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Results for “diffusion behavior”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 613 records · Page 34

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NASA NTRS1990

NASA/DOD Aerospace Knowledge Diffusion Research Project. Paper 1: The value of scientific and technical information (STI), its relationship to Research and Development (R/D), and its use by US aerospace engineers and scientists

This paper is based on the premise that scientific and technical information (STI), its use by aerospace engineers and scientists, and the aerospace research and development (R&D) process are related. We intend to support this premise with data gathered from numerous studies concerned with STI, the relationship of STI to the performance and management of R&D activities, and the information use and seeking behavior of engineers in general and aerospace engineers and scientists in particular. We intend to develop and present a synthesized appreciation of how aerospace R&D managers can improve the efficacy of the R&D process by understanding the role and value of STI in this process.

Pinelli, Thomas E.↗

NASA NTRS1973

Study of liquid-solid transition for materials processing in space. Analysis of field effects on dense liquid materials

The behavior of dense liquids near the solidification point under the influence of magnetic fields or near-zero gravity conditions were analyzed within the framework of existing liquid state models and classical field theory. The dynamic body forces which are an effect of the magnetic field on liquids are discussed. It is concluded that both magnetic fields and low gravity conditions produce an increase in the diffusion coefficient which result in an increased growth rate of crystals, and time varying magnetic fields induce eddy currents in the liquid which produce body forces and tend to disrupt convection.

Miller, R. I.↗

NASA NTRS2007

Oxidation of C/SiC Composites at Reduced Oxygen Partial Pressures

T-300 carbon fibers and T-300 carbon fiber reinforced silicon carbide composites (C/SiC) were oxidized in flowing reduced oxygen partial pressure environments at a total pressure of one atmosphere (0.5 atm O2, 0.05 atm O2 and 0.005 atm O2, balance argon). Experiments were conducted at four temperatures (816deg, 1149deg, 1343deg, and 1538 C). The oxidation kinetics were monitored using thermogravimetric analysis. T-300 fibers were oxidized to completion for times between 0.6 and 90 h. Results indicated that fiber oxidation kinetics were gas phase diffusion controlled. Oxidation rates had an oxygen partial pressure dependence with a power law exponent close to one. In addition, oxidation rates were only weakly dependent on temperature. The C/SiC coupon oxidation kinetics showed some variability, attributed to differences in the number and width of cracks in the SiC seal coat. In general, weight losses were observed indicating oxidation of the carbon fibers dominated the oxidation behavior. Low temperatures and high oxygen pressures resulted in the most rapid consumption of the carbon fibers. At higher temperatures, the lower oxidation rates were primarily attributed to crack closure due to SiC thermal expansion, rather than oxidation of SiC since these reduced rates were observed even at the lowest oxygen partial pressures where SiC oxidation is minimal.

Opila, E. J.↗

NASA NTRS1993

Heterodyne efficiency for a coherent laser radar with diffuse or aerosol targets

The performance of a Coherent Laser Radar is determined by the statistics of the coherent Doppler signal. The heterodyne efficiency is an excellent indication of performance because it is an absolute measure of beam alignment and is independent of the transmitter power, the target backscatter coefficient, the atmospheric attenuation, and the detector quantum efficiency and gain. The theoretical calculation of heterodyne efficiency for an optimal monostatic lidar with a circular aperture and Gaussian transmit laser is presented including beam misalignment in the far-field and near-field regimes. The statistical behavior of estimates of the heterodyne efficiency using a calibration hard target are considered. For space based applications, a biased estimate of heterodyne efficiency is proposed that removes the variability due to the random surface return but retains the sensitivity to misalignment. Physical insight is provided by simulation of the fields on the detector surface. The required detector calibration is also discussed.

Frehlich, R. G.↗

NASA NTRS1994

NASA/DOD Aerospace Knowledge Diffusion Research Project. Paper 42: An analysis of the transfer of Scientific and Technical Information (STI) in the US aerospace industry

The U.S. aerospace industry has a long history of federal support for research related to its needs. Since the establishment of the National Advisory Committee for Aeronautics (NACA) in 1915, the federal government has provided continuous research support related to flight and aircraft design. This research has contributed to the international preeminence of the U.S. aerospace industry. In this paper, we present a sociological analysis of aerospace engineers and scientists and how their attitudes and behaviors impact the flow of scientific and technical information (STI). We use a constructivist framework to explain the spotty dissemination of federally funded aerospace research. Our research is aimed towards providing federal policymakers with a clearer understanding of how and when federally funded aerospace research is used. This understanding will help policymakers design improved information transfer systems that will aid the competitiveness of the U.S. aerospace industry.

Kennedy, John M.↗

NASA NTRS1972

Thermal radiation heat transfer.

A comprehensive discussion of heat transfer by thermal radiation is presented, including the radiative behavior of materials, radiation between surfaces, and gas radiation. Among the topics considered are property prediction by electromagnetic theory, the observed properties of solid materials, radiation in the presence of other modes of energy transfer, the equations of transfer for an absorbing-emitting gas, and radiative transfer in scattering and absorbing media. Also considered are radiation exchange between black isothermal surfaces, radiation exchange in enclosures composed of diffuse gray surfaces and in enclosures having some specularly reflecting surfaces, and radiation exchange between nondiffuse nongray surfaces. The use of the Monte Carlo technique in solving radiant-exchange problems and problems of radiative transfer through absorbing-emitting media is explained.

Siegel, R.↗

NASA NTRS1983

The magnetosphere of Saturn

Characterizations of the Saturn magnetospheric activities that have been made possible through data gathered by means of the Pioneer 11 and Voyagers 1 and 2 flybys are reviewed. The spacecraft data confirmed the presence of a Saturn magnetosphere, which features inward diffusion and energization of trapped energetic particles as well as cosmic ray albedo neutron decay as a source of inner belt protons. A dense plasma was identified in the region covering the outer magnetosphere to the magnetopause, which extends outward 17.3-23.6 Saturn radii on the sunward side and from 30.3-70 radii on the far side, according to the satellite measurements. Characteristics of the particle populations and behaviors of the outer magnetosphere, the slot region, the inner magnetosphere, and the ring region are reviewed, as are those of the magnetic field, the solar wind-magnetospheric interaction, and the Titan-magnetospheric interaction are described. Further investigation of the longitudinal asymmetry of decimetric radio emissions from Saturn is recommended.

Schardt, A. W.↗

NASA NTRS1997

NASA/DOD Aerospace Knowledge Diffusion Research Project. Paper 60: Culture and Workplace Communications: A Comparison of the Technical Communications Practices of Japanese and US Aerospace Engineers and Scientists

The advent of global markets elevates the role and importance of culture as a mitigating factor in the diffusion of knowledge and technology and in product and process innovation. This is especially true in the Large Commercial Aircraft (LCA) sector where the production and market aspects are becoming increasingly international. As firms expand beyond their national borders, using such methods as risk- sharing partnerships, joint ventures, outsourcing, and alliances, they have to contend with national and corporate cultures. Our focus is on Japan, a 'program participant' in the production of the Boeing Company's 777; the influence of Japanese culture on the diffusion of knowledge and technology in aerospace at the national and international levels; those cultural determinants-the propensity to work together, a willingness to subsume individual interests to a greater good, and an emphasis on consensual decisionmaking-that have a direct bearing on the ability of Japanese firms to form alliances and compete in international markets; and those cultural determinants thought to influence the information- seeking behaviors and workplace communication practices of Japanese aerospace engineers and scientists. In this paper, we report selective results from a survey of Japanese and U.S. aerospace engineers and scientists that focused on workplace communications. Data are presented for the following topics: importance of and time spent communicating information, collaborative writing, need for an undergraduate course in technical communication, use of libraries, use and importance of electronic (computer) networks, and the use and importance of foreign and domestically produced technical reports.

Pinelli, Thomas E.↗

NASA NTRS1980

Experimental and theoretical investigations of the quality factor for N/+/P silicon solar cells

Many N(+)P silicon solar cells made with silicon from different growth techniques have current-voltage relations of the form: I = I(0) (exp(qV/AkT) - 1), where the quality factor A is nonintegral, is greater than 1, and shows a temperature dependence. The dark forward characteristics of such cells have been measured over a range of temperatures and the behavior of the factor A derived from them. Lack of agreement with previous models has led to the development of a new model, in which N(+) conduction electrons tunnel to deep levels near that side, these levels being due to junction contamination by impurities. Electron recombination then occurs with holes thermally assisted into the junction from the P side. This mechanism involves increased I(0) values over those for diffusion diode processes and thus reduces the cell power conversion efficiency.

Garlick, G. F. J.↗

NASA NTRS1982

Evidence for a poleward meridional flow on the sun

Two subsets of all polar zone filaments, designated polemost filament and polar filament bands, are defined for observational study of their behavior, which is compared with the evolution of the polar magnetic field over Howard and LaBonte's (1981) activity cycle. The magnetic data show that the polar magnetic fields are built up and maintained by the episodic arrival of discrete f-polarity regions originating in active region latitudes and subsequently drifting to the poles. F-polarity regions are carried poleward by a meridional flow, rather than by diffusion. It is noted that the mean latitude of the polemost filaments tracks the boundary of the polar field cap, and undergoes an equatorward dip during each arrival of additional polar field, and that the polar filament bands track the boundary latitudes of the unipolar regions, drifting poleward with the regions at about 10 m/sec.

Topka, K.↗

NASA NTRS1992

Oligomeric baroeffect and gas aggregation states

The baroeffect is analyzed to include a gas that aggregates into higher-order polymers or oligomers. The resulting pressure change is found to vary independently of the molecular weight of the gas components and to depend only on the aggregation or oligomeric order of the gas. With increasing aggregation, diffusive slip velocities are found to increase. The calculations are extended to include general counterdiffusion of two distinct aggregation states (k-, j-mer) for the gas, and the pressure change is derived as a function that is independent of both molecular weight and the absolute aggregation. The only parameter that determines the baroeffect is the ratio of aggregated states, beta = k/j. For gases that reversibly aggregate, possible oscillatory behavior and complex dynamics for pressure are discussed. Gas aggregation may play a role for low-temperature crystal-growth conditions in which vapor concentrations of one (or more) species are high.

Noever, David A.↗

NASA NTRS1999

Solidification of II-VI Compounds in a Rotating Magnetic Field

This project is aimed at using a rotating magnetic field (RMF) to control fluid flow and transport during directional solidification of elemental and compound melts. Microgravity experiments have demonstrated that small amounts of residual acceleration of less than a micro-g can initiate and prolong fluid flow, particularly when there is a static component of the field perpendicular to the liquid solid interface. Thus a true diffusion boundary layer is not formed, and it becomes difficult to verify theories of solidification or to achieve diffusion controlled solidification. The RMF superimposes a stirring effect on an electrically conducting liquid, and with appropriate field strengths and frequencies, controlled transport of material through a liquid column can be obtained. As diffusion conditions are precluded and complete mixing conditions prevail, the technique is appropriate for traveling solvent zone or float zone growth methods in which the overall composition of the liquid can be maintained throughout the growth experiment. Crystals grown by RMF techniques in microgravity in previous, unrelated missions have shown exceptional properties. The objective of the project is two-fold, namely (1) using numerical modeling to simulate the behavior of a solvent zone with applied thermal boundary conditions and demonstrate the effects of decreasing gravity levels, or an increasing applied RMF, or both, and (2) to grow elements and II-VI compounds from traveling solvent zones both with and without applied RMFs, and to determine objectively how well the modeling predicts solidification parameters. Numerical modeling has demonstrated that, in the growth of CdTe from a tellurium solution, a rotating magnetic field can advantageously modify the shape of the liquid solid interface such that the interface is convex as seen from the liquid. Under such circumstances, the defect structure is reduced as any defects which are formed tend to grow out and not propagate. The flow of liquid, however, is complex due to the competing flow induced by the rotating magnetic field and the buoyancy driven convection. When the acceleration forces are reduced to one thousandth of gravity, the flow pattern is much simplified and well controlled material transport through the solvent zone can be readily achieved. Triple axis diffractometry and x-ray synchrotron topography have demonstrated that there is no significant improvement in crystal quality for HgCdTe grown on earth from a tellurium solution when a rotating magnetic field is applied. However, modeling shows that the flow in microgravity with a rotating magnetic field would produce a superior product.

Gillies, D. C.↗

NASA NTRS2003

A 2-D Piston Effect Solution for the Relaxation in the MISTE Cell

When a large density stratification is no longer a problem in a microgravity environment, one would like to increase the sample size in order to increase the signal-to-noise ratio for a specific heat measurement. To reduce the equilibration time associated with the large sample size, we designed a cylindrical cell containing a stack of plates that separate the bulk fluid into 60 equally thin layers. To understand the thermal behavior of the whole cell, we analyzed the thermal behavior of a 2-D composite system of a cylindrical near-critical fluid layer in contact with a cylindrical copper plate. In this 2-D analysis, the circumference boundary of the two cylindrical layers is subjected to a step temperature change. The solution of this 2-D composite system includes the piston effect that speeds up the equilibration in the near-critical fluid layer and the pure diffusion in the copper plate. The results of this analysis indicate that the characteristic length for the equilibration of the stacked cell is determined by an effective thickness of a single fluid layer instead of the total height of the cylindrical cell.

Weilert, Mark↗

NASA NTRS1990

Lifetime studies of high power rhodium/tungsten and molybdenum electrodes for application to AMTEC (alkali metal thermal-to-electric converter)

A detailed and fundamental model for the electrochemical behavior of AMTEC electrodes is developed which can aid in interpreting the processes which occur during prolonged operation of these electrodes. Because the sintering and grain growth of metal particles is also a well-understood phenomenon, the changes in electrode performance which accompany its morphological evolution may be anticipated and modeled. The grain growth rate observed for porous Mo AMTEC electrodes is significantly higher than that predicted from surface diffusion data obtained at higher temperatures and incorporated into the grain growth model. The grain growth observed under AMTEC conditions is also somewhat higher than that measured for Mo films on BASE (beta-alumina solid electrolyte) substrates in vacuum or at similar temperatures. Results of modeling indicate that thin Mo electrodes may show significant performance degradation for extended operation (greater than 10,000 h) at higher operating temperatures (greater than 1150 K), whereas W/Rh and W/Pt electrodes are expected to show adequate performance at 1200 K for lifetimes greater than 10,000 h. It is pointed out that current collection grids and leads must consist of refractory metals such as Mo and W which do not accelerate sintering or metal migration.

Williams, R. M.↗

NASA NTRS1991

Radial propagation of solar energetic particles assuming large scattering mean free paths in the interplanetary medium

Observations of two flares which fit the diffusive model by Beeck et al. (1987) are employed to determine whether large solar-particle events can be explained by the mechanisms of small impulsive events. It is shown that the injection of particles at the source is extended in time and lasts more than approximately 10 hours. The extended injection at the sun is hypothesized to be the reason that large solar particles do not demonstrate the 'pulse/wake' behavior associated with the small impulsive events.

Mason, G. M.↗

NASA NTRS2004

Evaluation of a Multigrid Scheme for the Incompressible Navier-Stokes Equations

A fast multigrid solver for the steady, incompressible Navier-Stokes equations is presented. The multigrid solver is based upon a factorizable discrete scheme for the velocity-pressure form of the Navier-Stokes equations. This scheme correctly distinguishes between the advection-diffusion and elliptic parts of the operator, allowing efficient smoothers to be constructed. To evaluate the multigrid algorithm, solutions are computed for flow over a flat plate, parabola, and a Karman-Trefftz airfoil. Both nonlifting and lifting airfoil flows are considered, with a Reynolds number range of 200 to 800. Convergence and accuracy of the algorithm are discussed. Using Gauss-Seidel line relaxation in alternating directions, multigrid convergence behavior approaching that of O(N) methods is achieved. The computational efficiency of the numerical scheme is compared with that of Runge-Kutta and implicit upwind based multigrid methods.

Swanson, R. C.↗

NASA NTRS2017

Prediction of Turbulent Temperature Fluctuations in Hot Jets

Large-eddy simulations (LES) were used to investigate turbulent temperature fluctuations and turbulent heat flux in hot jets. A high-resolution finite-difference Navier-Stokes solver was used to compute the flow from a 2-inch round nozzle. Three different flow conditions of varying jet Mach numbers and temperature ratios were examined. The LES results showed that the temperature field behaves similar to the velocity field, but with a more rapidly spreading mixing layer. Predictions of mean, mu-bar(sub i), and fluctuating, mu'(sub i), velocities were compared to particle image velocimetry data. Predictions of mean, T-bar, and fluctuating, T', temperature were compared to data obtained using Rayleigh scattering and Raman spectroscopy. Very good agreement with experimental data was demonstrated for the mean and fluctuating velocities. The LES correctly predicts the behavior of the turbulent temperature field, but over-predicts the levels of the fluctuations. The turbulent heat flux was examined and compared to Reynolds-averaged Navier-Stokes (RANS) results. The LES and RANS simulations produced very similar results for the radial heat flux. However, the axial heat flux obtained from the LES differed significantly from the RANS result in both structure and magnitude, indicating that the gradient diffusion type model in RANS is inadequate. Finally, the LES data was used to compute the turbulent Prandtl number and verify that a constant value of 0.7 used in the RANS models is a reasonable assumption.

hot jets↗

NASA NTRS2016

Li-Doped Ionic Liquid Electrolytes: From Bulk Phase to Interfacial Behavior

Ionic liquids have been proposed as candidate electrolytes for high-energy density, rechargeable batteries. We present an extensive computational analysis supported by experimental comparisons of the bulk and interfacial properties of a representative set of these electrolytes as a function of Li-salt doping. We begin by investigating the bulk electrolyte using quantum chemistry and ab initio molecular dynamics to elucidate the solvation structure of Li(+). MD simulations using the polarizable force field of Borodin and coworkers were then performed, from which we obtain an array of thermodynamic and transport properties. Excellent agreement is found with experiments for diffusion, ionic conductivity, and viscosity. Combining MD simulations with electronic structure computations, we computed the electrochemical window of the electrolytes across a range of Li(+)-doping levels and comment on the role of the liquid environment. Finally, we performed a suite of simulations of these Li-doped electrolytes at ideal electrified interfaces to evaluate the differential capacitance and the equilibrium Li(+) distribution in the double layer. The magnitude of differential capacitance is in good agreement with our experiments and exhibits the characteristic camel-shaped profile. In addition, the simulations reveal Li(+) to be highly localized to the second molecular layer of the double layer, which is supported by additional computations that find this layer to be a free energy minimum with respect to Li(+) translation.

molecular dynamics↗