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At least 613 records · Page 34

Validation of the Porous Medium Approximation for Hydrodynamics Analysis in Compact Heat Exchangers

Compact heat exchangers (HXs) have gained attention in recent years in various fields such as solar and nuclear power generation, oil and gas, and refrigeration due to their low cost, high power density, and robustness in high-pressure and/or high-temperature environments. However, the large difference between a compact HX's overall dimensions (~m) and the much smaller scale of its channels (~mm) makes it challenging to model the entire HX at once, due to computational limitations. In this work, we treat the channeled region of a compact HX as a porous medium (PM) to circumvent the need to model/mesh each individual channel. This allows us to simulate the entire HX, including both the header and channeled regions while maintaining the computational cost at a practical level. Although the porous medium approach has been used to model heat exchangers, its validity is still questionable because (1) the resistance coefficients are heavily data-based and thus difficult to be applied to new heat exchangers and (2) the validation has been focused on matching the overall pressure drop in the channel region, which does not address whether such model can predict detailed pressure and velocity field. For the first time, this work addresses under what circumstances and with what uncertainty does the PM approach work for hydrodynamics modeling in compact HXs. By answering these questions, we introduce the PM approach as a powerful tool for HX hydrodynamics modeling that can predict not only the overall pressure drop but also the detailed pressure and velocity distributions.

Engineering↗

A Microchannel Heat Exchanger Produced From a Metal Matrix Composite by Hybrid Laser Powder Bed Fusion and Inkjet Printing

Abstract This paper explores the production of an oxide dispersion strengthened (ODS) 304L stainless steel microchannel heat exchanger (HX) using a hybrid additive manufacturing process of laser powder bed fusion and inkjet printing. The study investigates the capabilities and economics of the hybrid inkjet-laser powder bed fusion (LPBF) process and evaluates the dimensional accuracy, functionality, and mechanical properties of the resulting ODS alloy. The effectiveness and pressure drop of the ODS heat exchangers produced by the hybrid LPBF tool are also determined. Results show that the inkjet-doped samples have a lower mean channel height with higher standard deviation than samples produced by LPBF alone. This is attributed to greater absorption of laser energy for the powder coated with the oxide precursor. The economic analysis shows that the hybrid process has a potential for reducing the unit cost of the heat exchanger based on cost modeling assumptions.

Engineering↗

Joining Techniques for Novel Metal Polymer Hybrid Heat Exchangers

In the United States, over 50% of the unrecovered energy from industrial processes is in the form of low-grade heat (< 220°C). Materials and maintenance costs of common heat exchangers are typically too high to justify their usage. Polymers, though more affordable, are usually unsuitable for HX applications due to their low thermal conductivity (~0.2 W/mK). Here, we show that metal-polymer hybrids may be attractive from both performance and cost perspectives. The use of polymers further increases the resistance to corrosion by sulfuric and carbonic acids often present in flue gases. An ongoing work explores different configurations of layered polyimide-copper macroscale hybrids for heat exchanger applications using numerical simulations. This paper explores a manufacturing pathway for producing such layered hybrid tubes that involves directly rolling and bonding tapes made of polymer and copper foil into tubes. A critical problem in the fabrication process is the bonding of metal and polymers. We explore approaches involving adhesives (epoxy, acrylic and silicone) for metal/polymer interfaces and direct welding (ultrasonic) for metal/metal interfaces that can be integrated into the manufacturing process. We report characterizations of the thermomechanical properties of these joining processes. This work paves the way for realizing cost-effective manufacturing of heat exchangers for low grade waste heat recovery.

Kuntumalla, Gowtham↗

Species-specific ribosomal RNA-FISH identifies interspecies cellular-material exchange, active-cell population dynamics and cellular localization of translation machinery in clostridial cultures and co-cultures

ABSTRACT The development of synthetic microbial consortia in recent years has revealed that complex interspecies interactions, notably the exchange of cytoplasmic material, exist even among organisms that originate from different ecological niches. Although morphogenetic characteristics, viable RNA and protein dyes, and fluorescent reporter proteins have played an essential role in exploring such interactions, we hypothesized that ribosomal RNA-fluorescence in situ hybridization (rRNA-FISH) could be adapted and applied to further investigate interactions in synthetic or semisynthetic consortia. Despite its maturity, several challenges exist in using rRNA-FISH as a tool to quantify individual species population dynamics and interspecies interactions using high-throughput instrumentation such as flow cytometry. In this work, we resolve such challenges and apply rRNA-FISH to double and triple co-cultures of Clostridium acetobutylicum, Clostridium ljungdahlii, and Clostridium kluyveri . In pursuing our goal to capture each organism’s population dynamics, we demonstrate dynamic rRNA, and thus ribosome, exchange between the three species leading to the formation of hybrid cells. We also characterize the localization patterns of the translation machinery in the three species, identifying distinct, dynamic localization patterns among them. Our data also support the use of rRNA-FISH to assess the culture’s health and expansion potential, and, here again, our data find surprising differences among the three species examined. Taken together, our study argues for rRNA-FISH as a valuable and accessible tool for quantitative exploration of interspecies interactions, especially in organisms which cannot be genetically engineered or in consortia where selective pressures to maintain recombinant species cannot be used. IMPORTANCE Though dyes and fluorescent reporter proteins have played an essential role in identifying microbial species in co-cultures, we hypothesized that ribosomal RNA-fluorescence in situ hybridization (rRNA-FISH) could be adapted and applied to quantitatively probe complex interactions between organisms in synthetic consortia. Despite its maturity, several challenges existed before rRNA-FISH could be used to study Clostridium co-cultures of interest. First, species-specific probes for Clostridium acetobutylicum and Clostridium ljungdahlii had not been developed. Second, “state-of-the-art” labeling protocols were tedious and often resulted in sample loss. Third, it was unclear if FISH was compatible with existing fluorescent reporter proteins. We resolved these key challenges and applied the technique to co-cultures of C. acetobutylicum , C. ljungdahlii , and Clostridium kluyveri . We demonstrate that rRNA-FISH is capable of identifying rRNA/ribosome exchange between the three organisms and characterized rRNA localization patterns in each. In combination with flow cytometry, rRNA-FISH can capture sub-population dynamics in co-cultures.

Hill, John D.↗

Determination of two-photon exchange via $$e^+p/e^-p$$ scattering with CLAS12

The proton elastic form factor ratio shows a discrepancy between measurements using the Rosenbluth technique in unpolarized beam and target experiments and measurements using polarization degrees of freedom. The proposed explanation of this discrepancy is uncorrected hard two-photon exchange (TPE), a type of radiative correction that is conventionally neglected. The effect size and agreement with theoretical predictions has been tested recently by three experiments. While the results support the existence of a small two-photon exchange effect, they cannot establish that theoretical treatments are valid. At larger momentum transfers, theory remains untested. This proposal aims to measure two-photon exchange over an extended and so far largely untested $Q^2$ and $\varepsilon$ range with high precision using the {\tt CLAS12} experiment. Such data are crucial to clearly confirm or rule out TPE as the driver for the discrepancy as well as test several theoretical approaches, believed valid in different parts of the tested $Q^2$ range.

Bernauer, Jan C.↗

Influence of Supporting Electrolyte on Hydroxide Exchange Membrane Water Electrolysis Performance: Catholyte

Alkaline or hydroxide exchange membrane water electrolysis (HEMWE) is a promising technology for green hydrogen production using platinum group metal-free catalysts and stainless steel, an advantage of alkaline water electrolysis (AWE), and a gas-impermeable membrane, a parallel to proton exchange membrane electrolysis (PEMWE). However, the HEMWE requires supporting electrolytes and there is minimal understanding of their role on the respective reactions. Without SELs, HEMWE performance and durability are worse than PEMWE systems. Herein, consistently feeding potassium hydroxide anolyte, we systematically study the effects of catholyte SELs in HEMWEs including dry vs. wet operation, cation effects, anion effects, and cation/OH ratios on cell potential and stability. We report that (i) hydration of the cathode improves high current density operation by preventing dehydration of the hydroxide exchange membrane (HEM), (ii) there was no correlation between cation type and cell potential, (iii) cell potential and high frequency resistance did not correlate with SEL conductivity, (iv) cathodic carbonate SEL had a significant negative effect on cell performance, (v) increased cation/OH ratio also caused increased cell potentials. Overall, this study concludes that feeding water or potassium hydroxide solution is desirable to improve the AEMWE performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Ionomer Optimization for Hydroxide-Exchange-Membrane Water Electrolyzers Operated with Distilled Water: A Modeling Study

The hydroxide-exchange-membrane water electrolyzer (HEMWE) is a promising means to store intermittent renewable energy in the form of hydrogen chemical energy. The hydroxide-exchange ionomer (HEI) in the gas-evolving electrodes and the hydroxide-exchange membrane (HEM) are key components of HEMWE. In this work, we simulate the cell and examine explicitly the impact of HEI and HEM properties with a focus on improving HEMWE performance when operated with distilled water ( i.e ., no supporting electrolyte). The tradeoff between the ionic conductivity gain and electrochemically active surface area (ECSA) loss is studied. For a constant catalyst loading, distributing more catalyst next to the HEM or making thinner but denser catalyst layer is beneficial for HEMWE performance. The results demonstrate that a higher water diffusion coefficient is desired for HEM to supply reactant water to the cathode. In contrast, a lower water diffusion coefficient is preferred for the cathode HEI to retain the water in the regions with high reaction rates. Overall, the findings provide important insights to optimizing HEI/HEM materials for improved HEMWE performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Modeling Sorption of Water and Vanadium Cations by Ion-Exchange Membranes

We develop a macroscopic model for sorption of ions and solvent by ion-exchange membranes and use it to investigate how different membranes behave when exposed to electrolytes for vanadium flow batteries. The model combines a classical expression for the Gibbs free energy of a moderately concentrated electrolyte containing several ions with a term that describes elastic swelling of a polymer membrane. Parameters describing pairwise interactions between mobile ions and fixed membrane ions were fit to published experimental data and discussed in the context of the competition for sites in ion-exchange membranes. The model provides insights into why sorption of vanadium cations by Nafion is lower than predicted by Donnan theory and why switching to an anion-exchange membrane does not dramatically reduce vanadium sorption.

Electrochemistry↗

Atmospheric Variability Drives Anomalies in the Bering Sea Air–Sea Heat Exchange

Abstract High latitudes, including the Bering Sea, are experiencing unprecedented rates of change. Long-term Bering Sea warming trends have been identified, and marine heatwaves (MHWs), event-scale elevated sea surface temperature (SST) extremes, have also increased in frequency and longevity in recent years. Recent work has shown that variability in air–sea coupling plays a dominant role in driving Bering Sea upper-ocean thermal variability and that surface forcing has driven an increase in the occurrence of positive ocean temperature anomalies since 2010. In this work, we characterize the drivers of the anomalous surface air–sea heat fluxes in the Bering Sea over the period 2010–22 using ERA5 fields. We show that the surface turbulent heat flux dominates the net surface heat flux variability from September to April and is primarily a result of near-surface air temperature and specific humidity anomalies. The airmass anomalies that account for the majority of the turbulent heat flux variability are a function of wind direction, with southerly (northerly) wind advecting anomalously warm (cool), moist (dry) air over the Bering Sea, resulting in positive (negative) surface turbulent flux anomalies. During the remaining months of the year, anomalies in the surface radiative fluxes account for the majority of the net surface heat flux variability and are a result of anomalous cloud coverage, anomalous lower-tropospheric virtual temperature, and sea ice coverage variability. Our results indicate that atmospheric variability drives much of the Bering Sea upper-ocean temperature variability through the mediation of the surface heat fluxes during the analysis period. Significance Statement A long-term ocean warming trend and a recent increase in marine heatwaves in the Bering Sea have been identified. Previous work showed that anomalies in the exchange of heat between the ocean and the atmosphere were the primary driver of Bering Sea temperature variability, but the processes responsible for the heat exchange anomalies were unknown. In this work, we show that the atmosphere is the primary driver of anomalies in the Bering Sea air–sea heat exchange and therefore plays an important role in altering the thermal state of the Bering Sea. Our results highlight the importance of understanding more about how the ocean and the atmosphere interact at high latitudes and how this relationship will be affected by future climate change.

Hayden, Emily E. [a College of Earth, Ocean, and A↗

ESS-DIVE reporting format for leaf-level gas exchange data and metadata

Here we present documentation of the ESS-DIVE reporting format for leaf-level gas exchange data and metadata. This reporting format provides guidance to data contributors on how to store data to maximize their discoverability, facilitate their efficient reuse, and add value to individual datasets. For data users, the reporting format will better allow data repositories to optimize data search and extraction, and more readily integrate similar data into harmonized synthesis products. The reporting format specifies data table variable naming and unit conventions, as well as metadata characterizing experimental conditions and protocols. For common data types that were the focus of this initial version of the reporting format, i.e., survey measurements, dark respiration, carbon dioxide and light response curves, and parameters derived from those measurements, we took a further step of defining required additional data that would maximize the potential reuse of those data types. To aid data contributors and the development of data ingest tools by data repositories we provided a translation table comparing the outputs of common gas exchange instruments. The reporting format presented here is intended to form a foundation for future development that will incorporate additional data types and variables as gas exchange systems and measurement approaches advance in the future. The reporting format documentation is maintained and updated on the ESS-DIVE Community Space GitHub. This data package is the first published version of this reporting format, and comprises a zip file of the complete content of https://github.com/ess-dive-community/essdive-leaf-gas-exchange v1.0. The zip contains the reporting format description, guidelines, variable tables and instructions in GitHub markdown language (*.md) and 2 metadata templates as spreadsheets with drop down options (*.xlsx files, also function in GoogleSheets).

54 ENVIRONMENTAL SCIENCES↗

Leaf gas exchange data, Nov 2018 and May 2019, Daintree Rainforest, Australia

This data package contains leaf gas exchange data for 11 canopy tree species in the control and drought treatments at the Daintree Rainforest Observatory in Queensland, Australia (AU-DRO) with the purpose of testing for differences in gas exchange between treatments. Data were collected at the end of the dry season (November 2018) and end of the wet season (May 2019). Using a canopy crane, large branches (>1 m) were collected from the top of the canopy and immediately placed in a bucket of water, upon which the LI-6800 leaf chamber was clamped onto a recently mature leaf with minimal herbivory. Measurements were recorded every 3 seconds for 3 minutes total. The species included in the dataset are: Castanospermum australe, Cleistanthus myrianthus, Cryptocarya mackinnoniana, Dysoxylum papuanum, Elaeocarpus angustifolius (Elaeocarpus grandis), Endiandra microneura, Mallotus paniculatus, Myristica globosa, Rockinghamia angustifolia, Synima cordierorum, Syzygium spp. The two data files included are: 1. LICOR_Data_AU_DRO_2019_GasEx.csv (a compilation of individual LICOR output files, with correction of user input errors such as incorrect species spelling) 2. ESS_DIVE_Data_AU_DRO_2019_GasEx.csv (selected variables and converted units from LICOR_Data_AU_DRO_2019_GasEx.csv to follow the standard gas exchange reporting format from Ely et al. 2021 Ecological Informatics). The metadata files included are: (3) ESS_DIVE_Metadata_AU_DRO_2019_GasEx.xlsx (4) File_Submission_Metadata_AU_DRP_2019_GasEx.xlsx (5) E-Field_Log_AU_DRO_2019_GasEx.xlsx (6) Data_Column_Description_AU_DRO_2019_GasEx.xlsx.

54 ENVIRONMENTAL SCIENCES↗

Leaf gas exchange and fitted parameters, San Lorenzo, Panama, 2020

This data package contains photosynthetic CO2 response curves (ACi curves), light response curves (AQ curves), dark adapted dark respiration, conductance curves, and survey measurements for leaves measured at the San Lorenzo forest canopy crane site, Panama (PA-SLZ) from January to March 2020. Leaves were sampled from both the top of the canopy and multiple heights within the canopy from 10 vertical profiles and included around 50 species. In addition, six core species were also measured, from the top of the canopy. Fitted maximum carboxylation rate (Vcmax), maximum electron transport rate (Jmax), and triose phosphate utilization rate (TPU) were derived from measured data as well as the convexity, light use efficiency, apparent quantum yield, and Rdark. The measurements can also be used to derive the conductance parameters g0 and g1 of stomatal model. All the gas exchange data and metadata are presented in .csv files and complete instrument output are included in .zip folders. Data and metadata meet the ESS-DIVE leaf-level gas exchange reporting format requirements. The protocol details are provided as pdf documents. In addition to gas exchange data described here these samples were also used for measurement of leaf optical properties, carbon and nitrogen content, and leaf mass per unit leaf area (LMA) these data can be cross linked using the unique sample ID and are provided in separate related data packages. Sample information including canopy elevation and leaf area index (LAI) can be found in the related “Leaf and canopy traits” data package.

54 ENVIRONMENTAL SCIENCES↗

Leaf gas exchange and fitted parameters, two sites in Panama, 2022

Photosynthetic CO2 response curves (ACi curves), light response curves (AQ curves), dark adapted dark respiration, conductance curves, and survey measurements for leaves measured in the Parque Natural Metropolitano (PNM) and Gamboa, Panama, from January to April 2022 are presented. Measurements were made on leaves from 46 different tree, shrub and liana species, from sunlit canopy and understory locations. Leaf area index from 8 vertical profiles at PNM are also included. The aim of this measurement campaign was three-fold: (i) to improve our understanding of the vertical variation in leaf-level water use efficiency; (ii) to develop an understanding of the sensitivity of stomata to changes in environmental conditions, especially light, humidity, and temperature; (iii) to improve models which can predict leaf traits from leaf contact spectral measurements. All the gas exchange data and metadata are presented in .csv files and complete instrument output are included in .zip folders. Data and metadata meet the ESS-DIVE leaf-level gas exchange reporting format requirements. The protocol details are provided as pdf documents. In addition to gas exchange data reported here these samples were also used for measurement of leaf optical properties, carbon and nitrogen content, and leaf mass per unit leaf area (LMA). These data can be cross linked using the unique sample ID and are provided in separate data packages.

54 ENVIRONMENTAL SCIENCES↗

High flux boiling heat transfer enhancement using triangle shaped vertical walls in two-phase microchannel heat exchangers

Two-phase heat exchangers allow heat loads to be dissipated with lower fluid flow rates without inducing thermal gradients, and high surface area microchannels further reduce the thermal resistance of these heat exchangers. However, there are many practical limits that prevent widespread use of two-phase microchannel heat exchangers. Many authors have looked to address these practical limits by treating the channel floors or creating artificial nucleation sites. Few works look to enhance heat transfer in the walls of channels with hydraulic diameters below 200 μm. This work is aimed at increasing the efficacy of high aspect ratio silicon microchannels that use R134a as the working fluid. The 125 parallel channels are 40 μm wide, 200 μm deep, and 2 mm long and contain a 15 μm wide, 150 μm long restriction at each inlet. The thermal resistance and dryout characteristics of traditional, plain-walled channels are compared to channels with 2 area enhancement patterns each of which increases the area available for heat transfer by 41%. Furthermore, a resistance to dryout is seen in both area-enhanced test sections, and a 15.5% reduction in thermal resistance is shown for the area-enhanced part with a 6 μm triangular pitch. Only a 7.8% performance increase is seen in the test section with a 3 μm pitch. Both area enhancement patterns induce an average 27% increase in pressure drop for all tests. Heat transfer characteristics are solved for using a finite element analysis (FEA) model. By examining heat transfer coefficients and local heat fluxes, it is postulated that the area enhancement reduces heat transfer coefficients and the performance increase is caused by increasing the number of active nucleation sites.

42 ENGINEERING↗

Advancements Toward ASME Nuclear Code Case for Compact Heat Exchangers

Our research team proposes to advance the state of the ASME section III code (nuclear service) for Compact Heat Exchangers (CHX). This work will improve the technical state of CHXs and lay the foundation necessary for these heat exchangers to be certified for use in nuclear service. During the course of this work, we will advance the understanding of the performance, integrity, and lifetime of the CHXs for use in any industrial application, making their use more attractive and accessible to the industry. We will do this by developing qualification and inspection procedures that utilize Non-destructive evaluation (NDE) and advanced in-service inspection techniques, with insight from the industrial utility leader EPRI. We have enlisted colleagues at MPR Associates (MPR), an elite nuclear code consulting firm, who are experts on the ASME section III code and who, with input from members of the ASME section III committee, will direct the testing and help develop a series of documents that define the rules and regulations for use of the CHX. Colleagues at North Carolina State University (NCSU) and Oregon State University (OSU) will conduct extensive tensile, creep, and fatigue experiments on diffusion bonded samples (manufactured by US-based Vacuum Process engineering) along with modeling using the elastic perfectly plastic assumptions and comprehensive full inelastic finite element analysis (FEA). This work will allow analysis by design and confidence in the strength of different internal structures. To ensure industry acceptance and long term confidence, team members at the University of Wisconsin–Madison (UW), University of Michigan (UM), Georgia Tech (GT), and the University of Idaho (UI) will extensively test prototypic heat exchangers manufactured by US-based manufactures CompRex and Vacuum Process Engineering (VPE), a leader in the development of advanced CHX. This testing will include the use of various working fluids (salt, sodium, helium, and sCO2) to evaluate operational issues as well as structural integrity under the most severe conditions. Post-test analysis of the tested CHXs coupled with pre/in-service/post NDE (ultrasonic and radiography) led by the Electric Power Research Institute (EPRI) will be incorporated into the development of the rules and regulations for their use in nuclear service.

42 ENGINEERING↗

Surface Roughness Effects on Heat Transfer in Additively Manufactured sCO 2 Cycle Heat Exchangers

An experimental study was performed to consider the impact of surface roughness on heat transfer and pressure drop to supercritical carbon dioxide (sCO 2 ) in additively manufactured channels. All tests were performed in the Heat Exchange and Experimental Testing (HEET) rig at the U.S. Department of Energy’s (DOE) National Energy Technology Laboratory (NETL) in Morgantown, West Virginia. Four test articles were considered. The first was a hydrodynamically smooth, drawn tube. The other three were additively manufactured channels with square and rectangular cross sections, which were characterized by sand-grain roughness to hydraulic diameter ratios spanning 0.0029 to 0.0073. Friction factors were determined by measuring the tube mass flow rate and pressure drop. The tube side heat transfer coefficient was measured using the Wilson plot technique. It was found that the friction factor results were 8% greater than the Colebrook correlation. Greater deviation was observed between the heat transfer results and the correlations. The Gnielinski correlation overpredicted the experimental points by nominally 30% and the Norris correlation overpredicting the experimental points by nominally 25%. A thermal performance factor was formed from the friction factor augmentation and Nusselt number augmentation results. These results indicated a 10% improvement in heat duty for a heat exchanger constructed utilizing a tube with ϵ/D_h =0.0073 relative to a heat exchanger utilizing a smooth, conventional tube.

36 MATERIALS SCIENCE↗

On-Line Lead/Water Heat Exchanger Sensor/System Feasibility: CRADA 462 [Abstract Only]

The purpose of this project is to develop and demonstrate the feasibility of a high-temperature sensor for on-line structural health monitoring (OLSHM) of the novel heat exchanger tubes in the Hydromine lead cooled reactor. The high temperature sensor takes advantage of the Hydromine heat exchanger tube design that has a relatively cool inlet temperature (~ 350 °C) and the tube ends are in an Argon gas blanket rather than being submerged in a corrosive fluid and the tube ends are conveniently accessible from the periphery of the heat exchanger shell.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Solvent Exchange

This report summarizes the work of evaluating the chemical stability of phosphoramidic acid, N-N-diethyl-, bis(2-ethylhexyl) ester under the Solvent Exchange LDRD project, as a potential solvent exchange chemistry and analog to solvent exchange chemistries used in the TALSPEAK and ALSEP processes as alternatives to the use of tri-butyl phosphate in the PUREX process.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗