SEARCH · Engineering Papers
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
The cosmic-ray-source abundances inferred from HEAO-3 observation by the Heavy Nuclei Experiment for Z = 30-60 generally follow the correlation with first-ionization potential which has previously been observed for Z less than 30. However the low Ge abundance suggests that the elemental 'volatility' may be an organizing factor.
The pattern of solar elemental abundances agrees well with that shown by Cl chondrites for nonvolatile elements. For metals of the iron peak, the chief source of uncertainty seems to be the structure of the solar atmosphere. Lines of rare elements are frequently masked by atomic and molecular lines of abundant species. The vast majority of stars (including the sun) will do little to change the bulk composition of the interstellar medium from which new stars are formed. He, C, and N in small quantities are supplied by stars from 1 to 8 solar masses as they evolve and produce nebular envelopes that dissipate into the interstellar medium, but as has long been recognized, oxygen, heavier elements, and all r-process and proton-rich nuclides are made in massive stars.
Resonance ionization mass spectrometry (RIMS) is a relatively new laser-based technique for the determination of isotopic abundances. The resonance ionization process depends upon the stepwise absorption of photons from the laser, promoting atoms of the element of interest through progressively higher electronic states until an ion is formed. Sensitivity arises from the efficiency of the resonant absorption process when coupled with the power available from commercial laser sources. Selectivity derives naturally from the distinct electronic structure of different elements. This isobaric discrimination has provided the major impetus for development of the technique. Resonance ionization mass spectrometry was used for analysis of the isotopic abundances of the rare earth lutetium. Isobaric interferences from ytterbium severely effect the ability to measure small amounts of the neutron-deficient Lu isotopes by conventional mass spectrometric techniques. Resonance ionization for lutetium is performed using a continuous-wave laser operating at 452 nm, through a sequential two-photon process, with one photon exciting the intermediate resonance and the second photon causing ionization. Ion yields for microgram-sized quantities of lutetium lie between 10(6) and 10(7) ions per second, at overall ionization efficiencies approaching 10(-4). Discrimination factors against ytterbium greater than 10(6) have been measured. Resonance ionization for technetium is also being explored, again in response to an isobaric interference, molybdenum. Because of the relatively high ionization potential for Tc, three-photon, two-color RIMS processes are being developed.
New theoretical and experimental results have prompted a reinvestigation of the HCO(+)/HOC(+) abundance ratio in dense interstellar clouds. These results pertain principally but not exclusively to the reaction between HOC(+) and H2, which was previously calculated by DeFrees et al. (1984) to possess a large activation energy barrier. New calculations, reported here, indicate that this activation energy barrier is quite small and may well be zero. In addition, experimental results at higher energy and temperature indicate strongly that the reaction proceeds efficiently at interstellar temperatures. If HOC(+) does indeed react efficiently with H2 in interstellar clouds, the calculated HCO(+)/HOC(+) abundance ratio rises to a substantially greater value under standard dense cloud conditions than is deduced via the tentative observation of HOC(+) in Sgr B2.
Isotope production, particularly CNO, which are enhanced in novae events and the interstellar medium (ISM) by novae are discussed in terms of emission-line data taken a few weeks after novae events. The emission-line abundances emerge only after the fading of absorption spectrum, and are also detectable in thin shells which sometimes, though rarely, form after novae. CNO abundances in these shells are equivalent to those observed in fading novae, with CNO/H ratios being 100 times solar values. Possible heavy element production pathways in the events and their shrinking are discussed, along with observation techniques for detecting CNO isotopes through absorption data on atomic transitions in novae ejecta and the ISM.
On the basis of early absorption line studies of individual lines of sight with the Copernicus satellite, chlorine, sulphur and zinc were classed together as elements which showed little or no depletion, relative to hydrogen, in the interstellar medium. The abundances of other less volatile elements, such as Fe and Mg were found to vary widely from one sight-line to another with gas-phase abundances in some cases being orders of magnitude below their solar counterparts. Detailed studies are reported of the depletion/density behavior of two other volatile elements which were previously considered to be virtually undepleted, S and Zn, using equivalent width data from both Copernicus and IUE observations. The results provide further evidence that the established dependence of depletion on n bar (H) extends to volatile elements and show that their use as tracers of metallicity, or for estimating hydrogen column densities, may lead to large errors in sight-lines through dense regions. It now appears that such elements may take part in the surface chemistry of grains and be important constituents of grain mantle material, although they probably do not contribute significantly to the bulk mass of grains. Due to the very similar atomic masses and ionization potentials of sulphur and phosphorous, the thermal velocity distributions of the singly ionized species of these elements in interstellar clouds should be very similar. However, a comparison of Doppler widths (b-values) derived for SIT and PIT in the same sight-lines from the Bohlin et al Copernicus equivalent width measurements has revealed an unexpected systematic discrepancy of a factor of approx. 1.7. This Discrepancy indicates that the normally adopted oscillators strengths of the PII lambda lambda 1153 and 1302 A lines may require revision.
A survey is reported of interstellar densities, abundances, and cloud structure in the Galaxy, using the IUE and IRAS satellites. Heavy element depletions are discussed along with their correlations with mean density, reddening, and galactic location. Interesting correlations between the Fe/Si abundance ratio and the infrared diffuse cirrus is also reported, which may provide information on the history and formation of grains in the galactic halo.
The thermodynamic stability of clathrate hydrate is calculated to predict the formation conditions corresponding to a range of solar system parameters. The calculations were performed using the statistical mechanical theory developed by van der Waals and Platteeuw (1959) and existing experimental data concerning clathrate hydrate and its components. Dissociation pressures and partition functions (Langmuir constants) are predicted at low pressure for CO clathrate (hydrate) using the properties of chemicals similar to CO. It is argued that nonsolar but well constrained noble gas abundances may be measurable by the Galileo spacecraft in the Jovian atmosphere if the observed carbon enhancement is due to bombardment of the atmosphere by clathrate-bearing planetesimals sometime after planetary formation. The noble gas abundances of the Jovian satellite Titan are predicted, assuming that most of the methane in Titan is accreted as clathrate. It is suggested that under thermodynamically appropriate conditions, complete clathration of water ice could have occurred in high-pressure nebulas around giant planets, but probably not in the outer solar nebula. The stability of clathrate in other pressure ranges is also discussed.
A method for obtaining the C/O elemental abundance ratio for high excitation H II regions is discussed. This is applied to rederive C/O for the Orion Nebula from IUE observations using improved atomic data and extinction corrections. It is found that C/H is 20 to 40% lower than previously determined. When recombinations contribute importantly to (O II) 2470 and 7325 A emission, use of these lines for assessing the O(+) ionic abundance with the so-called empirical method is inadvisable.
The solar wind number density ratios of C(6+) + C(5+) and N(7+) + N(6+) + N(5+) relative to O(8+) + O(7+) + O(6+) have been measured for the first time using data from the Charge-Energy-Mass Spectrometer on the AMPTE/CCE spacecraft during four solar active periods from Sept. 19 to Nov. 1, 1984 when CCE traversed the subsolar magnetosheath of the compressed magnetosphere. It is found that the average values of the density ratios of C/O and N/O to be 0.43 + or - 0.03 and 0.15 + or - 0.06, respectively. These ratios, as well as the average He(2+)/O ratio of 43 + or - 5 for these same time periods, are in excellent agreement with Solar Energetic Particles (SEP) abundance ratios as well as SEP-derived coronal abundances of these elements. The solar wind C/O ratio is substantially below the generally accepted photospheric value of 0.60.
The relative volatilities of lithophile refractory trace elements (LRTE) were determined using calculated 50-percent condensation temperatures. Then, the refractory trace-element abundances were measured in about 100 Allende inclusions. The abundance patterns found in Allende Ca,Al-rich inclusions (CAIs) and ultrarefractory inclusions were used to empirically modify the calculated LRTE volatility sequence. In addition, the importance of crystal-chemical effects, diffusion constraints, and grain transport for the origin of the trace-element chemistry of Allende CAIs (which have important implications for chemical and physical processes in the solar nebula) is discussed.
Observations of the rare isotopes of HCN and HNC have been used to determine the relative abundance of these two chemical isomers along the central ridge of the Orion molecular cloud. The abundance ratio HCN/HNC decreases by more than an order of magnitude from the relatively warm plateau and hot core sources toward the KL nebula to the colder, more quiescent clouds to the north and south. Even in the cooler regions, however, the ratio is an order of magnitude larger than that found in previous investigations of cold dark clouds. The kinetic temperature in the regions studied is determined from new observations of methylacetylene (CH3CCH), together with other recent estimates of the gas temperature near KL. The results suggest that the warmer portions of the cloud are dominated by different chemical pathways that those in the general instellar cloud material.
Two far ultraviolet observations of comet Halley made on 26 February, 1986 and 13 March, 1986 with a sounding rocket experiment are reported. The observed CO spatial profiles can be modelled by a radial outflow model for a parent molecule and suggest that the CO is produced directly from the nucleus of the comet. Using the observed O I emission profile to deduce the H2O production rate, the abundance of CO relative to H2O is found to be 20 percent + or - 5 percent for the first flight and 17 percent + or - 4 percent for the second flight, making CO the second most abundant parent molecule in the coma. The derived production rate of atomic carbon is consistent with that expected from the photodissociation of carbon monoxide.
Abundance analyses using optical region data and fully line-blanketed model atmospheres have been performed for the sharp-lined superficially normal stars HR 6559 (A7 IV) and Eta Leporis (F0 IV), consistent with previous studies of middle B through early A type stars. HR 6559 and Eta Lep are slightly metal-weak in general. Their analyses and that of Theta Leo (A2 V) support the suggestion of Smith (1974) that sharp-lined normal A stars do not necessarily have photospheric abundances identical with those of normal middle to late B stars.
A simplified approach for estimating mineral abundances in mineral mixtures from bidirectional reflectance measurements is presented. Fundamental to this approach is a priori information concerning reflectance spectra of the individual minerals and an estimate of the particle sizes of the components. Simplified equations for bidirectional reflectance are used to linearize the systematics of spectral mixing. The method was used to determine the relative proportions of olivine, magnetite, enstatite, and anorthite in a mixture; the mass fractions of mixture components were calculated on the basis of known particle diameters. The results indicate that for materials without strongly adsorbing components, the accuracy of abundance determinations is better than 5 percent.
Hibonites from the CM meteorites Murchison, Murray, and Cold Bokkeveld, and hibonites and Ti-rich pyroxene from the CV chondrite Allende are studied. Electron microprobe measurements of major element concentrations and track and ion probe measurements of Mg and Ti isotopic ratios, rare earth elements (REEs), and trace element abundances are analyzed. Correlations between isotopic anomalies in Ti, Al-26, Pu-244, and Mg-26(asterisk) are examined. Ti isotopic anomalies are compared with REE and trace element abundance patterns. Reasons for the lack of Al-26 in the hibonites are investigated and discussed. It is observed that there is no correlation between the Ti isotopic compositions, and the presence of Mg-26(asterisk), Pu-244, and REE and trace element patterns in individual hibonite samples. The data reveal that hibonites are not interstellar dust grains but formed on a short time scale and in localized regions of the early solar system.
An abundance analysis using photographic region spectrograms and fully line-blanketed model atmospheres has been performed for the metallic-lined (Am) star 32 Aquarii consistent with previous papers of this series. Its pattern of abundance anomalies is not identical with those of the hot Am stars although there are definite similarities. Changes of up to order 1 dex are foundly by comparison with the previous analysis by Smith. Slightly better agreement is found with the recent analyses of singly-ionized rare earth lines by Magazzu and Cowley. Results are also presented for a model selected on the basis of photometric indices according to the formula of Moon and Dworetsky.
In the interstellar medium, a significant fraction of the free atoms for elements heavier than helium must have condensed into solids, in the form of small, interstellar dust grains. Observations of optical and ultraviolet absorption lines in the spectra of hot stars indicate that the depletions below the cosmic abundances of various elements range from almost none at all to a factor of 0.0001 and seem to be enhanced along lines of sight with higher mean density. Other methods of measuring abundances confirm the absorption line results. The available evidence supports the notion that the grains form in both the atmospheres of cool stars and in dense interstellar clouds, and they are destroyed by shocks which frequently pass through the low density gas.