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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 613 records · Page 34
All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

Sucrose regulation of ADP-glucose pyrophosphorylase subunit genes transcript levels in leaves and fruits

ADP-glucose pyrophosphorylase (AGPase, EC2.7.7.27) is a key regulatory enzyme in starch biosynthesis. The enzyme is a heterotetramer with two S and two B subunits. In tomato, there are three multiple forms of the S subunit gene. Agp S1, S2 and B are highly expressed in fruit from 10 to 25 days after anthesis. Agp S3 is only weakly expressed in fruit. Sucrose significantly elevates expression of Agp S1, S2 and B in both leaves and fruits. Agp S1 exhibits the highest degree of regulation by sucrose. In fact, sucrose may be required for Agp S1 expression. For excised leaves incubated in water, no transcripts for Agp S1 could be detected in the absence of sucrose, whereas it took up to 16 h in water before transcripts were no longer detectable for Agp S2 and B. Neither Agp S3 nor the tubulin gene is affected by sucrose, demonstrating that this response is specifically regulated by a carbohydrate metabolic signal, and is not due to a general increase in metabolism caused by sucrose treatment. Truncated versions of the promoter for Agp S1 indicate that a specific region 1.3-3.0 kb upstream from the transcription site is responsible for sucrose sensitivity. This region of the S1 promoter contains several cis-acting elements present in the promoters of other genes that are also regulated by sucrose. c2002 Elsevier Science Ireland Ltd. All rights reserved.

Non-NASA Center↗
DOE OSTI2026

$B \to π$, $B_{(s)} \to D_{(s)}$ from 2+1+1 Flavor Lattice QCD

We present a lattice-QCD calculation of the hadronic form factors for $B$-meson semileptonic decays computed using the highly improved staggered quark action for both valence and sea quarks on the MILC collaborations 2+1+1-flavor ensembles with lattice spacing ranging from 0.09 fm to 0.03 fm, many with physical pion masses On our finest ensembles, we compute the form factors directly at the physical $b$-quark mass. We discuss the computational setup and analysis strategies for two- and three-point correlation functions. For $B_{(s)} \to D_{(s)}$ we present preliminary results of chiral-continuum fits for the scalar and vector form factors. The goal of this project is a percent-level determination of the scalar and vector form factors to enable high-precision determinations of $|V_{ub}|$ and $|V_{cb}|$. This work fits into a broader program of lattice-QCD studies of weak $B$-meson decays by the Fermilab Lattice and MILC Collaborations.

Cassar, Nicholas [Colorado State U.]↗
NASA NTRS2019

FIGS: spectral fitting constraints on the star formation history of massive galaxies since the cosmic noon

We constrain the stellar population properties of a sample of 52 massive galaxies – with stellar mass log (M(s)/M(⊙)) ≳ 10.5 – over the redshift range 0.5 < z < 2 by use of observer-frame optical and near-infrared slitless spectra from Hubble Space Telescope’s ACS and WFC3 grisms. The deep exposures (∼100 ks) allow us to target individual spectra of massive galaxies to F160W = 22.5 AB. Our spectral fitting approach uses a set of six base models adapted to the redshift and spectral resolution of each observation, and fits the weights of the base models, including potential dust attenuation, via a Markov Chain Monte Carlo method. Our sample comprises a mixed distribution of quiescent (19) and star-forming galaxies (33). We quantify the width of the age distribution (Δt) that is found to dominate the variance of the retrieved parameters according to principal component analysis. The population parameters follow the expected trend towards older ages with increasing mass, and Δt appears to weakly anticorrelate with stellar mass, suggesting a more efficient star formation at the massive end. As expected, the redshift dependence of the relative stellar age (measured in units of the age of the Universe at the source) in the quiescent sample rejects the hypothesis of a single burst (aka monolithic collapse). Radial colour gradients within each galaxy are also explored, finding a wider scatter in the star-forming subsample, but no conclusive trend with respect to the population parameters.

Ignacio Ferreras↗
NASA NTRS2010

Relation Between Type II Bursts and CMEs Inferred from STEREO Observations

The inner coronagraph (COR1) of the Solar Terrestrial Relations Observatory (STEREO) mission has made it possible to observe coronal mass ejections (CMEs) a in the spatial domain overlapping with that of the metric type II radio bursts. The type II bursts were associated with generally weak flares (mostly B and C class soft X-ray flares), but the CMEs were quite energetic. Using CME data for a set of type II bursts during the declining phase of solar cycle 23, we determine the CME height when the type II bursts start, thus giving an estimate of the heliocentric distance at which CME-driven shocks form. This distance has been determined to be approximately 1.5Rs (solar radii), which coincides with the distance at which the Alfv?n speed profile has a minimum value. We also use type II radio observations from STEREO/WAVES and Wind/WAVES observations to show that CMEs with moderate speed drive either weak shocks or no shock at all when they attain a height where the Alfv?n speed peaks (?3Rs ? 4Rs). Thus the shocks seem to be most efficient in accelerating electrons in the heliocentric distance range of 1.5Rs to 4Rs. By combining the radial variation of the CME speed in the inner corona (CME speed increase) and interplanetary medium (speed decrease) we were able to correctly account for the deviations from the universal drift-rate spectrum of type II bursts, thus confirming the close physical connection between type II bursts and CMEs. The average height (approximately 1.5 Rs) of STEREO CMEs at the time of type II bursts is smaller than that (2.2 Rs) obtained for SOHO (Solar and Heliospheric Observatory) CMEs. We suggest that this may indicate, at least partly, the density reduction in the corona between the maximum and declining phases, so a given plasma level occurs closer to the Sun in the latter phase. In two cases, there was a diffuse shock-like feature ahead of the main body of the CME, indicating a standoff distance of 1Rs - 2Rs by the time the CME left the LASCO field of view.

Gopalswamy, N.↗
DOE OSTI2026

Rational Design of Weakly‐Solvating Molecules for Salt‐In‐Pre‐Ionic‐Liquid Electrolytes for Li Metal Batteries

Lithium metal batteries (LMBs) promise step‐changes in energy densities but suffer from poor cycle life due to unstable electrolyte‐lithium interfaces. Conventional carbonate electrolytes exhibit excessive lithium‐ion solvation and low oxidative stability, leading to rapid capacity loss. Herein, we report a rationally designed weakly‐solvating cyclic sulfonamide, 1‐trifluoromethanesulfonyl)amide pyrrolidine (TFMSPyr), which integrates an electron‐withdrawing trifluoromethanesulfonyl functional group at pyrrolidinic‐N. TFMSPyr acts as a pre‐ionic‐liquid solvent that forms intrinsically localized, anion‐dominated solvation, coupling molecular architecture, solvation topology, and transport dynamics. As a result, LiFSI based salt‐in‐pre‐ionic‐liquid (SIPIL) electrolytes exhibit high lithium‐ion transference number, oxidative stability > 5 V versus Li/Li + and anion‐derived solid electrolyte interphases (SEI). Li||Cu cells with SIPIL deliver a first cycle Coulombic efficiency (CE) of ≈ 99% with average CE of 99.2% for 100 cycles, and lithium half‐cells with lithium iron phosphate (LFP) cathode exhibit 82% capacity retention after 400 cycles with CE of 99.98%. In anode‐free full cells, 95% of initial capacity is retained after 63 cycles with an average CE of 99.5%. These results demonstrate that molecular engineering of solvents offers a powerful pathway to stabilize lithium metal interfaces and enable practical Anodeless LMBs.

25 ENERGY STORAGE↗
DOE OSTI2020

Phosphonate‐Modified UiO‐66 Brønsted Acid Catalyst and Its Use in Dehydra‐Decyclization of 2‐Methyltetrahydrofuran to Pentadienes

Abstract Phosphorus‐modified all‐silica zeolites exhibit activity and selectivity in certain Brønsted acid catalyzed reactions for biomass conversion. In an effort to achieve similar performance with catalysts having well‐defined sites, we report the incorporation of Brønsted acidity to metal–organic frameworks with the UiO‐66 topology, achieved by attaching phosphonic acid to the 1,4‐benzenedicarboxylate ligand and using it to form UiO‐66‐PO 3 H 2 by post‐synthesis modification. Characterization reveals that UiO‐66‐PO 3 H 2 retains stability similar to UiO‐66, and exhibits weak Brønsted acidity, as demonstrated by titrations, alcohol dehydration, and dehydra‐decyclization of 2‐methyltetrahydrofuran (2‐MTHF). For the later reaction, the reported catalyst exhibits site‐time yields and selectivity approaching that of phosphoric acid on all‐silica zeolites. Using solid‐state NMR and deprotonation energy calculations, the chemical environments of P and the corresponding acidities are determined.

Dorneles de Mello, Matheus↗
DOE OSTI2022

Tailoring solid-electrolyte interphase and solvation structure for subzero temperature, fast-charging, and long-cycle-life sodium-ion batteries

The sluggish Na + reaction kinetics with carbon materials limits the fast-charging capability, Coulombic efficiency, and cycle life of sodium-ion batteries, especially at low temperatures. Herein, free-standing carbon nanofiber films, with controllable crystallinity and surface chemistry, are used as a platform to investigate the correlation between Na + reaction kinetics, storage mechanism, and electrolyte environment. The ion solvation effect and solid-electrolyte interphase (SEI) properties determine the kinetics and storage mechanism. A strong Na + -solvent interaction, such as Na + -diglyme, tends to form a "pseudo-SEI" layer dominated by anion decomposition, enabling fast Na + -solvent co-intercalation kinetics. Tuning the SEI chemistries by pre-cycling in the weakly solvated electrolyte (e.g., ester electrolyte), the intercalation capacity rapidly disappears due to the high energy barrier for Na + transport. Finally, such mechanistic insights allow us to develop the optimal combination of electrode materials and electrolyte chemistry to achieve high initial Coulombic efficiency, ultra-long cycle life under fast charging, and excellent low-temperature performance.

25 ENERGY STORAGE↗
DOE OSTI2026

Dynamics of the water-plasma interface in various discharge modes of atmospheric-pressure plasmas

This paper presents an experimental study of the dynamics of the water-plasma interface during the interaction high-voltage (HV) atmospheric pressure discharge with the water surface. Under the influence of the voltage applied to the pin type electrode, discharges are formed at the air layer between the sharp-tip HV electrode and deionized water. Three discharge regimes were identified from synchronized electrical waveforms and imaging: (i) a weak linear regime at 3–10.6 kV, (ii) a branching streamer regime at the maximum applied voltage of 12.6 kV, and (iii) a continuous arc-like regime occurring during the transition to lower voltage and higher current (e.g., U ≈ 3.2 kV, I ≈ 4.07 mA). High-speed shadowgraph images showed a symmetric interfacial cavity whose depth increased nonlinearly with voltage from h 0 ≈ 0.1 mm at 3 kV to h 0 ≈ 2.7 mm at 10.6 kV, reaching a maximum depth of h 0 ≈ 5.9 mm at 12.6 kV, while the cavity disappeared in the continuous-channel regime and was replaced by outward-propagating wave-like motion. The deformation of the water surface during the discharge-water interaction is governed by the balance between electric field forces, surface tension, gravitational forces, and electrohydrodynamic forces, whose relative contributions vary with the applied voltage. This effect was explained by quantitatively estimating the magnitudes of the acting forces and establishing the force balance. Optical emission spectroscopy in the continuous-channel regime indicated air plasma signatures and yielded a gas temperature of approximately 400 K, while prolonged operation (≈ 20 min) increased the water temperature to ~ 70 °C, reduced the water-layer thickness from 6 mm to 3 mm, and decreased pH from 7 to 4. These regime-resolved, quantitative results clarify how the dominant interfacial forcing shifts with discharge mode and provide a mechanistic basis for controlling plasma-water interactions in atmospheric-pressure applications.

atmospheric pressure plasma↗
DOE OSTI2026

Dark Energy Survey Year 3: Blue shear

Modeling the intrinsic alignment (IA) of galaxies poses a challenge to weak lensing analyses. Here, using the Dark Energy Survey Year 3 shape catalog, we expect less impact from IA when we limit the sample to blue, star-forming galaxies. The cosmological parameter constraints from this BLUE cosmic shear sample are stable to IA model choice, unlike passive galaxies in the full DES Y3 sample, the goodness-of-fit is improved and the Ω m and 𝑆 8 better agree with the observations from Planck on the cosmic microwave background. Mitigating IA with sample selection in DES, rather than flexible model choices, can reduce uncertainty in 𝑆 8 by a factor of 1.5.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1975

Copernicus observations of Betelgeuse and Antares

Copernicus observations of the M-supergiants, alpha Ori and alpha Sco, are presented. The MgII h and k resonance lines are strongly in emission in both stars. The k line is highly asymmetric in both stars but the h line is symmetric. Upper limits for several other resonance lines are given for alpha Ori. The possibility is explored that the k line asymmetry is caused by overlying resonance lines of MnI and FeI formed in the cool circumstellar gas shells around these stars. Observations of the MnI 4030-4033 A lines are used to show that circumstellar shell absorption is too weak to explain the asymmetry. It is suggested that the absorption occurs in a cool turbulent region between the base of the circumstellar shell and the top of the chromosphere.

Bernat, A. P.↗
NASA NTRS1977

The Viking magnetic properties experiment - Primary mission results

Three permanent magnet arrays were mounted on each Viking lander: a strong array fixed on a photometric reference test chart on top of the landers; and two arrays, one strong and one weak, incorporated into the backhoe of the surface sampler. Some or all of the magnetic particles detected could be highly magnetic unoxidized mineral grains (metallic Fe, magnetite, pyrrhotite) forming the core beneath a reddish coating of limonite or hematite; or grains composed of gamma-Fe2O3, with and without other iron oxides; or igneous rock (or mineral particles) which consist of an admixture of unweathered silicate material or minerals with a significant fraction of highly magnetic phase, again with a reddish coating; they could be also igneous rock or mineral particles, intrinsically nonmagnetic, but having a reddish coating containing gamma-Fe2O3; or clay mineral particles which contain and/or are coated with Fe2O3, of which a substantial fraction is in the gamma-Fe2O3 form.

Hargraves, R. B.↗
NASA NTRS1985

On convergence of computation of chemically reacting flows

The computational problems associated with high-temperature flows undergoing finite-rate ionization reactions is investigated. The conservation equations governing chemical species and vibrational and electron energies are solved simultaneously with those for overall mass, momentum, and energy for a one-dimensional subsonic flow, through a constant-area duct, originating behind a normal shock wave, using an implicit time-marching technique. Boundary conditions are imposed in the form of characteristic wave variables accounting for the effects of chemical reactions on the speed of sound. Converging solutions are obtained for cases in which chemical reactions are weak, but difficulty is encountered in other cases. The cause of the difficulty is investigated and shown to be the sharp pressure disturbances produced by such reactions.

Park, C.↗
NASA NTRS1990

Comparisons of thermochemical nonequilibrium viscous flowfield predictions for AFE vehicle

Numerical solutions for the Aeroassist Flight Experiment vehicle were obtained from three methods at a trajectory point corresponding to the maximum aerodynamic heating. The flow regime and vehicle's speed require a viscous model of laminar flow and finite-rate chemical and thermal modeling. The computational domain covers both forebody and base such that the shock layer and near wake flowfield are included. Because of differences in computational grids, methods of solution, and models of rate equations, the results are generally in poor agreement. Temperature and species concentrations are strongly affected by the physical model equations and associated parameters. The chemistry model based on 11 species is found to yield lower translational temperature profile near stagnation than those from a seven-species model. The vibrational temperature varies according to the modeling details. All solutions indicate that strong neutral and/or molecular dissociation and weak ionization take place at the forebody and vibrational freezing is present in the afterbody expansion region where the vibrational temperature is higher than the translational temperature. Some forms of shear layer emanating from the aerobrake skirt coalesce in the region of reversed flow behind the vehicle.

Tam, Luen T.↗
NASA NTRS1990

Weakly multi-dimensional cosmic-ray-modified MHD shocks

The multi-dimensional structure of weak, energetic-particle-modified shocks is investigated by means of appropriate perturbation techniques. The time-dependent shock-structure equation is found to be a generalized form of the well-known one-dimensional Burgers equation, whose steady state, in the absence of cosmic rays, is shown to be related to an equation modeling steady transonic flow in several dimensions. The time-dependent (1 + 2)- and (1 + 3)-dimensional Burgers equations are integrated exactly by means of Hirota's technique for one-shock solutions. On the basis of the exact solutions, a discussion relating the various length scales associated with the shock is presented.

Zank, G. P.↗
NASA NTRS1993

Double layer propagation in experiments with electron beam injection

Electron beam injection into a plasma is investigated using the analytical inverted Bernstein-Green-Kruskal method. Particle number and momentum conservation laws are applied to evaluate the propagation velocity and potential drop on the leading edge of the beam. Electric potential is supposed to be monotonic, thus the leading front has a double-layer-like structure. For the case of cold particles, analytical expressions for the double layer velocity and potential drop are obtained. It is pointed out that double layer velocity differs from the initial electron speed: even for weak beams a noticeable deceleration takes place. Strong beams are found incapable of penetrating into plasma - their propagation velocity is very small. Ambient electrons undergo a considerable acceleration forming a return current which neutralizes the injector. Possible instability of the distribution functions is discussed.

Bruskin, L. G.↗
NASA NTRS2000

Realistic Solar Surface Convection Simulations

We perform essentially parameter free simulations with realistic physics of convection near the solar surface. We summarize the physics that is included and compare the simulation results with observations. Excellent agreement is obtained for the depth of the convection zone, the p-mode frequencies, the p-mode excitation rate, the distribution of the emergent continuum intensity, and the profiles of weak photospheric lines. We describe how solar convection is nonlocal. It is driven from a thin surface thermal boundary layer where radiative cooling produces low entropy gas which forms the cores of the downdrafts in which most of the buoyancy work occurs. We show that turbulence and vorticity are mostly confined to the intergranular lanes and underlying downdrafts. Finally, we illustrate our current work on magneto-convection.

Stein, Robert F.↗
NASA NTRS1993

Risk Assessment System

FEAT, a software system for evaluating risks, was developed by Lockheed and later enhanced under NASA funding. FEAT uses directed graph - or digraph - models to provide information on cause and effect if a set of failure events occurs. James Miller, the program designer at Lockheed, formed DiGraphics, Inc. to market the software that has evolved from FEAT. The Diquest Analyzer, the company's flagship product, assists product designers in identifying the redundancies and weaknesses of a system. The software has applications in the chemical industry for risk assessment, design evaluation, and change management. Additional markets have been found in operations monitoring diagnostics and training of new personnel.

Source record↗