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At least 613 records · Page 34
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

Laboratory absorption strengths and line shape parameters in the 4-0, 5-0, and 6-0 vibration bands of HD

Experimental values for the visible vibration-dipole bands of HD are improved through a study of weak, unsaturated absorption lines of HD against a well-defined white light continuum at low gas densities between 0.3 and 1.7 amagats. Spectral resolution was high enough to allow recovery of line profiles with only minor corrections for instrumental effects, so line strengths and shapes are determined directly without recourse to theoretical assumptions regarding the curve of growth, and the unusual phenomenon of collision narrowing in HD is directly observed in the line shape for the first time. Accurate line strengths are reported, the behavior of spectral profiles as a function of gas density is discussed, and the pressure shift coefficients are determined. These are compared with previous laboratory work done either at lower spectral resolving power or at higher gas densities.

Trauger, J. T.↗
NASA NTRS1983

Strength of mineral absorption features in the transmitted component of near-infrared reflected light - First results from RELAB

Bidirectional reflectance measurements are the only type of reflectance data available to the remote observer. For compositional interpretations, data are desired not only for identification of possible mineral components but also for modal abundance. The latter requires detailed information about the strength of absorption features. Using a new laboratory facility, the RELAB, laboratory data in the near infrared are presented that document effects of particle size, mineral mixtures, and viewing geometry for selected materials with well-developed absorption bands. The commonly observed increase in reflectance with decrease in particle size is also observed for absorption bands as well as a related decrease in absorption strength. For small particles in parts of the spectrum of maximum reflectance, however, a minor decrease in reflectance with a decrese in particle size is sometimes observed. Small particles dominate the observed characteristics of particulate surfaces, which contain a range of particle sizes. The mean optical path length (transmission through particles) of reflected radiation measured for a variety of particle sizes has an apparent upper limit of about 2 mm for particles of less than 250 microns. The typical number of particles involved in the optical path is less than 50.

Pieters, C. M.↗
NASA NTRS1984

Interstellar O2. II - VUV oscillator strengths of Schumann-Runge lines and prospects for Space Telescope observations

Interstellar molecular oxygen should be detectable in interstellar clouds through observation of its absorption lines in the spectra of background stars. This paper describes and presents the results of measurements of oscillator strengths for some lines in the vacuum ultraviolet (VUV) spectrum of O2. Lines of the (13, 0) through (16, 0) bands of the B 3Sigma(-)u - X 3Sigma(-)g, Schumann-Runge system between 1760 A and 1790 A will be the most suitable for searches for absorption by interstellar O2 with the High Resolution Spectrograph on Space Telescope. The strongest lines in these bands have oscillator strengths of about 3 x 10 to the -5th.

Smith, P. L.↗
NASA NTRS1983

Factors influencing the thermally-induced strength degradation of B/Al composites

Literature data related to the thermally-induced strength degradation of B/Al composites were examined in the light of fracture theories based on reaction-controlled fiber weakening. Under the assumption of a parabolic time-dependent growth for the interfacial reaction product, a Griffith-type fracture model was found to yield simple equations whose predictions were in good agreement with data for boron fiber average strength and for B/Al axial fracture strain. The only variables in these equations were the time and temperature of the thermal exposure and an empirical factor related to fiber surface smoothness prior to composite consolidation. Such variables as fiber diameter and aluminum alloy composition were found to have little influence. The basic and practical implications of the fracture model equations are discussed. Previously announced in STAR as N82-24297

Dicarlo, J. A.↗
NASA NTRS1984

Sinterability, strength and oxidation of alpha silicon carbide powders

An investigation is made of pressureless sintering of commercially available alpha-SiC powders at temperatures between 1900 and 2150 C for periods of 10 to 240 min under one atmosphere of argon pressure. It is found that alpha-SiC powder containing boron and carbon sintering aids is sinterable at 2150 C for a period of 30 min to a high final density (greater than 96 percent of theoretical). In alpha-SiC powder containing aluminum and carbon sintering aids, the final density achieved is only about 80 percent of theoretical. Determinations are made of room temperature and high temperature (1370 C) flexure strength and oxidation resistance on sintered high density (more than 96 percent of theoretical) alpha-SiC (boron, carbon) material. It is found that both the strength and the resistance to oxidation are equivalent and comparable to those of the sintered alpha-SiC which represents the state of the art.

Dutta, S.↗
NASA NTRS1984

Line strengths of N2O in the 1120-1440/cm region

Line strengths of N2O and its isotopic derivatives in the 1120-1440/cm region were measured at low pressure and high resolution (0.0054/cm). The band strength, rotationless dipole moment matrix elements, and F factor coefficients were considered. First-order nondegenerate perturbation theory was employed to derive explicit expressions for the rotationless dipole moment matrix elements and F factor coefficients. This made it possible to obtain general expressions for the F factor. The derived expressions were also applicable to CO2 bands.

Toth, R. A.↗
NASA NTRS1983

Vibration-rotation line strengths of the gas-phase OH radical

Absorption line strengths have been measured at 295 K for the first time for four vibration-rotation transitions of the OH radical, using a tunable, infrared diode-laser in conjunction with a molecular modulation spectrometer. A periodically varying OH concentration was created by photolysis, using a sinusoidally modulated 2537-A Hg lamp, of a flowing mixture of O3 and H2O contained within a quartz-walled White cell. The modulated absorption owing to the OH radical was subsequently observed by phase-sensitive detection. The absolute modulation amplitude of the OH number density was obtained by numerical simulation of the complete time-dependent photochemical system. The strongest transition measured was at 3407.607 kaysers, with a strength of 3.3 + or - 1.5 x 10 to the -20th per(cm molecule) sq cm.

Podolske, J.↗
NASA NTRS1984

Tensile strength of composite sheets with unidirectional stringers and crack-like damage: A brief report

The residual strength of composite sheets with bonded composite stringers loaded in tension was determined. The results are summarized. About 50 graphite/epoxy composite panels with crack-like slots were monotonically loaded in tension to failure. Both sheet layup and stringer configuration were varied. The composite panels have considerable damage tolerance. The stringers arrested cracks that ran from the crack-like slots, and the residual strengths were considerably greater than those of unstiffened composite sheets. A stress-intensity factor analysis was developed to predict the failing strains of the stiffened panels. Using the analysis, a single design curve was produced for composite sheets with bonded stringers of any configuration.

Poe, C. C., Jr.↗
NASA NTRS1984

Effect of Impact Damage and Open Holes on the Compression Strength of Tough Resin/high Strain Fiber Laminates

Tests to assess the performance of composite structures damaged by impact or containing local discontinuities such as cutouts are discussed. In particular, two plate specimen test configurations which were developed to define the serverity of compression strength reduction are described; one for impact damage and the other open hole specimens. The test technique for impact specimens involves damaging the plate at selected energies, measuring the size of damage by ultrasonic C-scan techniques and measuring the residual strength in a compression load test. Open-hole specimen compression tests are conducted for several different hole diameters and the failure strain and load and mode of failure recorded. The plate specimen used in these tests is designed with length, width, thickness and laminate stiffness to ensure that overall plate buckling is not responsible for initiating failure.

Williams, J. G.↗
NASA NTRS1985

The Strength and Characteristics of VPPA Welded 2219-T87 Aluminum Alloy

A study of the variable polarity plasma arc (VPPA) welding process and those factors that control the structure and properties of VPPA welded aluminum alloy 2219-T87 was conducted. The importance of joint preparation, alignment of parts and welding process variables are already established. Internal weld defects have been eliminated. However, a variation of properties was found to be due to the size variation of interdendritic particles in the fusion zone. These particles contribute to the void formation process, which controls the ultimate tensile strength of the welded alloy. A variation of 150 microns in particle size correlated with a 10 ksi variation of ultimate tensile strength. It was found that all fracture surfaces were of the dimple rupture type, with fracture initiating within the fusion zone.

Jemian, W. A.↗
NASA NTRS1984

Mechanism of strength degradation for hot corrosion of alpha-SiC

Sintered alpha SiC was corroded by thin films of Na2SO4 and Na2CO3 molten salts at 1000%. This hot corrosion attack reduced room temperature strengths by as much as 50%. Strength degradation was porportional to the degree and uniformity of corrosion pitting attack as controlled by the chemistry of the molten salt. Extensive fractography identified corrosion pits as the most prevalent source of failure. A fracture mechanics treatment of the strength/pit depth relationship produced an average K sub IC equal to 2.6 MPa sub m 1/2, which is consistent with published values.

Smialek, J. L.↗
NASA NTRS1985

Determination of band oscillator strengths of atmospheric molecules from high resolution vacuum ultraviolet cross section measurements

An account is given of progress during the six month period 1/11/84 to 4/30/85 in work on: (1) rovibronic assignments of the Schumann-Runge bands of O2-18; and (2) optical depth measurements of the Schumann-Runge bands of O2-18. The work summarized above is part of a comprehensive spectroscopic investigation of the absorption wavelengths, rotational line assignments, cross sections, and band oscillator strengths of the Schumann-Runge bands of O2-18 and O-18 O-16 in the wavelength region 175-205 nm. The investigation is conducted at high resolution with a 6.65 m scanning spectrometer/spectrograph which is, by reason of its small instrumental width (FWHM = 0.0013 nm), uniquely suitable for cross section measurements of molecular bands with discrete rotational structure. Absolute cross sections, which are independent of the instrumental function and from which band oscillator strengths are directly determined, will be measured for the absorption bands that are most predissociated.

Parkinson, W. H.↗
NASA NTRS1984

Collision strengths for 1199 and 1729 of S III

Collision strengths are calculated for the S III ground state from electron impact excitation in the Io torus. The study is based on data taken at 119.9 nm and 172.9 nm by the IUE spacecraft and with the rocket-borne Faint Object Telescope. The collision strengths of the 3p(2)3P3s3p(3)(5)S(4) and (3)P-3s3p(3)(3)D(0) UV lines are derived from a three-state close coupling aproximation. A Gailitis averaging scheme accounts for resonance effects in the forbidden transition. The calculated intensities of the two transitions at an electron temperature of 80,000 K are in agreement with observed intensities.

Ho, Y. K.↗
NASA NTRS1984

The depletion of pre-interstellar matter and an examination of Ni II oscillator strengths

IUE absorption-line data obtained at 110-320 nm with resolution 10-30 pm toward the B-star component of the multiple system of Alpha Sco are presented in graphs and tables and used to characterize the circumstellar shell around the M1.5 Iab component. Resonant lines of Ni II are identified at strengths in excess of 4 pm and fit to a growth curve constructed using the Fe II, Si II, and Mn II lines, and the results are found to confirm the oscillator strengths determined by Kurucz and Peytremann (1975) to within 50 percent. Shell depletions 2-20 times smaller than those for dense clouds such as the surrounding Oph complex are calculated and attributed to the formation of circumstellar dust. The implications of the results for the condensation of various elements in dense and diffuse clouds are explored.

Cardelli, J. A.↗
NASA NTRS1985

Line positions and strengths of CO2 in the 1200-1430/cm region

A study is reported in which the vibrational rotation spectrum of CO2 in the 1200-1430/cm region has been studied at a 0.005/cm resolution with a Fourier transform spectrometer. The positions and strengths of lines in the 10001-00001 bands of the species 628, 627, and 638 and the 11101-01101 and 11102-01101 bands of 628 have been measured and analyzed. Based on the results obtained, the band center frequencies, upper and lower state vibrational constants, band strengths, and coefficients in the F factor expression are determined.

Toth, R. A.↗
NASA NTRS1985

The influence of lay-up and thickness on composite impact damage and compression strength

The effects of composite stacking sequence, thickness, and percentage of zero-degree plies on the size, shape, and distribution of delamination through the laminate thickness and on residual compression strength following impact were studied. Graphite/epoxy laminates were impacted with an 0.5 inch diameter aluminum sphere at a specific low or high velocity. Impact damage was measured nondestructively by ultrasonic C-scans and X-radiography and destructively by the deply technique, and compression strength tests were performed. It was found that differences in compression failure strain due to stacking sequence were small, while laminates with very low percentages of zero-degree plies had similar failure loads but higher failure strains than laminates with higher percentages of zero-degree plies. Failure strain did not correlate with planar impact damage area, and delaminations in impact regions were associated with matrix cracking.

Guynn, E. G.↗
NASA NTRS1985

Grain refinement of high strength steels to improve cryogenic toughness

Grain-refining techniques using multistep heat treatments to reduce the grain size of five commercial high-strength steels were investigated. The goal of this investigation was to improve the low-temperature toughness as measured by Charpy V-notch impact test without a significant loss in tensile strength. The grain size of four of five alloys investigated was successfully reduced up to 1/10 of original size or smaller with increases in Charpy impact energy of 50 to 180 percent at -320 F. Tensile properties were reduced from 0 to 25 percent for the various alloys tested. An unexpected but highly beneficial side effect from grain refining was improved machinability.

Rush, H. F.↗
NASA NTRS1985

Notched strength of composite laminates: Predictions and experiments - A review

A self-contained review of several semiempirical fracture models for predicting notched strength of composite laminates is presented, based on notched strength data on 70 different laminate configurations of graphite/epoxy, boron/aluminum, and graphite/polyimide. Emphasis is placed on experimental results concerning such failure factors as delamination, splitting, and size of damage zone. Moreover, the fracture model parameters are correlated with the notch sensitivity of composite laminates, and the applicability of the correlations in describing the material notch sensitivity is evaluated. The predictions provided by the different models were found to be identical for all practical purposes.

Awerbuch, J.↗