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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Comparison of direct and heterodyne detection optical intersatellite communication links

The performance of direct and heterodyne detection optical intersatellite communication links are evaluated and compared. It is shown that the performance of optical links is very sensitive to the pointing and tracking errors at the transmitter and receiver. In the presence of random pointing and tracking errors, optimal antenna gains exist that will minimize the required transmitter power. In addition to limiting the antenna gains, random pointing and tracking errors also impose a power penalty in the link budget. This power penalty is between 1.6 to 3 dB for a direct detection QPPM link, and 3 to 5 dB for a heterodyne QFSK system. For the heterodyne systems, the carrier phase noise presents another major factor of performance degradation that must be considered. In contrast, the loss due to synchronization error is small. The link budgets for direct and heterodyne detection systems are evaluated. It is shown that, for systems with large pointing and tracking errors, the link budget is dominated by the spatial tracking error, and the direct detection system shows a superior performance because it is less sensitive to the spatial tracking error. On the other hand, for systems with small pointing and tracking jitters, the antenna gains are in general limited by the launch cost, and suboptimal antenna gains are often used in practice. In which case, the heterodyne system has a slightly higher power margin because of higher receiver sensitivity.

Chen, C. C.↗
NASA NTRS1993

Direction angle sensitivity of agricultural field backscatter with AIRSAR data

This paper presents a study of the direction angle sensitivity of radar backscatter from agricultural fields. The direction angle is defined as the angle between the incident plane and the perpendicular to the field row direction. Previous studies have concentrated on comparing the backscatter of agricultural fields imaged with 0, 45, and 90 degree direction angles. In contrast, this study concentrates on the backscatter changes occurring when the direction angle is modified by a few degrees or even by fractions of a degree. This is possible by using the output of the NASA/JPL AIRSAR processor, in which sixteen independent frames are formed, each one corresponding to the same radar scene imaged with a slightly different squint angle. The studied data set is an agricultural area in La Mancha, Spain acquired in June and July 1991 during the EFEDA experiment. This paper describes the observed backscatter variations of the agricultural fields with direction angle measured at P, L, and C bands. As expected, the backscatter is maximum for a 0 degree direction angle. For several fields, the backscatter at P and L bands drops by more than 10 dB for a 5 degree change in direction angle. Furthermore, the sensitivity to the direction angle decreases with increasing vegetation. The variations in backscatter are compared with model predictions. One model, which agrees with scatterometer data, underestimates the observed backscatter variations with direction angle by more than 10 dB. It does not take into account the possible coherent component of the radar signal. We believe the strong direction sensitivity of agricultural field backscatter obtained with SAR data is due to a Bragg resonant effect, resulting in a strong coherent return when the direction angle is zero. The observations are then projected to the case of spaceborne SAR data.

Dubois, Pascale C.↗
DOE OSTI2025

Assessing the fidelity of shallow-water carbonates as records of the Ni isotope composition of surface seawater

Nickel is a bioessential metal that is used in enzymes important to the C, N, and O cycles, and changes in its marine abundance and bioavailability may have affected the evolutionary trajectory of early life. Changes over time in the Ni isotope composition (δ 60 Ni) of surface seawater, which reflects biological demand for Ni, could allow for the reconstruction of the dynamics of Ni demand over Earth’s history, but this approach would require geologic records of surface seawater. Here, we investigate the fidelity of shallow-water carbonates as a record of the Ni isotope composition of surface seawater by determining how Ni is first partitioned into natural carbonates and then how post-depositional processes influence the Ni signal. Our samples come from the Great Bahama Bank, which is a well-studied, modern carbonate platform often used to study ancient platforms. We found that Ni is fractionated from seawater upon incorporation into carbonates capturing shallow (<18 cm), recent deposition (0.1 ‰–0.4 ‰ lighter than seawater). Variation among these [Ni] and δ 60 Ni values may be controlled by variation in mineral proportions. Meteoric diagenesis shifts δ 60 Ni to lower values, which we attribute to isotopically light meteoric fluids. In contrast, carbonates that experienced sediment-buffered marine diagenesis with respect to Ca isotopes and Sr/Ca ratios do not appear to differ in δ 60 Ni values from sediments generally representative of their initial deposition. The sensitivity of δ 60 Ni to diagenetic reset in these samples appears comparable to the sensitivities of Ca isotopes and Sr/Ca ratios, to first order. Thus, in general, carbonates that experienced sediment-buffered marine diagenesis with respect to these elements may hold the most promise as a record of the δ 60 Ni of coeval surface seawater. Additionally, we use our results to infer that the fraction of Ni removed from seawater into carbonates is less than 10 % of the total Ni output from the global oceans and incorporation of this Ni sink into global biogeochemical models will only have a minor impact on the modeled modern Ni budget.

Great Bahama Bank carbonates↗
DOE OSTI2022

Evolution of Bonding and Magnetism via Changes in Valence Electron Count in CuFe 2– x Co x Ge 2

A series of solid solutions, CuFe 2–x Co x Ge 2 (x = 0, 0.2, 0.4, 0.8, and 1.0), have been synthesized by arc-melting and characterized by powder X-ray and neutron diffraction, magnetic measurements, Mössbauer spectroscopy, and electronic band structure calculations. All compounds crystallize in the CuFe 2 Ge 2 structure type, which can be considered as a three-dimensional framework built of fused MGe6 octahedra and MGe 5 trigonal bipyramids (M = Fe and Co), with channels filled by rows of Cu atoms. As the Co content (x) increases, the unit cell volume decreases in an anisotropic fashion: the b and c lattice parameters decrease while the a parameter increases. The changes in all the parameters are nearly linear, thus following Vegard’s law. CuFe 2 Ge 2 exhibits two successive antiferromagnetic (AFM) orderings, corresponding to the formation of a commensurate AFM structure, followed by an incommensurate AFM structure observed at lower temperatures. Additionally, as the Co content increases, the AFM ordering temperature (TN) gradually decreases, and only one AFM transition is observed for x ≥ 0.2. The magnetic behavior of unsubstituted CuFe 2 Ge 2 was found to be sensitive to the preparation method. The temperature-dependent zero-field 57 Fe Mössbauer spectra reveal two hyperfine split components that evolve in agreement with the two consecutive AFM orderings observed in magnetic measurements. In contrast, the field-dependent spectra obtained for fields ≥ 2 T reveal a parallel arrangement of the moments associated with the two crystallographically unique metal sites. Electronic band structure calculations and chemical bonding analysis reveal a mix of strong M–M antibonding and non-bonding states at the Fermi level, in support of the overall AFM ordering observed in zero field. The substitution of Co for Fe reduces the population of the M–M antibonding states and the overall density of states at the Fermi level, thus suppressing the T N value.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Thermal responses of dissolved organic matter under global change

The diversity of intrinsic traits of different organic matter molecules makes it challenging to predict how they, and therefore the global carbon cycle, will respond to climate change. Here we develop an indicator of compositional-level environmental response for dissolved organic matter to quantify the aggregated response of individual molecules that positively and negatively associate with warming. We apply the indicator to assess the thermal response of sediment dissolved organic matter in 480 aquatic microcosms along nutrient gradients on three Eurasian mountainsides. Organic molecules consistently respond to temperature change within and across contrasting climate zones. At a compositional level, dissolved organic matter in warmer sites has a stronger thermal response and shows functional reorganization towards molecules with lower thermodynamic favorability for microbial decomposition. The thermal response is more sensitive to warming at higher nutrients, with increased sensitivity of up to 22% for each additional 1 mg L -1 of nitrogen loading. The utility of the thermal response indicator is further confirmed by laboratory experiments and reveals its positive links to greenhouse gas emissions.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

High sensitivity pressure and temperature quantum sensing in pentacene-doped p-terphenyl single crystals

Quantum sensors’ responsiveness to their physical environment enables detection of variables such as temperature (T), pressure (P), and strain. We present a molecular platform for PT sensing using para-terphenyl crystals doped with pentacene (PDP), leveraging optically detected magnetic resonance (ODMR) of photoexcited triplet electron spins. We observe maximal frequency variations of df/dP=1.8 MHz/bar from 0-8 bar and df/dT=247 kHz/K from 79–330 K, over 1200 times and threefold greater, respectively, than those seen with nitrogen-vacancy centers in diamond and > 85-fold greater pressure sensitivity over the previous record. Density functional theory calculations indicate picometer-level PT-induced molecular orbital shifts are measurable via ODMR. PDP offers additional advantages including high sensor doping levels, narrow ODMR linewidths, high contrast, and low-cost single crystal growth. Overall, this work reports low-cost, optically-interrogated PT sensors and lays the foundation for increased versatility of quantum sensors through synthetic molecular design.

Magnetic properties and materials↗
DOE OSTI2025

Probing a New Regime of Neutrino Self-Interactions with Astrophysical Neutrinos and the Relativistic Cosmic Neutrino Background

Neutrino self-interactions beyond the standard model have profound implications in astrophysics and cosmology. In this Letter, we study an uncharted scenario in which one of the three neutrino species has a mass smaller than the temperature of the cosmic neutrino background. This results in a relativistic component that significantly broadens the absorption feature on the astrophysical neutrino spectra, in contrast to the sharply peaked absorption expected in the extensively studied scenarios assuming a fully nonrelativistic cosmic neutrino background. By solving the Boltzmann equations for neutrino absorption and regeneration, we demonstrate that this mechanism provides novel sensitivity to sub-keV mediator masses, well below the traditional ∼1–100 MeV range. Future observations of the diffuse supernova neutrino background with Hyper-Kamiokande could probe coupling strengths down to 𝑔 ∼10 −8 , surpassing existing constraints by orders of magnitude. These findings open new directions for discoveries and offer crucial insights into the interplay between neutrinos and the dark sector.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Andreev reflection at the altermagnet-superconductor interface

Altermagnets are a new class of magnetic materials, which exhibit large spin splitting, but due to the combined spin and real space group symmetry protection maintain zero net macroscopic magnetization. Such a characteristic may prove them to be superior in applications in superconducting heterostructures and thus here we investigate the Andreev reflection at the altermagnet/superconductor interface. We compare and contrast altermagnets to other magnetic materials, revealing qualitative differences in the behavior of altermagnetic junction depending on the Fermi surface orientation. We study the resonant states arising in setups with strong tunneling barriers and show that sensitivity to nonmagnetic disorder is also dependent on the orientation. In conclusion, our results provide a building block for altermagnetic superconducting heterostructures such as Josephson π junctions with superior properties.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Revealing subterahertz atomic vibrations in quantum paraelectrics by surface-sensitive spintronic terahertz spectroscopy

Understanding surface collective dynamics in quantum materials is crucial for advancing quantum technologies. For example, surface phonon modes in quantum paraelectrics are thought to be essential in facilitating interfacial superconductivity. However, detecting these modes, especially below 1 terahertz, is challenging because of limited sampling volumes and the need for high spectroscopic resolution. Here, we report surface soft transverse optical (TO1) phonon dynamics in KTaO 3 and SrTiO 3 by surface-sensitive spintronic terahertz spectroscopy that can sense the collective modes only a few nanometers deep from the surface. In KTaO 3 , the TO1 mode softens and sharpens with decreasing temperature, leveling off at 0.7 terahertz. In contrast, this mode in SrTiO 3 broadens substantially below the quantum paraelectric crossover and coincides with the hardening of a sub–milli–electron volt phonon mode related to the antiferrodistortive transition. These observations that deviate from their bulk properties may have implications for interfacial superconductivity and ferroelectricity. The developed technique opens opportunities for sensing low-energy surface collective excitations.

Chu, Zhaodong↗
DOE OSTI2019

Characterizing Vulnerabilities Associated with Connected Lighting: Exploring Authorization Protocols

Cities are upgrading their infrastructure and converting traditional indoor and outdoor luminaires to Connected Lighting Systems equipped with sensors in an aggressive effort to reduce energy consumption, increase sustainability, and improve the quality of life. When you take something seemingly benign like a lighting system and connect it to the internet, if improperly secured a potential attack vector for hackers is created. Hackers could then access sensitive information, pivot into other networks, shut down services, or enslave devices to do their bidding. In attempt to close this attack vector and secure these systems, this paper extends previous work that investigated, compared and contrasted authentication vulnerabilities in Connected Lighting Systems that identified the need for additional testing and improved test method documentation. One additional authentication test and four new authorization tests were developed utilizing the Open Web Application Security Project (OWASP) as a test development and documentation guide. The new tests were integrated with the previous work to develop an updated test method with a focus on describing test procedures to make them easy to understand and repeat. In addition, a first Connected Lighting System use case was established to begin developing threat profiles that will aid in the identification of vulnerabilities whose focus areas extend beyond authentication and authorization. This use case describes the generation and flow of CLS data which assists in specifying methods to harden CLSs from outside interference and exploitation that can be implemented immediately on existing CLSs and as new products come to market.

97 MATHEMATICS AND COMPUTING↗
NASA NTRS1978

Cost benefit assessment of NASA remote sensing technology transferred to the State of Georgia

The benefits involved in the transfer of NASA remote sensing technology to eight Georgia state agencies are identified in quantifiable and qualitative terms, and a value for these benefits is computed by means of an effectiveness analysis. The benefits of the transfer are evaluated by contrasting a baseline scenario without Landsat and an alternative scenario with Landsat. The net present value of the Landsat technology being transferred is estimated at 9.5 million dollars. The estimated value of the transfer is most sensitive to discount rate, the cost of photo acquisition, and the cost of data digitalization. It is estimated that, if the budget is constrained, Landsat could provide data products roughly seven times more frequently than would otherwise be possible.

Kelly, D. L.↗
NASA NTRS1983

Enhanced crop discrimination using the mid-IR (1.55-1.75 microns)

Improvements in crop discrimination can be realized by using mid-IR bands (1.55 -1.75 and 2.08 -2.35 microns) which are sensitive to canopy moisture content. Analyses of data from two growing seasons in Webster County, Iowa clearly indicate that corn and soybeans are highly separable in the mid-IR from early season through harvest. This contrasts sharply with visible and near-IR bands where corn and soybeans are confused throughout much of the growing season. The mid-IR temporal reflectance behavior appears to result from differences between C4 monocot and C3 dicot internal leaf structure. If this hypothesis holds, mid-IR observations should improve discrimination in other instances where similar differences in internal leaf structure are present.

Ungar, S. G.↗
NASA NTRS1998

Nonlinear Analysis of the Space Shuttle Superlightweight LO2 Tank: Bahavior Under Booster Ascent Loads - Part 1

Results of linear bifurcation and nonlinear analyses of the Space Shuttle superlightweight (SLWT) external liquid-oxygen (LO2) tank for an important early booster ascent loading condition are presented. These results for thin-walled linear elastic shells that are subjected to combined mechanical and thermal loads illustrate an important type of response mode that may be encountered in the design of other liquid-fuel launch vehicles. Linear bifurcation analyses are presented that predict several nearly equal eigenvalues that correspond to local buckling modes in the forward ogive section of the LO2 tank. In contrast, the nonlinear response phenomenon is shown to consist of short-wavelength bending deformations in the forward ogive and barrel sections of the LO2 tank that growing amplitude in a stable manner increasing load. Imperfection sensitivity analyses are presented that show that the presence of several nearly equal eigenvalues does not lead to a premature general instability mode for the forward ogive section. For the linear bifurcation and nonlinear analyses, the results show that accurate predictions of the response of the shield generally require a large-scale, high-fidelity finite-element model. Results are also presented that show that the SLWT LO2 tank can support loads in excess of approximately 2.6 times the values of the operational loads considered.

Young, Richard D.↗
NASA NTRS2000

Aerosol Radiative Forcing in Asian Continental Outflow

Aerosols in elevated layers were sampled with FSSP-probes and wire impactors over the Pacific ocean aboard the NASA DC-8 aircraft. Analyses of particle size and morphology identifies two distinctly different aerosol types for cases when the mid-visible extinctions exceed 0.2/km. Smaller sizes (effective radii of 0.2 um) and moderate absorption (mid-visible single scattering albedo of.935) are typical for urban-industrial pollution. Larger sizes (effective radii of 0.7 um) and weak absorption (mid-visible single scattering albedo of 0.985) identify dust. This aerosol classification is in agreement with its origin as determined by airmass back trajectory analysis. Based on lidar vertical profiling, aerosol dominated by dust and urban-industrial pollution above 3km were assigned mid-visible optical depths of 0.50 and 0.27, respectively. Radiative transfer simulations, considering a 50% cloud-cover below the aerosol layers, suggest (on a daily tP C)C> basis) small reductions (-4W/m2) to the energy budget at the top of the atmosphere for both aerosol types. For c' 0 dust, more backscattering of sunlight (weaker solar absorption) is compensated by a stronger greenhouse effect due to larger sizes. Forced reductions to the energy budget at the surface are 12W/m2 for both aerosol types. In contrast, impacts on heating rates within the aerosol layers are quite different: While urban-industrial aerosol warms the layer (at +0.6K/day as solar heating dominates), dust cools (at -0.5K/day as infrared cooling dominates). Sensitivity tests show the dependence of the aerosol climatic impact on the optical depth, particle size, absorptivity, and altitude of the layers, as well as clouds and surface properties. Climatic cooling can be eliminated (1) for the urban-industrial aerosol if absorption is increased to yield a mid-visible single scattering albedo of 0.89, or if the ocean is replaced by a land surface; (2) for the dust aerosol if the effective radius is increased from 0.7 to 1.2 um. The removal of low-level clouds doubles the cooling at the top of the atmosphere to about -8W/m2.

Pueschel, R.↗
NASA NTRS2000

Time- and dose-related interactions between glucocorticoid and cyclic adenosine 3',5'-monophosphate on CCAAT/enhancer-binding protein-dependent insulin-like growth factor I expression by osteoblasts

Glucocorticoid has complex effects on osteoblasts. Several of these changes appear to be related to steroid concentration, duration of exposure, or specific effects on growth factor expression or activity within bone. One important bone growth factor, insulin-like growth factor I (IGF-I), is induced in osteoblasts by hormones such as PGE2 that increase intracellular cAMP levels. In this way, PGE2 activates transcription factor CCAAT/enhancer-binding protein-delta (C/EBPdelta) and enhances its binding to a specific control element found in exon 1 in the IGF-I gene. Our current studies show that preexposure to glucocorticoid enhanced C/EBPdelta and C/EBPbeta expression by osteoblasts and thereby potentiated IGF-I gene promoter activation in response to PGE2. Importantly, this directly contrasts with inhibitory effects on IGF-I expression that result from sustained or pharmacologically high levels of glucocorticoid exposure. Consistent with the stimulatory effect of IGF-I on bone protein synthesis, pretreatment with glucocorticoid sensitized osteoblasts to PGE2, and in this context significantly enhanced new collagen and noncollagen protein synthesis. Therefore, pharmacological levels of glucocorticoid may reduce IGF-I expression by osteoblasts and cause osteopenic disease, whereas physiological transient increases in glucocorticoid may permit or amplify the effectiveness of hormones that regulate skeletal tissue integrity. These events appear to converge on the important role of C/EBPdelta and C/EBPbeta on IGF-I expression by osteoblasts.

NASA Program Biomedical Research and Countermeasur↗
NASA NTRS2016

Deep Charging Evaluation of Satellite Power and Communication System Components

Deep charging, in contrast to surface charging, focuses on electron penetration deep into insulating materials applied over conductors. A classic example of this scenario is an insulated wire. Deep charging can pose a threat to material integrity, and to sensitive electronics, when it gives rise to an electrostatic discharge or arc. With the advent of Electric Orbit Raising, which requires spiraling through Earth's radiation belts, satellites are subjected to high energy electron environments which they normally would not encounter. Beyond Earth orbit, missions to Jupiter and Saturn face deep charging concerns due to the high energy radiation environments. While predictions can be made about charging in insulating materials, it is difficult to extend those predictions to complicated geometries, such as the case of an insulating coating around a small wire, or a non-uniform silicone grouting on a bus bar. Therefore, to conclusively determine the susceptibility of a system to arcs from deep charging, experimental investigations must be carried out. This paper will describe the evaluation carried out by NASA's Marshall Space Flight Center on subscale flight-like samples developed by Space Systems/Loral, LLC. Specifically, deep charging evaluations of solar array wire coupons, a photovoltaic cell coupon, and a coaxial microwave transmission cable, will be discussed. The results of each evaluation will be benchmarked against control sample tests, as well as typical power system levels, to show no significant deep charging threat existed for this set of samples under the conditions tested.

Schneider, T. A.↗
DOE OSTI2025

Degrees of rate control and AutoDiff-driven direct sensitivity analysis in heterogeneous catalysis

Despite the wide application and benefits of the degree of rate control (DRC) analysis, several details remain argued, particularly about the conservation of DRCs at transient (TR) and steady-state (SS) conditions, especially for complex reaction networks. This work argues that previous proofs about the conservation properties of DRCs have been incomplete, and we provide new mathematical proofs at TR and SS conditions. In addition, we use both analytical (automatic differentiation) and numerical (finite difference) approaches to compute DRCs for the case study of ethane hydrogenolysis (EH) over Pt(111). This work confirms that at both TR and SS conditions, the sum of all DRCs, i.e., sum of the degrees of kinetic (DKRC) and thermodynamic rate control (DTRC), is conserved at zero. At SS conditions, the sum of DKRC is conserved at 1 while the sum of DTRC is conserved at −1. In corroboration of previous works, we show that the DTRC for any adsorbate at SS is equal to the product of the species coverage and a constant. In contrast, at TR conditions, the individual sums of both DTRC and DKRC are not conserved and can be any real number, with potential implications for the novel field of dynamic catalysis. Finally, we show that the conventional finite difference (FD) approach, only useful at SS, is prone to inaccuracy and very sensitive to the value of the differential change applied. The optimal differential value also varies significantly with system and rate definition. Consequently, we describe and illustrate in this work the application of the automatic differentiation (AD) approach for the more accurate determination of DRCs at both TR and SS conditions.

Automatic differentiation↗