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At least 613 records · Page 34

Hemispherical variance anomaly and reionization optical depth

ABSTRACT Cosmic microwave background (CMB) full-sky temperature data show a hemispherical asymmetry in power nearly aligned with the Ecliptic, with the Northern hemisphere displaying an anomalously low variance, while the Southern hemisphere appears consistent with expectations from the best-fitting theory, Lambda Cold Dark Matter (ΛCDM). The low signal-to-noise ratio in current polarization data prevents a similar comparison. Polarization realizations constrained by temperature data show that in ΛCDM the lack of variance is not expected to be present in polarization data. Therefore, a natural way of testing whether the temperature result is a fluke is to measure the variance of CMB polarization components. In anticipation of future CMB experiments that will allow for high-precision large-scale polarization measurements, we study how the variance of polarization depends on ΛCDM-parameter uncertainties by forecasting polarization maps with Planck’s Markov chain Monte Carlo chains. We show that polarization variance is sensitive to present uncertainties in cosmological parameters, mainly due to current poor constraints on the reionization optical depth τ, which drives variance at low multipoles. We demonstrate how the improvement in the τ measurement seen between Planck’s two latest data releases results in a tighter constraint on polarization variance expectations. Finally, we consider even smaller uncertainties on τ and how more precise measurements of τ can drive the expectation for polarization variance in a hemisphere close to that of the cosmic-variance-limited distribution.

79 ASTRONOMY AND ASTROPHYSICS↗

Detecting Rain–Snow-Transition Elevations in Mountain Basins Using Wireless Sensor Networks

Here, to provide complementary information on the hydrologically important rain–snow-transition elevation in mountain basins, this study provides two estimation methods using ground measurements from basin-scale wireless sensor networks: one based on wet-bulb temperature T wet and the other based on snow-depth measurements of accumulation and ablation. With data from 17 spatially distributed clusters (178 nodes) from two networks, in the American and Feather River basins of California’s Sierra Nevada, we analyzed transition elevation during 76 storm events in 2014–18. A T wet threshold of 0.5°C best matched the transition elevation defined by snow depth. Transition elevations using T wet in upper elevations of the basins generally agreed with atmospheric snow level from radars located at lower elevations, while radar snow level was ~100 m higher due to snow-level lowering on windward mountainsides during orographic lifting. Diurnal patterns of the difference between transition elevation and radar snow level were observed in the American basin, related to diurnal ground-temperature variations. However, these patterns were not found in the Feather basin due to complex terrain and higher uncertainties in transition-elevation estimates. The American basin tends to exhibit 100-m-higher transition elevations than does the Feather basin, consistent with the Feather basin being about 1° latitude farther north. Transition elevation averaged 155 m higher in intense atmospheric river events than in other events; meanwhile, snow-level lowering was enhanced with a 90-m-larger difference between radar snow level and transition elevation. On-the-ground continuous observations from distributed sensor networks can complement radar data and provide important ground truth and spatially resolved information on transition elevations in mountain basins.

54 ENVIRONMENTAL SCIENCES↗

Field Soil Water Retention of the Prototype Hanford Barrier and Its Variability with Space and Time

Engineered surface barriers (or covers) are used to isolate underlying contaminants from water, plants, animals, and humans. To understand the flow processes within a barrier and the barrier's ability to store and release water, the field hydraulic properties of the barrier need to be known. A multiyear test of the evapotranspiration (ET) barrier at the US Department of Energy's Hanford Site in the southeast of the state of Washington has yielded in situ soil water content and pressure data from multiple locations for a 9‐yr period, offering the opportunity to estimate soil water retention properties at different locations and times. The upper 2‐m layer of the ET barrier is a silt loam, and the top 1 m also contains 15% (w/w) pea gravel. Within this layer, valid monitoring data from 1995 to 2003 for four depths at 12 monitoring stations were used to determine the field water retention of the silt loam, with and without gravel. The data covered a wide range of wetness, from near saturation to the permanent wilting point, and each retention curve contained 51 to 96 data points. The data were described well with the commonly used van Genuchten water retention model. It was found that the spatial variation of the saturated and residual water content and the pore size distribution parameter was relatively small, while that of the van Genuchten α was relatively large. The effects of spatial variability of the retention properties appeared to be larger than the combined effects of added pea gravel and plant roots on the properties. Neither the primary wetting process in the winter season nor the drying process in the summer season nor time had a detectable effect on the water retention of the silt loam barrier.

Zhang, Z. Fred↗

Commissioning and Validation of the First Monte Carlo Based Dose Calculation Algorithm Commercial Treatment Planning System in Mexico

This work presents the beam data commissioning and dose calculation validation of the first Monte Carlo (MC) based treatment planning system (TPS) installed in Mexico. According to the manufacturer specifications, the beam data commissioning needed for this model includes: several in-air and water profiles, depth dose curves, head-scatter factors and output factors (6x6, 12x12, 18x18, 24x24, 42x42, 60x60, 80x80 and 100x100 mm{sup 2}). Radiographic and radiochromic films, diode and ionization chambers were used for data acquisition. MC dose calculations in a water phantom were used to validate the MC simulations using comparisons with measured data. Gamma index criteria 2%/2 mm were used to evaluate the accuracy of MC calculations. MC calculated data show an excellent agreement for field sizes from 18x18 to 100x100 mm{sup 2}. Gamma analysis shows that in average, 95% and 100% of the data passes the gamma index criteria for these fields, respectively. For smaller fields (12x12 and 6x6 mm{sup 2}) only 92% of the data meet the criteria. Total scatter factors show a good agreement (<2.6%) between MC calculated and measured data, except for the smaller fields (12x12 and 6x6 mm{sup 2}) that show a error of 4.7%. MC dose calculations are accurate and precise for clinical treatment planning up to a field size of 18x18 mm{sup 2}. Special care must be taken for smaller fields.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Data for: Climatic Imprint on Interfacially-Controlled Platinum-Palladium Resources

Data package for manuscript "Climatic Imprint on Interfacially-Controlled Platinum-Palladium Resources" by Emily G. Wright, Ivey Wang, Yihang Fang, Elaine D. Flynn, and Jeffrey G. Catalano. This dataset contains adsorption results from experiments designed to investigate the effect of chloride on Pd(II) adsorption to goethite and Pt(II) adsorption to hematite and goethite, including lab experiments, X-ray absorption fine structure spectroscopy, and models of retention within a laterite. See the associated manuscript for full methods information. The file "Wright2025_PtAds_data.csv" contains the target starting Pt concentration (uM), final aqueous Pt and associated error (in uM), calculated adsorbed Pt and associated error (in umol/m2), target and measured aqueous chloride (mM), target aqueous nitrate (mM), final pH, and mineral concentration/loading (g/L). Associated mineral-free controls (mineral loading = 0 g/L) are included; the aqueous Pd error was not calculated and chloride was not measured in every sample. These data appear in Figures 1, S3, S4, S5, S20, and S22 in the associated manuscript. The file "Wright2025_PdAds_data.csv" contains the target starting Pd concentration (uM), final aqueous Pd and associated error (in uM), calculated adsorbed Pd and associated error (in umol/m2), target and measured aqueous chloride (mM), and mineral concentration/loading (g/L). Associated mineral-free controls (mineral loading = 0 g/L) are included; the aqueous Pd error was not calculated and chloride was not measured in every sample. These data appear in Figures 1, S3, S4, S5, and S20 in the associated manuscript. The file "Wright2025_MineralBatches_data.csv" contains the mineral identity and BET specific surface area (m2/g) for every mineral batch synthesized and used in experiments. The annealing time used is listed for hydrothermally annealed goethite. These data appear in Table S2 in the associated manuscript. The file "Wright2025_XRD_data.csv" contains the XRD patterns for every mineral batch synthesized as the counts as a function of two theta (in degrees). See "Wright2025_MineralBatches_data.csv" for more details on specific mineral batches. These data appear in Figure S2 in the associated manuscript. The file "Wright 2025_ZetaPotential_data.csv" contains the measured zeta potentials for samples of goethite (batch G2) at pH 4 the presence of varying amounts of sodium chloride. These data appear in Table S3 in the associated manuscript. The file "Wright2025_XAFSSamples_data.csv" contains the specific mineral batch, measured final aqueous Pd or Pt (uM), measured final aqueous chloride (mM), and estimated adsorbed Pd or Pt (umol/m2) of all XAFS samples. These data appear in Tables S4, S7, S8, and S10 in the associated manuscript. The files "Wright2025_PdXAFS_data.csv" and "Wright2025_PtXAFS_data.csv" contain the normalized spectra of Pd and Pt, respectively, adsorbed to minerals at varying chloride concentrations. See "Wright2025_XAFSSamples_data.csv" for a guide to sample names. Note that "05" in a sample name is equivalent to "0.5". These data appear in Figures 2, S6, S7, S8, S12, S13, and S14 in the associated manuscript. The file "Wright2025_LateriteProfileProfileModelParameters_data.csv" include the ratio of hematite to hematite and goethite in two synthetic, modeled profiles, as well as the modeled surface areas of goethite and hematite as a function of relative depth within the modeled weathering zone. These data were used, in conjunction with equations presented in the paper, to calculate the theoretical concentrations of Pd and Pt (and the resulting Pt/Pd ratio) within the profiles. These data appear in Figure 3 in the associated manuscript. The file "Wright2025_Imagery_data.zip" is a zipped folder containing the TEM and STEM images appear in Figures S18 and S19. Individual files are labeled as either STEM (Fig. S18) or TEM (Fig. S19) with a letter representing the part of the multipart figure.

58 GEOSCIENCES↗

Quantification of Wellbore Leakage Risk Using Non-destructive Borehole Logging Techniques

Well integrity is important at all potential CCS locations and may play a crucial role establishing leakage risk in areas where there is a high density of existing wells that could be impacted by the storage operations including depleted petroleum fields where EOR or CCS will occur. To address a need for risk quantification methods that can be directly applied to individual wells using borehole logging tools a study was conducted using data from five wells in Wyoming. The objectives of the study were: Objective 1: Develop methods to establish the baseline flow parameters (porosity and permeability or mobility) from individual measurements of the material properties and defects in a well. Objective 2: Develop a correlation between field flow-property data and cement logs that can be used to establish the flow-properties of well materials and well features using cement mapping tools. Objective 3: Establish a method that uses the flow-property model (Objective 2) to analyze the statistical uncertainties associated with individual well leakage that can provide basis for uncertainty in risk calculations. The project objectives were met through the logging of five wells in Carbon and Natrona County Wyoming to collect data that was used to estimate individual and average well flow properties and model the results using ultrasonic data collected during the logging. Three of the five wells provided data on point and average flow properties for well annuli. Data from the other two wells were used to create models of cement permeability and test whether information collected in one well could be used to characterize another well. The results of the in-situ point measurements were confirmed by the lab measurements sidewall cores collected near the same depths Objective 1 was met using the data collected through logging, testing, and sampling. The methods were developed that can establish baseline flow parameters of wells by both point and average test methods. The methods to estimate the flow properties modeling of point pressure tests, modeling of vertical interference tests, and laboratory measurement of cased-hole sidewall cores The wells were in sufficiently good shape to allow the development of the characterization methods while still having enough defects to study differences in results as they relate to well integrity. Samples and tests analyzed from three of five wells studied in showed the cements were largely intact and had not degraded from exposure native brines. Log results taken in conjunction with the core measurements indicate that interfaces and/or problems with cement placement due to eccentering provide preferential flow paths for fluids, which can increase the effective permeability of the barrier several orders of magnitude above the permeability of intact cement. The results of the maps created using logging tools indicating that the cement condition and bond are generally good identify a need for more research to understand how logs can be used to predicteffective well permeabilities such as those measured by the VITs in this study.

42 ENGINEERING↗

Measurements of Turbulence at Two Tidal Energy Sites in Puget Sound, WA

Field measurements of turbulence are pre- sented from two sites in Puget Sound, WA (USA) that are proposed for electrical power generation using tidal current turbines. Rapidly sampled data from multiple acoustic Doppler instruments are analyzed to obtain statistical mea- sures of fluctuations in both the magnitude and direction of the tidal currents. The resulting turbulence intensities (i.e., the turbulent velocity fluctuations normalized by the harmonic tidal currents) are typically 10% at the hub- heights (i.e., the relevant depth bin) of the proposed turbines. Length and time scales of the turbulence are also analyzed. Large-scale, anisotropic eddies dominate the energy spectra, which may be the result of proximity to headlands at each site. At small scales, an isotropic turbulent cascade is observed and used to estimate the dissipation rate of turbulent kinetic energy. Data quality and sampling parameters are discussed, with an emphasis on the removal of Doppler noise from turbulence statistics.

16 TIDAL AND WAVE POWER↗

Global Paleoclimatic Data for 6000 Yr B.P.

To determine regional and global climatic variations during the past 6000 years, pollen, lake level, and marine plankton data from 797 stations were compiled to form a global data set. Radiocarbon dating and dated tephras were used to determine the ages of the specimens. The data available for the pollen data are site number, site name, latitude, longitude, elevation, and percentages of various taxa. For lake-level data, the data are site number, site name, latitude, longitude, and lake-level status. And for marine plankton, the data are site number, site name, latitude, longitude, water depth, date, dating control code, depth of sample, interpolated age of sample, estimated winter and summer sea-surface temperatures, and percentages of various taxa. The data are in 55 files: 5 files for each of 9 geographic regions and 10 supplemental files. The files for each region include (1) a FORMAT file describing the format and contents of the data for that region, (2) an INDEX file containing descriptive information about each site and its data, (3) a DATA file containing the data and available climatic estimates, (4) a PUBINDEX file indexing the bibliographic references associated with each site, and (5) a REFERENCE file containing the bibliographic references. The files range in size from 2 to 66 kB.

54 ENVIRONMENTAL SCIENCES↗

Mapping systematic errors in helium abundance determinations using Markov Chain Monte Carlo

Monte Carlo techniques have been used to evaluate the statistical and systematic uncertainties in the helium abundances derived from extragalactic H II regions. The helium abundance is sensitive to several physical parameters associated with the H II region. In this work, we introduce Markov Chain Monte Carlo (MCMC) methods to efficiently explore the parameter space and determine the helium abundance, the physical parameters, and the uncertainties derived from observations of metal poor nebulae. Experiments with synthetic data show that the MCMC method is superior to previous implementations (based on flux perturbation) in that it is not affected by biases due to non-physical parameter space. The MCMC analysis allows a detailed exploration of degeneracies, and, in particular, a false minimum that occurs at large values of optical depth in the He I emission lines. We demonstrate that introducing the electron temperature derived from the [O III] emission lines as a prior, in a very conservative manner, produces negligible bias and effectively eliminates the false minima occurring at large optical depth. We perform a frequentist analysis on data from several ''high quality'' systems. Likelihood plots illustrate degeneracies, asymmetries, and limits of the determination. In agreement with previous work, we find relatively large systematic errors, limiting the precision of the primordial helium abundance for currently available spectra.

79 ASTRONOMY AND ASTROPHYSICS↗

Deep learning inversion of gravity data for detection of CO 2 plumes in overlying aquifers

In this work, we developed an effective U-Net based deep learning (DL) model for inversion of surface gravity data on a rectangular grid to predict 2-D high-resolution subsurface CO 2 distribution along a vertical cross-section due to CO 2 leakage through a wellbore within a deep CO 2 storage reservoir. We used synthetic data to model two types of CO 2 leakage scenarios: one CO 2 plume in a shallow aquifer (single plume case), and two plumes present at different depths (double plume case). The 3-D synthetic plume samples were created by sampling among predetermined CO 2 plume depths, saturations, and volumes. The corresponding surface gravity data on a rectangular grid were generated by a 3-D forward model. The U-Net model detected 72% of single-plume samples, and one or both plumes in 75% of double-plume samples. Most of the undetected single plumes have small gravity field strengths below the typical noise level of 5 μGal. This model generated reproducible, reliable predictions with acceptable errors and demonstrated improved spatial resolution over the conventional least-squares inversion. In contrast to the conventional least-squares inversion, which often overestimates the size of its target and underestimates its density, this U-Net model accurately delineated the boundary of a target. Furthermore, this DL inversion detected deep, small, or low saturation CO 2 plumes that are often more difficult to resolve with conventional gravity inversion methods. We note the limitations of this feasibility study, including the use of synthetic data with regular CO 2 plume shapes, and the prediction of a 2-D plume cross-section rather than the full 3-D plume, as well, we recognize the lower detection fraction for double-plume scenarios. Nevertheless, this study demonstrates that DL gravity inversion is a promising and potentially superior method to conventional least-squares inversion. Our U-Net based deep learning inversion approach may be adapted for inversion of other types of geophysical data. DL inversion can facilitate near real-time monitoring of geologic carbon sequestration to provide site operators with prompt information about subsurface CO 2 distribution for risk management and mitigation.

58 GEOSCIENCES↗

Data associated with the manuscript “Radiative impact of record-breaking wildfires from integrated ground-based data” collected in Richland, Washington in September 2020

This data package is associated with the publication “Radiative impact of record-breaking wildfires from integrated ground-based data” submitted to Nature Scientific Reports (Kassianov et al., 2024). Data from ground-based measurements of shortwave and spectrally resolved irradiance and aerosol optical depth (AOD) in the visible and near-infrared spectral ranges were assessed to quantify the radiative impact of the September 2020 wildfires that occurred in the Western United States. Data were collected in September 2020 by several ground-based instruments at the Atmospheric Measurements Laboratory (AML) located in Richland, Washington (46.3451, -119.2792). These data include (1) Aerosol Optical Depth (AOD); (2) spectrally resolved and shortwave (SW) irradiances; (3) backscatter profiles; (4) total sky images; and (5) near-surface ambient air temperatures.The data package consists of five sub-directories: (1) “AML_Ceilometer_”; (2)” AML_CSPHOT_”; (3) “AML_MFRSR_irradiances_”; (4) “AML_SW_irradiances_and_Temp_”; (5) “AML_TSI_images_”; and 6 files stored at the directory level, including the readme, file-level metadata file, and data dictionary. The file-level metadata file (the file ending in “_flmd.csv”) lists all files contained in this data package and descriptions for each. The data dictionary (the file ending in “_dd.csv”) describes each tabular column header’s unit, definition, and structure. Below are descriptions of each sub-directory:“AML_Ceilometer_” includes ceilometer data collected at the AML. These files contain the corresponding narratives of data. Details related to the ceilometer data can be found in Morris (2016). “AML_CSPHOT_” includes ascii files with high-temporal resolution (about 10-15 min) AML CSPHOT data and their daily-averaged counterparts. These two files contain the corresponding narratives of data. Details related to the CSPHOT data can be found in Gregory (2011). “AML_MFRSR_irradiances_” includes ascii files with the AML MFRSR-measured diffuse, normal, and total spectrally resolved irradiance. Details related to the MFRSR data can be found in Hodges and Michalsky (2016) and Koontz et al. (2013). “AML_SW_irradiances_+_Temp_” includes near-surface ambient air temperature and SW irradiances, namely direct normal, diffuse hemispherical, and total hemispheric (global), measured at the AML. These files also incorporate the corresponding narratives of data. Details related to the SW irradiances can be found in Andreas et al. (2018). “AML_TSI_images_” includes Total Sky Images (TSIs) collected at the AML. Details related to the TSI data can be found in Morris (2005).

54 ENVIRONMENTAL SCIENCES↗

Monitoring of ground water table depth and soil moisture at the Point Reyes field site

Ground water table (GWT) depth and soil moisture (SM) have been monitored at several locations at the Point Reyes field site (Californian coastal grassland) from 2021 to 2024. Monitoring is still on-going and data may be added to this archive at later time. The SM data have been acquired using Teros 12 Meter soil moisture sensors placed at 10, 30, 60 and 90 cm depth at 5 locations along a small hillslope. These sensors also collect soil temperature and bulk conductance. In addition, some collocated sensors provide pore pressure and Photochemical Reflectance Index (PRI). The GWT depth has been inferred from various type of Onset pressure transducers. The pressure measurements have been corrected for atmospheric pressure variations and sensor position relative to the ground surface to infer GWT depth, as well as with RTK GPS data to infer GWT elevation. The GWT data have been acquired at 5 distinct locations from 2020 to 2024 with the sensors placed at about 4 m depth. In addition, GWT data has been acquired for the 2023-2024 period with sensors located in 1 m deep shallow wells installed near each deeper well. This data is intended to evaluate possibly different dynamic in shallow (perched) and deep aquifer. The datasets are all provided in csv format. Please note that the interpretation of the GWT data needs to be done with consideration of environmental and well characteristics at the site and uncertainty in various variables. For more information on GWT and SM data, please contact the author.

54 ENVIRONMENTAL SCIENCES↗

SU-E-T-561: Monte Carlo-Based Organ Dose Reconstruction Using Pre-Contoured Human Model for Hodgkins Lymphoma Patients Treated by Cobalt-60 External Beam Therapy

Purpose: Organ doses for the Hodgkin’s lymphoma patients treated with cobalt-60 radiation were estimated using an anthropomorphic model and Monte Carlo modeling. Methods: A cobalt-60 treatment unit modeled in the BEAMnrc Monte Carlo code was used to produce phase space data. The Monte Carlo simulation was verified with percent depth dose measurement in water at various field sizes. Radiation transport through the lung blocks were modeled by adjusting the weights of phase space data. We imported a precontoured adult female hybrid model and generated a treatment plan. The adjusted phase space data and the human model were imported to the XVMC Monte Carlo code for dose calculation. The organ mean doses were estimated and dose volume histograms were plotted. Results: The percent depth dose agreement between measurement and calculation in water phantom was within 2% for all field sizes. The mean organ doses of heart, left breast, right breast, and spleen for the selected case were 44.3, 24.1, 14.6 and 3.4 Gy, respectively with the midline prescription dose of 40.0 Gy. Conclusion: Organ doses were estimated for the patient group whose threedimensional images are not available. This development may open the door to more accurate dose reconstruction and estimates of uncertainties in secondary cancer risk for Hodgkin’s lymphoma patients. This work was partially supported by the intramural research program of the National Institutes of Health, National Cancer Institute, Division of Cancer Epidemiology and Genetics.

61 RADIATION PROTECTION AND DOSIMETRY↗

SU-F-BRA-07: Dosimetric Verification of the Valencia Skin Applicator Using Gafchromic EBT3 Film

Purpose: The Valencia applicators have recently been introduced for HDR treatment of small and shallow superficial skin lesions (< 20 mm diameter and 3-mm depth). Per AAPM TG 56, any HDR applicator internal dimensions must be verified prior to clinical use. However radiographic and tomographic imaging to validate the Valencia applicators is impractical due to the Tungsten alloy housing and flattening filter. In this study, we propose to use EBT3 film to indirectly confirm the physical integrity of the Valencia applicators. Methods: Treatment plans were created using the Oncentra MasterPlan TPS v4.5 for the H2 (20-mm dia.) and H3 (30-mm dia.) Valencia Applicators. A virtual CT phantom (2-mm slice thickness) was created with one source position in water. The published effective depth method was used for each applicator to delivery 500 cGy to a 3-mm depth using the TG-43 formalism. Film measurements (n=3) at 3-mm depth and vertical plane in solid water were performed for each applicator to verify the prescribed dose calculated by the TPS. Percent depth dose curves and off-axis profiles (phantom surface and 3-mm depth) were measured and compared to published data. Films were analyzed using an in-house written program and RIT113 v6 software. Film calibration was performed per TG-55 protocol using the Ir-192 source with NIST-traceable calibration. Results: The prescription absolute dose difference was 1% for the Valencia H2 applicator and 4% for the Valencia H3 applicator. The measured percent depth dose curves and off-axis dose profiles measured for the H2 and H2 Valencia applicators are in excellent agreement with the Granero et al. Monte Carlo results{sup 1}. Conclusion: Gafchromic EBT3 film can be used to indirectly verify the internal components of special HDR skin applicators constructed from high Z materials.{sup 1}Granero et al. “Design and evaluation of a HDR skin applicator with flattening filter”, Med. Phys. 35(2), 495–503, 2008.

60 APPLIED LIFE SCIENCES↗

Method used in Tokunaga, T. et al. 2018 for simulating time- and depth- dependent temperature variations in soil and sediment in Rifle, Colorado, 2013-2016.

This data package contains temperature, moisture content, matric potential, and carbon dioxide (CO2) concentration data from the Rifle, Colorado field site and from a 2 meter tall laboratory soil/sediment column designed to simulate field conditions. In addition, redox potential data from the laboratory column are included. The purpose of the data and paper is to demonstrate how a laboratory column was constructed to reproduce the dynamics of nonisothermal conditions in the field, such that CO2 production above a variable-depth water table can be studied in the laboratory. The data package contains 3 data files corresponding to the figures in the related paper (Tokunaga, T. et al. 2018) and 1 README file with the paper information.

54 ENVIRONMENTAL SCIENCES↗

Geochemical characterization of floodplain sediments from Meander C and O in the East River Watershed, CO, USA

This data package is part of the Watershed Function SFA data collection and contains geochemical characterization of sediments as a function of depth in the pumphouse vicinity, including Meander C and Meander O (oxbow). This data was used in the manuscript "Fox, P.M., Bill, M., Heckman, K., Conrad, M., Anderson, C., Keiluweit, M., and Nico, P.S.Shale as a Source of Organic Carbon in Floodplain Sediments of a Mountainous Watershed" published in Journal of Geophysical Research: Biogeosciences. Data includes sieving, total organic carbon (TOC), total inorganic carbon (TIC), total nitrogen (TN), carbon isotopes (14C and 13C) of whole sediment. Sediment density fractionation data is also included, with measurements of TOC, TN, 14C and 13C on density fractions. Metal and carbon concentrations from various sediment extractions (HCl, dithionite, oxalate, water, and pyrophosphate) are included. Characterization of extracted carbon by fourier transform infrared spectroscopy (FTIR) and UV-Visible light spectroscopy. Characterization of density fractionated (light fractions) organic carbon by FTIR. Carbon X-ray spectroscopy (C near edge X-ray absorption fine structure spectroscopy [NEXAFS] and scanning transmission X-ray microscopy [STXM]) is also included for shale samples and sediment samples.Additional acknowledgements:1. M.K. and C.A. were supported by the Department of Energy, Office of Biological and Environmental Research, Subsurface Biosphere Research program (award no. DE-SC0016544).2. STXM and NEXAFS data was collected at the Canadian Light Source, which is supported by the Canada Foundation for Innovation, Natural Sciences and Engineering Research Council of Canada, the University of Saskatchewan, the Government of Saskatchewan, Western Economic Diversification Canada, the National Research Council Canada, and the Canadian Institutes of Health Research.3. Radiocarbon analysis was supported in part by the Radiocarbon Collaborative, which is jointly sponsored by the USDA Forest Service Northern Research Station, the KCCAMS Facility at UC Irvine, and Michigan Technological University.Update 11/06/2019: An .kml file was added with the GPS locations for all the sampling sites.

54 ENVIRONMENTAL SCIENCES↗

Planck 2013 results. XI. All-sky model of thermal dust emission

This work introduces an all-sky model of dust emission from the Planck 353, 545, and 857 GHz, and IRAS 100 μm data. Using a modified blackbody fit to the data we present all-sky maps of the dust optical depth, temperature, and spectral index over the 353-3000 GHz range. This model is a good representation of the IRAS and Planck data at 5' between 353 and 3000 GHz (850 and 100 μm). It shows variations of the order of 30% compared with the widely-used model of Finkbeiner, Davis, and Schlegel. The Planck data allow us to estimate the dust temperature uniformly over the whole sky, down to an angular resolution of 5', providing an improved estimate of the dust optical depth compared to previous all-sky dust model, especially in high-contrast molecular regions where the dust temperature varies strongly at small scales in response to dust evolution, extinction, and/or local production of heating photons. An increase of the dust opacity at 353 GHz, τ 353 / N H , from the diffuse to the denser interstellar medium (ISM) is reported. It is associated with a decrease in the observed dust temperature, T obs , that could be due at least in part to the increased dust opacity. We also report an excess of dust emission at H I column densities lower than 10 20 cm -2 that could be the signature of dust in the warm ionized medium. In the diffuse ISM at high Galactic latitude, we report an anticorrelation between τ 353 / N H and T obs while the dust specific luminosity, i.e., the total dust emission integrated over frequency (the radiance) per hydrogen atom, stays about constant, confirming one of the Planck Early Results obtained on selected fields. This effect is compatible with the view that, in the diffuse ISM, T obs responds to spatial variations of the dust opacity, due to variations of dust properties, in addition to (small) variations of the radiation field strength. The indication is that in the diffuse high-latitude ISM τ 353 is not as reliable a tracer of dust column density as we conclude it is in molecular clouds where the correlation of τ 353 with dust extinction estimated using colour excess measurements on stars is strong. To estimate Galactic E(B-V) in extragalactic fields at high latitude we develop a new method based on the thermal dust radiance, instead of the dust optical depth, calibrated to E(B -V) using reddening measurements of quasars deduced from Sloan Digital Sky Survey data.

79 ASTRONOMY AND ASTROPHYSICS↗

Completion Report for Well ER-2-2 Corrective Action Unit 97: Yucca Flat/Climax Mine

Well ER-2-2 was drilled for the U.S. Department of Energy, Nevada National Security Administration Nevada Field Office in support of the Underground Test Area (UGTA) Activity. The well was drilled from January 17 to February 8, 2016, as part of the Corrective Action Investigation Plan (CAIP) for Corrective Action Unit 97: Yucca Flat/Climax Mine, Nevada Test Site, Nevada. The primary purpose of the well was to collect hydrogeologic data to evaluate uncertainty in the flow and transport conceptual model and its contamination boundary forecasts, and to detect radionuclides in groundwater from the CALABASH (U2av) underground test. Well ER-2-2 was not completed as planned due to borehole stability problems. As completed, the well includes a piezometer (p1) to 582 meters (m) (1,909 feet [ft]) below ground surface (bgs) installed in the Timber Mountain lower vitric-tuff aquifer (TMLVTA) and a 12.25-inch (in.) diameter open borehole to 836 m (2,743 ft) bgs in the Lower tuff confining unit (LTCU). A 13.375-in. diameter carbon-steel casing is installed from the surface to a depth of 607 m (1,990 ft) bgs. Data collected during borehole construction include composite drill cutting samples collected every 3.0 m (10 ft), geophysical logs to a depth of 672.4 m (2,206 ft) bgs, water-quality measurements (including tritium), water-level measurements, and slug test data. The well penetrated 384.05 m (1,260 ft) of Quaternary alluvium, 541.93 m (1,778 ft) of Tertiary Volcanics (Tv) rocks, and 127.71 m (419 ft) of Paleozoic carbonates. The stratigraphy and lithology were generally as expected. However, several of the stratigraphic units were significantly thicker then predicted—principally, the Tunnel formation (Tn), which had been predicted to be 30 m (100 ft) thick; the actual thickness of this unit was 268.22 m (880 ft). Fluid depths were measured in the borehole during drilling as follows: (1) in the piezometer (p1) at 552.15 m (1,811.53 ft) bgs and (2) in the main casing (m1) at 551.69 m (1,810.01 ft) bgs. As expected, field measurements for tritium were above the Safe Drinking Water Act limit (20,000 picocuries per liter). All Fluid Management Plan requirements were met.

54 ENVIRONMENTAL SCIENCES↗