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At least 613 records · Page 34

Atmospheric pressure plasma processing of polymeric materials utilizing close proximity indirect exposure

A plasma treatment method that includes providing treatment chamber including an intermediate heating volume and an interior treatment volume. The interior treatment volume contains an electrode assembly for generating a plasma and the intermediate heating volume heats the interior treatment volume. A work piece is traversed through the treatment chamber. A process gas is introduced to the interior treatment volume of the treatment chamber. A plasma is formed with the electrode assembly from the process gas, wherein a reactive species of the plasma is accelerated towards the fiber tow by flow vortices produced in the interior treatment volume by the electrode assembly.

36 MATERIALS SCIENCE↗

Atmospheric pressure plasma processing of polymeric materials utilizing close proximity indirect exposure

A plasma treatment method that includes providing treatment chamber including an intermediate heating volume and an interior treatment volume. The interior treatment volume contains an electrode assembly for generating a plasma and the intermediate heating volume heats the interior treatment volume. A work piece is traversed through the treatment chamber. A process gas is introduced to the interior treatment volume of the treatment chamber. A plasma is formed with the electrode assembly from the process gas, wherein a reactive species of the plasma is accelerated towards the fiber tow by flow vortices produced in the interior treatment volume by the electrode assembly.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Evidence for Atmospheric Cold-trap Processes in the Noninverted Emission Spectrum of Kepler-13Ab Using HST /WFC3

We observed two eclipses of the Kepler-13A planetary system, on UT 2014 April 28 and UT 2014 October 13, in the near-infrared using Wide Field Camera 3 on the Hubble Space Telescope . By using the nearby binary stars Kepler-13BC as a reference, we were able to create a differential light curve for Kepler-13A that had little of the systematics typically present in HST /WFC3 spectrophotometry. We measure a broadband (1.1–1.65 μ m) eclipse depth of 734 ± 28 ppm and are able to measure the emission spectrum of the planet at R ≈ 50 with an average precision of 70 ppm. We find that Kepler-13Ab possesses a noninverted, monotonically decreasing vertical temperature profile. We exclude an isothermal profile and an inverted profile at more than 3 σ . We also find that the dayside emission of Kepler-13Ab appears generally similar to an isolated M7 brown dwarf at a similar effective temperature. Due to the relatively high mass and surface gravity of Kepler-13Ab, we suggest that the apparent lack of an inversion is due to cold-trap processes in the planet’s atmosphere. Using a toy model for where cold traps should inhibit inversions, as well as observations of other planets in this temperature range with measured emission spectra, we argue that with more detailed modeling and more observations we may be able to place useful constraints on the size of condensates on the daysides of hot Jupiters.

79 ASTRONOMY AND ASTROPHYSICS↗

Transport processes in the middle atmosphere: Reflections after MAP

The Middle Atmosphere Program (MAP) has provided a focus for considerable research on atmospherical radiative, chemical, and dynamical processes and the mutual coupling among these processes. In particular, major advances have occurred in the understanding of constituent transport as a result of near-global measurements obtained during MAP from several satellite based instruments (e.g., LIMS, SAMS, SAGE, and SSU among others). Using selected portions of these data, the development is reviewed of progress in understanding transport processes with special emphasis on dynamically active periods. Examples are presented which demonstrate coupling between chemistry and dynamics. In addition to the constituent data, the use is reviewed of Ertel's potential vorticity, inferred from satellite temperature data, as a diagnostic for interpreting transport phenomena. Finally, the use is briefly illustrated of 3-D model simulations, in conjunction with the satellite data, for providing additional insight into fundamental transport mechanisms.

Grose, W. L.↗

Impact of Atmospheric Rivers on Surface Hydrological Processes in Western U.S. Watersheds

Atmospheric rivers (ARs) can significantly modulate surface hydrological processes through the extreme precipitation they produce. Previously, studies have investigated the impact of ARs on individual hydrological processes, but a comprehensive evaluation of ARs’ impact on surface hydrology is lacking. This study used a high-resolution regional climate simulation to quantify the impact of ARs on surface hydrological processes across the western U.S. watersheds. The model performance is evaluated through extensive comparison against observations. Our analysis indicates that ARs produce heavy precipitation but suppress evapotranspiration. Snowpack ablates more during ARs, which is mainly driven by warmer air temperature and increased downward longwave radiation. At the 0oC to 10oC temperature range, ARs increase the probability of snow ablation from 0.33 to 0.57. Soil moisture responds similarly to AR and non-AR precipitation events. The runoff-to-precipitation ratio almost doubles due to modulation by heavy precipitation in the southwestern watersheds or intensification of snow ablation in the northwestern watersheds during AR events compared to non-AR events. From analysis of the relationship between the hydrological responses and different meteorological factors, precipitation, temperature and radiation were identified as the key drivers that distinguish the hydrologic responses between AR and non-AR events. Lastly, analysis of ARs and total runoff at annual scale and April 1st snowpack and winter precipitation shows that ARs explain 30% to 60% of the interannual variance and sharpen the seasonality of water resources availability in the west coast mountain watersheds.

54 ENVIRONMENTAL SCIENCES↗

NSA Site Science: Use of ARM Observations from Northern Alaska to Evaluate and Improve Prediction Capabilities

The Arctic is warming at a rate nearly double that of the rest of the planet, leading to profound changes in atmospheric, oceanic, and ice processes. The U.S. Department of Energy's (DOE) Atmospheric Radiation Measurement (ARM) user facility has played a significant role in Arctic research, operating observatories in Alaska's North Slope for over 25 years. These observatories provide a rich, and wide-reaching dataset that offers insight into atmospheric processes in northern Alaska. This report details the results of a nine-year research project (2015–2024) supported by the DOE Atmospheric Systems Research (ASR) program, that leverages data from ARM’s deployment of observing facilities at Utqiaġvik (known as the North Slope of Alaska, or NSA, site) and Oliktok Point, Alaska. The project was conducted in two phases: - Phase 1 (2015–2019): Focused on understanding key atmospheric processes at Oliktok Point, including cloud formation, high-latitude precipitation, aerosol-cloud interactions, and cloud properties. - Phase 2 (2019–2024): Extended the research to the broader North Slope region, using data from both Oliktok Point and Utqiaġvik. Topics explored included surface energy budgets, atmospheric stability, ice nucleation processes, and microphysics in Arctic clouds. The project resulted in numerous research products, including 50 peer-reviewed publications and dissertations, 169 presentations, and 10 data products. These products cover a variety of topics, including: - Cloud Macro- and Microphysical Properties: Arctic clouds play a crucial role in energy transfer, and accurate representation in models is critical. The study explored cloud transitions, ice crystal shapes, and dual-wavelength radar data to understand ice crystal habits and size distributions. - Aerosol Properties and Processes: The team examined aerosol sources in the Arctic, including industrial emissions and natural sources. Observations showed significant spatial gradients in aerosol concentrations due to human activities and wildfire smoke. The influence of aerosols on cloud formation and the surface energy budget was also assessed. - Aerosol-Cloud Interactions: Research revealed that aerosols might suppress cloud ice production, affecting cloud radiative forcing and precipitation. The impact of local industrial emissions on cloud properties was also investigated. - Contextualizing the North Slope of Alaska in the context of the broader Arctic: To understand broader trends, the project evaluated large-scale circulation patterns and the influence of weather systems on the Arctic. Studies indicated that large-scale processes play a significant role in temperature patterns and the timing of snowmelt. - Advancing ARM Observational and Modeling Capabilities: The project developed new radar data products and advanced measurement techniques, including clutter mitigation and drizzle detection. Uncrewed aerial systems (UAS) and tethered balloon systems (TBS) were deployed to gather detailed atmospheric data. Additionally, the project supported 10 early career scientists, providing training and mentorship to undergraduate interns, graduate students, postdoctoral researchers, and early career researchers. These efforts contributed to the advancement of ARM research capabilities and fostered a new generation of scientists skilled in Arctic atmospheric research. Ultimately, this ASR-supported project has provided valuable insights into Arctic atmospheric processes and their broader climate implications. Recommendations for future work include continuing support for long-term observing at Arctic locations to foster additional research, further exploration of aerosol-cloud interactions and the potential impacts of enhanced industrialization of the Arctic, and expanded use of uncrewed systems to gather data in this remote and harsh environment. Additionally, the data products developed by this work, and the data products developed through the ARM infrastructure, leave a treasure-trove of additional information that should be explored for many years to come to gain additional insight into physical processes in the Arctic atmosphere that drive the rapid changes occurring in at high latitudes and their global impact.

58 GEOSCIENCES↗

Integration of space and in-situ observations to study atmosphere, ocean and land processes

A research investigation was conducted into the possibility of using atmospheric observations made in the past from both terrestrial and space-based platforms to create a global, coherent four dimensional analysis for the purpose of studying atmospheric, oceanic, and land surface processes relevant to climate simulation, monitoring, and change. This investigation consisted of the following tasks: (1) a mature global data assimilation system was obtained from the National Meteorological Center and modified for use on a Cray X-MP computer system; (2) atmospheric observations for the period 20 Nov. 1982 through 1 Mar. 1983, including rawinsonde soundings, aircraft-based measurements, pilot balloons, and temperature soundings from polar orbiting satellites were obtained from several sources; and (3) the global data assimilation system was used to reassimilate the atmospheric observations to produce a new atmospheric analysis which was then compared with the contemporaneous analysis. The global hydrologic cycle, including fluxes between the atmosphere and both the land and ocean surfaces, was estimated. The flux of water from the ocean surface into the atmosphere, its transport in the form of latent heat to remote regions, and its return to the surface in the form of precipitation were estimated globally. In addition, several regional budgets for selected tropical oceanic and extratropical continental areas were also done.

Shukla, J.↗

Solar activity influences on atmospheric electricity and on some structures in the middle atmosphere

Only processes in the troposphere and the lower stratosphere are reviewed. General aspects of global atmospheric electricity are summarized in Chapter 3 of NCR (1986); Volland (1984) has outlined the overall problems of atmospheric electrodynamics; and Roble and Hays (1982) published a summary of solar effects on the global circuit. The solar variability and its atmospheric effects (overview by Donelly et al, 1987) and the solar-planetary relationships (survey by James et al. 1983) are so extremely complex that only particular results and selected papers of direct relevance or historical importance are compiled herein.

Reiter, Reinhold↗

Hydrological analysis in watersheds with a variable-resolution global climate model (VR-CESM)

Traditionally, watershed-scale hydrology is simulated by distributed hydrological models with offline meteorological forcing data, or by regional regional climate models that link atmospheric and land hydrology interactions. Global climate models (GCMs) are rarely used to study watershed-scale hydrology due to the relatively coarse grid resolution, computationally expensive downscaling, and simplified physical processes. Recently, however, watershed-scale hydrology analysis has become possible in GCMs due to the development of variable-resolution GCMs that dynamically couple the hydrological processes between atmosphere and land systems at fine resolutions in selected regions and coarse resolution elsewhere. In this study, we used the variable-resolution Community Earth System Model (VR-CESM) with refined-resolution (14 km) in the western U.S. and eastern China to evaluate watershed-scale hydrology. Furthermore, we compared the historical VR-CESM outputs with gauge measurements and other hydrological models (e.g., National Water Model in the U.S.) and calibrated the subsurface runoff capacities in four mountainous watersheds. An RCP8.5 projection from 2007 to 2050 is used to estimate the impact of changing precipitation and snow climatology on watershed hydrology. We also analyzed the long-term runoff variability and the possibility of extreme runoff events as simulated by the VR-CESM. Although calibration is not possible in larger-scale watersheds, VR-CESM simulates the long-term annual variability of watersheds and provides insights on climate change impacts on hydrology. We conclude that refined-resolution VR-CESM can be used for watershed-scale hydrology analysis to understand water resources and water balance, in addition to traditional watershed-scale hydrological models. It enables hydrological analysis at multiple watersheds in one simulation and can help understand the two-way dynamics between land surface hydrology and atmospheric processes, and is especially practical for projecting climate change impacts. However, it is challenging to apply VR-CESM for hydrologic analysis in regulated watersheds as human factors (e.g., pumping, irrigation, water diversion) have not been fully addressed in VR-CESM.

54 ENVIRONMENTAL SCIENCES↗

STOCHASTIC TRANSIENTS AS A SOURCE OF QUASI-PERIODIC PROCESSES IN THE SOLAR ATMOSPHERE

Solar dynamics and turbulence occur at all heights of the solar atmosphere and could be described as stochastic processes. We propose that finite-lifetime transients recurring at a certain place could trigger quasi-periodic processes in the associated structures. In this study, we developed a mathematical model for finite-lifetime and randomly occurring transients, and found that quasi-periodic processes with periods longer than the timescale of the transients, are detectable intrinsically in the form of trains. We simulate their propagation in an empirical solar atmospheric model with chromosphere, transition region, and corona. We found that, due to the filtering effect of the chromospheric cavity, only the resonance period of the acoustic resonator is able to propagate to the upper atmosphere; such a scenario is applicable to slow magnetoacoustic waves in sunspots and active regions. If the thermal structure of the atmosphere is less wild and acoustic resonance does not take place, the long-period oscillations could propagate to the upper atmosphere. Such a case would be more likely to occur in polar plumes.

79 ASTRONOMY AND ASTROPHYSICS↗

PACE Technical Report Series, Volume 7: Ocean Color Instrument (OCI) Concept Design Studies

Extending OCI hyperspectral radiance measurements in the ultraviolet to 320 nm on the blue spectrograph enables quantitation of atmospheric total column ozone (O3) for use in ocean color atmospheric correction algorithms. The strong absorption by atmospheric ozone below 340 nm enables the quantification of total column ozone. Other applications are possible but were not investigated due to their exploratory nature and lower priority.The first step in the atmospheric correction processing, which converts top-of-the-atmosphere radiances to water-leaving radiances, is removal of the absorbance by atmospheric trace gases such as water vapor, oxygen, ozone and nitrogen dioxide. Details of the atmospheric correction process currently used by the Ocean Biology Processing Group (OBPG) and will be employed for PACE with appropriate modifications, are described by Mobley et al. [2016]. Atmospheric ozone absorbs within the visible to near-infrared spectrum between ~450 nm and 800nm and most appreciably between 530 nm and 650 nm, a spectral region critical for maintaining NASA's chlorophyll-a climate data record and for PACE algorithms planned to characterize phytoplankton community composition and other ocean color products.While satellite-based observations will likely be available during PACE's mission lifetime, the difference in acquisition time with PACE, the coarseness in their spatial resolution, and differences in viewing geometries will introduce significant levels of uncertainties in PACE ocean color data products.

Cetinic, Ivona↗

New Potential Sources for Black Onaping Carbon

One intriguing and important issue of the Sudbury Structure concerns the source of the relatively large amount of C in the Onaping Formation Black member. This dilemma was recently addressed, and the conclusion was reached that an impactor could not have delivered all of the requisite C. Becker et al. have suggested that much of the C came from the impactor and reported the presence of interstellar He "caged" inside some fullerenes that may have survived the impact. So, conceivably, the C inventory in the Sudbury Structure comes from both target and impactor materials, although the known target rocks have little C. We discuss here the possibility of two terrestrial sources for at least some of the C: (1) impact evaporation/dissociation of C from carbonate target rocks and (2) the presence of heretofore-unrecognized C-rich (up to 26 wt%) siliceous "shale," fragments, which are found in the upper, reworked Black member. Experimental: Hypervelocity impact of a 0.635-diameter Al projectile into dolomite at 5.03 km/s (performed at the Ames Research Center vertical gun range) produced a thin, black layer (= 0.05 mm thick) that partially lined the crater and coated impactor remnants. Scanning electronic microscope (SEM) imagery shows this layer to be spongelike on a submicron scale and Auger spectroscopic analyses yield: 33% C, 22% Mg, 19% 0, and 9% Al (from the projectile). Elemental mapping shows that all of the available 0 is combined with Ca and Mg, Al is not oxidized, and C is in elemental form. Dissociation efficiency of C from CO2 is estimated to be <10% of crater volume. Raman spectroscopy indicates that the C is highly disorganized graphite. Another impact experiment [4] also produced highly disordered graphite from a limestone target (reducing collector), in addition to small amounts of diamond/lonsdaleite/chaoite (oxidizing collector). These experiments confirm the reduction of C from carbonates in impact vapor plumes. Observational: SEM observations and microprobe analyses of small, black shalelike inclusions in the upper Black Onaping indicate high C contents (7-26 wt% avg. = 16%). They contain mostly quartz and carbonaceous matter with small amounts of altered K-feldspar, clays, Fe oxide, and a sulfide. No evidence of shock is seen in quartz, and overall characteristics indicate a natural, lightly metamorphosed carbonaceous shale or mudstone that probably existed as a preimpact rock in the target region and distal fragments washed in during early crater filling. Fragments range in size from tens of microns to cm and increase in abundance in the upper Black toward the Onwatin contact, although their distribution is highly irregular. This increase corresponds to an increase in "organic" C with increasingly negative delta-13 C values and S, together with a decrease in fullerene abundance. In addition, we have found soot in acid-demineralized residues of the Onwatin but not in the Onaping samples. These data could be consistent with impact plume and atmospheric chemical processes, with possible diageneric ovedays. We are analyzing carbonaceous fractions of the Onaping and Onwatin to determine diagnostic C isotopic signatures Analyses by Whitehead et al. on bulk samples revealed no definitive source or processes, although delta-13 C values for "organic" C overlapped those for some meteorites. Discussion: If impact evaporation of Sudbury target carbonates did occur, then where are the carbonates? Distal carbonate (limestone/dolostone) exposures of the Espanola Formation (Huronian Supergroup) are generally thin-bedded, although remnants that partially encompass the Sudbury Crater are variable in thickness and may locally reach 250 m . If a carbonate thickness of 100-200 in existed at the target site, then copious amounts of C could have been reduced by impact processing of carbonates and also C-shale, depending on the efficiency of the processing and the amount of postimpact oxidation. Conclusion: The Sudbury crater offers a unique opportunity to study preserved characteristics of immediate carbonaceous fallback matter and particles of short-term residency in the impact plume as well as dust/aerosols from postimpact atmospheric processing.

Bunch, T. E.↗

Present state of knowledge of the upper atmosphere: An assessment report; processes that control ozone and other climatically important trace gases

The state of knowledge of the upper atmosphere was assessed as of January 1986. The physical, chemical, and radiative processes which control the spatial and temporal distribution of ozone in the atmosphere; the predicted magnitude of ozone perturbations and climate changes for a variety of trace gas scenarios; and the ozone and temperature data used to detect the presence or absence of a long term trend were discussed. This assessment report was written by a small group of NASA scientists, was peer reviewed, and is based primarily on the comprehensive international assessment document entitled Atmospheric Ozone 1985: Assessment of Our Understanding of the Processes Controlling Its Present Distribution and Change, to be published as the World Meteorological Organization Global Ozone Research and Monitoring Project Report No. 16.

Watson, R. T.↗

Theoretical studies of important processes in planetary and comet atmospheres. Renewel request

Current efforts have focused on the dissociative recombination (DR) of O2(+), a process of great importance in planetary atmospheres. This process is difficult to study experimentally because of the need to determine the dependence of the product electronic states and kinetic energies upon the vibrational distribution of the ion and electron temperature. The knowledge of these characteristics of DR is needed to accurately model planetary ionospheres. Using a theoretical quantum chemical approach, the generation of O(1S) from DR was studied in detail.

Guberman, Steven L.↗

Relative Contributions of Atmospheric, Oceanic, and Coupled Processes to North Pacific and North Atlantic Variability

Patterns of sea surface temperature (SST) variability over the northern oceans arise from a combination of atmospheric, oceanic, and coupled processes. In this work, we use a novel methodology and a suite of observations to quantify the processes contributing to the dominant patterns of interannual SST variability over these regions. We decompose the upper ocean heat content tendency associated with such dominant patterns into contributions from different heat fluxes: (a) atmospherically driven, (b) surface feedbacks, and (c) oceanic. We find that in the subtropics, cloud radiative flux, turbulent heat flux, and residual oceanic processes each contributes substantially to North Pacific SST variability, whereas turbulent heat flux primarily induces North Atlantic SST variability. Cloud radiative fluxes therefore provide a major source of interannual SST variability in the North Pacific but not in the North Atlantic. In midlatitudes, SST fluctuations over the northern oceans are driven by the combination of turbulent and oceanic heat fluxes.

54 ENVIRONMENTAL SCIENCES↗

Evaluation of Shortwave Infrared Atmospheric Correction for Ocean Color Remote Sensing of Chesapeake Bay

The NASA Moderate Resolution Imaging Spectroradiometer onboard the Aqua platform (MODIS-Aqua) provides a viable data stream for operational water quality monitoring of Chesapeake Bay. Marine geophysical products from MODIS-Aqua depend on the efficacy of the atmospheric correction process, which can be problematic in coastal environments. The operational atmospheric correction algorithm for MODIS-Aqua requires an assumption of negligible near-infrared water-leaving radiance, nL(sub w)(NIR). This assumption progressively degrades with increasing turbidity and, as such, methods exist to account for non-negligible nL(sub w)(NIR) within the atmospheric correction process or to use alternate radiometric bands where the assumption is satisfied, such as those positioned within shortwave infrared (SWIR) region of the spectrum. We evaluated a decade-long time-series of nL(sub w)(lambda) from MODIS-Aqua in Chesapeake Bay derived using NIR and SWIR bands for atmospheric correction. Low signal-to-noise ratios (SNR) for the SWIR bands of MODIS-Aqua added noise errors to the derived radiances, which produced broad, flat frequency distributions of nL(sub w)(lambda) relative to those produced using the NIR bands. The SWIR approach produced an increased number of negative nL(sub w)(lambda) and decreased sample size relative to the NIR approach. Revised vicarious calibration and regional tuning of the scheme to switch between the NIR and SWIR approaches may improve retrievals in Chesapeake Bay, however, poor SNR values for the MODIS-Aqua SWIR bands remain the primary deficiency of the SWIR-based atmospheric correction approach.

Werdell, P. Jeremy↗

AOIPS - An interactive image processing system

The Atmospheric and Oceanographic Information Processing System (AOIPS) was developed to help applications investigators perform required interactive image data analysis rapidly and to eliminate the inefficiencies and problems associated with batch operation. This paper describes the configuration and processing capabilities of AOIPS and presents unique subsystems for displaying, analyzing, storing, and manipulating digital image data. Applications of AOIPS to research investigations in meteorology and earth resources are featured.

Bracken, P. A.↗