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At least 613 records · Page 34

Surface effects of corrosive media on hardness, friction, and wear of materials

Hardness, friction, and wear experiments were conducted with magnesium oxide exposed to various corrosive media and also with elemental iron and nickel exposed to water and NaOH. Chlorides such as MgCl2 and sodium containing films were formed on cleaved magnesium oxide surfaces. The MgCl2 films softened the magnesium oxide surfaces and caused high friction and great deformation. Hardness was strongly influenced by the pH value of the HCl-containing solution. The lower the pH, the lower the microhardness. Neither the pH value of nor the immersion time in NaOH containing, NaCl containing, and HNO3 containing solutions influenced the microhardness of magnesium oxide. NaOH formed a protective and low friction film on iron surfaces. The coefficient of friction and the wear for iron were low at concentrations of NaOH higher than 0.01 N. An increase in NaOH concentration resulted in a decrease in the concentration of ferric oxide on the iron surface. It took less NaOH to form a protective, low friction film on nickel than on iron.

Miyoshi, K.↗

A new method for fabrication of diamond-dust blocking filters

Thermal embedding of diamond dust onto a polyethylene-coated Al plate has been used to make a blocking filter for FIR applications. The Al plate is sandwiched between two Mylar 'blankets' and the air between the layers is removed by means of a small vacuum pump. After the polyethylene is heated and softened, the diamond dust is applied to the polyethylene coating using a brush. The optimum diamond dust grain sizes corresponding to polyethylene layer thicknesses of 9-12 microns are given in a table, and the application of the blocking filter to spectrometric measurements in the FIR is described. An exploded view diagram of the layered structure of the blocking filter is provided.

Collard, H. R.↗

Vibration and buckling of rotating, pretwisted, preconed beams including Coriolis effects

The effects of pretwist, precone, setting angle and Coriolis forces on the vibration and buckling behavior of rotating, torsionally rigid, cantilevered beams were studied. The beam is considered to be clamped on the axis of rotation in one case, and off the axis of rotation in the other. Two methods are employed for the solution of the vibration problem: (1) one based upon a finite-difference approach using second order central differences for solution of the equations of motion, and (2) based upon the minimum of the total potential energy functional with a Ritz type of solution procedure making use of complex forms of shape functions for the dependent variables. The individual and collective effects of pretwist, precone, setting angle, thickness ratio and Coriolis forces on the natural frequencies and the buckling boundaries are presented. It is shown that the inclusion of Coriolis effects is necessary for blades of moderate to large thickness ratios while these effects are not so important for small thickness ratio blades. The possibility of buckling due to centrifugal softening terms for large values of precone and rotation is shown.

Subrahmanyam, K. B.↗

The effect of diffusive hydrogen segregation on fracture of polycrystalline nickel

Hydrogen embrittlement of polycrystalline nickel was studied under conditions which allowed the diffusion and segregation of hydrogen to grain boundaries to be controlled. It was shown that even at high solute concentrations of hydrogen, the fracture mode was ductile shear rupture, if transport of hydrogen to the grain boundaries was not allowed. As the amount of hydrogen segregation to the grain boundaries was increased, the fracture mode became increasingly intergranular. Analysis of the temperature dependence of this transition from ductile rupture to transgranular fracture yields a hydrogen segregation enthalpy of 11.6 kJ/mol. The transition in the fracture mode was also observed at a constant aging temperature by increasing the solute hydrogen concentration. The kinetics of this fracture transition suggest that the hydrogen segregation layer extends about 35 nm from the grain boundary. It is suggested that the fracture mechanism is a softening of the material in this segregation region due to the high hydrogen concentration.

Lassila, D. H.↗

Hydrogen effects on the age hardening behavior of 2024 aluminum

It has been found that the fatigue crack growth rate in aluminum alloys increases significantly in the presence of moisture. This phenomenon along with a moisture effect observed in another context has been attributed to 'embrittlement' of the aluminum by absorbed hydrogen generated by the reaction of moisture with freshly exposed aluminum. A description is given of a number of age hardening experiments involving 2024 aluminum. These experiments show that a mechanism related to the segregation of absorbed hydrogen to the coherent theta-double-prime interfaces may account for the observed reduction in fatigue life. It is pointed out that this segregation promotes a loss of coherency in the hydrogen rich region at a fatigue crack tip. Subsequently, the loss of coherency causes local softening and reduces fatigue life.

Wagner, J. A.↗

Estimation of high temperature low cycle fatigue on the basis of inelastic strain and strainrate

Fatigue life at elevated temperature can be predicted by introducing parametric values obtained from monotonic constitutive behavior into the Universal-Slopes Equation. For directionally solidified MAR-M200+HF at 975 C, these parameters are the maximum stress achievable under entirely plastic (time-independent) and purely creep (time-dependent) conditions and the corresponding inelastic strains, as well as the elastic modulus. For materials which exhibit plasticity/creep interaction, two more pairs of monotonic parameters must be evaluated for fatigue life prediction. This life-prediction method based on the Universal-Slopes Equation, resulted from a constitutive model characterizing monotonic and cyclic data as inelastic strainrate as a function of inelastic strain. Characterizing monotonic data is this way, permitted distinction between different material responses such as strain-hardening, strain-softening, and dynamic recovery effects. Understanding and defining the region of influence of each of these effects facilitated formulation of the constitutive model in relation to the mechanical and microstructural processes occurring in the material under cyclic loading.

Berkovits, A.↗

A Constitutive Model for the Inelastic Multiaxial Cyclic Response of a Nickel Base Superalloy Rene 80

The objective was to develop unified constitutive equations which can model a variety of nonlinear material phenomena observed in Rene 80 at elevated temperatures. A constitutive model was developed based on back stress and drag stress. The tensorial back stress was used to model directional effects; whereas, the scalar drag stress was used to model isotropic effects and cyclic hardening or softening. A flow equation and evolution equations for the state variables were developed in multiaxial form. Procedures were developed to generate the material parameters. The model predicted very well the monotonic tensile, cyclic, creep, and stress relaxation behavior of Rene 80 at 982 C. The model was then extended to 871, 760, and 538 C. It was shown that strain rate dependent behavior at high temperatures and strain rate independent behavior at the lower temperatures could be predicted very well. A large number of monotonic tensile, creep, stress relation, and cyclic experiments were predicted. The multiaxial capabilities of the model were verified extensively for combined tension/torsion experiments. The prediction of the model agreed very well for proportional, nonproportional, and pure shear cyclic loading conditions at 982 and 871 C.

Ramaswamy, V. G.↗

Addition polymers from 1,4,5,8-tetrahydro-1,4;5,8-diepoxyanthracene and Bis-dienes: Processable resins for high temperature application

1,4,5,8-Tetrahydro-1,4;5,8-diepoxyanthracene reacts with various anthracene endcapped polyimide oligomers to form Diels-Alder cycloaddition copolymers. The polymers are soluble in common organic solvents, and have molecular weights of approximately 21,000 to 32,000. Interestingly, these resins appear to be more stable in air then in nitrogen. This is shown to be due to a unique dehydration (loss of water ranges from 2 to 5 percent) at temperatures of 390 to 400 C to give thermo-oxidatively stable pentiptycene units along the polymer backbone. Because of their high softening points and good thermo-oxidative stability, the polymers have potential as processible, matrix resins for high temperature composite applications.

Meador, Mary Ann B.↗

A NASTRAN primer for the analysis of rotating flexible blades

This primer provides documentation for using MSC NASTRAN in analyzing rotating flexible blades. The analysis of these blades includes geometrically nonlinear (large displacement) analysis under centrifugal loading, and frequency and mode shape (normal modes) determination. The geometrically nonlinear analysis using NASTRAN Solution sequence 64 is discussed along with the determination of frequencies and mode shapes using Solution Sequence 63. A sample problem with the complete NASTRAN input data is included. Items unique to rotating blade analyses, such as setting angle and centrifugal softening effects are emphasized.

Lawrence, Charles↗

Geomorphic evidence for ancient seas in west Deuteronilus Mensae, Mars-1: Regional geomorphology

The fretted terrain in west Deuteronilus Mensae consists of extensive cratered upland penninsulas or isolated plateaus cut by long, finger-like canyons typically 10 to 20 km wide and upwards of 300 km long. The longest of these canyons trend roughly north-south to north-northeast, which may reflect some local structural and/or topographic control. At least three geomorphic zones roughly parallel to the lowland/upland boundary, suggestive of increasing modification northward, can be recognized on the fretted region of the region. The southern-most zone (zone A) consists of sharply defined fretted terrain. The middle zone (zone B) consists of well defined fretted terrain in which the plateau surfaces appear smoother, with a somewhat darker and much less varied albedo surface than those of zone A. The northern-most zone (zone C) consists of rounded or softened fretted terrain. The zones were interpreted as surface exposures of successively lower stratigraphic units.

Parker, Timothy J.↗

Rapid temporal evolution of radiation from non-thermal electrons in solar flares

Solutions of the time dependent Fokker-Planck equation was found for accelerated electrons undergoing Coulomb collisions in a magnetized, fully ionized plasma. An exact solution was found for arbitrary pitch angle and energy distribution in a uniform background plasma. Then, for an inhomogeneous plasma, a solution was found for particles with small pitch angles. These solutions were used to calculate the temporal evolution of bremsstrahlung x-rays from short bursts of nonthermal electron beams, and these spectra were compared with observed high time resolution spectra of short timescale solar hard x-ray bursts. It is shown that the observed softening in time of the spectra rules out a homogeneous background and therefore the possibility of electrons being confined to the corona either because of converging magnetic field or high densities. The inhomogeneous solution was also applied to a model with constant coronal density and exponentially rising chromospheric density. The spectra are shown to be consistent with that produced by a collimated beam of electrons accelerated in the corona with certain given conditions. These conditions could be violated if large pitch angle electrons are present.

Lu, Edward T.↗

Multiple-mode nonlinear free and forced vibrations of beams using finite element method

Multiple-mode nonlinear free and forced vibration of a beam is analyzed by the finite element method. The geometric nonlinearity is investigated. Inplane displacement and inertia (IDI) are also considered in the formulation. Harmonic force matrix is derived and explained. Nonlinear free vibration can be simply treated as a special case of the general forced vibration by setting the harmonic force matrix equal to zero. The effect of the higher modes is more pronouced for the clamped supported beam than the simply supported one. Beams without IDI yield more effect of the higher modes than the one with IDI. The effects of IDI are to reduce nonlinearity. For beams with end supports restrained from axial movement (immovable cases), only the hardening type nonlinearity is observed. However, beams of small slenderness ratio (L/R = 20) with movable end supports, the softening type nonlinearity is found. The concentrated force case yields a more severe response than the uniformly distributed force case. Finite element results are in good agreement with the solution of simple elliptic response, harmonic balance method, and Runge-Kutte method and experiment.

Mei, Chuh↗

Dissociative excitation of the N(+)(5S) state by electron impact on N2 - Excitation function and quenching

Metastable N(+)(5S) ions were produced in the laboratory by dissociative excitation of N2 with energetic electrons. The resulting radiative decay of the N(+)(5S) state was observed with sufficient resolution to completely resolve the doublet from the nearby N2 molecular radiation. The excitation function was measured from threshold to 500 eV. The cross section peaks at a high electron energy and also exhibits a high threshold energy both of which are typical of dissociative excitation-ionization processes. This finding complicates the explanation of electron impact on N2 as the mechanism for the source of the 2145 A 'auroral mystery feature' by further increasing the required peak cross section. It is suggested that the apparent N(+)(5S) quenching in auroras may be an artifact due to the softening of the electron energy spectrum in the auroral E region.

Erdman, P. W.↗

Compton scattering in strong magnetic fields

The relativistic cross section for Compton scattering by electrons in strong magnetic fields is derived. The results confirm and extend earlier work which has treated only transitions to the lowest or first excited Landau levels. For the teragauss field strengths expected in neutron star magnetospheres, the relative rates for excited state transitions are found to be significant, especially for incident photon energies several times the cyclotron frequency. Since these transitions must result in the rapid emission of one or more cyclotron photons as well as the Compton-scattered photon, the scattering process actually becomes a photon 'splitting' mechanism which acts to soften hard photon spectra, and also provides a specific mechanism for populating higher Landau levels in the electron distribution function. The results should be significant for models of gamma-ray bursters and pulsating X-ray sources.

Daugherty, Joseph K.↗

Low cycle fatigue behaviour of a plasma-sprayed coating material

Single crystal nickel-base superalloys employed in turbine blade applications are often used with a plasma spray coating for oxidation and hot corrosion resistance. These coatings may also affect fatigue life of the superalloy substrate. As part of a large program to understand the fatigue behavior of coated single crystals, fully reversed, total strain controlled fatigue tests were run on a free standing NiCoCrAlY coating alloy, PWA 276, at 0.1 Hz. Fatigue tests were conducted at 650 C, where the NiCoCrAlY alloy has modest ductility, and at 1050 C, where it is extremely ductile, showing tensile elongation in excess of 100 percent. At the lower test temperature, deformation induced disordering softened the NiCoCrAlY alloy, while at the higher test temperature cyclic hardening was observed which was linked to gradual coarsening of the two phase microstructure. Fatigue life of the NiCoCrAlY alloy was significantly longer at the higher temperature. Further, the life of the NiCoCrAlY alloy exceeds that of coated, /001/-oriented PWA 1480 single crystals at 1050 C but at 650 C the life of the coated crystal is greater than that of the NiCoCrAlY alloy on a total strain basis.

Gayda, J.↗

Subsidence of topography on Io

The underlying roots of Io's topographic features are softened and eroded by contact with the hot mantle, resulting in a subsidence which is analogous to the progress of a butter pat on a frying pan. This process would be offset by crustal thickening due to continuing volcanism if the rate for this phenomenon were more than the observed 1 cm/year or less. Because the crustal thinning would occur at about 50 cm/year if the material underneath were a pure magma ocean, Io cannot have a global magna ocean, and interior viscosities greater than about 10 to the 10th P are implied.

Webb, Erik K.↗

Influence of thread construction on strength of ceramic sewing threads

The effects of two thread construction variables, yarn twist and polymeric sizing, on break strength were obtained for a silica thread and two types of aluminoborosilicate (ABS) threads at temperatures ranging from 23 C to 1200 C. It was shown that increasing the degree of twist for the silica thread produced an optimum twist level until all the yarn finish was removed. The break strength of both ABS threads was inversely proportional to the degree of twist caused by increased filament breakage with increasing twist that was controlled by the gradual removal of the polymeric processing aids. At elevated temperatures, above 950 C, strength loss was observed for both ABS threads because of the presence of a glass phase that softens and causes fiber deformation. This was not observed for the silica thread at similar test temperatures because of the higher viscosity of the pure silica glass phase.

Sawko, Paul M.↗

Thermal-mechanical fatigue crack growth in B-1900+Hf

Thermal-mechanical fatigue crack growth (TMFCG) rates in B-1900+Hf were measured under strain-controlled conditions in the temperature range 400-925 C. A poor correlation between isothermal and TMFCG rates under elastic and fully plastic conditions was observed when test data were analyzed using a strain-based approach. A stress-based approach taking into account the hardening and softening behavior of the material and load shedding provided an adequate description of the isothermal and TMFCG rates. Also, the isothermal crack growth rates at minimum and maximum temperatures provided upper and lower bounds, respectively, on the TMFCG rates.

Marchand, N.↗