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Superconducting films made in relatively simple process. Thick films of YBa2Cu3O7-x superconductor deposited on highly-polished alumina substrates by screen printing. In addition to simplicity, screen-printing technique offers advantage that patterns for electronic and microwave circuits and devices printed directly, without additional etching steps.
Classical non-topological soliton configurations are considered within the theory of a complex scalar field with a gauged U symmetry. Their existence and stability against dispersion are demonstrated and some of their properties are investigated analytically and numerically. The soliton configuration is such that inside the soliton the local U symmetry is broken, the gauge field becomes massive and for a range of values of the coupling constants the soliton becomes a superconductor pushing the charge to the surface. Furthermore, because of the repulsive Coulomb force, there is a maximum size for these objects, making impossible the existence of Q-matter in bulk form. Also briefly discussed are solitons with fermions in a U gauge theory.
Thin film high temperature superconductors have the potential to change the microwave technology for space communications systems. For such applications it is desirable that the films be formed on substrates such as Al2O3 which have good microwave properties. The use of ZrO2 buffer layers between Y-Ba-Cu-O and the substrate has been investigated. These superconducting films have been formed by multilayer sequential electron beam evaporation of Cu, BaF2 and Y with subsequent annealing. The three layer sequence of Y/BaF2/Cu is repeated four times for a total of twelve layers. Such a multilayer film, approximately 1 micron thick, deposited directly on SrTiO3 and annealed at 900 C for 45 min produces a film with a superconducting onset of 93 K and critical temperature of 85 K. Auger electron spectroscopy in conjunction with argon ion sputtering was used to obtain the distribution of each element as a function of depth for an unannealed film, the annealed film on SrTiO3 and annealed films on ZrO2 buffer layers. The individual layers were apparent. After annealing, the bulk of the film on SrTiO3 is observed to be fairly uniform while films on the substrates with buffer layers are less uniform. The Y-Ba-Cu-O/ZrO2 interface is broad with a long Ba tail into the ZrO2, suggesting interaction between the film and the buffer layer. The underlying ZrO2/Si interface is sharper. The detailed Auger results are presented and compared with samples annealed at different temperatures and durations.
The application of superconductor technology to several key aspects of an advanced-stage Lunar Base is described. Applications in magnetic energy storage, electromagnetic launching, and radiation shielding are discussed.
A magnetometer is described which was constructed to facilitate the study and characterization of the magnetic properties of high transition temperature superconductors. This instrument was used to measure the dc magnetic susceptibility of several superconducting compounds as a function of temperature. The construction of the magnetometer and the operating parameters are discussed in detail.
The current status of NASA R&D programs for space power systems is reviewed and illustrated with drawings and diagrams. Topics addressed include photovoltaic systems, energy-storage technology, solar-dynamic systems, the SP-100 Advanced Technology Program, Stirling engine technology, and thermal management. Consideration is given to power management and distribution, power-system autonomy, high-Tc superconductor technology, space power materials, and environmental interactions.
A new concept for materials processing in space exploits the ultravacuum component of space for thin film epitaxial growth. The unique low earth orbit space environment is expected to yield 10 to the -14th torr or better pressures, semiinfinite pumping speeds, and large ultravacuum volume without walls. These space ultravacuum properties promise major improvement in the quality, unique nature, and the throughput of epitaxially grown materials. Advanced thin film materials to be epitaxially grown in space include semiconductors, magnetic materials, and thin film high temperature superconductors.
This paper reports on the magnetic field dependence of the transport critical current and dc magnetic susceptibility measurements on YBa2Cu3O(7-x) superconductors formed by melt-solid reactions at 950 C between Ba-Cu-O (or Tb-Ba-cu-O) and solid nonstoichiometric Y-Ba-Cu oxide. Four-probe dc critical current measurements at 77, 64, and 4.2 K show strong depression of the critical current density with increasing magnetic field, in agreement with a model of weakly linked superconducting regions. Diamagnetic shielding and Meissner flux expulsion measurements in the temperature range 10-300 K show about one-third volume fraction of perfect superconductivity. Both shielding and flux expulsion were observed to be approximately temperature independent below 60 K, indicating strong coupling between the grains throughout the entire volume below this temperature.
The low-temperature scanning tunneling microscope (STM) system described by LeDuc et al. (1987) was used to observe the phonon density of states effects in a superconductor. Using techniques based on those employed in macroscopic tunneling spectroscopy, electron tunneling current-voltage (I-V) spectra were measured for NbN and Pb, and dI/dV vs V spectra were measured using standard analog derivative techniques. I-V measurements on NbN and Pb samples under typical STM conditions showed no evidence for multiparticle tunneling effects.
EDXS performed on isolated particles of the Bi-Ca-Sr-Cu-O high-temperature ceramic superconductor has verified the presence of significant elemental exchange between the Ca and Sr, and, to a lesser extent, between Cu and Bi. Two primary preparations, identified as primarily 24.4 A and 30.6 A, respectively, are identified. The Cu:Bi ratio in the 30.6 A material is approximately 1:1 for most particles, although only a few particles of the nominally 24.4 A material have the expected 1:2 ratio. No unequivocal assignment of atomic composition to the predominantly 24.4 A or 30.6 A appears possible, if major syntactic problems are present.
It is shown that temperature-dependent ultrasonic attenuation data of YBa2Cu3O7 at various frequencies exhibit anomalies at temperatures close to Tc. These attenuation maxima are found to be the result of a relaxation mechanism added on top of an unusual attenuation background. It is proposed that the grain boundary motions induced by the structural distortion and the propagation of sound waves enhances the energy dissipation around Tc. Whether this structural distortion is the consequence of the onset of a superconducting state remains undetermined. It is also possible that either a tunneling effect or the acoustoelectric effect contributes to sound energy dissipation. The temperature dependence of ultrasonic velocity shows a softening around Tc which may be an intrinsic property of high-temperature superconductors.
Treatment of YBa2Cu3O(7-x) films with a nonaqueous solution of HF in absolute ethanol results in the formation of an oxyfluoride with relative Y:Ba:Cu concentrations of 1:4:3 on the surface, as determined by X-ray photoelectron spectroscopy. The passivation properties of chemically treated films were tested by monitoring the growth of the high binding energy O 1s peak, associated with nonsuperconducting surface species, as a function of air exposure time, for both HF-treated and untreated films. The native oxyfluoride is shown to reduce the reactivity of the superconductor to air.
An effective theory of superconductivity based on a microscopic theory of the T- and P-breaking spin-liquid state is proposed. There are two independent gauge invariances broken by two separate condensates. The theory may be useful for phenomenological calculations. In particular, it is found that the H(c1) are different for magnetic fields with opposite orientations. It is also found that the polarization of an electromagnetic wave is rotated after reflection from these T- and P-breaking superconductors.
In oxide superconductors the local suppression of antiferromagnetic correlations in the vicinity of a hole lowers the energy of the system. This quasi two-dimensional bag of weakened spin order follows the hole in its motion. In addition, holes prefer to share a bag, leading to a strong pairing attraction and a high Tc superconductivity. There are many experimental consequences of this mechanism for both the superconducting and normal phases.
A new concept for materials processing in space exploits the ultravacuum component of space for thin-film epitaxial growth. The unique LEO space environment is expected to yield 10-ftorr or better pressures, semiinfinite pumping speeds, and large ultravacuum volume (about 100 cu m) without walls. These space ultravacuum properties promise major improvement in the quality, unique nature, and throughput of epitaxially grown materials, including semiconductors, magnetic materials, and thin-film high-temperature superconductors.
Bi sub 1.5 SrCaCu sub 2 O sub x has been prepared in the glassy state by rapid quenching of the melt. The kinetics of crystallization of various phases in the glass have been evaluated by a variable heating rate differential scanning calorimetry method. The formation various phases on thermal treatments of the glass has been investigated by powder X-ray diffraction and electrical resistivity measurements. Heating at 450 C formed Bi sub 2 Sr sub 2 CuO sub 6, which disappeared on further heating at 765 C, where Bi sub 2 Sr sub 2 CaCu sub 2 O sub 8 formed. Prolonged heating at 845 C resulted in the formation of a small amount of a phase with T sub c onset of approx. 108 K, believed to be Bi sub 2 Sr sub 2 Ca sub 2 Cu sub 3 O sub 10. This specimen showed zero resistivity at 54 K. The glass ceramic approach could offer several advantages in the fabrication of the high-T sub c superconductors in desired practical shapes such as continuous fibers, wires, tapes, etc.
The automated data acquisition system developed in the Space Science Laboratory at Marshall Space Flight Center for measuring electrical properties of high temperature superconductors is described. The acquisition system, consisting of a computer and computer-controlled hardware, allows large numbers of voltage, current, temperature, and magnetic measurements to be performed on bulk and thin film samples. Typical results are shown characterizing transition temperature (T sub c), critical current density (J sub c), and magnetic properties of bulk high T(sub c) materials as a function of temperature.
The development of open resonator mixer structures and laser local oscillators has made heterodyne spectroscopy at far infrared (FIR) wavelengths between 150 and 400 microns a reality. Several laser based receivers are now part of the instrument complement flown aboard the Kuiper Airborne Observatory. Lasers are eminently practical as FIR local oscillators whenever there is close frequency coincidence between a strong laser transition and the Doppler-shifted astronomical line. While it is desirable to have continuous frequency coverage in a spectrometer, it should be recognized that most astronomers will focus their interest on the few spectral lines deemed optimum for probing the cosmos. Ultimately, the development of a reliable thin film technology for the new high temperature oxide superconductors may favor SIS-type devices for all wavelengths in future space based FIR receivers.