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At least 613 records · Page 34
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

A one-dimensional photochemical model of the troposphere with planetary boundary-layer parameterization

A time-dependent, one-dimensional photochemical model of the troposphere is used to describe the vertical distribution of atmospheric trace constituents for summer-time conditions at midlatitudes in the Northern Hemisphere. The model incorporates a planetary boundary layer (PBL) parametrization and a detailed chemical mechanism that includes the photochemistry of important nonmethane hydrocarbon species formed during the oxidation process. One result of the parametrized PBL is that the concentrations of some trace species in the free troposphere are 20-30 percent higher than when mixing processes are described by a vertical eddy diffusion coefficient which is held constant with respect to height and time. The lifetime of the oxides of nitrogen against photochemical conversion to nitric acid during summertime conditions is on the order of six hours. This lifetime is short enough to deplete most of the NO(x) in the PBL so that other reactive nitrogen species are more abundant than NO(x) throughout the free troposphere.

Fishman, J.↗
NASA NTRS1983

Methylhydrazinium nitrate

Methylhydrazinium nitrate was synthesized by the reaction of dilute nitric acid with methylhydrazine in water and in methanol. The white needles formed are extremely hygroscopic and melt at 37.5-40.5 C. The IR spectrum differs from that reported elsewhere. The mass spectrum exhibited no parent peak at 109 m/z, and thermogravimetric analysis indicated that the compound decomposed slowly at 63-103 C to give ammonium and methylammonium nitrate. The density is near 1.55 g/cu cm.

Lawton, E. A.↗
NASA NTRS1984

The global distribution and variability of stratospheric constituents measured by LIMS

The purpose of the Nimbus 7 LIMS experiment was to sound the composition and structure of the upper atmosphere and provide data for study of photochemistry, radiation, and dynamics processes. Vertical profiles were measured of temperature and ozone (O3) over the 10-km to 65-km range and water vapor, nitrogen dioxide, and nitric acid over the 10-km to 50-km range. Latitude coverage extended from 64 deg S to 84 deg N. Several general features of the atmosphere have emerged from data analyzes thus far. Nitrogen dioxide exhibits rapid latitudinal variations in winter and shows hemispheric asymmetry with generally higher vertical column amount in the summer hemisphere. HNO3 data show that this gas is highly variable with altitude, latitude, and season. Smallest mixing ratios occur in the tropics, and the largest values occur in the high latitude winter hemisphere. The results show that O3, NO2, and HNO3 are strongly affected during a stratospheric warming.

Russell, J. M., III↗
NASA NTRS1986

Transient medium-scale wave activity in the summer stratosphere

Observations of medium-scale transient wave activity in the middle-latitude Southern Hemisphere summer stratosphere are interpreted using isentropic potential vorticity (IPV) distributions inferred from temperature data from the Nimbus-7 Limb Infrared Monitor of the Stratosphere (LIMS) instrument. Despite problems with errors in reference-level synoptic height information, the derived IPV distributions clearly exhibit dynamically coherent signatures of eddy mixing due to medium-scale disturbances in the lower-middle stratosphere during early January 1979. The IPV distributions are shown to be strongly correlated with those of a contemporaneous set of isentropic maps of quasi-conservative tracers such as ozone and nitric acid. The results suggest that IPV maps inferred from satellite temperature data provide a useful diagnostic for studies of large-scale dynamics and/or transport in the extratropical stratosphere. Furthermore, the comparatively high vertical resolution of the LIMS data has enabled the vertical attenuation of Southern Hemisphere wave activity to be diagnosed in greater detail than could be achieved from nadir-viewing satellite information.

Miles, T.↗
NASA NTRS1987

Fluidized-Bed Cleaning of Silicon Particles

Fluidized-bed chemical cleaning process developed to remove metallic impurities from small silicon particles. Particles (250 micrometer in size) utilized as seed material in silane pyrolysis process for production of 1-mm-size silicon. Product silicon (1 mm in size) used as raw material for fabrication of solar cells and other semiconductor devices. Principal cleaning step is wash in mixture of hydrochloric and nitric acids, leaching out metals and carrying them away as soluble chlorides. Particles fluidized by cleaning solution to assure good mixing and uniform wetting.

Rohatgi, Naresh K.↗
NASA NTRS1987

Antarctic stratospheric chemistry of chlorine nitrate, hydrogen chloride, and ice - Release of active chlorine

The reaction rate between atmospheric hydrogen chloride (HCl) and chlorine nitrate (ClONO2) is greatly enhanced in the presence of ice particles; HCl dissolves readily into ice, and the collisional reaction probability for ClONO2 on the surface of ice with HCl in the mole fraction range from about 0.003 to 0.010 is in the range from about 0.05 to 0.1 for temperatures near 200 K. Chlorine is released into the gas phase on a time scale of at most a few milliseconds, whereas nitric acid (HNO3), the other product, remains in the condensed phase. This reaction could play an important role in explaining the observed depletion of ozone over Antarctica; it releases photolytically active chlorine from its most abundant reservoir species, and it promotes the formation of HNO3 and thus removes nitrogen dioxide from the gas phase. Hence it establishes the necessary conditions for the efficient catalytic destruction of ozone by halogenated free radicals.

Molina, Mario J.↗
NASA NTRS1987

Middle atmosphere trace constituents; Proceedings of Workshop 9 of the Twenty-sixth COSPAR Plenary Meeting, Toulouse, France, June 30-July 11, 1986

Papers are presented on a reference model for stratospheric NO2, a proposed reference model for nitric acid, proposed reference models for ozone, and a background stratospheric aerosol reference model. Other topics include a comparison between the observed and calculated distributions of trace species in the middle atmosphere, recent measurements of trace constituents from rocket and balloon probes, NO2 field observations in the stratosphere during the MAP/GLOBUS Campaign in 1983 and 1985, and the vertical distribution of ozone in the equatorial zone. Also considered are precision measurements of stratospheric ozone profiles by rocket-borne optical ozonesondes, vertical profiles of source gases at tropical latitudes, and measurements of stratospheric trace constituent distributions from balloon-borne far infrared observations.

Keating, G. M.↗
NASA NTRS1988

Aerosol measurements in the winter/spring Antarctic stratosphere. I - Correlative measurements with ozone. II - Impact on polar stratospheric cloud theories

Aerosol measurements collected from August 25-November 3, 1986 at McMurdo Station using balloon-borne optical particle counters are examined in order to study the relationship between aerosol and ozone distribution and the formation of polar stratospheric clouds (PSCs). Ozone, aerosol, and condensation nuclei profiles, and pressure, temperature, and humidity measurements are analyzed. It is observed that the height of the stratospheric sulfate layer decreases over the period of measurement suggesting that upwelling in the votex is not important in the zone depletion process. Three theories on PSC formation are described, and the effects of the aerosol measurements on the theories are considered. The three theories are: (1) the original theory of water vapor pressure over a solution of H2SO4 of Steele et al. (1983) and Hamill and Mc Master (1984); (2) the nitric acid theory of PSCs of Toon et al. (1986) and Hamill et al. (1986); and (3) the quasi-cirrus cloud theory of Heymsfield (1986).

Hofmann, D. J.↗
NASA NTRS1988

Laboratory studies of sticking coefficients and heterogeneous reactions important in the Antarctic stratosphere

Laboratory studies of sticking coefficients of H2O, HCl, Cl2, and HNO3 on ice and heterogeneous reactions of ClONO2 with ice or HCl/ice have been performed in a fast flow reactor. A quadrupole mass spectrometer with electron impact ionization was used as a detector. Measured sticking coefficients are: 0.3 (+0.7, -0.1) for H2O, 0.4 (+0.6, -0.2) for HCL, less than 0.0001 for Cl2, and 0.3 (+0.7, -0.1) for HNO3 at 200 K. The reaction probability of ClONO2 on ice was found to be 0.06 (+ or - 0.03) while HOCl was observed as a sole product in the gas phase. With HCl present in ice, the reaction probability of ClONO2 is greatly enhanced, approaching 0.27 (+0.73, -0.13) while molecular chlorine was found to be the major product in the gas phase. Another reaction product was nitric acid which remained in the solid phase. Since the polar stratospheric clouds contain ice particles or possibly HCl/ice particles on the surface, the present results should be a major factor in producing the observed springtime ozone depletion in the Antarctic stratosphere.

Leu, Ming-Taun↗
NASA NTRS1988

Balloon borne Antarctic frost point measurements and their impact on polar stratospheric cloud theories

The first balloon-borne frost point measurements over Antarctica were made during September and October, 1987 as part of the NOZE 2 effort at McMurdo. The results indicate water vapor mixing ratios on the order of 2 ppmv in the 15 to 20 km region which is somewhat smaller than the typical values currently being used significantly smaller than the typical values currently being used in polar stratospheric cloud (PSC) theories. The observed water vapor mixing ratio would correspond to saturated conditions for what is thought to be the lowest stratospheric temperatures encountered over the Antarctic. Through the use of available lidar observations there appears to be significant evidence that some PSCs form at temperatures higher than the local frost point (with respect to water) in the 10 to 20 km region thus supporting the nitric acid theory of PSC composition. Clouds near 15 km and below appear to form in regions saturated with respect to water and thus are probably mostly ice water clouds although they could contain relatively small amounts of other constituents. Photographic evidence suggests that the clouds forming above the frost point probably have an appearance quite different from the lower altitude iridescent, colored nacreous clouds.

Rosen, James M.↗
NASA NTRS1988

Laboratory studies of sticking coefficients and heterogeneous reactions important in the stratosphere

The discovery of ozone depletion during spring in the Antarctic stratosphere has received wide spread attention. Both meteorological and chemical mechanisms have been used in attempts to explain this observation. The chemical theory focused on the chlorofluoromethanes released into the atmosphere. However, gas-phase, homogeneous reactions alone in the model can not adequately explain such a depletion. Heterogeneous reactions on ice surfaces could be important in the Antarctic stratosphere. These reactions are thought to convert ClONO2 and N2O5 into HNO3 in the solid phase while Cl2, HOCl, and ClNO2 are released into the stratosphere as gas-phase products. The photolysis of Cl2, HOCl, and ClNO2, then produces active chlorine which subsequently removes ozone through several catalytic cycles, including the Cl2O2 mechanism. The polar stratospheric clouds are thought to consist of mixtures of water ice, nitric acid, and sulfuric acid. Condensation of HCl onto the PSC's could provide active surfaces for heterogeneous reactions.

Leu, Ming-Taun↗
NASA NTRS1988

Rocket- and aircraft-borne trace gas measurements in the winter polar stratosphere

In January and February 1987 stratospheric rocket- and aircraft-borne trace gas measurements were done in the North Polar region using ACIMS (Active Chemical Ionization Mass Spectrometry) and PACIMS (PAssive Chemical Ionization Mass Spectrometry) instruments. The rocket was launched at ESRANGE (European Sounding Rocket Launching Range) (68 N, 21 E, Northern Sweden) and the twin-jet research aircraft operated by the DFVLR (Deutsche Forschungs- und Versuchs-anstalt fuer Luft- und Raumfahrt), and equipped with a mass spectrometer laboratory was stationed at Kiruna airport. Various stratospheric trace gases were measured including nitric acid, sulfuric acid, non-methane hydrocarbons (acetone, hydrogen cyanide, acetonitrile, methanol etc.), and ambient cluster ions. The experimental data is presented and possible implications for polar stratospheric ozone discussed.

Arnold, F.↗
NASA NTRS1988

Acute effects of a large bolide impact simulated by a global atmospheric circulation model

The goal is to use a global three-dimensional atmospheric circulation model developed for studies of atmospheric effects of nuclear war to examine the time evolution of atmospheric effects from a large bolide impact. The model allows for dust and NOx injection, atmospheric transport by winds, removal by precipitation, radiative transfer effects, stratospheric ozone chemistry, and nitric acid formation and deposition on a simulated Earth having realistic geography. Researchers assume a modest 2 km-diameter impactor of the type that could have formed the 32 km-diameter impact structure found near Manson, Iowa and dated at roughly 66 Ma. Such an impact would have created on the order of 5 x 10 to the 10th power metric tons of atmospheric dust (about 0.01 g cm(-2) if spread globally) and 1 x 10 to the 37th power molecules of NO, or two orders of magnitude more stratospheric NO than might be produced in a large nuclear war. Researchers ignore potential injections of CO2 and wildfire smoke, and assume the direct heating of the atmosphere by impact ejecta on a regional scale is not large compared to absorption of solar energy by dust. Researchers assume an impact site at 45 N in the interior of present day North America.

Thompson, Starley L.↗
NASA NTRS1989

The use of assimilated stratospheric data in constituent transport calculations

A stratospheric assimilation system has been developed, which generates wind data that is consistent with the geopotential height (and temperature) field and the primitive equations in the general circulation model. This paper reports the first known calculations to use data from an assimilation to calculate constituent transport in the stratosphere. Nitric acid (NHO3) during the Limb IR Monitor of the Stratosphere (Gille et al., 1984) period is studied. The high-latitude time variance of the HNO3 is accurately captured. These studies suggest that data from an assimilation process offers tremendous potential for studying stratospheric dynamics, constituent transport, and chemistry.

Rood, Richard B.↗
NASA NTRS1989

Measurements of size and composition of particles in polar stratospheric clouds from infrared solar absorption spectra

Results are presented on polar stratospheric cloud (PSC) observations, based on IR measurements of solar extinction, made by the airborne JPL Mark IV interferometer during the Airborne Antarctic Ozone Expedition in 1987, together with the instrumentation and the theoretical aspects of data analysis. Thirty-three PSC cases were analyzed and categorized into two types, I and II, which were found to occur at different altitudes during September. Type I clouds, seen at altitudes above 15 km, contained particles with radii of about 0.5 micarons and nitric acid concentrations greater than 40 percent, while type II clouds, found usually below 15 km, contained particles with radii of 6 microns and larger, composed of water ice. In addition, particles of larger than the 15-micron-size detection limit were encounterd.

Kinne, S.↗
NASA NTRS1989

Laboratory chemistry and stratospheric clouds

Results are presented from laboratory experiments on the chemistry of ice particles to study the role of HCl and ClONO2 from CFCs in stratospheric ozone depletion over Antarctica. It is found that gaseous HCl is scavenged with high efficiency by the ice and the gas phase chlorine nitrate may react with the HCL-containing ice to produce Cl2. Also, consideration is given ot the behavior of solid nitric acid trihydrate and sulfuric acid aerosols.

Molina, Mario J.↗
NASA NTRS1990

Nongeostrophic theory of zonally averaged circulation. II - Eliassen-Palm flux divergence and isentropic mixing coefficient

A diagnostic study of Eliassen-Palm flux divergence and isentropic mixing coefficient (Kyy) in the stratosphere is performed for different seasons and for both hemispheres, based on the nongeostrophic theory of zonally averaged circulation of Tung (1986). An easily implementable procedure is described which yields a Kyy field that is consistent with advective transport. It is shown that the resultant time- and space-varying structure of Kyy leads to improved simulation of stratospheric species whose distributions are affected by dynamical transport. In particular, it is shown that the simulation of nitric acid is more satisfactory than previous model calculations.

Yang, H.↗
NASA NTRS1990

Radiative effects of polar stratospheric clouds

Radiative transfer calculations are performed for polar stratospheric clouds (PSCs) using newly acquired PSC properties and polar atmospheric data. PSC radiative effects depend strongly on upwelling thermal radiation and vary from infrared heating over warm polar surfaces, such as oceans, to cooling over cold surfaces, such as the Antarctic plateau. Heating and cooling rates of nitric acid PSCs are smaller than + or - 0.1 K/day. Rates for optically thicker ice PSCs vary from 1.0 to -0.2 K/day, those for orographically forced ice PSCs even from 3.0 to -0.5 K/day. Frequently observed optically thick cirrus decks near the tropopause provide a very cold radiative surface. These clouds not only act to prevent heating and enhance cooling in ice PSCs to -0.5 K/day and orographic ice PSCs to 2 K/day, but such cirrus cloud decks also cool the entire stratosphere by up to -0.5 K/day over warm surfaces, even in the absence of PSCs.

Kinne, S.↗