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At least 613 records · Page 34
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Preservation of erniettomorph fossils in clay-rich siliciclastic deposits from the Ediacaran Wood Canyon Formation, Nevada

Three-dimensionally preserved Ediacaran fossils occur globally within sandstone beds. Sandy siliciclastic deposits of the Ediacaran Wood Canyon Formation (WCF) in the Montgomery Mountains, Nevada, contain two fossil morphologies with similar shapes and sizes: one exhibits mm-scale ridges and a distinct lower boundary and the other is devoid of these diagnostic features. We interpret these as taphomorphs of erniettomorphs, soft-bodied organisms with uncertain taxonomic affinities. We explore the cast-and-mould preservation of both taphomorphs by petrography, Raman spectroscopy, X-ray fluorescence microprobe and X-ray diffraction. All fossils and the surrounding sedimentary matrix contain quartz grains, iron-rich chlorite and muscovite. The ridged fossils contain about 70% larger quartz grains compared to the ridgeless taphomorph, indicating a lower abundance of clay minerals in the ridged fossil. Chlorite and muscovite likely originated from smectite and kaolinite precursors that underwent lower greenschist facies metamorphism. Kaolinite and smectite are inferred to have been abundant in sediments around the ridged fossil, which enabled the preservation of a continuous, distinct, clay- and kerogen-rich bottom boundary. The prevalence of quartz in the ridged fossils of the WCF and in erniettomorphs from other localities also suggests a role for this mineral in three-dimensional preservation of erniettomorphs in sandstone and siltstone deposits.

58 GEOSCIENCES↗
NASA NTRS1984

The Colony meteorite and the possible existence of a new chemical subgroup of CO3 chondrites

The Colony meteorite, found in Oklahoma around 1975, has an unrecrystallized texture and contains heterogeneous olivine and low Ca pyroxene, kamacite with low Ni and Co and high Cr, amoeboid inclusions with low FeO and MnO, and numerous small chondrules with clear pink glass. These characteristics are shared by members of the least metamorphosed subgroup of CO3 chondrites. Colony contains a fine grained matrix that has higher FeO and K2O and lower MgO and Na2O than normal CO3 matrices. Allan Hills A77307 is another unmetamorphosed meteorite that has many petrologic similarities to normal CO chondrites, including matrix abundance, mineral compositions and chondrule size. However, it differs from them in its abundance of magnetite and presence of iron carbides. The olivine and low Ca pyroxene compositional distributions of Colony and A77307 are very similar. The shapes of the thermoluminescence glow curves of Colony and A77307 are very similar, but differ significantly from those of normal CO chondrites. It is suggested that Colony and A77307 represent a distinct chemical subgroup of CO3 chondrites, characterized by low Ni, Co, S, Ca, Mg, Mn and, possibly, high Cd.

Rubin, A. E.↗
NASA NTRS1984

X-radiography of slices of the Allende Meteorite

A 2.2 kg fragment of the Allende Meteorite was derinded and sliced by bandsawing. Several X-radiographs were made of all slices. The following features are resolved: grains of blocky troilite (bright spots), troilite rimmed chondrules (bright halos), chondrules with central vugs (dim halos), white aggregates (dark patches), and dark inclusions (medium dark patches). The number of FeS grains larger than about 0.5 mm is one per 6 + or - 1 gram of this fragment. Their concentration appears to be uniform at the 1 kg weight level, but is not uniform at the 100 g level. The number of FeS rimmed chondrules is one per 10 g. Their concentration is also nonuniform at the 100 g weight level. The number of white aggregates is roughly one per 20 g. These disc shaped objects show a distinct preferred orientation of the axis orthogonal to the plane of the disc. Chondrules with central vugs are numerous. Linear and curved arrays of chondrules, up to a few cm long, were observed. An interpretation of the observed features is given.

Smith, M. J.↗
DOE OSTI2021

Improvements to the Powder Processing of near-Final Shape alnico Magnets

Alnico permanent magnets (PMs), a recent PM system of interest as an attractive rare earth-free PM alternative, have advantageous high operating temperature and magnetic saturation with the potential for utilization in electric machines, e.g. interior-PM motors found in electric vehicles, if current directional solidification methods can be replaced by a true mass production approach. Recently, two unique alnico compositions, termed Full-Co and Co-lean, with improved coercivity, were gas atomized, compression molded, and vacuum sintered (4h at 1240°C) to high densities of 97.8% and 99.3%, respectively. However, the Co-lean remained fine grained isotropic magnets and the Full-Co grains were not textured, lowering magnetic strength in spite of attempts to grow large textured grains by a stress-biased solid state grain alignment method to convert them to high energy anisotropic magnets. It was hypothesized that oxidation during de-binding in air left many prior particle boundary oxides within the sintered microstructure that hindered grain growth and texturing during the stress-biased texturing procedure and prevented the desired abnormal grain growth (AGG). Here we explored a vacuum de-binding step that was linked (in-place) to vacuum sintering and found that the Co-lean exhibited faster uniform grain growth that doubled the average grain size (40 μm to 80 μm). Linked vacuum de-binding and sintering of Full-Co produced some AGG after only 1 h of 1240°C sintering. A new direction for promoting AGG (and stress-biased texturing) in alnico is being explored that utilizes a fundamental analysis of systems with second phase particles that either inhibit or boost grain growth. This effort explores the influence of vacuum de-binding linked to a series of lower sintering temperatures at a fixed time (4h) to see if oxide particle size and volume fraction can be changed to promote AGG conditions in alnico. Surprising qualitative results indicate that AGG may be promoted for vacuum sintering at less than 1200°C.

Rinko, Emily↗
NASA NTRS2006

Carbon-rich Chondritic Clast PV1 from the Plainview H-chondrite Regolith Formation from H3 Chondrite Material by Possible Cometary Impact

Chondritic clast PV1 from the Plainview H-chondrite regolith breccia is a subrounded, 5-mm diameter unequilibrated chondritic fragment that contains 13 wt% C occurring mainly within irregularly shaped 30-400-micron-size opaque patches. The clast formed from H3 chondrite material as indicated by the mean apparent chondrule diameter (310 micron vs. approximately 300 micron in H3 chondrites), the mean Mg-normalized refractory lithophile abundance ratio (1.00 +/- 0.09 XH), the previously determined 0-isotopic composition (Delta O-17 = 0.66% vs. 0.68 +/- 0.04%0 in H3 chondrites and 0.73 +/- 0.09% in H4-6 chondrites), the heterogeneous olivine compositions in grain cores (with a minimum range of Fal-19), and the presence of glass in some chondrules. Although the clast lacks the fine-grained, ferroan silicate matrix material present in type 3 ordinary chondrites, PV1 contains objects that appear to be recrystallized clumps of matrix material. Similarly, the apparent dearth of radial pyroxene and cryptocrystalline chondrules in PV1 is accounted for by the presence of some recrystallized fragments of these chondrule textural types. All of the chondrules in PV1 are interfused indicating that temperatures must have briefly reached approximately 1100C (the approximate solidus temperature of H-chondrite silicate). The most likely source of this heating was by an impact. Some metal was lost during impact heating as indicated by the moderately low abundance of metallic Fe-Ni in PV1 (approximately 14 wt%) compared to that in mean H chondrites (approximately 18 wt%). The carbon enrichment of the clast may have resulted from a second impact event, one involving a cometary projectile, possibly a Jupiter-family comet. As the clast cooled, it experienced hydrothermal alteration at low water/rock ratios as evidenced by the thick rims of ferroan olivine around low-FeO olivine cores. The C-rich chondritic clast was later incorporated into the H-chondrite parent-body regolith and extensively fractured and faulted.

Rubin, Alan E.↗
NASA NTRSDate not supplied

X-Ray Diffraction Based Phase Identification in NiTiHf Shape Memory Alloys with Variable Hf Content

NiTiHf type shape memory alloys have been studied for use in high temperature actuator applications, the most studied of which is the NiTi-20Hf atomic % composition. In this study, six samples of NiTi-Hf including 20Hf, 30Hf, 35Hf, 40Hf, 45Hf, and 50Hf were evaluated by both 1D and 2D X-ray diffraction (XRD) to elucidate what phases and crystal structures were present at room temperature. Given small sample sizes and relatively large grains, multiple cross-sections were measured to increase the sampling statistics, and 2D XRD frames were collected to corroborate the 1D XRD data. Rietveld and structureless refinements were both performed, allowing for adjustments in orientation lattice constant, and structure factor. At room temperature, the primary martensitic phase in the NiTiHf alloys with 20 at% and lower Hf is a monoclinic B19’ phase (P1121/m space group). This phase was identifiable, even in small amounts, in the higher Hf samples. The primary phase in the 30 -50 at% Hf samples is an orthorhombic B33 (Cmcm space group) phase. This work supported thermal analyses indicating the phase transition paths from the two different room temperature martensitic phases to the B2 austenitic phase.

Laura Wilson↗
NASA NTRS1984

High spatial resolution observations of NGC 7027 with a 10 micron array camera

First observations of a planetary nebula with an infrared charge injection device (CID) array camera are reported. The 10 micron images of NGC 7027 have spatial resolution comparable to that of the highest resolution (less than 2 arcsec) radio aperture-synthesis maps of this source. A much closer correspondence between the mid-infrared and radio appearance of NGC 7027 was found than was known previously, confirming that warm dust is coextensive and well mixed with the gas in the ionized zone. Using maps at three wavelengths, the spatial dependence of the shape of the 8-13 micron spectrum within the nebula is examined. The dip at 9.60 microns is shallowest in regions of enhanced optical extinction (as determined from new images near 4000 and 9000 A obtained with an optical charge coupled device). The 9.60 micron emission is strongest in these same positions. It is shown that the results may be explained not by silicate absorption, but by a combination of emission from two distinct grain populations, one of which is also partly responsible for the variation in extinction across the nebula.

Arens, J. F.↗
NASA NTRS1989

Using infrared spectral features to probe circumstellar dust shells around cool stars

IRAS observations of cool stars provide low resolution spectra in the mid-infrared and also give fluxes at four wavelength bands from which color-color diagrams are constructed. The later have been used to study the evolution of these stars: as an O-rich star evolves to become a C-rich star and its detached dust shell moves further away, its evolution can be tracked on a color-color diagram. A major factor in determining the position of either C-rich or O-rich stars on the 12-25-60 micron color-color diagram is the presence of spectral features in the mid-IR. O-rich stars show a 9.8 micron silicate feature, while C-rich stars have a SiC feature at 11.2 microns. IRAS observations indicate that the SiC feature is quite narrow and uniform in shape showing little variation from star to star. The full width at half maximum (FWHM) is 1.6 + or - 0.15 microns. On the other hand, the shape of the silicate feature varies widely among the O-rich stars, with a FWHM ranging from 2 to 3 microns. The characteristics of circumstellar dust shells should manifest themselves both in the flux spectrum and in the details of the spectral features. To provide a coherent interpretation for these IRAS observations, models were constructed (using a radiative transfer code) of dust shells around O-rich and C-rich stars. Realistic grain opacities were used which include spectral features of varying intrinsic widths (e.g., Gaussian features at 10 microns with half width at half maximum of 0.5 and 1.0 microns).

Egan, Michael P.↗
NASA NTRS1998

Characterization of Al-Cu-Li Alloy 2090 Near Net Shape Extrusion

Aluminum-lithium (Al-Li) alloys near net shape extrusions are being evaluated for potential application in launch vehicle structures. The objective of this study was to determine tensile and fracture properties, corrosion resistance, and weldability of integrally stiffened panels of Al-Cu-Li alloy 2090 in the T8 temper. The microstructure was pre-dominantly unrecrystallized. Texture analyses revealed the presence of fiber components in the stiffeners and a combination of fiber and rolling components in the skin. Variations in grain morphology and texture through the extruded cross section were correlated with the tensile, fracture, and corrosion behavior. Tensile strengths at room and cryogenic temperatures of the 2090 extrusions were similar to other 2090 product forms and were higher than 2219-T87, the primary structural material in the Space Shuttle external tank; however, ductilities were lower. The fracture resistance of the 2090 extrusion was lower than 2219-T87 plate at room temperature. At cryogenic temperatures, tensile ductility and fracture behavior of the 2090 extrusion were similar to other 2090 product forms but were lower than 2219-T87 plate. The exfoliation and stress corrosion resistance of the 2090 extrusion compared favorably with the characteristics of other 2090 product forms. The weldability and weldment properties of the extrusions were similar to 2090 and 2219 plates.

Birt, M. J.↗
DOE OSTI2024

Unprecedented electrical performance of friction-extruded copper-graphene composites

Copper-graphene composites show remarkable electrical performance surpassing traditional copper conductors albeit at a micron scale; there are several challenges in demonstrating similar performance at the bulk scale. In this study, we used shear extrusion to synthesize macro-scale copper-graphene composites with a simultaneously lower temperature coefficient of resistance (TCR) and improved electrical conductivity over copper-only samples. We showed that the addition of 18 ppm of graphene decreased the TCR of C11000 alloy by nearly 11%. A suite of characterization tools involving scanning and transmission electron microscopy along with atom probe tomography were used to characterize the grain size, crystallographic orientation, structure, and composition of copper grains and graphene additives in the feedstock and processed samples. We posit that the shear extrusion process may have transformed some of the feedstock graphene additives into higher defect-density agglomerates while retaining the structure of others as mono-to-trilete flakes with lower defect density. The combination of these additives with heterogeneous structures may have been responsible for the simultaneous decrease in TCR and enhanced electrical conductivity of the copper-graphene ShAPE composites.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Advanced Fabrication Techniques of Metal Hydrides for Science and Technology Applications (Abbreviated Final Report)

Lithium Hydride (LiH) atomic properties make it an excellent candidate for thermal energy storage, hydrogen storage, and nuclear reactor technology. High Energy Density (HED) experiments on LiH at the National Ignition Facility (NIF) can also provide critical Equation of State (EOS) and Hugoniot data. Density requirements for LiH vary per application and therefore physical and structural requirements for LiH are non-uniform. Historical production of LiH relies on casting processesthat are limited by density and grain-size control, which leads to unfavorable machinable characteristics. LiH manufacturing is further hindered due to its chemical reactivity and propensity to readily react with moisture. This work aimed at exploring advanced fabrication techniques for LiH such as 1) uniaxial powder pressing methods and 2) laser powder bed fusion (L-PBF) additive manufacturing. Uniaxial powder compaction offers advantageous tailorable mechanical and physical properties via density control, and L-PBF can produce net-shaped complex parts with unique microstructure. Uniaxial pressing proved successful in readily producing LiH with density control.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Advanced Fabrication Techniques of Metal Hydrides for Science and Technology Applications (Full Technical Report)

Lithium Hydride (LiH) atomic properties make it an excellent candidate for thermal energy storage, hydrogen storage, and nuclear reactor technology. High Energy Density (HED) experiments on LiH at the National Ignition Facility (NIF) can also provide critical Equation of State (EOS) and Hugoniot data. Density requirements for LiH vary per application and therefore physical and structural requirements for LiH are non-uniform. Historical production of LiH relies on casting processes that are limited by density and grain-size control, which leads to unfavorable machinable characteristics. LiH manufacturing is further hindered due to its chemical reactivity and propensity to readily react with moisture. This work aimed at exploring advanced fabrication techniques for LiH such as 1) uniaxial powder pressing methods and 2) laser powder bed fusion (L-PBF) additive manufacturing. Uniaxial powder compaction offers advantageous tailorable mechanical and physical properties via density control, and L-PBF can produce net-shaped complex parts with unique microstructure. Uniaxial pressing proved successful in readily producing LiH with density control.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Determination of single crystal thermal expansion in Uranium-6wt%Niobium shape memory alloy using in-situ diffraction and modeling of textured polycrystalline samples

In-situ neutron diffraction and ex-situ dilatometry experiments were performed on a chemically banded, quenched uranium-6wt% niobium shape memory alloy to study the impact of deformation-(detwinning-) induced texture on the evolution of thermally induced strains (and associated stresses). Thermal heating and cooling cycles between 5K and 473K were performed in-situ with neutron diffraction, and the lattice strain evolution is reported for the observed monoclinic α" phase. Comparisons between the measured diffraction strains and macroscopic dilatometry experiments reveal relationships between micro- and macro-level thermal expansion. Softening of the texture during heating suggests that twin boundary motion can accommodate the large internal thermal strains which are approximately 2% greater than that typically observed during the 175K heating interval used to age more randomly oriented polycrystalline material. Assuming weak constraint of neighboring grains in randomly textured polycrystals, the single crystal thermal expansion tensor is extracted from measurements of lattice strains over the range 5K to 473K. Predictions of polycrystalline thermal expansion, based upon this single crystal thermal expansion tensor, are shown to compare favorably with bulk thermal expansion observations of the as quenched microstructure. However, such a lower-bound estimate is insufficient to explain all aspects of the behavior of the textured material, where the matrix is not isotropic. In conclusion, it is hypothesized that relaxation processes which occur within the quenched microstructure during heating are responsible for the distinct thermal expansion behavior observed during the initial heating cycle compared to cooling and subsequent cycling.

36 MATERIALS SCIENCE↗
NASA NTRS2006

Effect of Thermomechanical Processing on the Microstructure, Properties, and Work Behavior of a Ti50.5 Ni29.5 Pt20 High-Temperature Shape Memory Alloy

TiNiPt shape memory alloys are particularly promising for use as solid state actuators in environments up to 300 C, due to a reasonable balance of properties, including acceptable work output. However, one of the challenges to commercializing a viable high-temperature shape memory alloy (HTSMA) is to establish the appropriate primary and secondary processing techniques for fabrication of the material in a required product form such as rod and wire. Consequently, a Ti(50.5)Ni(29.5)Pt20 alloy was processed using several techniques including single-pass high-temperature extrusion, multiple-pass high-temperature extrusion, and cold drawing to produce bar stock, thin rod, and fine wire, respectively. The effects of heat treatment on the hardness, grain size, room temperature tensile properties, and transformation temperatures of hot- and cold-worked material were examined. Basic tensile properties as a function of temperature and the strain-temperature response of the alloy under constant load, for the determination of work output, were also investigated for various forms of the Ti(50.5)Ni(29.5)Pt20 alloy, including fine wire.

Noebe, Ronald↗
NASA NTRSDate not supplied

Coarsening Up: Expanding the Particle Size Distributions of Lunar Simulants to Encompass A Comprehensive Range of Regolith Granularity

Due to a paucity of lunar regolith samples, simulated granular materials (simulants) have been developed and deployed for a variety of engineering and research purposes in an attempt to meet the requirements for lunar exploration. Broadly speaking, these manufactured materials aim to replicate the compositional (i.e., mineralogy and chemistry) and physical (e.g., particle size distribution, particle shape) profiles of lunar soil samples collected during the Apollo missions. While creating a “near-perfect” lunar simulant is prohibitive due to the unique formative processes (i.e., meteorite impacts, solar wind implantation) and conditions (anhydrous, reducing environment and exposure to radiation on the surface over billions of years) encountered on the moon, certain granular properties of the regolith can be recreated with a high level of fidelity by leveraging contemporary technologies. A fundamental physical property and descriptor, grain size can be correlated between samples and replicated through processing; however, a holistic understanding of the particle size distribution of lunar regolith must be considered when creating analog materials. This study produces particle size distributions for Apollo 16 returned samples, incorporating the sieved out >1 cm coarse-grained fraction, in order to provide a more comprehensive characterization of surficial lunar regolith grain sizes for the development of highlands-type granular analog testing materials.

R. N. Kovtun↗
DOE OSTI2020

High-throughput experimentation for microstructural design in additively manufactured 316L stainless steel

In the present study, a combination of high-throughput (HT) and low-throughput (LT) techniques was used to rapidly determine the processing window and generate processing maps for Selective Laser Melting (SLM) of 316L stainless steel. The HT method includes the fabrication of hundreds of hex nut-shaped specimens, each processed with a unique combination of laser power, scanning speed, and hatch spacing. An easily removable scaffolding permitted rapid sample extraction from the base plate, thus saving machining cost and time. Hardness and immersion density measurements were used for HT characterization to identify a processing window for maximum strength and density. Within the defined processing window, a low-throughput (LT) microstructural interrogation of specimens were performed. The microstructural analysis included quantification at various length scales (i.e., grains size and morphology, texture, primary dendrite arm spacing, and melt pool geometry analysis). Microstructure-based processing maps as a function of volumetric energy density were generated. The combination of HT and LT methods produced a predictive relationship between hardness and primary dendrite arm spacing using a Hall-Petch relationship. A model is proposed to explain the dependence of microstructure on the melt pool geometry. Here, the HT method can be applied for the microstructural design of SLM-fabricated components in other alloys.

316L stainless steel↗
NASA NTRS1997

Original Size and Shape of the Sudbury Structure

This paper presents new evidence bearing on the original size and shape of the Sudbury impact structure. Current opinion is almost unanimous that the structure is a multiring basin with an original diameter of about 200 km and a circular shape that has since been shortened in a northwest-southeast direction by Penokean deformation Evidence for this interpretation, collected chiefly from north of the Sudbury Igneous Complex (SIC), includes supposed outer rings on Landsat imagery, distant occurrences of "Sudbury breccia" (generally defined as pseudotachylite), shatter cone occurrences, and outliers of Huronian sedimentary rock thought to be down-faulted rings. New data from imaging radar and field work north of the SIC, however, contradict this evidence. Radar imagery shows no signs of the supposed outer rings mapped by earlier workers on Landsat images. The most prominent ring has been found to be a chance alignment of two independent fracture sets. Radar imagery from the CCRS Convair 580, with look direction almost normal to the north rim of the SIC, shows no evidence of the rings despite strong look azimuth highlighting. Radar imagery has shown many unmapped diabase dikes north of the SIC. Several exposures of supposed Sudbury breccia are associated with these dikes or with Nipissing diabase intrusions, in some cases actually inside the dikes or directly continuous with them. They appear to be igneous intrusion breccias with no relation to impact. Shock-wave interaction at lithologic contacts cannot be invoked for most of these, because they are part of a northwest trending swarm cutting the SIC in the North Range, and hence too young for an impact origin. Similar diabase-related breccias and pseudotachylite-like veins have been found far outside the Sudbury area between Chapleau and Thessalon. Shatter cones north of the SIC are few and poorly developed, perhaps due to the coarse-grained Footwall rock, and cannot be considered a continuous zone analogous to their occurrence on the South Range in Huronian rocks. Supposed down-faulted outliers of Huronian rocks north of the SIC show no consistent relation to faulting, and the Huronian/Archean contact is locally erosional. Radar imagery and field-checking confirm Rousell's conclusion that the North Range has undergone little or no Penokean deformation. T'his implies that the plan view outline of the crater (floor of the SIC) is original. Extrapolation of the North Range as part of a circular arc leads to an impossibly great diameter. It is concluded that although Penokean deformation largely accounts for the structure's shape, the original crater was not circular and was much smaller than 200 km across.

Lowman, P. D., Jr.↗