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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 613 records · Page 34
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Techno-Economic Analysis and Market Potential of Geological Thermal Energy Storage (GeoTES) Charged With Solar Thermal and Heat Pumps into Depleted Oil/Gas Reservoirs and Shallow Reservoirs: A Technology Overview: Preprint

Depleted oil/gas reservoirs represent a waste of underground resources and investments of drilling, and also a potential risk to the earth's environment. Geologic thermal energy storage (GeoTES) is proposed as a solution to convert depleted oil/gas reservoirs into long-term seasonal energy storage. GeoTES can be hybridized with other techniques for viable commercial deployment, such as 1) concentrating solar power (CSP) collectors and 2) heat pumps with excess renewable energy. Here, a technology overview is given on the two GeoTES technologies, which includes system overview, techno-economic models, and case study. Both GeoTES technologies show great potential in the economics of individual project deployment and applicability across the US.

concentrating solar power↗
DOE OSTI2021

Quantifying Rooftop Solar Benefits: A State-Level Value of Solar Analysis for India

Analyses that quantify the costs and benefits associated with rooftop solar (RTS) adoption and operation can inform decision-makers in the development and evaluation of RTS policies. One such analysis is a Value of Solar (VOS) study, which quantifies select costs and benefits surrounding RTS based on the electricity system context. These studies can drive changes to existing policies towards fairer, more cost-reflective RTS compensation or alternatively can provide confidence for the decision-maker to stay the course and largely maintain existing policies. This report provides a VOS analysis for two states in India: Gujarat and Jharkhand and provides details related to the methodology and key findings.

14 SOLAR ENERGY↗
DOE OSTI2024

Community Solar and Community Solar+Storage: A Roadmap of Barriers and Solutions for Commercial Systems in NYC

Sustainable CUNY worked with decision makers and subject matter experts (SME's) to identify the barriers to and solutions for advancing commercial Community Solar (CS) and CS+Storage (CS+S) in urban areas. This roadmap captures the key challenges and solutions identified by New York City (NYC) stakeholders, including the Real Estate Board of New York (REBNY), through a collaborative process. Solar, as well as storage, are among the fastest growing energy segments in the United States, with CS, also known as Community Distributed Generation (CDG), gaining popularity with those who may not own or have access to a viable roof. Urban areas like NYC, which have a large population of renters, are particularly well suited for CS projects where credits from the power produced by a large remote installation are offered on a subscription basis to residents or businesses in the community. However, CS and CS+S projects have stalled at the doorstep of many cities. Host site owners, particularly those with large rooftops, have been slow to commit to installing CS due to competing rooftop usage and programs, limited knowledge about incentives, lack of economic data, and a complicated implementation process.

14 SOLAR ENERGY↗
DOE OSTI2017

Features of load current–voltage characteristics of a monocrystalline silicon solar cell at various levels of solar illumination

We have studied the electric current characteristics of a monocrystalline silicon solar cell (SC) at various solar radiation power levels from 0.05 kW/m{sup 2} to 1 kW/m{sup 2} (АМ1). It has been found that the energy efficiency of the SC increases from 9.5 to 15% with an increase in the power of radiation. The series resistance and shunt resistance of the SC decrease, which is associated with the modulation of the photoactive layers of SC.

14 SOLAR ENERGY↗
DOE OSTI2017

GaSb‐Based Solar Cells for Full Solar Spectrum Energy Harvesting

Abstract In this work, a multijunction solar cell is developed on a GaSb substrate that can efficiently convert the long‐wavelength photons typically lost in a multijunction solar cell into electricity. A combination of modeling and experimental device development is used to optimize the performance of a dual junction GaSb/InGaAsSb concentrator solar cell. Using transfer printing, a commercially available GaAs‐based triple junction cell is stacked mechanically with the GaSb‐based materials to create a four‐terminal, five junction cell with a spectral response range covering the region containing >99% of the available direct‐beam power from the Sun reaching the surface of the Earth. The cell is assembled in a mini‐module with a geometric concentration ratio of 744 suns on a two‐axis tracking system and demonstrated a combined module efficiency of 41.2%, measured outdoors in Durham, NC. Taking into account the measured transmission of the optics gives an implied cell efficiency of 44.5%.

Lumb, Matthew P.↗
DOE OSTI2018

Improving Solar Cell Performance Using Quantum Dot Triad Charge-Separation Engines

Here, we use kinetic modeling to explore the current–voltage, power–voltage, and power conversion efficiency characteristics of quantum dot dyads and triads as possible light absorption and charge separation engines in quantum dot, bulk heterojunction solar cells. The external and internal power conversion quantum efficiencies are significantly enhanced by introducing a third quantum dot between the donor and acceptor quantum dots. Given the constraint of comparable charge-recombination and charge-separation rates, open-circuit voltages for triads are predicted to be about 10%–17% larger than those for dyads, and short-circuit currents for triads are about 400% larger than those for dyads. These improvements in the efficiencies can be further enhanced by tuning the band-edge energy offset of the middle-position quantum dot from its neighbors. The band-edge energies of the middle quantum dot should be tuned so that they form a cascading band-edge energy alignment from the band-edge energies of the left CdTe QD to the right CdSe QD. To produce the most favorable solar cell performance, the middle quantum dot’s conduction (valence) band edge should be closer to the right quantum dot’s band edge when the charge recombination rates are low (high) and near the conduction (valence) band edge of the left quantum dot when the charge recombination rates are high (low). This analysis identifies prime strategies to design multi-QD assemblies for solar energy harvesting and conversion.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Hydrogen from Sunlight and Water: A Side-by-Side Comparison between Photoelectrochemical and Solar Thermochemical Water-Splitting

Photoelectrochemical (PEC) and solar thermochemical (STCH) water-splitting represent two promising pathways for direct solar hydrogen generation. PEC water-splitting integrates multiple functional materials and utilizes energetic electrons and holes generated from sunlight to produce hydrogen and oxygen in two half-reactions, while STCH water-splitting couples a series of consecutive chemical reactions and uses absorbed heat from sunlight to generate hydrogen and oxygen in two full reactions. In this Focus Review, the basic operating principles, sunlight utilization, device architecture, reactor design, instantaneous and annually averaged solar-to-hydrogen (STH) conversion efficiency, and the operating conditions and constraints of both pathways are compared. A side-by-side comparison addresses some common sources of confusion and misinterpretation, especially in the evaluation of STH conversion efficiencies, and reveals distinct features and challenges in both PEC and STCH technologies. Furthermore, this Focus Review also addresses materials and device challenges in PEC and STCH for cost-competitive hydrogen generation.

08 HYDROGEN↗
DOE OSTI2017

Simultaneous Increase in Open-Circuit Voltage and Efficiency of Fullerene-Free Solar Cells through Chlorinated Thieno[3,4- b ]thiophene Polymer Donor

The chlorinated polymer, PBTCl, has been found to be an efficient donor in nonfullerene polymer solar cells (PSCs), which showed a blue-shifted absorbance compared to that of its fluorine analogue (PTB7-th) and resulted in more complementary light absorption with a nonfullerene acceptor, such as ITIC. Meanwhile, chlorine substitution lowered the HOMO level of PBTCl, which increased the open-circuit voltage of the corresponding polymer-based devices. The 2D GIWAXS analysis illustrated that the PBTCl/ITIC blend film exhibited a “face-on” orientation and scattering features of both PBTCl and ITIC, suggesting that the blend of PBTCl and ITIC was phase-separated and formed individual crystalline domains of the donor and acceptor, which promoted charge transfer in the bicontinuous film and eventually elevated the solar energy conversion efficiency. The PBTCl-based nonfullerene PSC exhibited a maximum PCE of 7.57% with a Voc of 0.91 V, which was an approximately 13% increasing in the PCE compared to that of the fluorine-analogue-based device.

36 MATERIALS SCIENCE↗
DOE OSTI2017

A new strategy to engineer polymer bulk heterojunction solar cells with thick active layers via self-assembly of the tertiary columnar phase

Here, we report that the addition of a non-photoactive tertiary polymer phase in the binary bulk heterojunction (BHJ) polymer solar cell leads to a self-assembled columnar nanostructure, enhancing the charge mobilities and photovoltaic efficiency with surprisingly increased optimal active blend thicknesses over 300 nm, 3–4 times larger than that of the binary counterpart. Using the prototypical poly(3-hexylthiophene) (P3HT):fullerene blend as a model BHJ system, we discover that the inert poly(methyl methacrylate) (PMMA) added in the binary BHJ blend self-assembles into vertical columns, which not only template the phase segregation of electron acceptor fullerenes but also induce the out-of-plane rotation of the edge-on-orientated crystalline P3HT phase. Using complementary interrogation methods including neutron reflectivity, X-ray scattering, atomic force microscopy, transmission electron microscopy, and molecular dynamics simulations, we show that the enhanced charge transport originates from the more randomized molecular stacking of the P3HT phase and the spontaneous segregation of fullerenes at the P3HT/PMMA interface, driven by the high surface tension between the two polymeric components. The results demonstrate a potential method for increasing the thicknesses of high-performance polymer BHJ solar cells with improved photovoltaic efficiency, alleviating the burden of stringently controlling the ultrathin blend thickness during the roll-to-roll-type large-area manufacturing environment.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2018

Unassisted solar water splitting with 9.8% efficiency and over 100 h stability based on Si solar cells and photoelectrodes catalyzed by bifunctional Ni–Mo/Ni

Designing a highly efficient and stable photoelectrochemical (PEC) tandem cell for unassisted solar water splitting is considered a promising approach for large-scale solar energy storage. To date, various tandem device configurations have been reported. However, the achievement of a solar-to-hydrogen conversion efficiency (η STH ) of 10% is still full of challenges, due to the incompatibility between the two photoelectrode materials. Here, we report a highly efficient and stable photovoltaic (PV)–PEC tandem device composed of a dual Si photoelectrode and two series-connected ordinary Si PV cells. The dual-photoelectrode device consists of an n + np + -Si photocathode and p + pn + -Si photoanode, which allow back illumination from the Si substrate, spatially and functionally decoupling the optical absorption and the catalytic activity. By further employing a Ni protective layer together with a bifunctional Ni–Mo catalyst for both the Si photocathode and photoanode, the PV–PEC tandem cell can perform spontaneous water splitting without any applied bias. A high η STH of 9.8% with a stability of over 100 h was achieved in alkaline solution under parallel AM 1.5G 1 sun illumination. Furthermore, this work essentially allows a modular independent optimization of each component which can enhance the efficiency and stability of the PV–PEC cells.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

β-Functionalized push–pull opp-dibenzoporphyrins as sensitizers for dye-sensitized solar cells: the role of the phenylethynyl bridge

A novel class of β-functionalized push–pull zinc opp-dibenzoporphyrins was designed and synthesized as sensitizers for dye-sensitized solar cells. Dibenzoporphyrin YH7 displayed strong push–pull characteristics, which included clearly segregated HOMO/LUMO and fast charge injection from the singlet excited state of zinc porphyrin to the conduction band of TiO 2 . The incorporation of both the phenylethynyl bridge and amino group was critical to achieve the enhanced push–pull effect. The highest PCE value in this series obtained with the YH6 cell was 6.7%, which is comparable to that of the best ruthenium dye, N719 (η = 7.4%), under similar conditions. The high PCE of the YH6 cell is ascribed to its high light harvesting ability and favorable cell kinetics, which is supported by electrochemical impedance spectroscopy studies and femtosecond transient absorption studies. An unusual illumination-induced photodegradation was observed for YH7, which was attributed as the major reason for the unexpected lower PCE of the YH7 cell (η = 5.7%). Furthermore, this work demonstrates the applicability of π-extended porphyrins as a new generation of sensitizers for high performance dye-sensitized solar cells.

Hu, Yi↗
NASA NTRS1972

Radiation scales on which standard values of the solar constant and solar spectral irradiance are based

The question of radiation scales is critically examined. There are two radiation scales which are of fundamental validity and there are several calibration standards and radiation scales which have been set up for practical convenience. The interrelation between these scales is investigated. It is shown that within the limits of accuracy of irradiance measurements in general and solar irradiance measurements in particular, the proposed standard values of the solar constant and solar spectrum should be considered to be on radiation scales of fundamental validity; those based on absolute electrical units and on the thermodynamic Kelvin temperature scale.

Thekaekara, M. P.↗
NASA NTRS1972

Revised standards for the solar constant and the solar spectrum

The values of the solar constant and solar spectrum are presented which are proposed as revised standards for science and technology. A solar constant value of 1.94 cal/sq cm min or 135.3 mW/sq cm was proposed. A detailed spectral irradiance table is given for the range of 0.12 to 1000 microns.

Thekaekara, M. P.↗
NASA NTRS1972

Solar flares and solar wind helium enrichments - July 1965-July 1967.

It has previously been suggested that the very high relative abundances of helium occasionally observed in the solar wind mark the plasma accelerated by major solar flares. To confirm this hypothesis, we have studied the 43 spectra with He/H greater than 15% that were observed among 10,300 spectra collected by Vela 3 between July 1965-July 1967. Six new flare-enhancement events are discussed in this paper. It is concluded that the association of helium enhancements with major flares is real, nonrandom, and very strong. With this study, there are 12 cases of reliable associations between helium enhancements and flares reported in the literature. The general characteristics of these events are discussed. It is found that the flares are typically large and bright (2B or 3B), often they produce cosmic ray protons, and they are widely distributed in solar longitude. A qualitative discussion of some of the possibilities for the source of helium enhanced plasma is presented. It is suggested that the helium enriched plasma may be the piston producing the shock causing the Type II radio emission.

Hirshberg, J.↗
NASA NTRS1972

Solar wind helium enhancements following major solar flares

The observations of solar wind helium enhancements following major solar flares are reviewed, and the hypothesis that helium enhancements often mark flare piston plasma is confirmed. Helium enhancements were observed during each of the three periods (March 1966, July 1966, August/September 1966) of major solar activity that occurred from October 1965 to October 1966. No enhancements were seen during the long quiet periods that occurred that year. At 1 AU, the helium-enhanced plasma pistons had slowed so that the velocity was 80 percent of the mean transit velocity, in general agreement with theoretical models of the propagation of flare disturbances. A qualitative model, in which the piston plasma is accelerated from the flare site deep in the corona, is discussed briefly. If the model is valid in general outline, the piston plasmas provide samples of material from the lower levels of the corona.

Hirshberg, J.↗