Temperature Additive Architectures for 65% Efficiency (Final Report)

GE Power (GEP) proposed a development program that targets advanced high temperature additive components that contribute towards the DOE’s goal for advanced gas turbines that are capable of 65%, or greater, efficiency in combined cycle application. GEP proposed to leverage state-of-the-art additive manufacturing to develop novel and innovative component airfoil and end wall architectures that provide cooling flow savings while maintaining the component durability expected in today’s gas turbines. The objective of this program was to develop advanced component designs and architectures enabled by additive manufacturing, and the materials systems and additive manufacturing technology required for these designs. This Phase I program leveraged existing design and analysis knowledge and techniques for additive materials and methods and utilized extensive analytical evaluations to develop and refine designs for advanced turbine hot gas path (HGP) components. The design will be the basis for development and testing in a potential Phase II program. The goal of this Phase I program was to establish a feasible conceptual design for advanced additive turbine hot section components along with a technology maturation plan involving testing to address risk areas and needed validation. It was approached through two primary elements: 1) conceptual design and analysis of wall architectures, advanced airfoil cooling concepts, and advanced system-level concepts, and 2) investigation of additive modalities and associated materials systems. The Phase I program has concluded with the down-select of a primary design concept for a potential Phase II program.

36 MATERIALS SCIENCE↗

TRANSENSOR: Transformer Real-time Assessment INtelligent System with Embedded Network of Sensors and Optical Readout. Final Report

Utilities across the world are wrestling with evolving market dynamics, population growth and climate change. Distributed Energy Resources (DERs) such as solar photovoltaics, distributed generators and energy storage systems are becoming important parts of the U.S. energy mix. These factors are driving an increasing need for low-cost grid asset monitoring. Aside from being costly, traditional utility monitoring systems are not sufficiently robust and do not provide real-time visibility into the condition of grid assets such as transformers. Lack of accurate real-time measurements on performance has resulted in the use of lagging indicators, such as oil sample analysis. To address this need, an innovative embedded optical sensing technology, Transformer Real-time Assessment Intelligent System (TRANSENSOR) was developed, validated and demonstrated in this project. To date, TRANSENSOR has focused on transformers but is extendable to other grid assets. In addition to the technology being embedded into new transformers during manufacturing, a retrofit configuration that can be installed on existing transformers in the field was also developed. It is anticipated that the ability to retrofit existing transformers will help accelerate adoption of the underlying TRANSENSOR technology. Phase 1 of the project focused on laboratory development and qualification of the technology. Following iterations and exploration of relevant optical sensing modalities and multiplexed configurations of interest for the transformer environment, an effective candidate configuration was agreed upon, down-selected and custom-designed for embedding into General Electric (GE) network transformers. Two new GE 500 kilovolt ampere (kVA), 27 kilovolt (kV) distribution network transformers were built with embedded fiber-optic (FO) sensors and successfully qualified per industry standards at GE’s Shreveport, Louisiana facility during Phase 1 of the project. Following the successful completion of Phase 1, the team proceeded to Phase 2, which focused on a field demonstration of the technology. Over Phase 2, the first new GE transformer built with embedded fiber-optic sensors was installed in an above-ground cage and connected to the grid at Con Edison’s Astoria facility. A second transformer equipped with TRANSENSOR was installed in an underground vault. Additionally, an older (1982 year model) GE transformer in an above-ground cage was retrofitted with fiber- optic sensors and reconnected to the grid at ConEd’s facility. Analysis of data acquired from the sensors showed interesting correlations with transformer loading. Additionally, key events such as transformer low-voltage network connection, primary-side energizing, and a pressure loss event from an oil sampling were detected by the TRANSENSOR system. Online data processing/feature extraction algorithms for the second transformer in the underground vault detected key features and event alerts that were transmitted through a wireless 4G connection. The remote deployment concept showed promising results with data collection running for a total of 8 months across the three (3) GE transformers instrumented for the Phase 2 field demonstration. This sets the stage well for further development and commercialization.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Advanced Simulation and Experiments of Strongly Coupled Geomechanics and Flow for Gas Hydrate Deposits: Validation and Field Application. Final Report

The objectives of the proposed research are (1) to investigate geomechanical responses induced by depressurization experimentally and numerically; (2) to enhance the current numerical simulation technology in order to simulate complex physically coupled processes by depressurization and (3) to perform in-depth numerical analyses of two selected potential production test sites: one based on the deposits observed at the Ulleung basin UBGH2-6 site; and the other based on well-characterized accumulations from the westend Prudhoe Bay. To these ends, the recipient will have the following specific objectives: 1). Information obtained from multi-scale experiments previously conducted at the recipient’s research partner (the Korean Institute of Geoscience and Mineral Resources (KIGAM)) that were designed to represent the most promising known Ulleung Basin gas hydrate deposit as drilled at site UBGH2-6 will be evaluated (Task 2). These findings will be further tested by new experimental studies at Lawrence Berkeley National Laboratory (LBNL) and Texas A&M (TAMU) (Task 3) that are designed capture complex coupled physical processes between flow and geomechanics, such as sand production, capillarity, and formation of secondary hydrates. The findings of Tasks 2 and 3 will be used to further improve numerical codes. 2) Develop (in Tasks 4 through 6) an advanced coupled geomechanics and non-isothermal flow simulator (T+MAM) to account for large deformation and strong capillarity. This new code will be validated using data from the literature, from previous work by the project team, and with the results of the proposed experimental studies. The developed simulator will be applied to both Ulleung Basin and Prudhoe Bay sites, effectively addressing complex geomechanical and petrophysical changes induced by depressurization (e.g., frost-heave, strong capillarity, cryo-suction, induced fracturing, and dynamic permeability).

02 PETROLEUM↗

Characterization of oceanic post-cold frontal clouds and their model representation. Final report

Low-level clouds are ubiquitous over the oceans, and their impact on the Earth’ radiative budget is important. However, general circulation models (GCMs) that are used to represent our climate and its evolution still experience problems to represent their correct amount and radiative impact. In the extratropical latitudes (~30-60 N/S), cloud properties are strongly modulated by the occurrence of anti-cyclones (high pressure systems) and cyclones (low pressure systems). While deep clouds dominate in cyclones near the center and along the cold and warm fronts, low-level clouds populate the colder regions of the cyclones, and more specifically the region in the wake of the cold fronts, the post-cold frontal region (PCF). The GCMs mentioned above were found to underestimate the amount of these PCF clouds, and this caused errors in their representation of the amount of solar radiation at the surface of the southern hemisphere oceans, causing an excess in absorption and errors in long-term predictions. To better understand which processes are ill-represented in the GCMs to cause such issues, we used ground-based observations from the Eastern North Atlantic (ENA) ARM site and a high resolution regional model (called WRF) to examine the properties of PCF clouds. With the WRF model, we simulated the passage of a cold front at the ENA site using theoretically distinct representations of convection and the physics of the boundary layer. While these physical representations had little impact on the timing, structure and circulation of the cold front, we found a high sensitivity to how the large scale information was fed into the model. Errors rapidly developed if the incoming flow information was injected too far from the site, but 1000 km was found to be an optimal distance between the outer boundary and the ENA site for a realistic cold front passage. With this model, we then conducted a series of experiment where convection and boundary layer schemes were changed, and revealed that 1) the clouds were more sensitive to the convection than boundary layer schemes and 2) the interaction between the two has a large impact. Furthermore, changing the representation of the physics in the model had greater impacts on PCF clouds than changing the initial conditions. As large-scale models increase their spatial resolution, convection will eventually be resolved but it remains that their representation of the physics of the boundary layer will matter for the correct representation of shallow (low-level) clouds. Observations were used to find which large-scale information had a clear relationship with PCF cloud and precipitation properties, in view of helping with GCM parameterizations and evaluation. Both lower troposphere stability and surface forcing were found to be important for PCF clouds that experience more vigorous dynamics than their tropical or subtropical counterparts. For cloud base and top heights, a simple measure of the change in potential temperature between the surface and the 800 hPa was found to be a good predictor. This relationship was found to hold as well when using data from campaigns recently conducted in the southern ocean south of Tasmania. A recent GCM was found to succeed in representing similar relations. For cloud depth, water content, and different characteristics of precipitation both the temperature contrast between the surface and near-air and the near-surface wind speed had a strong relationship. To summarize, through observational constraints and regional model experiments, the project has provided guidance to evaluate GCMs and tools to improve their representation of low-level clouds in the extratropics. It has also highlighted differences in behavior between these clouds and those typically found in the subtropics, thus opening new avenues of research for shallow clouds in general.

54 ENVIRONMENTAL SCIENCES↗

Water Power Technologies Office 2019 Peer Review Final Report

The U.S. Department of Energy’s (DOE’s) Office of Energy Efficiency and Renewable Energy’s (EERE’s) Water Power Technologies Office (WPTO, or “the office”) 2019 Peer Review was held on October 8–10, 2019, in Alexandria, Virginia. The purpose of the peer review was to evaluate DOE-funded projects for their contribution to the mission and goals of the office, to assess progress made against stated objectives, and to assess the office’s overall management and performance. All programs within EERE are required to undertake rigorous, objective peer reviews covering their key projects, as well as 80%–90% of their funded active project portfolio every two years.

13 HYDRO ENERGY↗

Commercialization of the Sandia Cooler (Final Report)

This Technology Commercialization Fund (TCF) project was a complete success. As described in our original TCF proposal, TRL1 through TRL5 development of Sandia Cooler technology was carried out under EERE BTO and Sandia LDRD funding. The objective of this TCF project was for Sandia National Labs and commercial partner Wakefield-Vette to convert this TRL5 DOE technology to a market-ready, cost-competitive, electronics thermal management product (TRL 8). A further objective was to target an energy sector application with high-visibility that can effectively serve as an advertisement for DOE's Sandia Cooler technology.

42 ENGINEERING↗

Ultra-Low SWaP CO 2 Sensing for Demand Control Ventilation (Final Report)

In this project PARC and Energy ETC aimed to develop an ultra-low cost, size, weight, and power (SWaP) printed CO 2 sensor system for occupancy detection to enable Demand Control Ventilation (DCV) on a per-room basis. The CO 2 sensor technology is based on the temperature variation when CO 2 reversibly physisorbs to a highly conductive and high surface area sorbent surface, and is compatible with integration with PARC innovations in printed sensors and flexible electronics, for which PARC is a globally leading research center. The printed CO 2 sensor itself is designed to be compatible with PARC’s “peel-and-stick” platform of ultra-low power, low-cost, distributed sensors, and to facilitate real-time DCV based on overall indoor air quality (IAQ). Previously, PARC has developed flexible hybrid electronics (FHE) compatible materials to measure humidity, temperature, light, strain, and gases such as carbon monoxide, methane, ammonia, and hydrogen sulfide. Through this project, PARC developed FHE-compatible materials to measure CO 2 . Thus, with one <$15 FHE “peel-and-stick” based sensor node, a building management system (BMS) will be able to capture a complete picture of the indoor environment. This includes IAQ, light, temperature, and other comfort factors that impact building operations. Combined with optimized DCV, this low-cost sensor capability can be a key enabler of annual primary energy savings of ~ 0.3-0.4 Quad in commercial buildings while ensuring healthy IAQ. Energy ETC is a leader in supplier-agnostic BMS deployments and will design the commissioning and deployment procedures to maximize system interoperability.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Rice Business Plan Competition (Final Report)

During the grant period, Rice University held a total of three regional Clean Energy Business Plan Competitions for graduate level students with a particular focus on attracting student startups in the clean energy space (clean tech, renewable energy, transportation, batteries, sustainability, etc.) Over the three years of the grant, the Rice Business Plan Competition awarded a total of three ${$}$50,000 DOE-sponsored prizes to the winning startups (${$}$150,000 total). The Rice Energy Business Plan Competition’s DOE Clean Tech competition leveraged the resources and infrastructure of the existing annual Rice Business Plan Competition (RBPC), which is the world’s largest and richest intercollegiate graduate-level business plan competition in the world

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

From Interstellar Cloud to Star to Laboratory: Frontier HEDP Studies of Magnetized Colliding Plasma Flows with Strong Radiative Cooling (Final Report)

High-speed flows of gas are the norm in astrophysics where exploding stars, winds from the regions around black holes and streams of galactic material create “supersonic flows”. As the flows collide, strong shock waves are formed where gas is compressed and heated. The regions behind these shock waves are of great interest to scientists. New stars can form in these shock regions in the context of galaxies. In the context of planets like our Earth, the shocks waves come from the interaction of the solar wind with our planets’ magnetic field causing Aurora and placing astronauts and satellites in jeopardy. Thus, understanding supersonic flows of magnetized plasmas is essential for progress in many fields of astronomy and space physics (relevant to planets and the Earth). Remarkably, we can also create these kinds of flows in the laboratory using Z-pinches and laser driven experiments that include magnetic fields. The exploration of these forms of “High Energy Density Physics” (HEDP) flows is also critical in order to achieve Inertial Confinement Fusion, which is a step towards developing a sustainable source of Fusion energy.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Development of thinned silicon sensors on 8” wafers (CRADA FRA-2015-0015 Final Report)

Sensors fabricated from high resistivity, float zone, silicon material have been the basis of vertex detectors and trackers for the last 30 years. The areas of these devices have increased from a few square cm to >200 m 2 for the existing CMS tracker. CMS and ATLAS upgrades will each require more than 200 m 2 of silicon and the CMS High Granularity Calorimeter (HGC) will require more than 600 m 2 . Cost and complexity of assembly of these devices is related to the area of each module, which in turn is set by the area of the silicon sensors. A move from 4” and 6” wafers (the only sizes currently available) to 8” diameter in volume production has the potential for savings of tens of millions of dollars in the detector upgrade programs at the Large Hadron Collider (LHC) and future experiments. In addition to large area, the devices must be radiation hard, which can be achieved by the use of sensors thinned to 200 microns or less. The combination of wafer thinning and large wafer diameter is a significant technical challenge, and is the subject of this work.

43 PARTICLE ACCELERATORS↗