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At least 631 records · Page 35

Unusual electrical and magnetic properties in layered EuZn 2 As 2

Eu-based compounds often exhibit unusual magnetism, which is critical for nontrivial topological properties seen in materials such as EuCd 2 As 2 . The authors investigate the structure and physical properties of EuZn 2 As 2 through measurements of the electrical resistivity, Hall effect, magnetization, and neutron diffraction. Their data show that EuZn 2 As 2 orders antiferromagnetically with an A-type spin configuration below T N = 19 K. Surprisingly, there is strong evidence for dominant ferromagnetic fluctuations above T N , as reflected by positive Curie–Weiss temperature and extremely large negative magnetoresistance (MR) between T N and T fl ≈200 K. Furthermore, the angle dependence of the MRab indicates field-induced spin reorientation from the ab-plane to a direction ≈45° from the ab plane. Compared to EuCd 2 As 2 , the doubled T N and T fl make EuZn 2 As 2 a better platform for exploring nontrivial magnetic and electronic properties in both magnetic fluctuation (T N < T < T fl ) and ordered (T < T N ) regimes.

36 MATERIALS SCIENCE↗

First-Principles Insights into the Thermocatalytic Cracking of Ammonia-Hydrogen Blends on Fe(110): 1. Thermodynamics

Ammonia (NH 3 ) is being considered as a practical means to transport hydrogen (H 2 ) because of its higher volumetric energy density for the same temperature and pressure. Thermodynamics suggest high temperature is needed to decompose NH 3 to nitrogen (N 2 ) and H 2 . Furthermore, overcoming decomposition kinetic barriers requires a catalyst. Via density functional theory, we study this reaction on a model catalyst: the close-packed (110) facet of α-Fe. Specifically, we predict detailed in-operando temperature- and pressure-dependent surface phase diagrams on this benchmark catalyst that offer insights for the design of optimal NH 3 decomposition catalysts. Here, we explore the equilibrium composition(s) of the Fe(110) surface when exposed to NH 3 –H 2 mixtures. Further, we predict that both N and NH partially cover the Fe(110) surface at 300–400 °C (far above the NH 3 decomposition-formation coexistence temperature at standard partial pressures of 1 bar: ~ 180 °C) and 2–4 bar of total reactor pressure. At the equilibrium N/NH coverage, these species inhibit coadsorption of H, indicating that direct H 2 production may occur. However, from thermodynamics alone, removal of N/NH as N 2 (g) is extremely unfavorable even at these elevated temperatures–effectively deactivating the surface toward further NH 3 decomposition. Thus, catalysts that remain active toward N–H bond breaking but with weakened N binding relative to Fe are needed to enable high-turnover catalytic NH 3 decomposition to release H 2 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The global Sahel monsoon ocean-pressure index reconciles its regional and large-scale features

Monitoring Sahelian rainfall variability is increasingly critical as climate extremes intensify across the region. Here, we develop the Sahelian Monsoon Ocean-Pressure Index (SMOPI), a novel global synthetic indicator constructed from five dynamically coherent sea-level pressure regions statistically linked to June-September Sahel monsoon rainfall. SMOPI captures intra-seasonal and interannual variability, and crucially, reflects the influence of both regional processes and large-scale teleconnections on monsoon dynamics. It aligns with the dominant rainfall variability mode in reanalyses and 29 CMIP6 models. Strong/positive SMOPI phases coincide with wet years and are associated with enhanced convergence, favorable jet configurations, and robust Pacific, Atlantic, and Indian Ocean teleconnections. Conversely, weak/negative SMOPI phases correspond to drought conditions and divergent moisture fluxes. SMOPI exposes model failures in reproducing historical droughts and offers new physical insights into rainfall-driving mechanisms. It stands out as a scalable, potentially transferable diagnostic tool for monitoring/forecasting and evaluating Sahelian monsoon rainfall under global warming.

Tamoffo, Alain T. [Helmholtz-Zentrum Hereon GmbH, ↗

A dynamic microbial sulfur cycle in a serpentinizing continental ophiolite

Summary Serpentinization is the hydration and oxidation of ultramafic rock, which occurs as oceanic lithosphere is emplaced onto continental margins (ophiolites), and along the seafloor as faulting exposes this mantle‐derived material to circulating hydrothermal fluids. This process leads to distinctive fluid chemistries as molecular hydrogen (H 2 ) and hydroxyl ions (OH − ) are produced and reduced carbon compounds are mobilized. Serpentinizing ophiolites also serve as a vector to transport sulfur compounds from the seafloor onto the continents. We investigated hyperalkaline, sulfur‐rich, brackish groundwater in a serpentinizing continental ophiolite to elucidate the role of sulfur compounds in fuelling in situ microbial activities. Here we illustrate that key sulfur‐cycling taxa, including Dethiobacter , Desulfitispora and ‘ Desulforudis ’, persist throughout this extreme environment. Biologically catalysed redox reactions involving sulfate, sulfide and intermediate sulfur compounds are thermodynamically favourable in the groundwater, which indicates they may be vital to sustaining life in these characteristically oxidant‐ and energy‐limited systems. Furthermore, metagenomic and metatranscriptomic analyses reveal a complex network involving sulfate reduction, sulfide oxidation and thiosulfate reactions. Our findings highlight the importance of the complete inorganic sulfur cycle in serpentinizing fluids and suggest sulfur biogeochemistry provides a key link between terrestrial serpentinizing ecosystems and their submarine heritage.

Sabuda, Mary C.↗

How Today's Hydropower Impacts Tomorrow's Grid: Counterfactual Scenarios Showing Grid Impacts if Hydropower Goes Away

Amidst ongoing discussions about hydropower removals, retirements, and reduced availability due to drought and other environmental considerations, it is important to understand the long-term effects of reduced hydropower resources on the U.S. electric grid. This analysis uses the Regional Energy Deployment System (ReEDS™) grid planning model to compare several representative scenarios of retiring hydropower and pumped storage hydropower (PSH) capacity over time and explore the overall implications on the U.S. grid from present day through 2050. Reduced hydropower capacity and generation is replaced by a mix of both fossil and non-fossil resources, including natural gas, wind, solar, and battery technologies. Additional natural gas usage leads to an increase in cumulative national electric sector carbon dioxide and criteria pollutant operating emissions of less than 1% in many scenarios but up to 4-5.3% in some cases. Total electric sector costs also increase by <1% in many scenarios but up to 3.6% in the most extreme scenarios where nearly all the hydropower and PSH fleet retires, equating to $\$$340 billion in undiscounted costs. National results indicate that absent additional interventions, retiring hydropower and PSH capacity could increase electric sector emissions and direct capital and operating costs. However, more focused analysis is required to evaluate specific asset-level, local, and regional implications, and a broader scope is necessary to weigh these electric sector impacts alongside economic, ecological, water management, and other cross-sectoral effects that could be either negative or positive.

14 SOLAR ENERGY↗

Shuttle ECLSS ammonia delivery capability

The possible effects of excessive requirements on ammonia flow rates required for entry cooling, due to extreme temperatures, on mission plans for the space shuttles, were investigated. An analysis of worst case conditions was performed, and indicates that adequate flow rates are available. No mission impact is therefore anticipated.

Source record↗

The Sm-Nd history of KREEP

Sm-Nd whole rock measurements on a variety of KREEP-rich samples from different landing sites are reported. Despite a variation of Nd and Sm concentrations of almost a factor of 3, the Sm-Nd ratios, as well as the Nd-143/Nd-144 values, show an extremely close grouping. No systematic differences between samples from different landing sites are resolved. These results are taken to be indicative of a moon-wide process having been responsible for the generation of the KREEP source reservoir, 4.36 plus or minus 0.06 AE ago, as estimated from model age calculation.

Lugmair, G. W.↗

Sensing propagation events and fade statistics at C-band for two over-water, line-of-sight propagation paths over a one year period

We examine signal fading statistics over a year period corresponding to two over-water, line-of-site, propagation links in the mid-Atlantic coast of the US. These links are comprised of a transmitter on a tower at Parramore Island, VA operating at 4.7 GHz sending simultaneous cw signals to two receiver systems located on a lighthouse and a lookout tower on Assateague Beach, VA at distances of 44 and 39 km, respectively. The receiving sites are separated by approximately 5 km. Cumulative fade distributions corresponding to yearly, monthly, and diurnal time scales were derived. Fade duration statistics correspond to sustained attenuation events were also derived. These events, which were arbitrarily defined as having fades relative to free space powers in excess of 20 dB for durations of two hours or more, are believed to be generally due to subrefraction. Analysis of synoptic weather conditions and nearby rawindsonde data during two sustained deep fading periods showed atmospheric conditions consistent with extreme subrefraction, where the refractivity-height profile had a positive lapse rate. The efficacy of employing the links as indicators of real time conditions of atmospheric propagation was also demonstrated by a telephone call-up procedure which enabled displays of time series of the fading at remote locations to be generated.

Goldhirsh, Julius↗

Cascaded VLSI neural network architecture for on-line learning

High-speed, analog, fully-parallel, and asynchronous building blocks are cascaded for larger sizes and enhanced resolution. A hardware compatible algorithm permits hardware-in-the-loop learning despite limited weight resolution. A computation intensive feature classification application was demonstrated with this flexible hardware and new algorithm at high speed. This result indicates that these building block chips can be embedded as an application specific coprocessor for solving real world problems at extremely high data rates.

Thakoor, Anilkumar P.↗

Automated eddy current inspection of Space Shuttle APU turbine wheel blades

An automated inspection system based on eddy current testing (ET) techniques has been developed to inspect turbine wheel blades on the APU used in NASA's Space Transportation system. The APU is a hydrazine-powered gas turbine with a 15-cm diameter Rene 41 turbine wheel, which has 123 first-stage blades and 123 second-stage blades. The flaw detection capability of the ET system is verified through comparison with fluorescent penetrant test results. Results of the comparison indicate that ET is capable of inspecting surfaces with very restrictive geometries. The ET capability requires development of probes with extremely small coils to allow inspection within 0.4 mm of the blade root and the leading and trailing edges of the blade and within a height restriction of less than 1 mm. The color 2D presentation of the ET data provided crack-growth pattern and length information similar to those found with visual techniques. It also provided visual clues to minimize geometry effects such as generated from blade edges, a neighoring blade, and changes in the blade thickness.

Fisher, Jay L.↗

A hydrogen isotope study of CO3 type carbonaceous chondrites; comparison with type 3 ordinary chondrites

Meteorites of the Ornans type 3 carbonaceous chondrites exhibit a range in degree of equilibration, attributed to differing amounts of thermal metamorphism. These differences have been used to split the CO3 chondrites into petrologic sub-types from 3.0, least equilibrated, to 3.7, being most equilibrated. This is similar to the system of assigning the type 3 ordinary chondrites into petrologic sub-types 3.0 to 3.9 based upon thermoluminescence (TL) and other properties; however, the actual range of thermal metamorphism experienced by CO3 chondrites is much less than that of the type 3 ordinary chondrites. The least equilibrated ordinary chondrites show evidence of aqueous alteration and have high D/H ratios possibly due to a deuterium-rich organic carrier. The aim of this study was to determine whether the CO3 chondrites, which have experienced similar secondary conditions to the type 3 ordinary chondrites, also contain a similar deuterium-rich carrier. To date a total of 5 CO3 meteorites, out of a set of 11 for which carbon and nitrogen isotopic data are available, have been analyzed. Ornans has not been analyzed yet, because it does not appear to fit in with the metamorphic sequence exhibited by the other CO3 chondrites; it also has an extremely high delta-D value of +2150 percent, unusual for such a comparatively equilibrated meteorite (type 3.4). Initial results indicate that the more equilibrated CO3's tend to have lower delta-D values, analogous to the higher petrologic type ordinary chondrites. However this is complicated by the effects of terrestrial weathering and the small data-set.

Morse, A. D.↗

Endothelial Cell Morphology and Migration are Altered by Changes in Gravitational Fields

Many of the physiological changes of the cardiovascular system during space flight may originate from the dysfunction of basic biological mechanisms caused by microgravity. The weightlessness affects the system when blood and other fluids move to the upper body causing the heart to enlarge to handle the increased blood flow to the upper extremities and decrease circulating volume. Increase arterial pressure triggers baroreceptors which signal the brain to adjust heart rate. Hemodynarnic studies indicate that the microgravity-induced headward fluid redistribution results in various cardiovascular changes such as; alteration of vascular permeability resulting in lipid accumulation in the lumen of the vasculature and degeneration of the the vascular wall, capillary alteration with extensive endothelial invagination. Achieving a true microgravity environment in ground based studies for prolonged periods is virtually impossible. The application of vector-averaged gravity to mammalian cells using horizontal clinostat produces alterations of cellular behavior similar to those observed in microgravity. Similarly, the low shear, horizontally rotating bioreactor (originally designed by NASA) also duplicates several properties of microgravity. Additionally, increasing gravity, i.e., hypcrgravity is easily achieved. Hypergravity has been found to increase the proliferation of several different cell lines (e.g., chick embryo fibroblasts) while decreasing cell motility and slowing liver regeneration following partial hepatectomy. The effect of altered gravity on cells maybe similar to those of other physical forces, i.e. shear stress. Previous studies examining laminar flow and shear stress on endothelial cells found that the cells elongate, orient with the direction of flow, and reorganize their F-actin structure, with concomitant increase in cell stiffness. These studies suggest that alterations in the gravity environment will change the behavior of most cells, including vascular cells. However, few studies have been directed at assessing the effect of altered gravitational field on vascular cell fiction and metabolism, Using image analysis we examined how bovine aortic endothelial cells altered their morphological characteristics and their response to a denudation injury when cells were subjected to simulated microgravity and hypergravity.

Melhado, Caroline↗

Tides and Decadal Variability

This paper reviews the mechanisms by which oceanic tides and decadal variability in the oceans are connected. We distinguish between variability caused by tides and variability observed in the tides themselves. Both effects have been detected at some level. The most obvious connection with decadal timescales is through the 18.6-year precession of the moon's orbit plane. This precession gives rise to a small tide of the same period and to 18.6-year modulations in the phase and amplitudes of short-period tides. The 18.6-year "node tide" is very small, no more than 2 cm anywhere, and in sea level data it is dominated by the ocean's natural Variability. Some authors have naively attributed climate variations with periods near 19 years directly to the node tide, but the amplitude of the tide is too small for this mechanism to be operative. The more likely explanation (Loder and Garrett, JGR, 83, 1967-70, 1978) is that the 18.6-y modulations in short-period tides, especially h e principal tide M2, cause variations in ocean mixing, which is then observed in temperature and other climatic indicators. Tidally forced variability has also been proposed by some authors, either in response to occasional (and highly predictable) tidal extremes or as a nonlinear low-frequency oscillation caused by interactions between short-period tides. The former mechanism can produce only short-duration events hardly more significant than normal tidal ranges, but the latter mechanism can in principle induce low-frequency oscillations. The most recent proposal of this type is by Keeling and Whorf, who highlight the 1800-year spectral peak discovered by Bond et al. (1997). But the proposal appears contrived and should be considered, in the words of Munk et al. (2002), "as the most likely among unlikely candidates."

Ray, Richard D.↗

Toward Martian agriculture: responses of plants to hypobaria

The recent surge of interest in human missions to Mars has also generated considerable interest in the responses of plants to hypobaria (reduced atmospheric pressure), particularly among those in the advanced life support community. Potential for in situ resource utilization, challenges in meeting engineering constraints for mass and energy, the prospect of using lightweight plant growth structures on Mars, and the minimal literature on plant responses to low pressure all suggest much needed research in this area. However, the limited literature on hypobaria combined with previous findings on plant responses to atmospheric composition and established principles of mass transfer of gases suggest that some plants will be capable of tolerating and growing at pressures below 20 kPa; and for other species, perhaps as low as 5-10 kPa. In addition, normal and perhaps enhanced growth of many plants will likely occur at reduced partial pressures of oxygen (e.g., 5 kPa). Growth of plants at such low and partial pressures indicates the feasibility of cultivating plants in lightweight, transparent "greenhouses" on the surface of Mars or in other extraterrestrial or extreme environment locations. There are numerous, accessible terrestrial analogs for moderately low pressure ranges, but not for very low and extremely low atmospheric pressures. Research pertaining to very low pressures has been historically restricted to the use of vacuum chambers. Future research prospects, approaches, and priorities for plant growth experiments at low pressure are considered and discussed as they apply to prospects for Martian agriculture.

NASA Discipline Life Support Systems↗

Nexus of thermal resilience and energy efficiency in buildings: A case study of a nursing home

Extreme weather events become more frequent and severe due to climate change. Although energy efficiency technologies can influence thermal resilience of buildings, they are traditionally studied separately, and their interconnections are rarely quantified. This study developed a methodology of modeling and analysis to provide insights into the nexus of thermal resilience and energy efficiency of buildings. In this work, we conducted a case study of a real nursing home in Florida, where 12 patients died during Hurricane Irma in 2017 due to HVAC system power loss, to understand and quantify how passive and active energy efficiency measures (EEMs) can improve thermal resilience to reduce heat-exposure risk of patients. Results show that passive measures of opening windows and doors for natural ventilation, as well as miscellaneous load reduction, are very effective in eliminating the extreme dangerous occasions. However, to maintain safe conditions, active measures such as on-site power generators and thermal storage are also needed. The nursing home was further studied by changing its location to two other cities: San Francisco (mild climate) and Chicago (cold winter and hot summer). Results revealed that the EEMs' impacts on thermal resilience vary significantly by climate and building characteristics. The study also estimated the costs of EEMs to help stakeholders prioritize the measures. Passive measures that may not save energy may greatly improve thermal resilience, and thus should be considered in building design or retrofit. Findings from this study indicate energy efficiency technologies should be evaluated not only by their energy savings performance but also by their influence on a building's resilience to extreme weather events.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Magnetic loops, downflows, and convection in the solar corona

Optical and extreme-ultraviolet observations of solar loop structures show that flows of cool plasma from condensations near the loop apex are a common property of loops associated with radiations whose maximum temperature is greater than approximately 7000 K and less than approximately 3,000,000 K. It is suggested that the mass balance of these structures indicates reconnection by means of plasma motion across field lines under rather general circumstances (not only after flares). It is shown that the cool material has lower gas pressure than the surrounding coronal medium. The density structure of the bright extreme ultraviolet loops suggests that downflows of cool gas result from isobaric condensation of plasma that is either out of thermal equilibrium with the local energy deposition rate into the corona, or is thermally unstable. The evidence is thought to indicate that magnetic fields act to induce a pattern of forced convection.

Foukal, P.↗

The Application of Remote Sensing using NASA Earth Observations paired with Sociodemographic Indicators to Identify Communities Most Susceptible to Urban Heat Exposure in Austin, Texas

In recent years, Austin, Texas has experienced an increase in population and urban development. Additionally, the City’s climate—already characterized by periods of extreme heat and drought—continues to change. As temperatures and demand for utilities and cooling resources rise, the number of heat-related deaths and illnesses in socially vulnerable populations (e.g., older, lower-income populations) is expected to increase. The City of Austin, The University of Texas at Austin (UT Austin), and The University of Texas Health Science Center at Houston (UT Health) partnered with NASA DEVELOP to examine the distribution of urban heat throughout the City. This project used land surface temperature, greenness, plant water content, and urban surface material analysis parameters derived from NASA Earth observations from Landsat 8 Operational Land Imager (OLI), Landsat 8 Thermal Infrared Sensor (TIRS), and Aqua and Terra Moderate Resolution Imaging Spectroradiometer (MODIS). The project team produced three different indices to create a spatial analysis for the study area including a social vulnerability index (SoVI), heat exposure index (HEI), and an overall heat priority index (HPI) score. This overall score was determined with a weighted analysis of heat-related environmental variables from NASA Earth observations and socioeconomic data from the 2019 American Community Survey. Based on the HPI score, the project team identified 121 census block groups out of 605 total that are designated as being most at risk of adverse impacts from extreme heat events. To test the sensitivity of the HPI, the team used a Monte Carlo analysis using different approaches for geographic scale, variable inclusion, census uncertainty, and index aggregation. Based on the sensitivity analysis, the resulting HPI score showed the metric was consistent with the baseline HPI. This provided increased confidence the score can be used as a tool to make informed infrastructure improvement plans in targeted areas (e.g., siting of cooling centers) and ensure equitable sustainable development.

Ryan Hammock↗

J1046+4047: an extremely low-metallicity dwarf star-forming galaxy with O32 = 57

ABSTRACT Using the optical spectrum obtained with the Kitt Peak Ohio State Multi-Object Spectrograph mounted on the Apache Point Observatory 3.5 m Telescope and the Sloan Digital Sky Survey spectrum, we study the properties of one of the most metal-poor dwarf star-forming galaxies (SFGs) in the local Universe, J1046+4047. The galaxy, with a redshift z = 0.04874, was selected from the Data Release 16 of the SDSS. Its properties are among the most extreme for SFGs in several ways. The oxygen abundance 12 + log(O/H) = 7.082 ± 0.016 in J1046+4047 is among the lowest ever observed. With an absolute magnitude Mg = −16.51 mag, a low stellar mass M⋆ = 1.8 × 106 M⊙, and a very low mass-to-light ratio M⋆/Lg ∼ 0.0029 (in solar units), J1046+4047 has a very high specific star formation rate sSFR ∼ 430 Gyr−1, indicating very active ongoing star formation. Another striking feature of J1046+4047 is that it possesses a ratio O32 = I([O iii] λ5007)/I([O ii] λ3727) ∼ 57. Using this extremely high O32, we have confirmed and improved the strong-line calibration for the determination of oxygen abundances in the most metal-deficient galaxies, in the range 12 + log(O/H) ≲ 7.65. This improved method is applicable for all galaxies with O32 ≤ 60. We find the H α emission line in J1046+4047 to be enhanced by some non-recombination processes and thus cannot be used for the determination of interstellar extinction.

Izotov, Y. I. (ORCID:0000000214166082)↗