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At least 613 records · Page 34
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

On the generation of magnetohydrodynamic waves in a stratified and magnetized fluid. I - Vertical propagation

The generation of MHD waves by turbulent motions in a stratified medium with an embedded uniform magnetic field, a topic which is relevant to the study of the solar atmosphere, is considered. Both compressible and incompressible MHD waves are treated in a one-dimensional approach; however, the direction of the background magnetic field is permitted to vary in an arbitrary direction. Theoretical expressions for MHD energy fluxes are obtained as a function of wave frequency and multipole coefficients. It is shown that monopole, dipole, and quadrupole emissions are responsible for the generation of the compressible components of the fast and slow modes. However, the incompressible components and the Alfven modes can be generated by the dipole emission only. Specific results obtained for special magnetic field geometries are discussed for the fast and slow modes.

Musielak, Z. E.↗
NASA NTRS1987

The magnetosphere of Saturn

Pioneer 11 and Voyager 1 and 2 magnetic field measurements over the entire flyby of Saturn's magnetic field have been analyzed by fitting a magnetospheric dipole field (i.e., a dipole field plus the field due to currents in the magnetopause), higher moments of the internal field aligned with the dipole along the rotation axis, and the field due to an equatorial sheet current to the magnetic measurements. A dipole moment of 21,431 nT R(s) exp 3, a quadrupole moment of 2403 nT R(s) exp 4, an octopole moment of 2173 nT R(s) exp 5, and an equatorial sheet current of half thickness 2.0 R(s) from about 5 R(s) to the solar edge of the magnetopause, fit the measurements over the entire magnetosphere with an rms deviation of 3.2 nT where R(s) is the planet radius, 66,330 km. The primary feature of the present analysis is the explicit inclusion of the calculated magnetopause current field, which reduces the overall rms deviation over the entire flyby from sigma values of 4.7 and 5.9 nT, using previous models, to 3.2 nT using the present.

Beard, David B.↗
NASA NTRS1987

Monitoring of space station life support systems with miniature mass spectrometry and artificial intelligence

The combination of quadrupole ion trap tandem mass spectroscopy with artificial intelligence is a promising approach for monitoring the performance of the life support systems in the space station. Such an analytical system can provide the selectivity, sensitivity, speed, small size, and decision making intelligence to detect, identify, and quantify trace toxic compounds which may accumulate in the space station habitat.

Yost, Richard A.↗
NASA NTRS1987

Measurements of the cosmic background radiation

Maps of the large scale structure (theta is greater than 6 deg) of the cosmic background radiation covering 90 percent of the sky are now available. The data show a very strong 50-100 sigma (statistical error) dipole component, interpreted as being due to our motion, with a direction of alpha = 11.5 + or - 0.15 hours, sigma = -5.6 + or - 2.0 deg. The inferred direction of the velocity of our galaxy relative to the cosmic background radiation is alpha = 10.6 + or - 0.3 hours, sigma = -2.3 + or - 5 deg. This is 44 deg from the center of the Virgo cluster. After removing the dipole component, the data show a galactic signature but no apparent residual structure. An autocorrelation of the residual data, after substraction of the galactic component from a combined Berkeley (3 mm) and Princeton (12 mm) data sets, show no apparent structure from 10 to 180 deg with a rms of 0.01 mK(sup 2). At 90 percent confidence level limit of .00007 is placed on a quadrupole component.

Lubin, P.↗
NASA NTRS1987

Quadrupolar Kondo effect in uranium heavy-electron materials?

The possibility of an electric quadrupole Kondo effect for a non-Kramers doublet on a uranium (U) ion is a cubic metallic host is demonstrated by model calculations showing a Kondo upturn in the resistivity, universal quenching of the quadrupolar moment, and a heavy-electron anomaly in the electronic specific heat. With inclusion of excited crystal-field levels, some of the unusual magnetic-response data in the heavy-electron superconductor UBe13 may be understood. Structural phase transitions at unprecedented low temperatures may occur in U-based heavy-electron materials.

Cox, D. L.↗
NASA NTRS1987

Polarized fluorescence spectroscopy of O2(+)

Polarized fluorescence measurements involving the A 2Pi(u) - X 2Pi(g) and b 4Sigma(g)(-) - a 4Pi(u) transitions in O2(+) following narrow-band photoexcitation of O2/X 3Sigma(g)(-)/ are reported. The analysis, based on the conventional high-J limit, involves deducing the quadrupole alignment factor from which the relative strengths of degenerate photoexcitation channels responsible for the population distribution in the A 2Pi(u) and b 4Sigma(g)(-) states of O2(+) can be estimated. The measured A-channel polarization exhibits pronounced structure which correlates well with the known positions of Rydberg states, whereas the polarization signal in the b channel has broad and less prominent features. Discrepancies between theoretical and measured results can largely be accounted for by additional configuration mixing and autoionization considerations.

Keller, J. W.↗
NASA NTRS1987

Characteristics of wavelike fluctuations in Dynamics Explorer neutral composition data

Wavelike fluctuations in neutral composition data obtained with the neutral atmospheric composition system quadrupole mass spectrometer carried aboard the Dynamics Explorer (DE 2) satellite are at a maximum in the vicinity of the magnetic poles. Typical rms amplitudes near the poles for N2, O, He, and Ar fluctuations in the 400- to 4000-km-wavelength band are found to be 11, 6, 6, and 20 percent, respectively. Amplitudes near the equator are roughly a third of the polar amplitudes, and activity in the 50- to 400-km-wavlength band is roughly 20 percent of the longer-wavelength activity.

Hedin, A. E.↗
NASA NTRS1987

Wave energy in white dwarf atmospheres. I - Magnetohydrodynamic energy spectra for homogeneous DB and layered DA stars

The radiative damping of acoustic and MHD waves that propagate through white dwarf photospheric layers is studied, and other damping processes that may be important for the propagation of the MHD waves are calculated. The amount of energy remaining after the damping processes have occurred in different types of waves is estimated. The results show that lower acoustic fluxes should be expected in layered DA and homogeneous DB white dwarfs than had previously been estimated. Acoustic emission manifests itself in an enhancement of the quadrupole term, but this term may become comparable to or even lower than the dipole term for cool white dwarfs. Energy carried by the acoustic waves is significantly dissipated in deep photospheric layers, mainly because of radiative damping. Acoustically heated corona cannot exist around DA and DB white dwarfs in a range T(eff) = 10,000-30,000 K and for log g = 7 and 8. However, relatively hot and massive white dwarfs could be exceptions.

Musielak, Zdzislaw E.↗
NASA NTRS1987

The magnetic field of Uranus

Aspherical harmonic model of the planetary magnetic field of Uranus is obtained from the Voyager 2 encounter observations using generalized inverse techniques which allow partial solutions to complex (underdetermined) problems. The Goddard Space Flight Center 'Q3' model is characterized by a large dipole tilt (58.6 deg) relative to the rotation axis, a dipole moment of 0.228 G R(Uranus radii cubed) and an unusually large quadrupole moment. Characteristics of this complex model magnetic field are illustrated using contour maps of the field on the planet's surface and discussed in the context of possible dynamo generation in the relatively poorly conducting 'ice' mantle.

Connerney, J. E. P.↗
NASA NTRS1988

Laboratory studies of sticking coefficients and heterogeneous reactions important in the Antarctic stratosphere

Laboratory studies of sticking coefficients of H2O, HCl, Cl2, and HNO3 on ice and heterogeneous reactions of ClONO2 with ice or HCl/ice have been performed in a fast flow reactor. A quadrupole mass spectrometer with electron impact ionization was used as a detector. Measured sticking coefficients are: 0.3 (+0.7, -0.1) for H2O, 0.4 (+0.6, -0.2) for HCL, less than 0.0001 for Cl2, and 0.3 (+0.7, -0.1) for HNO3 at 200 K. The reaction probability of ClONO2 on ice was found to be 0.06 (+ or - 0.03) while HOCl was observed as a sole product in the gas phase. With HCl present in ice, the reaction probability of ClONO2 is greatly enhanced, approaching 0.27 (+0.73, -0.13) while molecular chlorine was found to be the major product in the gas phase. Another reaction product was nitric acid which remained in the solid phase. Since the polar stratospheric clouds contain ice particles or possibly HCl/ice particles on the surface, the present results should be a major factor in producing the observed springtime ozone depletion in the Antarctic stratosphere.

Leu, Ming-Taun↗
NASA NTRS1987

Charged drop levitators and their applications

An account is given of the charged drop levitation characteristics of two different devices: (1) a feedback-controlled electrostatic levitator able to lift a several mm-diameter drop in 1g conditions, which is applicable to drop dynamics, crystal growth, and supercooling/solidification experiments; and (2) a linear quadrupole levitator, whose advantages are demonstrated in light of the results obtained for the charged drop instability experiment. The cause of the premature drop burstings observed is suggested to be an electron avalanche in the surrounding gaseous medium rather than the Rayleigh limit.

Rhim, W. K.↗
NASA NTRS1988

A study of C3HD in cold interstellar clouds

The 1(10)-1(01) transition of C3HD was detected at 19.418 GHz at twelve positions in cold, dark clouds, and the D hyperfine components were resolved in two sources (L1498 and TMC-1C) well enough to derive values for the D quadrupole coupling constants. Simultaneous observations of C3H2 in each source yield relative integrated line intensities in the range 0.10-0.18, from which relative C3HD/C3H2 abundances in the range 0.05-0.15 were derived. These are among the highest deuteration ratios yet observed. Within the limits of the observational and modeling uncertainties, it is possible to explain the derived C3HD/C3H2 ratios by ion-molecule chemistry if e is equal to about 3 x 10 to the -7th.

Bell, M. B.↗
NASA NTRS1987

Development of an effusive inlet for mass spectrometric gas analysis of hypersonic boundary layer

The use of a microchannel plate (MCP) as a mass spectrometer inlet device to allow nonintrusive sampling of flight vehicle boundary layers is investigated. Two possible configurations for mounting the inlet are studied: (1) flow coaxial with the channels; and (2) flow perpendicular to the channel axis. The test gases are pure Kr; pure Ne; and a mixture of 10 pct Kr, 10 pct Ne, and 80 pct N2. The pressure ranges studied vary from 500 to 10 microns. A mass discrimination at the quadrupole mass spectrometer is observed, indicating an enrichment in the heavier gas. Possible explanations for this enrichment are discussed. It is shown that an MCP is capable of acting as a nonintrusive sampling device. Further work that will enable quantitative determination of the species at the surface is discussed.

Brown, Kenneth G.↗
NASA NTRS1988

Theoretical characterization of the minimum energy path for the reaction H + O2 to HO2(asterisk) to HO + O

The potential energy surface for the H + O2 to HO2(asterisk) to HO + O reaction has been investigated in the region of the minimum energy path using CASSCF/contracted CI (CCI) calculations with a large basis set. The results show no barrier for the addition of an H atom to O2, in agreement with previous studies. A crossing between the surface for electrostatic (OH dipole-O quadrupole) interaction and that for the formation of an O-O chemical bond, at r(infinity) of about 5.5 a(0), results in a small (about 0.5 kcal/mol) barrier.

Walch, Stephen P.↗
NASA NTRS1988

Heterogeneous reactions of N2O5 with H2O and HCl on ice surfaces - Implications for Antarctic ozone depletion

This paper reports on the measurements of reaction probabilities for heterogeneous reaction of N2O5 with H2O and HCl on ice surfaces at 195 K, using a fast-flow reactor coupled with a quadrupole mass spectrometer. The reaction probability for N2O5 on pure-water ice was found to be 0.028 + or - 0.011, with nitric acid in the solid phase as the sole product. In the presence of HCl in ice, the probability of N2O5 reaction was enhanced (to 0.037); the reaction produced, besides solid-phase nitric acid, ClNO2 and ClONO which were released into the gas phase within a few milliseconds. The latter two compounds can be readily photolyzed in the austral spring to form active chlorine which would remove stratospheric ozone. It is suggested that, since the polar stratospheric clouds are believed to contain HCl-ice mixture on the surface, the reactions of N2O5 on H2O/HCl particles is a major factor in the Antarctic springtime ozone depletion.

Leu, Ming-Taun↗
NASA NTRS1988

Magnetospheric convection in the nondipolar magnetic field of Uranus

A method for determining the magnetospheric convection electric field, using simple analytic approximations under the assumption of uniform ionospheric conductivity, is described and applied to Uranus. Magnetic field models including quadrupole and octupole moments are used to determine the shape of the polar caps and the mapping of the electric field and parallel currents between ionosphere and magnetosphere. The model predictions are compared with plasma data taken by Voyager 2 in the inner Uranian magnetosphere.

Selesnick, Richard S.↗
NASA NTRS1989

Photopolymerization Of Levitated Droplets

Experimental containerless process combines two established techniques to make variety of polymeric microspheres. In single step, electrostatically-levitated monomer droplets polymerized by ultraviolet light. Faster than multiple-step emulsion polymerization process used to make microspheres. Droplets suspended in cylindrical quadrupole electrostatic levitator. Alternating electrostatic field produces dynamic potential along axis. Process enables tailoring of microspheres for medical, scientific, and industrial applications.

Rembaum, Alan↗
NASA NTRS1988

Cosmological cosmic strings

The effect of an infinite cosmic string on a cosmological background is investigated. It is found that the metric is approximately a scaled version of the empty space string metric, i.e., conical in nature. Results are used to place bounds on the amount of cylindrical gravitational radiation currently emitted by such a string. The gravitational radiation equations are then analyzed explicitly and it is shown that even initially large disturbances are rapidly damped as the expansion proceeds. The implications of the gravitational radiation background and the limitations of the quadrupole formula are discussed.

Gregory, Ruth↗