Improvement of the Database on the 1.13-microns Band of Water Vapor
Corrections have recently been reported (Giver et al.) on the short-wave (visible and near-infrared) line intensities of water vapor that were catalogued in the spectroscopic database known as HITRAN. These updates have been posted on www.hitran.com, and are being used to reanalyze the polar stratospheric absorption in the 0.94 microns band as observed in POAM. We are currently investigating additional improvement in the 1.13 microns band using data obtained by us with an absorption path length of 1.107 km and 4 torr of water vapor and the ab initio line list of Partridge and Schwenke (needs ref). We are proposing the following four types of improvement of the HITRAN database in this region: 1) HITRAN has nearly 200 lines in this region without proper assignments of rotational quantum levels. Nearly all of them can now be assigned. 2) We have measured positions of the observable H2O-17 and H2O-18 lines. These lines in HITRAN currently have approximate positions based upon rather aged computations. 3) Some additional lines are observed and assigned which should be included in the database. 4) Corrections are necessary for the lower state energies E" for the HITRAN lines of the 121-010 "hot" band.