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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 613 records · Page 34

High-temperature ceramic heat exchanger element for a solar thermal receiver

A study has been completed on the development of a high-temperature ceramic heat exchanger element to be integrated into a solar reciver producing heated air. A number of conceptual designs were developed for heat exchanger elements of differing configuration. These were evaluated with respect to thermal performance, pressure drop, structural integrity, and fabricability. The final design selection identified a finned ceramic shell as the most favorable concept. The ceramic shell is surrounded by a larger metallic shell. The flanges of the two shells are sealed to provide a leak-tight pressure vessel. The ceramic shell is fabricated by an innovative combination of slip casting the receiver walls and precision casting the heat transfer finned plates. The fins are bonded to the shell during firing. Fabrication of a one-half scale demonstrator ceramic receiver has been completed.

Strumpf, H. J.↗

Promoted Combustion Behavior of 316 Stainless Steel and 6061 Aluminum Alloys in Elevated Pressure Nitrox Environments

Promoted combustion testing (outlined in the ASTM G124 “Standard Test Method for Determining the Combustion Behavior of Metallic Materials in Oxygen Enriched Atmospheres”) refers to a useful testing method to evaluate how metallic materials will behave when combusted in environments with high oxygen concentrations, elevated pressure, or both. These tests yield data which is useful for engineers and scientists from a variety of industries who need and rely on oxygen systems. Oxygen Compatibility Assessments (OCA’s) are vital for ensuring that materials will be safe for use, and these assessments rely on data from OCA’s or interpolation if a desired pressure/concentration is outside of previously tested bounds. It was identified that these bounds leave out significant areas of data for materials which are tested at high pressures (above 1500 psi) and variable oxygen concentrations (with nitrogen as the diluent gas). For this reason, the authors posited that conducting promoted combustion testing on materials above 1500 psi and in various concentrations of oxygen would be incredibly useful in future analyses for oxygen compatibility with similar environments (such as breathing air) as well as for further understanding of how materials behave at very high pressures (such as 10000 psi). Two materials were selected which are commonly used in industry today - 316 stainless steel and 6061 aluminum – and they were tested and analyzed for the purposes of this study.

oxygen compatibility↗

Reaction Pathways and Energy Consumption in NH 3 Decomposition for H 2 Production by Low Temperature, Atmospheric Pressure Plasma

Pathways for NH 3 decomposition to N 2 and N 2 H 4 by atmospheric pressure nonthermal plasma are analyzed using a combination of molecular beam mass spectrometry measurements and zero-dimensional kinetic modeling. Experimental measurements show that NH 3 conversion and selectivity towards N 2 formation scale monotonically with the specific energy input into the plasma with ~ 100% selectivity to N 2 formation achieved at specific energy inputs above 0.12 J cm −3 (3.1 eV (molecule NH 3 ) −1 ). The kinetic model recovers these trends, although it underpredicts N 2 selectivity at low specific energy input. These discrepancies can be explained by the underestimation of reaction rate coefficients for reactions that consume N 2 H x species in collisions with H radicals and/or radial nonuniformities in power deposition, gas temperature, and species concentrations that are not represented by the plug flow approximation used in the model. The kinetic model shows that N 2 formation proceeds through N 2 H x decomposition pathways rather than NH x decomposition pathways in low temperature, atmospheric pressure plasma. Higher selectivity toward N 2 production can be achieved by operating at higher NH 3 conversion and with a higher gas temperature. Furthermore, the high energy cost of NH 3 decomposition by atmospheric pressure nonthermal plasma found in this work (25–50 eV (molecule NH 3 converted) −1 ; 17–33 eV (molecule H 2 formed) −1 ) is a result of the energy requirement for electron-impact dissociation of NH 3 and the significant re-formation of NH 3 by three-body recombination reactions between NH 2 and H.

Nonthermal plasma↗

Ares I Scale Model Acoustic Test Instrumentation for Acoustic and Pressure Measurements

Ares I Scale Model Acoustic Test (ASMAT) is a 5% scale model test of the Ares I vehicle, launch pad and support structures conducted at MSFC to verify acoustic and ignition environments and evaluate water suppression systems Test design considerations 5% measurements must be scaled to full scale requiring high frequency measurements Users had different frequencies of interest Acoustics: 200 - 2,000 Hz full scale equals 4,000 - 40,000 Hz model scale Ignition Transient: 0 - 100 Hz full scale equals 0 - 2,000 Hz model scale Environment exposure Weather exposure: heat, humidity, thunderstorms, rain, cold and snow Test environments: Plume impingement heat and pressure, and water deluge impingement Several types of sensors were used to measure the environments Different instrument mounts were used according to the location and exposure to the environment This presentation addresses the observed effects of the selected sensors and mount design on the acoustic and pressure measurements

Vargas, Magda B.↗

Validation of a Two-Phase CFD Model for Autogenous Pressurization and Expulsion

This paper presents a two-phase computational fluid dynamics (CFD) model for simulating autogenous pressurization and expulsion in a cryogenic liquid hydrogen storage tank, utilizing a volume-of-fluid (VOF) approach combined with the kinetics-based Schrage equation to accurately capture the phase boundary and interfacial heat, mass, and momentum transfer between liquid and vapor phases. The model is validated against experimental data from NASA's K-site tank facility, specifically experimental case 225, which involved pressurization and controlled expulsion of liquid hydrogen. Various turbulence models are evaluated to assess their influence on model accuracy. The CFD simulations successfully replicate key thermodynamic behaviors observed during the experiments, including pressure evolution, temperature profiles, and phase-change dynamics at the vapor-liquid interface. The predicted tank pressures, temperatures, and pressurant requirements agree with experimental data, with pressurant mass predictions within 16\% of observed values. This study highlights the importance of selecting appropriate turbulence models to accurately simulate complex flow and heat transfer phenomena during tank pressurization and expulsion. By enhancing the accuracy and reliability of CFD models for liquid hydrogen under cryogenic conditions, this research contributes to developing efficient cryogenic propellant management strategies for future space missions.

Computational Fluid Dynamics↗

A study of real jet effects on the surface pressure distribution induced by a jet in a crossflow

A study of jet exit profile, exit Mach number, swirl and turbulence level on jet-induced loadings for jets exhausting from a surface into a crossflow is presented. The importance of each of these real jet characteristics is assessed using available data. Where adequate surface pressure distribution data are available, a correlation method to predict surface pressure for a jet exhausting from an infinite flat plate is used either to attempt to develop a correlation based on the real jet characteristics or to model the effects of that characteristic. Data comparisons are presented for selected cases. Also, a summary of information on surface pressure distribution data for jet exhausting from flat plates into a subsonic crossflow is presented.

Perkins, S. C., Jr.↗

Evaluations of Damaged High-Pressure Compressor Blades in Two Turbine Engines of NASA DC–8

A series of flights were performed by the NASA DC-8 for the FIREX-AQ missions to observe the effects of wildfires and agricultural fires on air quality and climate in selected locations of the United States. Borescope evaluations after these flights indicated accelerated damage had occurred over this flight series to the blades in the high pressure compressor section of all four CFM56-2C1 turbine engines. This erosion and impact damage appeared to vary in severity, and appeared most severe for engines 3 and 4 located on the right wing of the DC-8.Engine 3 had the most flight hours and cycles since last overhaul of 7,152 h and 2,502 cycles. Engine 4 had the lowest flight hours and cycles since last overhaul of 1,354 h and 369 cycles. For these reasons, three noticeably damaged blades were selected from the high pressure compressor for each of these two engines, and then evaluated at NASA GRC using optical and scanning electron microscopy. Engine 3 compressor blades had both erosion and impact damage that were observed and characterized. The erosion damage was associated with embedded particles 13 μm to 42 μm in sectioned width, composed of varied compositions ranging from SiO2 to SiO2 also containing Ca, Mg, and Al (CMAS). The impact damage was associated with the impacts of larger objects at least 650 μm to 850 μm in width, but only small fragments 5 μm to 15 μm in sectioned width were embedded in the impact surface, also composed of SiO2 to SiO2 containing Ca, Mg, and Al (CMAS). On the other hand, engine 4 blades had only impact damage that was observed and characterized. This impact damage was associated with impacts of objects at least 1,480 μm to 2,080μm in width. Small fragments 5 μm to 15 μm in sectioned width were embedded in the impact surface. For one impact, the fragments were again composed of SiO2 to SiO2 containing Ca, Mg, and Al (CMAS). For two other impacts, the fragments were often composed of Fe, and less frequently Cu.

turbine↗

Non-Oxidative Ethane Dehydrogenation in a Packed-Bed DBD Plasma Reactor

Abstract Plasma-assisted conversion of ethane (C 2 H 6 ) can produce value-added chemical building blocks using green electricity. Here we employ a simple packed-bed coaxial dielectric barrier discharge (DBD) reactor to convert C 2 H 6 at mild operating conditions unattainable by conventional thermocatalysis. Ethylene (C 2 H 4 ), acetylene (C 2 H 2 ), and methane (CH 4 ) are the main products along with small fractions of C 3 and C 4 hydrocarbons. Interestingly, the C 2 H 4 selectivity is primarily correlated to C 2 H 6 conversion, dominated by electron dissociation and recombination reactions irrespective of the dielectric properties of the packed bed material (SiO 2 , Al 2 O 3 , ZrO 2 , TiO 2 , and BaTiO 3 ), packing material size, supplied power, and C 2 H 6 concentration. While a distortion of the electric field and discharge propagation results in varying dissipated power as materials change, the C 2 H 4 energy yield remains constant. The particle size appears to affect conversion mainly due to pressure alterations. Pd/SiO 2 catalyst can change the selectivity, favoring saturated species by expending hydrogen.

Engineering↗

Structural load challenges during space shuttle development

The challenges that resulted from the unique configuration of the space shuttle and capabilities developed to meet these challenges are described. The methods and the organization that were developed to perform dynamic loads analyses on the space shuttle configuration and to assess dynamic data developed after design are discussed. Examples are presented from the dynamic loads analysis of the lift-off and maximum dynamic pressure portion of ascent. Also shown are orbital flight test results, for which selected predicted responses are compared to measured data for the lift-off and high-dynamic-pressure times of ascent. These results have generally verified the design analysis. However, subscale testing was found to be deficient in predicting full-scale results in two areas: the ignition overpressure at lift-off and the aerodynamics/plume interactions at high-q boost. In these areas, the results of the flight test program were accommodated with no impact to the vehicle design.

Mackey, A. C.↗

Electrically Driven Ion Separations in Permeable Membranes

Ion separations are critical for producing materials such as Li and rare-earth element salts that are essential for applications including energy storage and production. This research aimed to develop and understand separations of singly and multiply charged ions as well as separations among different singly charged ions such as Li + and Na + . Thin layers of polyelectrolytes on membranes allow passage of singly charged ions at rates 1000 times faster than those for multiply charged ions. This allows purification of mixtures with equal concentrations of Li + and Mg 2+ to create a permeate solution with >99% Li + . Such membranes may also effectively isolate rare earth elements. To separate Li + and K + , this work developed opposing flow and current in membranes. The current overcomes the flow of K + to allow Li + to selectively pass through the membrane, leading to Li + /K + selectivities around 70. All of the research employs modelling to better understand the mechanism of these separations, which includes transport driven by gradients in electrical potential, concentration, and pressure. The interplay of these driving forces can create highly selective separations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Magmas as Selective Filters of Volatiles Between Planetary Mantles and Surfaces

The composition of early planetary atmospheres and biospheres which is a knowledge of the relationship between mantle volatiles and volcanic gases was analyzed. In the case of Earth it appears that volcanic rocks and gases are relatively oxidized compared to the upper mantle. In the case of the C-O-H volatiles, (H2O, CO2, CO, CH4, H2) the volcanic gases are enriched in H2O and CO2 while the volatiles in the mantle may be dominated by H2O, H2 and possibly CH4. An experimental technique was perfected for phase equilibrium studies in the 5-30 kbar range which allows accurate control of volatile species activities in the fluid phase. The system was used to measure the relative solubilities of H2O, CO2, CO, CH4 and H2 in magmas at 10 kbar pressure. It is found that mantle magmas will selectively screen volatiles from planetary surfaces, forcing volcanic gases towards the neutral QFM oxidation state where H2O is the dominant species.

Holloway, J. R.↗

Ion Separations Based on Spontaneously Arising Streaming Potentials in Rotating Isoporous Membranes

Highly selective ion separations are vital for producing pure salts, and membrane-based separations are promising alternatives to conventional ion-separation techniques. Our previous work demonstrated that simple pressure-driven flow through negatively charged isoporous membranes can separate Li+ and K+ with selectivities as high as 70 in dilute solutions. The separation mechanism relies on spontaneously arising streaming potentials that induce electromigration, which opposes advection and separates cations based on differences in their electrophoretic mobilities. Although the separation technique is simple, this work shows that high selectivities are possible only with careful consideration of experimental conditions including transmembrane pressure, solution ionic strength, the K+/Li+ ratio in the feed, and the extent of concentration polarization. Separations conducted with a rotating membrane show Li+/K+ selectivities as high as 150 with a 1000 rpm membrane rotation rate, but the selectivity decreases to 1.3 at 95 rpm. These results demonstrate the benefits and necessity of quantitative control of concentration polarization in highly selective separations. Increases in solution ionic strength or the K+/Li+ feed ratio can also decrease selectivities more than an order of magnitude.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Selected Area Deposition of High Purity Gold for Functional 3D Architectures

Selected area deposition of high purity gold films onto nanoscale 3D architectures is highly desirable as gold is conductive, inert, plasmonically active, and can be functionalized with thiol chemistries, which are useful in many biological applications. Here, we show that high-purity gold coatings can be selectively grown with the Me 2 Au (acac) precursor onto nanoscale 3D architectures via a pulsed laser pyrolytic chemical vapor deposition process. The selected area of deposition is achieved due to the high thermal resistance of the nanoscale geometries. Focused electron beam induced deposits (FEBID) and carbon nanofibers are functionalized with gold coatings, and we demonstrate the effects that laser irradiance, pulse width, and precursor pressure have on the growth rate. Furthermore, we demonstrate selected area deposition with a feature-targeting resolutions of ~100 and 5 µm, using diode lasers coupled to a multimode (915 nm) and single mode (785 nm) fiber optic, respectively. The experimental results are rationalized via finite element thermal modeling.

3-dimensional nanostructures↗

Material Selection and Heat Transfer Model for PTUHS Device

The Path to Ultimate Heat Sink Device (PTUHS) is a passive safety system that utilizes a radiative heat transfer valve to control the rate at which heat is removed from a nuclear reactor pressure vessel (RPV) and dispersed into surrounding soil. The material selection for the PTUHS device is investigated, where the thermophysical properties are either maximized or minimized bases on what section of the PTUHS that material is being used for. Final recommendations of material choice are then presented. The heat transfer model of the PTUHS device is solved in ABAQUS, where a normal operating conditions and SCRAM conditions are solved. These temperature maps and heat flux of the system show the system's ability, where minimal heat is lost during normal operating conditions and system failure in a SCRAM scenario due to temperatures that were reached.

42 - ENGINEERING↗

Pressure data for four analytically defined arrow wings in supersonic flow

In order to provide experimental data for comparison with newly developed finite difference methods for computing supersonic flows over aircraft configurations, wind tunnel tests were conducted on four arrow wing models. The models were machined under numeric control to precisely duplicate analytically defined shapes. They were heavily instrumented with pressure orifices at several cross sections ahead of and in the region where there is a gap between the body and the wing trailing edge. The test Mach numbers were 2.36, 2.96, and 4.63. Tabulated pressure data for the complete test series are presented along with selected oil flow photographs. Comparisons of some preliminary numerical results at zero angle of attack show good to excellent agreement with the experimental pressure distributions.

Townsend, J. C.↗

Solar Thermal Upper Stage Liquid Hydrogen Pressure Control Testing

High-energy cryogenic propellant is an essential element in future space exploration programs. Therefore, NASA and its industrial partners are committed to an advanced development/technology program that will broaden the experience base for the entire cryogenic fluid management community. Furthermore, the high cost of microgravity experiments has motivated NASA to establish government/aerospace industry teams to aggressively explore combinations of ground testing and analytical modeling to the greatest extent possible, thereby benefitting both industry and government entities. One such team consisting of ManTech SRS, Inc., Edwards Air Force Base, and Marshall Space Flight Center (MSFC) was formed to pursue a technology project designed to demonstrate technology readiness for an SRS liquid hydrogen (LH2) in-space propellant management concept. The subject testing was cooperatively performed June 21-30, 2000, through a partially reimbursable Space Act Agreement between SRS, MSFC, and the Air Force Research Laboratory. The joint statement of work used to guide the technical activity is presented in appendix A. The key elements of the SRS concept consisted of an LH2 storage and supply system that used all of the vented H2 for solar engine thrusting, accommodated pressure control without a thermodynamic vent system (TVS), and minimized or eliminated the need for a capillary liquid acquisition device (LAD). The strategy was to balance the LH2 storage tank pressure control requirements with the engine thrusting requirements to selectively provide either liquid or vapor H2 at a controlled rate to a solar thermal engine in the low-gravity environment of space operations. The overall test objective was to verify that the proposed concept could enable simultaneous control of LH2 tank pressure and feed system flow to the thruster without necessitating a TVS and a capillary LAD. The primary program objectives were designed to demonstrate technology readiness of the SRS concept at a system level as a first step toward actual flight vehicle demonstrations. More specific objectives included testing the pressure and feed control system concept hardware for functionality, operability, and performance. Valuable LH2 thermodynamic and fluid dynamics data were obtained for application to both the SRS concept and to future missions requiring space-based cryogen propellant management.

Moore, J. D.↗

Selective butene formation in direct ethanol-to-C3+-olefin valorization over Zn-Y/Beta and single-atom alloy composite catalysts using in situ generated hydrogen

The selective production of C3+ olefins from renewable feedstocks, especially via C1 and C2 platform chemicals, is a critical challenge for obtaining economically viable low-carbon middle distillate transportation fuels (i.e., jet and diesel). Here, we report a multifunctional catalyst system composed of Zn-Y/Beta and “single-atom” alloy (SAA) Pt-Cu/Al2O3 which selectively catalyzes ethanol-to-olefins (C3+, ETO) valorization in the absence of cofed hydrogen, forming butenes as the primary olefin products. Beta zeolites containing predominately isolated Zn and Y metal sites catalyze ethanol upgrading steps (588 K, 3.1 kPa ethanol, ambient pressure) regardless of cofed hydrogen partial pressure (0-98.3 kPa H2), forming butadiene as the primary product (60% selectivity at 87% conversion). The Zn-Y/Beta catalyst possesses site-isolated Zn and Y Lewis acid sites (at ~7 wt% Y) and Brønsted acidic Y sites, the latter of which has been previously uncharacterized. A secondary bed of SAA Pt-Cu/Al2O3 selectively hydrogenates butadiene to butene isomers at a consistent reaction temperature using hydrogen generated in situ from ethanol-to-butadiene (ETB) conversion. This unique hydrogenation reactivity at near-stoichiometric hydrogen and butadiene partial pressures is not observed over monometallic Pt or Cu catalysts, highlighting these operating conditions as a critical SAA catalyst application area for conjugated diene selective hydrogenation at high reaction temperatures (>573 K) and low H2/diene ratios (e.g., 1:1). Single-bed steady state selective hydrogenation rates, associated apparent hydrogen and butadiene reaction orders, and DFT calculations of the Horiuti-Polanyi reaction mechanisms indicate that the unique butadiene selective hydrogenation reactivity over SAA Pt-Cu/Al2O3 reflects lower hydrogen scission barriers relative to monometallic Cu surfaces and limited butene binding energies relative to monometallic Pt surfaces. DFT calculations further indicate the preferential desorption of butene isomers over SAA Pt-Cu(111) and Cu(111) surfaces while Pt(111) surface favors subsequent butene hydrogenation reactions to form butane over butene desorption events. Under operating conditions without of hydrogen cofeeding, this combination of Zn-Y/Beta and SAA Pt-Cu catalysts can selectively form butenes (65% butenes, 78% C3+ selectivity at 94% conversion) and avoid butane formation using only in situ generated hydrogen, avoiding costly hydrogen cofeeding requirements that hinder many renewable energy processes.

Cordon, Michael↗

Heat Exchanger Design Optimization for Mitigation of Diesel Engine Exhaust Fouling

Abstract The design optimization of a diesel exhaust-coupled heat and mass exchanger that drives a 2.71 kW cooling capacity absorption heat pump is presented in this study. Fouling layer thermal resistance and pressure drops from single-tube experiments are used to develop a thermodynamic, heat transfer, and pressure drop model for the exhaust-coupled desorber. A parametric study is performed to select a desorber design that meets system performance while minimizing footprint. Experimental heat duties and pressure drops are within 10% and 3%, respectively, of the model predictions. Thus, large data sets from single-tube experiments with representative geometries are successful in accounting for fouling effects at the component level. Desorber design optimization based on this approach ensures continued heat pump performance after fouling. This study, along with the single-tube experiments, presents a systematic approach to design exhaust-coupled heat exchangers while considering the effects of fouling. These results are applicable for a wide range of waste-heat recovery applications, and this method can be extended to different geometries and operating conditions.

Energy & Fuels↗