Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Co”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 631 records · Page 35
All sourcesNASA NTRSDOE OSTI
NASA NTRS1972

Photodissociation of CO2 to produce CO /a super 3 pi/.

Carbon dioxide in a helium buffer at room temperature was irradiated with a photon beam. The wavelengths used in the investigation were in the range from 850 to 1090 A. Phosphorescence from CO Cameron bands was observed. The phosphorescent yield is zero at threshold and increases smoothly to a maximum of about 60% near 900 A. The smoothness of the percentage yield was an unexpected observation and is explained by postulating that the relevant potential surface crossings are outside the Franck-Condon region of carbon dioxide absorption.

Lawrence, G. M.↗
NASA NTRS1972

Mechanisms of oxidation in the Co-Cr system.

Oxidation has been studied both as a function of temperature in the range from 900 to 1300 C and of the partial pressure of oxygen in the range from 0.05 to 760 torr. In addition, microstructures of oxide scales have been studied and characterized in more detail utilizing metallographic and X-ray techniques combined with electron microprobe analysis. The parabolic rate constants in 1100 C and at 100 and 10 torr oxygen are presented in a graph as a function of chromium content. Three main different mechanisms of oxidation in the Co-Cr system have been identified. In two of these, the rate determining process controlling the oxidation is the solid state diffusion of cobalt through the oxide CoO. The rate controlling process governing the oxidation for the third mechanism is chromium diffusion in dichromium trioxide.

Kofstad, P. K.↗
NASA NTRS1972

Electron impact excitation cross sections and energy degradation in CO.

We determine a comprehensive set of electron impact cross sections for carbon monoxide mainly on the basis of recently accumulated data on electron impact spectra, the Born approximation at high energies, and simple rules developed earlier to take into account low-energy effects. The calculation of the complete energy degradation of electrons incident on CO is carried out with these input cross sections, and the efficiencies associated with possible loss channels are presented.

Sawada, T.↗
NASA NTRS1973

The effect of thermal cycling on the structure and properties of a Co, Cr, Ni-TaC directionally solidified eutectic composite

A Co, Cr, Ni-TaC directionally solidified eutectic composite was subjected to thermal fatigue between 427-1093°C. The material suffered degradation in microstructure and elevated temperature mechanical properties. The loss in properties varied with the maximum cycling temperature and number of cycles. This behavior is attributed to the increasing solubility of the TaC in the matrix with temperature from 0.4% at room temperature to 2.2% at 1200°C. During the thermal cycling, the TaC is subjected to solution and reprecipitation which form serrations on the fibers since the easy growth planes of the TaC are not coincident with the fiber faces exposed to the matrix.

Composites↗
NASA NTRS1972

Vibrational excitation in CO by electron impact in the energy range 10-90 eV.

The ratio of the scattering intensity for the v double prime = 1 excitation to the elastic scattering intensity at 40- and 80-deg scattering angles has been determined for 10- to 90-eV impact energies for electron scattering by CO. These ratio curves exhibit broad peaks near 20-eV impact energy which cannot be accounted for by plane-wave calculations based on potential scattering models. The peaks are indicative of a resonant excitation process (or processes) in the v double prime = 1 channel in the range from 15 to 25 eV.

Chutjian, A.↗
NASA NTRS1972

CW operation in some CO lines below 5.0 microns.

CW laser emission has been observed from a He-N2-O2-CO laser on six vibration-rotation lines of carbon monoxide that lie below 5.0 microns. The lines correspond to V = 4:3 transitions.

Weisbach, M. F.↗
NASA NTRS1973

Analysis of Mossbauer Fe-57 absorption in an F.C.C. Fe-Co-V alloy

Mossbauer Fe-57 absorption spectra of superparamagnetic F.C.C. Fe sub .34 Co sub .52 V sub 14 (Vicalloy II) have been analyzed using a cluster model and magnetic resonance relaxation theory. The number and magnetic moment of the clusters were determined from magnetization data. A least squares fit to the spectrum at 4.2 K gives sub Hhyp = 175. kG, substantially greater than the value 55 kG inferred just from the observed broadening of the single line spectrum. From this broadening an estimate of 40 kG is obtained for the width of the distribution in Hhyp at 4.2 K arising from compositional fluctuations sub and small cluster effects.

Bambakidis, G.↗
NASA NTRS1974

A general form of the co-moving tensorial derivative

A general expression for the co-moving derivative of a tensor is derived. A variable describing the coordinate velocity field is introduced. Time dependency of the metric elements is expressed in terms of this velocity field. The resulting description of motion is one of which the Eulerian and Lagrangian viewpoints are special cases. This general description is useful in problems involving moving boundaries or discontinuities.

Huckins, E. K., III↗
NASA NTRS1973

Photoionization branching ratios and vibrational intensity distribution for N2, CO; and CO2 between 53 and 75 nm

The probability of radiation producing ions in specific electronic and vibrational levels was documented. For example, when a narrow band-pass of solar ionizing photons is incident on an atmospheric species it is now possible to describe, accurately, how the radiant energy is shared among the various electronic states of the ions produced. The molecules studied were N2, CO, and CO2. These molecules were photoionized by radiation between 53 and 75 nm. The effects of autoionization are discussed and continuum vibrational intensities are tabulated and compared with theoretical Franck-Condon factors where available. The branching ratios and partial cross sections for ionization into various electronic states are tabulated.

Samson, J. A. R.↗
NASA NTRS1973

Observation of the J = 2 to J = 1 transition of interstellar CO at 1.3 millimeters

The NRAO 36-foot antenna at Kitt Peak with a novel type of millimeter-wave superheterodyne receiver was used in observations of 1.3-mm line interstellar radiation due to J ? 2-1 transitions of C(12)0(16) and C(13)0(16). The liquid-helium-cooled hot-electron bolometer mixer of the superheterodyne receiver was used as the detecting element. The Orion Nebula CO system was found to be thermalized, showing a peak excitation temperature of about 76 K.

Phillips, T. G.↗
NASA NTRS1974

Shock tube measurements of specific reaction rates in the branched chain CH4-CO-O2 system

Rate constants of two elementary bimolecular reactions involved in the oxidation of methane have been determined by monitoring the exponential growth of CO flame band emission behind incident shocks in three suitably chosen gas mixtures. The data do not support a mechanism which invokes the four center process CH3 + O2 yields CH2O + OH for the reaction of methyl with oxygen.

Brabbs, T. A.↗
NASA NTRS1974

Decomposition of NO studied by infrared emission and CO laser absorption

A diagnostic technique for monitoring the concentration of NO using absorption of CO laser radiation was developed and applied in a study of the decomposition kinetics of NO. Simultaneous measurements of infrared emission by NO at 5.3 microns were also made to validate the laser absorption technique. The data were obtained behind incident shocks in NO-N2O-Ar (or Kr) mixtures, with temperatures in the range 2400-4100 K. Rate constants for dominant reactions were inferred from comparisons with computer simulations of the reactive flow.

Hanson, R. K.↗
NASA NTRS1975

CO observations of the expanding envelope of IRC plus 10216

High-sensitivity emission profiles were observed for the transition of C12O16 and C13O16 towards IRC + or - 10216. It appears that the spherically symmetric uniform mass-outflow model proposed by Morris is necessary to describe the line profiles. The outflow appears to be slightly accelerated, having a velocity of 15 km/sec at the edges of the CO cloud, compared with 12 km/sec for the more centrally confined molecules.

Kuiper, T. B. H.↗
NASA NTRS1974

Rate of recombination of oxygen atoms and CO at temperatures below ambient

The measurements reported were conducted with 30.0 torr CO, 40.0 torr argon, and varying amounts of carbon dioxide from about 20 to 230 torr. Measurements were made at 277, 272, 263, and 257 K. The pseudo-first-order decay rate as a function of carbon dioxide pressure is shown in a graph. An Arrhenius plot for the rate constants obtained from the measurements is also presented. A value for the activation energy was determined on the basis of a linear least-squares fit to the data.

Inn, E. C. Y.↗
NASA NTRS1975

Turbulent pressure field in a co-annular jet

Single point and two-point fluctuating static pressure measurements have been made in the initial mixing and transition regions in a co-annular circular jet. Space scales, correlation and time scales in the convected frame, and convection velocities have been determined for both broad band and narrow band frequency components. Analytical functionals describing the structural behavior of the turbulent pressure field have been developed from the data which are suitable for direct application in predicting the sound power level radiated from this turbulent field. Effects of both area and velocity ratios are incorporated in the model.

Hammersley, R. J.↗
NASA NTRS1975

Measurement of line widths of CO of planetary interest at low temperatures

Self-broadened, air-broadened and CO2-broadened half-widths of lines R(0) through R(16) in the CO fundamental have been measured at 100 K (self-broadening only), 200 K, 250 K and 300 K using the Ladenburg-Reiche curve-of-growth. The relation which we found previously for the nitrogen-broadened half-widths of R(0), R(8), and R(16), is shown to be valid for all of the line widths measured in the present study.

Varanasi, P.↗
NASA NTRS1975

Ultraviolet-gas phase and -photocatalytic synthesis from CO and NH3

Ammonium cyanate is identified as the major product of the photolysis of gaseous NH3-CO mixtures at 206.2 or 184.9 nm. Lesser amounts of urea, biurea, biuret semicarbazide, formamide and cyanide are observed. A series of 18 reactions underlying the formation of photolysis products is presented and discussed. Photocatalytic syntheses of C-14-urea, -formamide, and -formaldehyde are carried out through irradiation of (C-14)O and NH3 in the presence of Vycor, silica gel, or volcanic ash shale surfaces. The possible contributions of the relevant reactions to the abiotic synthesis of organic nitrogen compounds on Mars, the primitive earth, and in interstellar space are examined.

Hubbard, J. S.↗