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At least 613 records · Page 34
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

The dispersed fluorescence spectrum of NaAr - Ground and excited state potential curves

Potential curves for the ground state and the first excited state of NaAr were determined. The van der Waals molecule NaAr was prepared by supersonic free jet expansion of a mixture of sodium, argon, and helium. The electronic transition from the ground state to the first excited state A2pi was excited by a tunable dye laser and the resulting fluorescence was studied. The dispersed fluorescence spectra show discrete and diffuse features, corresponding to transitions from excited vibrational levels of the A state to bound and unbound levels of the x state. The characteristic reflection structure in the bound-free spectra permits an unambiguous assignment of the vibrational numbering in the A state, and this assignment together with previously measured spectroscopic constants are used to calculate the potential curve of the A state. The discrete structure in the fluorescence spectra is used to determine the potential curve of the x state in the well region, and the repulsive part of the X curve is then deduced through trial-and-error simulation of the bound-free spectra.

Tellinghuisen, J.↗
NASA NTRS1979

Airborne laser induced fluorescence system for measuring OH and other trace gases in the parts-per-quadrillion to parts-per-trillion range

Described in detail is a laser induced fluorescence system which has been successfully interfaced with two aircraft sampling platforms (i.e., Sabreliner jet and an L-188C Electra). This system, which has been under development for four years, presently consists of the following major components: (1) a Nd-Yag laser driven oscillator-amplifier dye laser; (2) a sampling manifold with associated fluorescence detection optics; (3) an OH calibration chamber; (4) a laser beam steering assembly; and (5) sampling electronics and data processing hardware. During the last three years, this system has been flown some 50,000 air miles making tropospheric OH radical measurements over the latitude range of 70 N to 57 S. OH concentrations measured during these flights have ranged from 30 parts-per-quadrillion (3.7 x 10 to the 5th molecules/sq cm) at altitudes of 6 km to 0.8 parts-per-trillion (2.0 x 10 to the 7th molecules/sq cm) at 0.5 km. Computations have been completed which indicate that the existing aircraft system with modest modifications should also be capable of detecting natural tropospheric levels of NO, SO2, CH2O, NO2, HNO2, NO3, H2O2 and CS2 by using both conventional laser-induced fluorescence methodology and multiphoton techniques.

Davis, D. D.↗
NASA NTRS1981

Fluorescence equilibrium in the ultraviolet spectra of Comets Seargent (1978 m) and Bradfield (1979 l)

Detailed fluorescence calculations for OH including the Swings effect were performed. These calculations were used to reproduce the high resolution spectra of Comets Seargent and Bradfield taken with IUE. The calculations also provide the OH fluorescence efficiencies (g factors), as a function of heliocentric radial velocity, which are needed to derive OH abundances from measured fluxes. A close examination of the spectra shows no sign of the corresponding emission bands of OD allowing upper limits to be placed on the ratio N(OD)/N(OH). Preliminary attempts to reproduce the CO+ band structure by fluorescence are discussed.

Donn, B.↗
NASA NTRS1980

Photofragmentation-laser induced fluorescence - A new method for detecting atmospheric trace gases

A new method for the in situ detection of nonfluorescing molecular species is proposed: photofragmentation-laser induced fluorescence (PF-LIF). In this approach, the species to be detected is first laser photolyzed at a wavelength lambda (1), producing one or more vibrationally excited photofragments. Before vibrational relaxation occurs, one of these photofragments is pumped into a bonding excited state by a second laser pulse centered at wavelength lambda (2). Fluorescence is sampled at a wavelength lambda (3), where lambda (3) is less then lambda (2) and lambda (1). This pumping configuration thus permits massive discrimination against Rayleigh and Raman scattering as well as white noise fluorescence from the laser wavelengths lambda (1) and lambda (2). The technique should be both highly sensitive and selective for numerous atmospheric trace gases. Specific sampling schemes for detecting NO2, NO3, and HNO2 are proposed. Various noise sources and chemical interferences are discussed. Specific calculations that estimate the sensitivity of the PF-LIF system for detecting NO2, NO3, and HNO2 are given.

Rodgers, M. O.↗
NASA NTRS1980

Laboratory verification of the lunar orbital X-ray fluorescence experiment - Initial results

The combined use of remote sensing and returned sample chemical data in lunar studies presumes a direct link between the two types of data. Laboratory experiments have demonstrated that within the precision of the lunar orbital X-ray fluorescence data there is a direct relationship between the fluorescence K-series X-radiation emitted from Mg, Al and Si in the surfaces of lunar soil samples and the concentrations of these elements in the bulk soil samples. This relationship encompasses both mare and terra soils. The degree of maturity is not an important variable for the existing orbital X-ray data. It is argued that these results are directly applicable to the lunar surface analyzed by the Apollo orbital X-ray fluorescence experiment.

Hubbard, N.↗
NASA NTRS1981

Bowen fluorescence on the sun

An identification is made of a weak line in the high-resolution EUV solar spectrum, and the contribution of the Bowen fluorescence mechanism to line emission is considered. The line at 303.625 A is noted to coincide with the 2p 3d(3P2 0) - 2p2(3P1) transition of O III at 303.621 A, which could be excited by He II line excitation of the O III 2p2(3P2) - 2p 3d(3P2 0) transition at 303.799 A. Computations of the collisionally induced intensities of the 2p2(3P) - 2p3d(3P 0) multiplet are shown to result in values not observed in the solar spectrum, indicating that Bowen fluorescence, rather than collisional excitation, is the source of the line. The Bowen fluorescence mechanism is noted to have implications for the identification of other spectral lines, and for models of the solar corona.

Kastner, S. O.↗
NASA NTRS1981

Two-photon excitation of nitric oxide fluorescence as a temperature indicator in unsteady gasdynamic processes

A laser-induced fluorescence technique based on the pulsed two-photon excitation of NO is presented which is especially suited for the measurement of fluctuating temperatures in cold turbulent flows. The technique uses the fluorescence from the UV gamma bands of NO produced by two-photon excitation of NO (A 2 Sigma +, nu-prime = 0 - X 2 Pi, nu-double prime = 0) to obtain a rotational temperature. An analysis is presented of relevant aspects of the two-photon absorption process including microphysical processes, spectral intensities as a function of transition and laser spectral widths, line-shape integrals, the nonequilibrium response of the medium to a laser pulse, fluorescence energies, signal to noise ratio, and focusing effects. An analysis of absolute two-photon absorptivity measured in a nonflowing cell is then presented and used to predict signal to noise ratios greater than 50 for supersonic flows at temperatures below 300 K.

Mckenzie, R. L.↗
NASA NTRS1981

Lyman-alpha fluorescence from hydrogen photofragments of CH4 and H2O

The process of H-Lyman-alpha fluorescence produced through photodissociation of CH4 and H2O provides an example for the usefulness of the detection of fluorescence of dissociation fragments as an aid in identifying some high lying Rydberg states. In the first experiment reported, an electron storage ring synchrotron radiation source was used. The fluorescence produced was detected with a solar blind photomultiplier and a Cs photocathode with a spectral sensitivity in the wavelength range from 1050 to 1950 A. In the second experiment considered, an intense atomic line source was employed.

Wu, C. Y. R.↗
NASA NTRS1982

Model studies of nitric oxide fluorescence in the earth's backscattered spectrum

Fluorescent emissions from nitric oxide appear imposed upon the Rayleigh backscattered spectrum of the earth's atmosphere between 250 and 300 nm in wavelength. Satellite instruments designed to monitor the global ozone distribution can routinely observe these signals although techniques for exploiting the data are not yet available. Application of a radiative transfer equation developed for an atmosphere including absorption by ozone, molecular scattering, and nitric oxide fluorescence shows the three most prominent NO emissions relative to the 250-300 nm backscattered sunlight to be the (1,4), (1,6), and (0,3) gamma bands. Analysis of the contribution function for each emission band indicates that the fluorescent signals can provide useful information on the magnitude and variability of nitric oxide between 40 and 140 km in altitude.

Frederick, J. E.↗
NASA NTRS1983

Experimental feasibility of the airborne measurement of absolute oil fluorescence spectral conversion efficiency

Airborne lidar oil spill experiments carried out to determine the practicability of the AOFSCE (absolute oil fluorescence spectral conversion efficiency) computational model are described. The results reveal that the model is suitable over a considerable range of oil film thicknesses provided the fluorescence efficiency of the oil does not approach the minimum detection sensitivity limitations of the lidar system. Separate airborne lidar experiments to demonstrate measurement of the water column Raman conversion efficiency are also conducted to ascertain the ultimate feasibility of converting such relative oil fluorescence to absolute values. Whereas the AOFSCE model is seen as highly promising, further airborne water column Raman conversion efficiency experiments with improved temporal or depth-resolved waveform calibration and software deconvolution techniques are thought necessary for a final determination of suitability.

Hoge, F. E.↗
NASA NTRS1983

Fluorescence yield from photodissociation of CH4 at 1060-1420 A

The photoabsorption and fluorescence cross sections of CH4 were measured using synchrotron radiation at 1060-1420 A. The fluorescence starts to appear at 1330 A, and its cross section increases with decreasing photon wavelengths. The fluorescence cross section at 1060 A is 0.38 x 10 to the -18th sq cm, which is much smaller than the theoretical expectation. It is unlikely that the CH2 production from CH4 photodissociation will have a population inversion in the singlet system. A vibrational structure observed at 1060-1120 A is probably the 1t2-3p Rydberg transition of CH4.

Lee, L. C.↗
NASA NTRS1982

Atomic fluorescence study of high temperature aerodynamic levitation

Ultraviolet laser induced atomic fluorescence has been used to characterize supersonic jet aerodynamic levitation experiments. The levitated specimen was a 0.4 cm sapphire sphere that was separately heated at temperatures up to 2327 K by an infrared laser. The supersonic jet expansion and thermal gradients in the specimen wake were studied by measuring spatial variations in the concentration of atomic Hg added to the levitating argon gas stream. Further applications of atomic fluorescence in containerless experiments, such as ideal gas fluorescence thermometry and containerless process control are discussed.

Nordine, P. C.↗
NASA NTRS1983

Remote sensing of OH in the atmosphere using the technique of laser-induced fluorescence

The use of a laser-induced fluorescence technique for the sensitive measurement of the atmospheric hydroxyl radical is discussed. Results of laboratory studies of the fluorescence and other spectroscopic properties of OH which allow the calculation of OH concentrations from the returned signals for various altitudes, water vapor contents and temperatures are presented. The experimental setup used for airborne OH measurements is then described, with particular attention given to the use of a telescope for excitation and light collection in a coaxial configuration and the periodic tuning of the exciting radiation necessary to obtain an OH signal in the presence of strong solar and nonresonant fluorescence backgrounds. The best detection limit obtained to date with the system is noted to be about 700,000 OH/cu cm, and it is expected that, with planned improvements in detection and tuning schemes, limits in the neighborhood of 1,000,000 OH/cu cm will be achieved routinely.

Wang, C. C.↗
NASA NTRS1983

Feasibility of airborne detection of laser-induced fluorescence emissions from green terrestrial plants

The present investigation provides a demonstration of the feasibility of the airborne detection of the laser-induced fluorescence spectral emissions from living terrestrial grasses, shrubs, and trees using existing levels of lidar technology. Airborne studies were performed to ascertain system requirements necessary to detect laser-induced fluorescence from living terrestrial plants, to assess the practical acquisition of useful single-shot laser-induced fluorescence (LIF) waveforms over vegetative canopies, and to determine the comparative suitability of laser system, airborne platform, and terrestrial environmental parameters. The field experiment was conducted on May 3, 1982, over the northern portion of Wallops Island, VA. Attention is given to airborne lidar results and the description of laboratory investigations.

Hoge, F. E.↗
NASA NTRS1982

Fluorescent discharge lamp

A rapidly illuminating fluorescent lamp 1,200 mm long and 32.5 mm in diameter with an interior conducting strip which is compatible with conventional fixtures and ballasts is described. The fluorescent lamp is composed of a linear glass tube, electrodes sealed at both ends, mercury and raregas sealed in the glass tube, a fluorescent substance clad on the inner walls of the glass tube, and a clad conducting strip extending the entire length of the glass tube in the axial direction on the inner surface of the tube.

Mukai, E.↗
NASA NTRS1983

Comments on laser-excited fluorescence of the hydroxyl radical: Relaxation coefficients at atmospheric pressure, appendix 5

The lifetime of the excited state of a atom or molecule is often determined from the rate of fluorescence decay originating as a function of buffer gas pressure, an accurate determination is made of the rates of collision induced transitions away from the excited state. Deconvolution can in principle be employed to resolve fluorescence times shorter than the response times of the system. However, attainable reproducibility and accuracy in actual experiments usually set a limit beyond which no meaningful results are expected. Prudence thus dictates that the results of deconvolution be viewed with extreme caution whenever fluorescence time much shorter than the response of times of the system are indicated.

Wang, C. C.↗
NASA NTRS1984

Fluorescence from photofragments as an aid in identifying new molecular states - The N2 case

Synchrotron radiation has been used to measure the excitation function for producing fluorescence in the 1050-1800 A region through photodissociative excitation of N2 in the 400-620 A region and the photoabsorption cross section of N2 in the 600-670 A region. From the fluorescence excitation function there is found (1) a molecular state(s) in the 21-22.5 eV region which has not been observed in absorption and photoionization spectra, (2) structures which correlate with known two-electron excited Rydberg states, and (3) a decrease in fluorescence cross section at photon energies greater than 23.8 eV, which indicates the existence of new competing processes. The observed molecular state(s) as well as the weak absorption structure in the 19-21 eV region are tentatively assigned as a Rydberg series leading to the D2Pi(g) of N2(+). The newly observed Rydberg states in the 21-22.5 eV region may account for the unusual behavior recently reported in photoelectron spectroscopy results.

Wu, C. Y. R.↗
NASA NTRS1984

Spectrum of squeezing in resonance fluorescence

A spectral analysis of the squeezing in resonance fluorescence is accomplished via a study of a phase sensitive correlation function. In the case of resonance fluorescence from a two-level system, the initial state is a coherent state for the laser mode, a vacuum for the other states of the radiation field, and the atoms in the lower level. Maximum squeezing for resonance excitation is obtained for near resonant frequencies of the fluorescent light. Possible experimental configurations are discussed in order to detect spectral squeezing.

Collett, M. J.↗