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NASA NTRS2015

On Possible Arc Inception on Low Voltage Solar Array

Recent analysis of spacecraft failures during the period of 1990-2013 demonstrated clearly that electrostatic discharges caused more than 8 percent of all registered failures and anomalies, and comprised the most costly losses (25 percent) for operating companies and agencies. The electrostatic discharges on spacecraft surfaces are the results of differential charging above some critical (threshold) voltages. The mechanisms of differential charging are well known, and various methods have been developed to prevent a generation of significant electric fields in areas of triple junctions. For example, low bus voltages in Low Earth Orbit plasma environment and slightly conducting layer over cover-glass (ITO) in Geosynchronous Orbit surroundings are believed to be quite reliable measures to prevent discharges on respective surfaces. In most cases, the vulnerable elements of spacecraft (solar arrays, diode boards, etc.) go through comprehensive ground tests in vacuum chambers. However, tests articles contain the miniscule fragments of spacecraft components such as 10-30 solar cells of many thousands deployed on spacecraft in orbit. This is one reason why manufacturing defects may not be revealed in ground tests but expose themselves in arcing on array surface in space. The other reason for ineffectiveness of discharge preventive measures is aging of all materials in harsh orbital environments. The expected life time of modern spacecraft varies within the range of five-fifteen years, and thermal cycling, radiation damages, and mechanical stresses can result in surface erosion on conductive layers and microscopic cracks in cover-glass sheets and adhesive films. These possible damages may cause significant increases in local electric field strengths and subsequent discharges. The primary discharges may or may not be detrimental to spacecraft operation, but they can produce the necessary conditions for sustained arcs initiation. Multiple measures were developed to prevent sustained discharges between adjacent strings, and many ground tests were performed to determine threshold parameters (voltage and current) for sustained arcs. And again, manufacturing defects and aging in space environments may result in considerable decrease of critical threshold parameters. This paper is devoted to the analysis of possible reasons behind arcing on spacecraft with low bus voltages.

low voltage solar array↗

NASA NTRS1995

The stellar content of 30 doradus derived from spatially integrated ultraviolet spectra: A test of spectral synthesis models

Using the IUE satellite, we have obtained spatially integrated ultraviolet spectra of three areas within the giant H II region 30 Dor in the Large Magellanic Cloud. The spectra correspond to spatial reginswith sizes of 20 sec x 20 sec, 1 min x 1 min, and 3 min x 3 min, all of which are approximately centered on R136. We have performed a spectral synthesis analysis of the spectra of the two larger regions and compared the results with the known stellar content in these regions. The spectral synthesis models are sensitive to the ultraviolet continuum level, the P Cygni profile of the C Iv wavelength 1550 line, the absorption strength of the Si IV wavelength 1400 line, and the emission strength of the He II wavelength 1640 line. The intrinsic continuum levels and the profiles of these stellar wind lines provide constraints on the age and duration of the starburst episode within a region, as well as on the upper curoff mass of the initial mass function. From our analysis we find that the present-day value of the upper cutoff mass in the 1 min x 1 min and 3 min x 3 min regions has a lower limit of approximately 50 solar mass, a result which is in good agreement with several other recent determinations. The age of the starburst episode must be less than approximately 3 Myr, also in agreement with other estimates. Comparison of the observed total numbers of O and W-R stars with those predicted from the various models favors an instantaneous burst of star formation in the regions. However, the differences between the two burst scenarios we investigated (instantaneous and continuous) are small at such a young age, and distinguishing between the two is difficult. We are now confident that these spectral synthesis models can be used to determine the stellar content of more distant star-forming regions.

Vacca, William D.↗

DOE OSTI2023

Subsurface Characteristics of Metal-Halide Perovskites Polished by an Argon Ion Beam

Focused ion beam (FIB) techniques have been frequently used to section metal-halide perovskites for microstructural investigations. However, the ion beams directly irradiating the sample surface may alter its properties far different from those of pristine, potentially leading to modified deterioration mechanisms under aging stressors. Here, we combine complementary approaches to measure the subsurface characteristics of polished perovskites and identify the chemical species responsible for the measured properties. Analysis of the experimental results in conjunction with Monte Carlo simulations indicates that atomic displacements and local heating occur in the first ≈15 nm of the subsurface of methylammonium lead iodide (MAPbI 3 ) by glancing-angle Ar + beam irradiation (4 kV at 3°). The lead-rich, iodine-deficient surface promotes rapid phase segregation under thermal aging conditions. On the other hand, despite the subsurface modification, our experiments confirm that the rest of the MAPbI 3 bulk retains the material integrity. Our observation supports that polished perovskites could serve in studying the properties of bulk or buried junctions far away from the altered subsurface with care.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2014

Multilayer Pressure Vessel Materials Testing and Analysis

To provide NASA a comprehensive suite of materials strength, fracture toughness and crack growth rate test results for use in remaining life calculations for aging multilayer pressure vessels, Southwest Research Institute (R) (SwRI) was contracted in two phases to obtain relevant material property data from a representative vessel. This report describes Phase 1 of this effort which includes a preliminary material property assessment as well as a fractographic, fracture mechanics and fatigue crack growth analyses of an induced flaw in the outer shell of a representative multilayer vessel that was subjected to cyclic pressure test. SwRI performed this Phase 1 effort under contract to the Digital Wave Corporation in support of their contract to Jacobs ATOM for the NASA Ames Research Center.

Cardinal, Joseph W.↗

NASA NTRS2000

Fractal correlation properties of R-R interval dynamics and mortality in patients with depressed left ventricular function after an acute myocardial infarction

BACKGROUND: Preliminary data suggest that the analysis of R-R interval variability by fractal analysis methods may provide clinically useful information on patients with heart failure. The purpose of this study was to compare the prognostic power of new fractal and traditional measures of R-R interval variability as predictors of death after acute myocardial infarction. METHODS AND RESULTS: Time and frequency domain heart rate (HR) variability measures, along with short- and long-term correlation (fractal) properties of R-R intervals (exponents alpha(1) and alpha(2)) and power-law scaling of the power spectra (exponent beta), were assessed from 24-hour Holter recordings in 446 survivors of acute myocardial infarction with a depressed left ventricular function (ejection fraction </=35%). During a mean+/-SD follow-up period of 685+/-360 days, 114 patients died (25.6%), with 75 deaths classified as arrhythmic (17.0%) and 28 as nonarrhythmic (6.3%) cardiac deaths. Several traditional and fractal measures of R-R interval variability were significant univariate predictors of all-cause mortality. Reduced short-term scaling exponent alpha(1) was the most powerful R-R interval variability measure as a predictor of all-cause mortality (alpha(1) <0.75, relative risk 3.0, 95% confidence interval 2.5 to 4.2, P<0.001). It remained an independent predictor of death (P<0.001) after adjustment for other postinfarction risk markers, such as age, ejection fraction, NYHA class, and medication. Reduced alpha(1) predicted both arrhythmic death (P<0.001) and nonarrhythmic cardiac death (P<0.001). CONCLUSIONS: Analysis of the fractal characteristics of short-term R-R interval dynamics yields more powerful prognostic information than the traditional measures of HR variability among patients with depressed left ventricular function after an acute myocardial infarction.

Non-NASA Center↗

NASA NTRSDate not supplied

Nanopore Sequencing in Space: The Advancement of In Situ Microbiome Analysis for the International Space Station and Beyond

Introduction: Routine assessment of the International Space Station (ISS) microbiome has been performed through in-flight culture and Earth-based analysis. Through utilization of the ISS, significant progress toward in situ microbial identification has been achieved. In 2016, the molecular space age began when DNA-based, Earth-prepared samples were amplified within miniPCR (Genes in Space-1), and subsequent samples were sequenced with the MinION (Biomolecule Sequencer). The following year, these platforms were used collectively to yield the first off-Earth identification of unknown bacteria collected and cultured onboard the ISS (Genes in Space-3). Further advancement occurred in 2018 when a culture-independent, direct swab-to-sequencer method revealed a more thorough depiction of the ISS surface microbiome (BEST). As NASA looks towards Artemis and extended exploration missions, it is critical to continue to harness the ISS to expand in situ nanopore sequencing-based analysis in support of microbial-related crew health, planetary protection, and space research initiatives.

Christian G. Mena↗

DOE OSTI2021

The influence of electrochemical cycling protocols on capacity loss in nickel-rich lithium-ion batteries

The transition towards electric vehicles and more sustainable transportation is dependent on lithium-ion battery (LIB) performance. Ni-rich layered transition metal oxides, such as NMC811 (LiNi 0.8 Mn 0.1 Co 0.1 O 2 ), are promising cathode candidates for LIBs due to their higher specific capacity and lower cost compared with lower Ni content materials. However, complex degradation mechanisms inhibit their use. In this work, tailored aging protocols are employed to decouple the effect of electrochemical stimuli on the degradation mechanisms in graphite/NMC811 full cells. Using these protocols, impedance measurements, and differential voltage analysis, the primary drivers for capacity fade and impedance rise are shown to be large state of charge changes combined with high upper cut-off voltage. Focused ion beam-scanning electron microscopy highlights that extensive microscale NMC particle cracking, caused by electrode manufacturing and calendering, is present prior to aging and not immediately detrimental to the gravimetric capacity and impedance. Scanning transmission electron microscopy electron energy loss spectroscopy reveals a correlation between impedance rise and the level of transition metal reduction at the surfaces of aged NMC811. The present study provides insight into the leading causes for LIB performance fading, and highlights the defining role played by the evolving properties of the cathode particle surface layer.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1974

Bone mineral content in normal US whites

Photon absorptiometry with I-125 was used to measure the bone mineral content and the bone width on 763 children between the ages of 5 and 19 years, on 538 adults between the ages of 20 and 49 years, and on 550 adults over the age of 50 years. Measurements were made on the midshaft and the distal end of the radius and the ulna, and on the humerus midshaft. This has permitted analysis of annual bone growth in children, and the rate of change in elderly adults per decade. Male and female children grew at about the same rate until adolescence. After adolescence females grew at a slow rate until the mid-twenties, while males reached adult mineralization by age 20. Males remained relatively constant until the fifties, and females began their decline in the forties.

Mazess, R. B.↗

DOE OSTI2021

Cloud condensation nuclei characteristics at the Southern Great Plains site: role of particle size distribution and aerosol hygroscopicity

The activation ability of aerosols as cloud condensation nuclei (CCN) is crucial in climate and hydrological cycle studies, but their properties are not well known. We investigated the long-term measurements of atmospheric aerosol properties, CCN concentrations (N CCN ) at supersaturation (SS = 0.1%–1.0%), and hygroscopicity at the Department of Energy's Southern Great Plains (SGP) site to illustrate the dependence of N CCN on aerosol properties and transport pathways. Cluster analysis was applied to the back trajectories of air masses to investigate their respective source regions. The results showed that aged biomass burning aerosols from Central America were characterized by higher accumulation mode particles (N accu ; median value 805 cm -3 ) and relatively high aerosol hygroscopicity (κ; median value ~0.25) values that result in the higher CCN activation and relatively high N CCN (median value 258–1578 cm -3 at a SS of 0.1%–1.0%). Aerosols from the Gulf of Mexico were characterized by higher N accu (~35%), and N CCN (230–1721 cm -3 at a SS of 0.1%–1.0%) with the lowest κ (~0.17). In contrast, relatively high nucleation mode particles (N nucl ; ~20%) and low N CCN (128–1553 cm -3 at a SS of 0.1%–1.0%) with higher κ (~0.30) values were observed on the aerosols associated with a westerly wind. The results indicate particle size as the most critical factor influencing the ability of aerosols to activate, whereas the effect of chemical composition was secondary. Our CCN closure analysis suggests that chemical composition and mixing state information are more crucial at lower SS, whereas at higher SS, most particles become activated regardless of their chemical composition and size. This study affirms that soluble organic fraction information is required at higher SS for better N CCN prediction, but both the soluble organics fraction and mixing state are vital to reduce the N CCN prediction uncertainty at lower SS.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS2004

Design and Analysis of FKSI Nulling Interferometry Testbed

The Fourier Kelvin Stellar Interferometer is a space borne mission whose purpose is to validate the existence of previously detected Extra Solar Giant Planets (EGP's) and determine the age and primary atmospheric constituents of these EGP's. It consists of 2 collecting telescopes followed by a Mach Zehnder interferometer working in a wavelength range of 3-8 microns. To support this concept, a testbed is being built at NASA Goddard Space Flight Center to demonstrate feasibility of achieving the required nulling ratio (10e-4) across the waveband. This paper describes the design and performance analysis of the testbed. Considerations such as polarization, pupil overlap, and optical path length control are discussed.

Wilson, Mark↗

NASA NTRS2011

A Data Mining Project to Identify Cardiovascular Related Factors That May Contribute to Changes in Visual Acuity Within the US Astronaut Corps

Many of the cardiovascular-related adaptations that occur in the microgravity environment are due, in part, to a well-characterized cephalad-fluid shift that is evidenced by facial edema and decreased lower limb circumference. It is believed that most of these alterations occur as a compensatory response necessary to maintain a "normal" blood pressure and cardiac output while in space. However, data from both flight and analog research suggest that in some instances these microgravity-induced alterations may contribute to cardiovascular-related pathologies. Most concerning is the potential relation between the vision disturbances experienced by some long duration crewmembers and changes in cerebral blood flow and intra-ocular pressure. The purpose of this project was to identify cardiovascular measures that may potentially distinguish individuals at risk for visual disturbances after long duration space flight. Toward this goal, we constructed a dataset from Medical Operation tilt/stand test evaluations pre- (days L-15-L-5) and immediate post-flight (day R+0) on 20 (3 females, 17 males). We restricted our evaluation to only crewmembers who participated in both shuttle and space station missions. Data analysis was performed using both descriptive and analytical methods (Stata 11.2, College Station, TX) and are presented as means +/- 95% CI. Crewmembers averaged 5207 (3447 - 8934) flight hours across both long (MIR-23 through Expedition16) and short (STS-27 through STS-101) duration missions between 1988 and 2008. The mean age of the crew at the time of their most recent shuttle flight was 41 (34-44) compared to 47 (40-54) years during their time on station. In order to focus our analysis (we did not have codes to separate out subjects by symptomotology) , we performed a visual inspection of each cardiovascular measures captured during testing and plotted them against stand time, pre- to post-flight, and between mission duration. It was found that pulse pressure most clearly differentiated the two mission types. Statistical analysis confirmed that pulse pressure was significantly higher before [45.6; (42.1 to 49.1)] and after [50.7; (46.9 to 54.6)] time on station compared with their most recent shuttle flight [31.6 (27.8 to 35.4), and 32.2 (28.3 to 36.0) respectively] even after correcting differences in age and cumulative number of mission hours. Without knowing the identity of which long duration crewmembers demonstrated visual changes, we were limited to examining whether certain crew regulate components of pulse pressure, systolic and diastolic blood pressure, differently due to microgravity exposure. To that end, we stratified crew into tertiles based on either their pre-flight measure of systolic or diastolic blood pressure. Those crew in the highest tertile for both systolic (lower tertile (n=8; 103-111), middle tertile (n=7; 113-121), and upper tertile (n=5; 125-136) and diastolic blood pressure (lower tertile (n=8; 58-64), middle tertile (n=7; 67-73), and upper tertile (n=5; 75-81) demonstrated less variability in pulse pressure between R+0 and L-10 (Figure 2). Interestingly, those crewmembers with the highest resting systolic blood pressure demonstrated either no change or in some instances an increase in total peripheral resistance, where those in the lower tertiles had lower values of total peripheral resistance compared to pre-flight levels. In this study, it was found that crewmembers in the highest tertile for both systolic and diastolic blood pressure demonstrated less variability in pulse pressure and that the decrease in variability was due in part to lower levels of compliance as indicated by similar or higher levels of total peripheral resistance after compared with before flight levels. Whether there is a relation between blood pressure regulation and total peripheral resistance in crew presenting with negative changes in visual acuity remains unknown.

Westby, Christian M.↗

DOE OSTI2021

Thermal stability of filler‐based ethylene/vinyl acetate/vinyl alcohol terpolymer in nitroplasticizer oxidative environment

Abstract To study the thermal stability of ethylene/vinyl acetate/vinyl alcohol (EVA‐OH) composite with filler particles, systematic thermogravimetric analysis (TGA) investigation was conducted in both nonisothermal and isothermal modes. The effect of polymer concentration on the aging behavior of EVA‐OH was investigated in the nitroplasticizer (NP) environment. Fourier transform infrared spectroscopy was used to probe chemical structural changes in the EVA‐OH polymer before and after thermal aging. The results suggest that filler addition accelerates the rate of NP exudation out of the EVA‐OH composites and deteriorates the thermal stability of NP at moderate temperatures (up to 70°C). The degradation of NP, in turn, accelerates the degradation of EVA‐OH polymer in its composite form through oxidation and hydrolysis indicating the importance of antioxidants in such phase blends.

36 MATERIALS SCIENCE↗

DOE OSTI2021

Time-temperature-superposition analysis of diverse datasets by the minimum-arclength method: long-term prediction with uncertainty margins

In a recent publication, we carried out an extensive analysis of an unsupervised method of determining optimum shift factors in time-temperature-superposition of accelerated-aging data that involves minimizing the vertical arclength to obtain the master curve. For synthetic Arrhenius data with a variety of noise distributions, the work showed that, in conjunction with bootstrap-resampling, the method can produce reliable estimates of the mean activation energy along with uncertainty quantification. Here, we apply the above method to six different datasets taken from the published literature and demonstrate accurate prediction of mean activation energy from the data as-is without the need for any pre-processing or fitting. We also compare uncertainty margins computed by second-order bootstrap with that by linear regression theory and show that the former appears to provide consistent margins in the presence of common noise types in real data, including intra-isotherm measurement-errors, sample-to-sample variations, and intrinsic deviation from perfect Arrhenius behavior.

36 MATERIALS SCIENCE↗

DOE OSTI2022

Oxyanion Surface Complexes Control the Kinetics and Pathway of Ferrihydrite Transformation to Goethite and Hematite

The rate and pathway of ferrihydrite (Fh) transformation at oxic conditions to more stable products is controlled largely by temperature, pH, and the presence of other ions in the system such as nitrate (NO 3 - ), sulfate (SO 4 2- ), and arsenate (AsO 4 3- ). Although the mechanism of Fh transformation and oxyanion complexation have been separately studied, the effect of surface complex type and strength on the rate and pathway remains only partly understood. We have developed a kinetic model that describes the effects of surface complex type and strength on Fh transformation to goethite (Gt) and hematite (Hm). Two sets of oxyanion-adsorbed Fh samples were prepared, nonbuffered and buffered, aged at 70 ± 1.5 °C, and then characterized using synchrotron X-ray scattering methods and wet chemical analysis. Kinetic modeling showed a significant decrease in the rate of Fh transformation for oxyanion surface complexes dominated by strong inner-sphere (SO 4 2- and AsO 4 3- ) versus weak outer-sphere (NO 3 - ) bonding and the control. The results also showed that the Fh transformation pathway is influenced by the type of surface complex such that with increasing strength of bonding, a smaller fraction of Gt forms compared with Hm. In conclusion, these findings are important for understanding and predicting the role of Fh in controlling the transport and fate of metal and metalloid oxyanions in natural and applied systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2023

Pyrolysis of Oils from Unconventional Resources

In this study, oils from various sources were subjected to pyrolysis conditions; that is, without oxidizer, as the samples were heated to 500 °C, and held at that temperature. The oils studied included: (1) heavy oil from Grassy Creek, Missouri; (2) oil from tar sands of Asphalt Ridge in Utah; (3) mid-continent oil shales of three formations (two of Chattanooga formation, Pennsylvanian (age) formation, and Woodford formation); and (4) a Colorado Piceance Basin shale. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) with either gas chromatography (GC) or mass spectrometry (MS) were used to quantify the produced gases evolved in the tests. Purge gases of helium, argon, and humid carbon dioxide were utilized. Larger scale pyrolysis tests were conducted in a tube furnace coupled to a MS and a GC. The results consistently showed that pyrolysis occurred between 300 °C and 500 °C, with the majority of gases being mainly hydrogen and light alkanes. This behavior was essentially consistent, regardless of the oil source.

42 ENGINEERING↗

DOE OSTI2020

The Great Inequality and the Dynamical Disintegration of the Outer Solar System

Using an ensemble of N-body simulations, this paper considers the fate of the outer gas giants (Jupiter, Saturn, Uranus, and Neptune) after the Sun leaves the main sequence and completes its stellar evolution. Due to solar mass loss—which is expected to remove roughly half of the star’s mass—the orbits of the giant planets expand. This adiabatic process maintains the orbital period ratios, but the mutual interactions between planets and the width of mean-motion resonances (MMR) increase, leading to the capture of Jupiter and Saturn into a stable 5:2 resonant configuration. The expanded orbits, coupled with the large-amplitude librations of the critical MMR angle, make the system more susceptible to perturbations from stellar flyby interactions. Accordingly, within about 30 Gyr, stellar encounters perturb the planets onto the chaotic subdomain of the 5:2 resonance, triggering a large-scale instability, which culminates in the ejections of all but one planet over the subsequent ∼10 Gyr. After an additional ∼50 Gyr, a close stellar encounter (with a perihelion distance less than ∼200 au) liberates the final planet. Through this sequence of events, the characteristic timescale over which the solar system will be completely dissolved is roughly 100 Gyr. Our analysis thus indicates that the expected dynamical lifetime of the solar system is much longer than the current age of the universe, but is significantly shorter than previous estimates.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS1970

Neutron ages computed from experimental activation data

Computer program reduces time manually required to compute neutron age and to provide definite plan of procedural choices. Program allows convenient comparison of several fitting and error analysis procedures. Program code provides for error estimation of various integration options.

Semler, T. T.↗

NASA NTRS1978

High Temperature Adhesives for Bonding Kapton

Experimental polyimide resins were developed and evaluated as potential high temperature adhesives for bonding Kapton polyimide film. Lap shear strengths of Kapton/Kapton bonds were obtained as a function of test temperature, adherend thickness, and long term aging at 575K (575 F) in vacuum. Glass transition temperatures of the polyimide/Kapton bondlines were monitored by thermomechanical analysis.

Stclair, A. K.↗