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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 631 records · Page 35

All sources NASA NTRS DOE OSTI

DOE OSTI2022

Kinetic modelling of an environmentally friendly carbamazepine synthesis via urea and iminostilbene in batch and continuous processes

Accurate kinetic models for reaction systems allow for improved process understanding and greater quality control, which is particularly beneficial as the pharmaceutical industry shifts from batch to continuous manufacturing (CM). In this work, a first principles kinetic model has been developed for the synthesis of carbamazepine (CBZ) from iminostilbene and urea, starting in a batch reactor and subsequently in a continuous flow reactor. An eco-friendly reaction pathway using urea was selected to avoid the toxic reagents that are typically used for synthesis of CBZ. The kinetic parameters determined from batch reactions were utilized in a MATLAB based kinetic model to simulate the yield for the continuous process. Overall, good agreement between the model prediction and corresponding experimental values was observed for the batch and continuous reaction systems within the full factorial design space. However, the model slightly overpredicted the yield of the continuous reaction system for higher conversion values (>60%) since it did not account for the reverse reaction that can occur at the studied reaction conditions. Here, the use of broken order kinetics was compared with whole number orders, and it was determined that the whole number orders resulted in better agreement at all conversion values for the continuous system.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

A resonant electro-physical transmutation method for water purification

We present an electro-transmutation (ET) method of water purification using the Quantum Kinetic Fusor™. Electrolysis experiments were performed with residential well water and seawater coupled with two different electrode materials—stainless steel and aluminum—to test the effectiveness of ET in removing contaminants and altering the physiochemistry (e.g., pH, alkalinity) and isotopic composition of water. ET effectively removed contaminants at power inputs as low 0.142 mA cm –2 , i.e., 1.9–4.2 watts, which is substantially lower than other electrochemical techniques. The ET process also reduces, and in some cases eliminates, electrode surface area degradation. This outcome is outside the field of traditional Faraday electrolysis, further distinguishing the ET process as potentially more cost-effective than other water purification methods. Importantly, the experiments reveal ET is an exceptionally low input energy generator. This finding is based on the presence of exotic x-rays (Bremsstrahlung) emissions during operation (1–20 KeV).

42 ENGINEERING↗

DOE OSTI2020

Soil Water Content (m3 m-3) from Australia, November 2007 - May 2009

Hourly data processed to monthly. Data collected from Eddy Covariance Flux Tower at near-surface (0-10 cm). Site located at latitude -13.08 deg N, longitude 131.12 deg E. Data was downloaded from the FluxNet soil moisture data network and is publicly available. Data from this site located at, referenced as Australia (3) in Table 1 and Figure 4 of Solander et al., 2020, The pan-tropical soil moisture response to El Nino, Hydrol. Earth Syst. Sci., in press.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2020

Soil Water Content (m3 m-3) from Australia, August 2001 - December 2014

Hourly data processed to monthly. Data collected from Eddy Covariance Flux Tower at near-surface (0-10 cm). Site located at latitude -12.49 deg N, longitude 131.15 deg E. Data was downloaded from the FluxNet soil moisture data network and is publicly available. Data from this site is referenced as Australia (4) in Table 1 and Figure 4 of Solander et al., 2020, The pan-tropical soil moisture response to El Nino, Hydrol. Earth Syst. Sci., in press.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1977

Random and systematic measurement errors in acoustic impedance as determined by the transmission line method

The effect of random and systematic errors associated with the measurement of normal incidence acoustic impedance in a zero-mean-flow environment was investigated by the transmission line method. The influence of random measurement errors in the reflection coefficients and pressure minima positions was investigated by computing fractional standard deviations of the normalized impedance. Both the standard techniques of random process theory and a simplified technique were used. Over a wavelength range of 68 to 10 cm random measurement errors in the reflection coefficients and pressure minima positions could be described adequately by normal probability distributions with standard deviations of 0.001 and 0.0098 cm, respectively. An error propagation technique based on the observed concentration of the probability density functions was found to give essentially the same results but with a computation time of about 1 percent of that required for the standard technique. The results suggest that careful experimental design reduces the effect of random measurement errors to insignificant levels for moderate ranges of test specimen impedance component magnitudes. Most of the observed random scatter can be attributed to lack of control by the mounting arrangement over mechanical boundary conditions of the test sample.

Parrott, T. L.↗

NASA NTRS1977

Charge exchange of metastable 2D oxygen ions with N2 in the thermosphere

The charge exchange of metastable 2D oxygen ions with N2 in the thermosphere is investigated through analysis of N2 (+) measurements and related data obtained by the Atmosphere Explorer-C satellite. The rate coefficient for the charge exchange process is found to be 5 + or - 1.7 times 10 to the negative 10th power cu cm per sec. A rate coefficient is also developed for atomic oxygen quenching of the metastable 2D oxygen ions.

Torr, D. G.↗

NASA NTRS1979

Geologic interpretation from composited radar and Landsat imagery

Dual polarization L-band (lambda = 25 cm) radar imagery and Landsat multispectral scanner (MSS) data from central Death Valley have been computer processed and combined digitally in order to utilize the complementary information contained in multisensor data sets. Physically, like-polarized radar data gives roughness information on a scale proportional to radar wavelength. Cross-polarized data adds information on the overall roughness, particle shape, and packing density. Visible and near IR reflectivities pertain to surface chemistry. Surficial geologic units in Death Valley are defined on the basis of compositional and textural differences: optical and microwave scattering properties encoded in the multisensor image are sufficient to discriminate most of the units. This synergistic effect is most pronounced for the alluvial fans. Using radar scattering data and measured sun angle, passively-sensed (passive microwave, visible, near IR) images can be corrected for shadowing effects.

Daily, M. I.↗

NASA NTRS1982

Large area low-cost space solar cell development

A development program to produce large-area (5.9 x 5.9 cm) space quality silicon solar cells with a cost goal of 30 $/watt is descibed. Five cell types under investigation include wraparound dielectric, mechanical wraparound and conventional contact configurations with combinations of 2 or 10 ohm-cm resistivity, back surface reflectors and/or fields, and diffused or ion implanted junctions. A single step process to cut cell and cover-glass simultaneously is being developed. A description of cell developments by Applied Solar Energy Corp., Spectrolab and Spire is included. Results are given for cell and array tests, performed by Lockheed, TRW and NASA. Future large solar arrays that might use cells of this type are discussed.

Baraona, C. R.↗

NASA NTRS1988

Benchmarking and performance analysis of the CM-2

A suite of benchmarking routines testing communication, basic arithmetic operations, and selected kernel algorithms written in LISP and PARIS was developed for the CM-2. Experiment runs are automated via a software framework that sequences individual tests, allowing for unattended overnight operation. Multiple measurements are made and treated statistically to generate well-characterized results from the noisy values given by cm:time. The results obtained provide a comparison with similar, but less extensive, testing done on a CM-1. Tests were chosen to aid the algorithmist in constructing fast, efficient, and correct code on the CM-2, as well as gain insight into what performance criteria are needed when evaluating parallel processing machines.

Myers, David W.↗

NASA NTRS1987

An optical processor for object recognition and tracking

The design and development of a miniaturized optical processor that performs real time image correlation are described. The optical correlator utilizes the Vander Lugt matched spatial filter technique. The correlation output, a focused beam of light, is imaged onto a CMOS photodetector array. In addition to performing target recognition, the device also tracks the target. The hardware, composed of optical and electro-optical components, occupies only 590 cu cm of volume. A complete correlator system would also include an input imaging lens. This optical processing system is compact, rugged, requires only 3.5 watts of operating power, and weighs less than 3 kg. It represents a major achievement in miniaturizing optical processors. When considered as a special-purpose processing unit, it is an attractive alternative to conventional digital image recognition processing. It is conceivable that the combined technology of both optical and ditital processing could result in a very advanced robot vision system.

Sloan, J.↗

NASA NTRS2009

Ceramics for Molten Materials Containment, Transfer and Handling on the Lunar Surface

As part of a project on Molten Materials Transfer and Handling on the Lunar Surface, molten materials containment samples of various ceramics were tested to determine their performance in contact with a melt of lunar regolith simulant. The test temperature was 1600 C with contact times ranging from 0 to 12 hours. Regolith simulant was pressed into cylinders with the approximate dimensions of 1.25 dia x 1.25cm height and then melted on ceramic substrates. The regolith-ceramic interface was examined after processing to determine the melt/ceramic interaction. It was found that the molten regolith wetted all oxide ceramics tested extremely well which resulted in chemical reaction between the materials in each case. Alumina substrates were identified which withstood contact at the operating temperature of a molten regolith electrolysis cell (1600 C) for eight hours with little interaction or deformation. This represents an improvement over alumina grades currently in use and will provide a lifetime adequate for electrolysis experiments lasting 24 hours or more. Two types of non-oxide ceramics were also tested. It was found that they interacted to a limited degree with the melt resulting in little corrosion. These ceramics, Sic and BN, were not wetted as well as the oxides by the melt, and so remain possible materials for molten regolith handling. Tests wing longer holding periods and larger volumes of regolith are necessary to determine the ultimate performance of the tested ceramics.

Standish, Evan↗

NASA NTRS2018

Orion Ground Test Article Water Impact Tests: Photogrammetric Evaluation of Impact Conditions

The Ground Test Article (GTA) is an early production version of the Orion Crew Module (CM). The structural design of the Orion CM is being developed based on LS-DYNA water landing simulations. As part of the process of confirming the accuracy of LS-DYNA water landing simulations, the GTA water impact test series was conducted at NASA Langley Research Center (LaRC) to gather data for comparison with simulations. The simulation of the GTA water impact tests requires the accurate determination of the impact conditions. To accomplish this, the GTA was outfitted with an array of photogrammetry targets. The photogrammetry system utilizes images from two cameras with a specialized tracking software to determine time histories for the 3-D coordinates of each target. The impact conditions can then be determined from the target location data.

Vassilakos, Gregory J.↗

NASA NTRS2018

MODIS Collection 6 MAIAC Algorithm

This paper describes the latest version of the algorithm MAIAC (Multi-Angle Implementation of Atmospheric Correction) used for processing the MODIS (Moderate-resolution Imaging Spectroradiometer) Collection6 data record. Since initial publication in 2011-2012, MAIAC has changed considerably to adapt to global processing and improve cloud/snow detection, aerosol retrievals and atmospheric correction of MODIS data. The main changes include (1) transition from a 25 to 1 km scale for retrieval of the spectral regression coefficient (SRC) which helped to remove occasional blockiness at 25 km scale in the aerosol optical depth (AOD) and in the surface reflectance, (2) continuous improvements of cloud detection, (3) introduction of smoke and dust tests to discriminate absorbing fine- and coarse mode aerosols, (4) adding over-water processing, (5) general optimization of the LUT (LookUp-Table)-based radiative transfer for the global processing, and others. MAIAC provides an interdisciplinary suite of atmospheric and land products, including cloud mask (CM), column water vapor (CWV), AOD at 0.47 and 0.55 m, aerosol type (background, smoke or dust) and fine-mode fraction over water; spectral bidirectional reflectance factors (BRF), parameters of Ross-thick Lisparse (RTLS) bidirectional reflectance distribution function (BRDF) model and instantaneous albedo. For snow-covered surfaces, we provide subpixel snow fraction and snow grain size. All products come in standard HDF4 (software library) format at 1 km resolution, except for BRF, which is also provided at 500 m resolution on a sinusoidal grid adopted by the MODIS Land team. All products are provided on per-observation basis in daily files except for the BRDF/Albedo product, which is reported every 8 days. Because MAIAC uses a time series approach, BRDF/Albedo is naturally gap-filled over land where missing values are filled-in with results from the previous retrieval. While the BRDF model is reported for MODIS Land bands 1-7 and ocean band 8, BRF is reported for both land and ocean bands 1-12. This paper focuses on MAIAC cloud detection, aerosol retrievals and atmospheric correction and describes MCD19 data products and quality assurance (QA) flags.

MAIAC Algorithm↗

NASA NTRS2022

Reevaluating How Charged Particles Cause Space Weathering on Airless Bodies

Many experiments have attempted to simulate how charged particles cause space weathering on airless bodies throughout the Solar System. Researchers have typically applied these experimental results by assuming that high laboratory fluxes cause the same effects as do the significantly lower fluxes found in nature. New work, however, shows that this assumption may often be invalid. In particular, experiments using charged particle fluences cm−2 without adequate steps to neutralize the targets risk causing dielectric breakdown, or “sparking”—a process that may affect some airless bodies. Consequently, it is critical to understand the laboratory conditions under which breakdown occurs, both to ensure that experiments properly simulate the effects of charged particles and to study the possibility that dielectric breakdown can, in some locations, contribute to space weathering.

A P Jordan↗

NASA NTRS1975

Effects of processing on the carrier lifetime in silicon solar cells

Measurements were taken to determine the effects that solar cell processing steps have on the minority carrier lifetime in silicon. The experimental work included measurements of diffusion lengths of the silicon at various stages of cell fabrication, of solar cell properties, and of the PN junction properties for ingots covering a wide range of doping and other ingot properties. Resistivities covered the range of 0.01 to 10 ohm-cm, and combinations of extreme concentrations (high and low) of dislocations and oxygen were included. The results showed that the major cell process steps did not usually cause any appreciable change in diffusion lengths. The solar cell currents obtained supported the diffusion length measurements. The effects of heavy doping concentrations on solar cell performance were studied. Attempts were made to relate the voltage behavior of the cells with the diode properties and the properties of the ingots.

Iles, P. A.↗

DOE OSTI2025

Revolutionizing Methane Transformation with the Dual Production of Aromatics and Electricity in a Protonic Ceramic Electrocatalytic Membrane Reactor

Reducing the energy and carbon intensity of the conventional chemical processing industry can be achieved by electrochemically transforming natural gases into higher-value chemicals with higher efficiency and near-zero emissions. In this work, the direct conversion of methane to aromatics and electricity has been achieved in a protonic ceramic electrocatalytic membrane reactor through the integration of a proton-conducting membrane assembly and a trimetallic Pt–Cu/Mo/ZSM-5 catalyst for the nonoxidative methane dehydro-aromatization reaction. In this integrated system, a remarkable 15.6% single-pass methane conversion with an 11.4% benzene yield has been demonstrated, while a peak power density of 276 mW cm –2 is obtained at 700 °C. The enhanced 15.7% increase in conversion and 16.0% improvement in the yield are observed when compared with the thermochemical process, which is attributed to the shift of reaction equilibrium by the removal of hydrogen through the protonic membrane. Concurrently, the faster H2 removal at a higher electrical current gave rise to a higher methane conversion and benzene yield. Furthermore, the catalyst can be efficiently regenerated by eliminating carbon deposition. A stable cell potential is maintained for 45 h under a constant current load of 0.13 A cm –2 . Lastly, the dual production of aromatics and electricity in the electrocatalytic membrane reactor has been demonstrated to be an attractive approach for decarbonizing chemical processing.

aromatic compounds↗

NASA NTRS1976

Experimental investigation of the excess charge and time constant of minority carriers in the thin diffused layer of 0.1 ohm-cm silicon solar cells

An experimental method is presented that can be used to interpret the relative roles of bandgap narrowing and recombination processes in the diffused layer. This method involves measuring the device time constant by open-circuit voltage decay and the base region diffusion length by X-ray excitation. A unique illuminated diode method is used to obtain the diode saturation current. These data are interpreted using a simple model to determine individually the minority carrier lifetime and the excess charge. These parameters are then used to infer the relative importance of bandgap narrowing and recombination processes in the diffused layer.

Godlewski, M. P.↗

NASA NTRS1993

Thermally altered palagonitic tephra - A spectral and process analog to the soil and dust of Mars

Six palagonitic soil samples (PH-1 through PH-6) which were collected at 30-cm intervals from a lava slab on Mauna Kea, Hawaii, are studied. The samples present an alteration sequence caused by heating during emplacement of molten lava over a preexisting tephra cone. Techniques employed include visible and near-IUR spectroscopy, Moessbauer spectroscopy, and magnetic analysis. The four samples closest to the slab (PH-1 through PH-4) were strongly altered in response to heating during its emplacement; their iron oxide mineralogy is dominated by nanophase ferric oxide. The sample adjacent to the slab (PH-1) has a factor of 3 less H2O and contains crystalline hematite and magnetite in addition to nanophase ferric oxide. It is argued that localized thermal alteration events may provide a volumetrically important mechanism for the palagonitization of basaltic glass and the production of crystalline ferric oxides on Mars.

Bell, James F., III↗