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At least 613 records · Page 34

Floating solar panels on reservoirs impact phytoplankton populations: A modelling experiment

Floating solar photovoltaic (FPV) deployments are increasing globally as the switch to renewable energy intensifies, representing a considerable water surface transformation. FPV installations can potentially impact aquatic ecosystem function, either positively or negatively. However, these impacts are poorly resolved given the challenges of collecting empirical data for field or modelling experiments. In particular, there is limited evidence on the response of phytoplankton to changes in water body thermal dynamics and light climate with FPV. Given the importance of understanding phytoplankton biomass and species composition for managing ecosystem services, we use an uncertainty estimation approach to simulate the effect of FPV coverage and array siting location on a UK reservoir. FPV coverage was modified in 10% increments from a baseline with 0% coverage to 100% coverage for three different FPV array siting locations based on reservoir circulation patterns. Results showed that FPV coverage significantly impacted thermal properties, resulting in highly variable impacts on phytoplankton biomass and species composition. The impacts on phytoplankton were often dependent on array siting location as well as surface coverage. Changes to phytoplankton species composition were offset by the decrease in phytoplankton biomass associated with increasing FPV coverage. We identified that similar phytoplankton biomass reductions could be achieved with less FPV coverage by deploying the FPV array on the water body's faster-flowing area than the central or slower flowing areas. The difference in response dependent on siting location could be used to tailor phytoplankton management in water bodies. Simulation of water body-FPV interactions efficiently using an uncertainty approach is an essential tool to rapidly develop understanding and ultimately inform FPV developers and water body managers looking to minimise negative impacts and maximise co-benefits.

14 SOLAR ENERGY↗

High-throughput screening of hypothetical metal-organic frameworks for thermal conductivity

Thermal energy management in metal-organic frameworks (MOFs) is an important, yet often neglected, challenge for many adsorption-based applications such as gas storage and separations. Despite its importance, there is insufficient understanding of the structure-property relationships governing thermal transport in MOFs. To provide a data-driven perspective into these relationships, here we perform large-scale computational screening of thermal conductivity k in MOFs, leveraging classical molecular dynamics simulations and 10,194 hypothetical MOFs created using the ToBaCCo 3.0 code. We found that high thermal conductivity in MOFs is favored by high densities (> 1.0 g cm -3 ), small pores (< 10 Å), and four-connected metal nodes. We also found that 36 MOFs exhibit ultra-low thermal conductivity (< 0.02 W m -1 K -1 ), which is primarily due to having extremely large pores (~65 Å). Furthermore, we discovered six hypothetical MOFs with very high thermal conductivity (>10 Wm -1 K -1 ), the structures of which we describe in additional detail.

36 MATERIALS SCIENCE↗

Forest discrimination with multipolarization imaging radar

The use of radar polarization diversity for discriminating forest canopy variables on airborne synthetic-aperture radar (SAR) images is evaluated. SAR images were acquired at L-Band (24.6 cm) simultaneously in four linear polarization states (HH, HV, VH, and VV) in South Carolina on March 1, 1984. In order to relate the polarization signatures to biophysical properties, false-color composite images were compared to maps of forest stands in the timber compartment. In decreasing order, the most useful correlative forest data are stand basal area, forest age, site condition index, and forest management type. It is found that multipolarization images discriminate variation in tree density and difference in the amount of understory, but do not discriminate between evergreen and deciduous forest types.

Ford, J. P.↗

Communications and Tracking Development Laboratory/Building 44. Historical Documentation

As part of this nation-wide study, in September 2006, historical survey and evaluation of NASA-owned and managed facilities was conducted by NASA's Lyndon B. Johnson Space Center (JSC) in Houston, Texas. The results of this study are presented in a report entitled, Survey and Evaluation of NASA-owned Historic Facilities and Properties in the Context of the U.S. Space Shuttle Program, Lyndon B. Johnson Space Center, Houston, Texas, prepared in November 2007 by NASA JSC s contractor, Archaeological Consultants, Inc. As a result of this survey, the Communications and Tracking Development Laboratory (Building 44) was determined eligible for listing in the NRHP, with concurrence by the Texas State Historic Preservation Officer (SHPO). The survey concluded that Building 44 is eligible for the NRHP under Criteria A and C in the context of the U.S. Space Shuttle Program (1969-2010). Because it has achieved significance within the past 50 years, Criteria Consideration G applies. At the time of this documentation, Building 44 was still used to support the SSP as an engineering research facility, which is also sometimes used for astronaut training. This documentation package precedes any undertaking as defined by Section 106 of the NHPA, as amended, and implemented by 36 CFR Part 800, as NASA JSC has decided to proactively pursue efforts to mitigate the potential adverse affects of any future modifications to the facility. It includes a historical summary of the Space Shuttle Program; the history of JSC in relation to the SSP; a narrative of the history of Building 44 and how it supported the SSP; and a physical description of the building. In addition, photographs documenting the construction and historical use of Building 44 in support of the SSP, as well as photographs of the facility documenting the existing conditions, special technological features, and engineering details, are included. A contact sheet printed on archival paper, and an electronic copy of the work product on CD, are also provided.

Slovinac, Patricia↗

Mission Control Center/Building 30. Historical Documentation

As part of this nation-wide study, in September 2006, historical survey and evaluation of NASA-owned and managed facilities was conducted by NASA's Lyndon B. Johnson Space Center (JSC) in Houston, Texas. The results of this study are presented in a report entitled, Survey and Evaluation of NASA-owned Historic Facilities and Properties in the Context of the U.S. Space Shuttle Program, Lyndon B. Johnson Space Center, Houston, Texas, prepared in November 2007 by NASA JSC s contractor, Archaeological Consultants, Inc. As a result of this survey, the Mission Control Center (Building 30) was determined eligible for listing in the NRHP, with concurrence by the Texas State Historic Preservation Officer (SHPO). The survey concluded that Building 30 is eligible for the NRHP under Criteria A and C in the context of the U.S. Space Shuttle Program (1969-2010). Because it has achieved significance within the past 50 years, Criteria Consideration G applies. It should be noted that the Mission Control Center was designated a National Historic Landmark in 1985 for its role in the Apollo 11 Lunar Landing. At the time of this documentation, Building 30 was still used to support the SSP as an engineering research facility, which is also sometimes used for astronaut training. This documentation package precedes any undertaking as defined by Section 106 of the NHPA, as amended, and implemented in 36 CFR Part 800, as NASA JSC has decided to proactively pursue efforts to mitigate the potential adverse affects of any future modifications to the facility. It includes a historical summary of the Space Shuttle program; the history of JSC in relation to the SSP; a narrative of the history of Building 30 and how it supported the SSP; and a physical description of the structure. In addition, photographs documenting the construction and historical use of Building 30 in support of the SSP, as well as photographs of the facility documenting the existing conditions, special technological features, and engineering details, are included. A contact sheet printed on archival paper, and an electronic copy of the work product on CD, are also provided.

Source record↗

Analysis of short‐ and long‐term system response during gas production from a gas hydrate deposit at the UBGH2‐6 site of the Ulleung Basin in the Korean East Sea

Abstract This study is a continuation of an investigation into the feasibility of long‐term production from a marine hydrate accumulation that has the properties and conditions of the UBGH2‐6 (UBGH2, Ulleung Basin Gas Hydrates 2; 2 is the number of the scientific expedition) site at the Ulleung Basin in the Korean East Sea. The 12.7 m‐thick system is in deep water (2157 m), but at 140 m below the seafloor. It is characterized by alternating hydrate‐free clays and muds and hydrate‐rich sand layers. The layered stratigraphy and the presence of mud layers favours the use of vertical wells rather than horizontal wells for production. The analysis indicates that production from such a hydrate accumulation is technically feasible, but the gas production rates are generally low. Water production accompanying gas production from this deposit appears manageable under all the scenarios investigated in this study, however, the water‐to‐gas ratio is high. Subsidence at the ocean floor at the end of a 14 day test is quite limited. However, there is significant uncertainty in the predictions of the geomechanical system's behaviour because they are not based on measured system properties but only on estimates/assumptions from analogues. The long‐term production potential of the reservoir at the site investigated here appears challenging because of the limited effectiveness of dissociation and large water production, in addition to substantial subsidence.

Moridis, George J.↗

Adhesion Capabilities of Permanent Foaming Fixatives for Deactivation and Decommissioning Activities - 20308

Florida International University's Applied Research Center and the Department of Energy's Savannah River National Laboratory are examining various mechanical properties of intumescent rigid polyurethane foams in order to be used as a permanent foaming fixative. Intumescent polyurethane foams are favored more than non-intumescent polyurethane foams due to their ability to mitigate flame and smoke propagation when exposed to a fire. As a consequence, this ability, known as intumescing, will allow fire personnel ample time to arrive at a scene. Due to sites being dormant for many decades before the final decontamination stages, the likelihood of a fire remains high. Adhesion properties will ensure quality immobilization performance. The analysis consisted of evaluating tensile adhesion strengths on a variety of commercial-off-the-shelf polyurethane (PU) foams. The foams consisted of intumescent and a combination of flexible and rigid foams. The goal was to down select the rigid foams out of the group in terms of tensile adhesion performance. The ensuing analysis was to conduct shear adhesion testing on the rigid foams in an operational volume with one of the rigid foams being intumescent. This approach helped down select the intumescent rigid foam in an adhesion and operational sense. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Product Consistency Test Results for the HFG1 Glasses

The U.S. Department of Energy (DOE) is responsible for building the Hanford Tank Waste Treatment and Immobilization Plant (WTP) at the Hanford site in Washington to remediate 55 million gallons of radioactive waste that is temporarily stored in 177 underground tanks. The Office of River Protection (ORP) has requested that the Savannah River National Laboratory (SRNL) contribute in areas of recognized capabilities and expertise for glass waste form development to support successful startup of the WTP. As part of this effort, the Pacific Northwest National Laboratory (PNNL) is developing, batching, and fabricating simulated high-level waste (HLW) glasses to generate the associated property data needed to validate or identify areas of potential characterization improvement in the current glass property/composition models. Currently, the models cover only a small fraction of the waste compositions projected in the Hanford tank farm; therefore, the models must be expanded to include high fluoride compositions to successfully complete the WTP mission. SRNL support of this work is defined in the Task Technical and Quality Assurance Plan (TTQAP). This report provides the results of the Product Consistency Test (PCT) leachates from the High Fluoride Glasses-1 (HFG1), a series of simulated nuclear waste glasses fabricated at PNNL. The series included quenched (Q) and canister-centerline cooled (CCC) versions of the glasses. The glasses were selected as part of a broader study of the influence of glass composition on chemical durability, sulfur retention, and other properties. These data will be used to validate or identify areas of potential characterization improvements in the current glass property/composition models.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Physical Properties of the Salt Waste Processing Next Generation Solvent Formulation

In 2020, a review team examined the risks associated with the implementation of a new solvent formulation, similar to what was used in Modular Caustic-Side Solvent Extraction Unit (MCU). The team identified a number of risks associated with the change and pathways to mitigate some of the risks. SRNL has been tasked with examination and testing of a Salt Waste Processing Facility (SWPF) formulation for a Next Generation Solvent (NGS) intended for use at that facility. This formulation is known as the “$NGS\tiny{OPTIMUM}$”. This formulation consists of: 50 mM MAXCalix; 3 mM TiDG•HCl; 0.65 M Modifier; Remainder Isopar-L™. SRNL examined several physical aspects of this solvent in order to confirm its suitability for use at SWPF, such as viscosity, dispersion, surface tension, and third phase formation. Results indicate no unusual properties of this solvent when compared to the current “BOBCalix” solvent in use at SWPF.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Technology Assessment for Radioiodine at the Hanford Site - 20240

An evaluation was conducted to assess the practicability of technologies of sufficient promise and maturity to warrant treatability tests for remediating radioiodine (I-129) in groundwater at the 200-UP-1 operable unit at the U.S. Department of Energy Hanford Site. Technologies were evaluated based on recent updated knowledge of subsurface iodine transport behavior at Hanford, and the effectiveness, implementability, and cost of potential treatment technologies for I-129. Because more than two-thirds of the iodine at Hanford is estimated to be present in its oxidized form as iodate, treatment technologies were evaluated with respect to addressing iodate. In situ treatments were identified as having limited implementability because the plume core is located directly beneath the Environmental Restoration Disposal Facility disposal cells, a landfill used for the disposal of low-level radioactive, hazardous, and mixed wastes generated from Hanford cleanup activities. Further limitations in treatment technologies for radioiodine were due to the isotopic distribution of subsurface iodine. Data indicate that stable iodine (I- 127) concentrations are up to three orders of magnitude greater than I-129, limiting the effectiveness of potential technologies because they are not isotope-specific. Ex situ approaches also lacked the effectiveness and maturity required to treat I-129. Hence, the technology evaluation did not identify any technologies that needed treatability testing, driven by site and contaminant properties that hinder effectiveness and/or implementability of the technologies. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Finite Element Models for Electron Beam Freeform Fabrication Process

Electron beam freeform fabrication (EBF3) is a member of an emerging class of direct manufacturing processes known as solid freeform fabrication (SFF); another member of the class is the laser deposition process. Successful application of the EBF3 process requires precise control of a number of process parameters such as the EB power, speed, and metal feed rate in order to ensure thermal management; good fusion between the substrate and the first layer and between successive layers; minimize part distortion and residual stresses; and control the microstructure of the finished product. This is the only effort thus far that has addressed computer simulation of the EBF3 process. The models developed in this effort can assist in reducing the number of trials in the laboratory or on the shop floor while making high-quality parts. With some modifications, their use can be further extended to the simulation of laser, TIG (tungsten inert gas), and other deposition processes. A solid mechanics-based finite element code, ABAQUS, was chosen as the primary engine in developing these models whereas a computational fluid dynamics (CFD) code, Fluent, was used in a support role. Several innovative concepts were developed, some of which are highlighted below. These concepts were implemented in a number of new computer models either in the form of stand-alone programs or as user subroutines for ABAQUS and Fluent codes. A database of thermo-physical, mechanical, fluid, and metallurgical properties of stainless steel 304 was developed. Computing models for Gaussian and raster modes of the electron beam heat input were developed. Also, new schemes were devised to account for the heat sink effect during the deposition process. These innovations, and others, lead to improved models for thermal management and prediction of transient/residual stresses and distortions. Two approaches for the prediction of microstructure were pursued. The first was an empirical approach involving the computation of thermal gradient, solidification rate, and velocity (G,R,V) coupled with the use of a solidification map that should be known a priori. The second approach relies completely on computer simulation. For this purpose a criterion for the prediction of morphology was proposed, which was combined with three alternative models for the prediction of microstructure; one based on solidification kinetics, the second on phase diagram, and the third on differential scanning calorimetry data. The last was found to be the simplest and the most versatile; it can be used with multicomponent alloys and rapid solidification without any additional difficulty. For the purpose of (limited) experimental validation, finite element models developed in this effort were applied to three different shapes made of stainless steel 304 material, designed expressly for this effort with an increasing level of complexity. These finite element models require large computation time, especially when applied to deposits with multiple adjacent beads and layers. This problem can be overcome, to some extent, by the use of fast, multi-core computers. Also, due to their numerical nature coupled with the fact that solid mechanics- based models are being used to represent the material behavior in liquid and vapor phases as well, the models have some inherent approximations that become more pronounced when dealing with multi-bead and multi-layer deposits.

Chandra, Umesh↗

FY25 Task 5: Small-Scale Mixing

The U.S. Department of Energy (DOE) Hanford Site has 177 underground storage tanks that contain a complex and diverse mix of chemical and radioactive wastes from past nuclear fuel reprocessing and waste management operations. The strategy of the DOE Hanford Field Office is to retrieve this waste, ~20 vol% of which is in the form of insoluble undissolved solids (UDS) or sludge, and treat it via immobilization at the Hanford Waste Treatment and Immobilization Plant (WTP). The diverse properties and characteristics of Hanford tank waste lead to major challenges related to its transport from the underground tanks to the WTP. These challenges, however, can be addressed by investigating the behavior of tank waste samples and simulant materials and evaluating their behavior against the capabilities of mixing and transport system designs that may be incorporated to retrieve and treat the waste.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Thermochemical characterization of intumescent materials and their application in FEM models using Aria

Intumescent materials are in wide use as protective coatings in fire protection or thermal management applications. These materials undergo chemical reactions occurring from approximately 300°C to 900°C, which outgas and expand the material, providing an appreciable increase in insulative performance. However, the complicated chemical mechanisms and large changes in materials properties complicate the incorporation of these materials into predictive thermal models. This document serves to outline the thermochemical characterization of select intumescent materials, the extraction of relevant parameters, and the incorporation of these parameters into the ChemEQ reaction model implemented in Aria. This work was performed in 2016 and documented in a draft SAND report in March 2017. In 2022, the draft SAND report was discovered and put through R&A.

36 MATERIALS SCIENCE↗

Developing a Database of Bio-based Materials for Building Envelope Applications

Oak Ridge National Laboratory (ORNL) has been funded by the Department of Energy (DOE) to help accelerate the introduction of building envelope materials that would reduce the carbon footprint of the buildings sector. The DOE’s Building Technologies Office has historically sought to resolve the knowledge gaps regarding the energy efficiency and moisture durability of building envelope systems and to develop the data, guidance, and tools needed to facilitate rapid industry adoption of high-performance, moisture-managed envelope systems. This project will help accelerate the widespread acceptance of a new generation of building materials developed specifically with the intent of reducing the carbon footprint of buildings. We have produced a database of hygrothermal transport properties on low embodied carbon building materials that can be added to energy and durability simulation tools. Properties that were measured include density, heat capacity, thermal conductivity as a function of temperature and relative humidity, moisture dependent permeance, and sorption isotherms as a function of relative humidity. These data sets were measured following consensus national standards using state-of-the-art facilities. The data has been compiled and is being made available to building designers who require these data to assess these new materials in their designs. We will publish the data and seek its addition to reference databases such as the ASHRAE Handbook of Fundamentals.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Analysis of Ground Source Heat Pump ECMs: Implemented Under DOE ESPC IDIQ Contract

Several federal performance and decarbonization objectives are driving the U.S. government to transition to net-zero emissions across the federal building portfolio. The overarching purpose of this Federal Energy Management Program (FEMP)-Geothermal Technologies Office (GTO) work is to support federal facilities in accomplishing the administration’s federal building decarbonization goals. Creating awareness of existing geothermal (or ground-source) heat pump (GHP) systems deployed on federal property, implemented using performance contracts and evaluating the energy and environmental impacts of these systems, this work will assist federal facilities in considering inclusion of GHP technology energy conservation measures (ECMs) in future performance contracting project awards. This report summarizes analyses of data from GHP ECMs installed under the DOE ESPC IDIQ contract across various climate areas and geographic locations, agencies, and building use types. Through the analysis of proposed GHP ECMs and understanding key metrics on implemented GHP systems in a variety of applications, FEMP and GTO can further support federal agencies in meeting decarbonization and net-zero building goals by evaluating and incorporating GHP systems into performance contracts and communicate the benefits of this technology.

15 GEOTHERMAL ENERGY↗

Steady state radiolysis–polyhalide accumulation products [Poster]

The study of steady-state radiolysis of polyhalides is crucial as it simulates the prolonged radiation exposure that materials (e.g., alloys, molten salts) experience in reactor environments. This research provides valuable insights into the long-term effects on material properties, chemical stability, and structural integrity. It is closely linked with fundamental radiation chemistry, which aids in predicting the chemical behavior of accumulation products. Understanding the initial speciation, yield, and chemical evolution of radiolysis products is essential for managing material degradation, controlling corrosion, and ensuring reactor safety.

36 - MATERIALS SCIENCE↗

Free Surface Phenomena Under Low- and Zero-Gravity Conditions

In a low- or zero-gravity environment the free surface of a liquid can behave in striking, unexpected ways. For example, in a partially filled container, a free surface that is well behaved under terrestrial conditions can rise to an arbitrarily large height or even fail to exist when gravity is absent. An answer is sought to the central mathematical questions: Under what conditions can free surfaces exist and what are their properties? -- and experimental questions of what means can be devised to observe and to measure the surfaces quantitatively. Current activity focuses on material selection and the design of optical diagnostic methods for in-space experiments. These experiments will test mathematical predictions of discontinuous transition from existence to nonexistence of capillary free surfaces in certain geometric configurations under zero gravity conditions. Liquids and container materials suitable for achieving the required contact-angle range and optical properties are being investigated, as well as the effects of contaminants and fluid motion on contact angle. The optical diagnostic technique investigation concerns laser-induced fluorescence, including emphasis on data on acquisition, sources and detectors, reliability, data management, and computer control.

Concus, P.↗

Space Electrochemical Research and Technology

Individual papers presented at the conference address the following topics: development of a micro-fiber nickel electrode for nickel-hydrogen cell, high performance nickel electrodes for space power application, bending properties of nickel electrodes for nickel-hydrogen batteries, effect of KOH concentration and anions on the performance of a Ni-H2 battery positive plate, advanced dependent pressure vessel nickel hydrogen spacecraft cell and battery design, electrolyte management considerations in modern nickel hydrogen and nickel cadmium cell and battery design, a novel unitized regenerative proton exchange membrane fuel cell, fuel cell systems for first lunar outpost - reactant storage options, the TMI regenerable solid oxide fuel cell, engineering development program of a closed aluminum-oxygen semi-cell system for an unmanned underwater vehicle, SPE OBOGS on-board oxygen generating system, hermetically sealed aluminum electrolytic capacitor, sol-gel technology and advanced electrochemical energy storage materials, development of electrochemical supercapacitors for EMA applications, and high energy density electrolytic capacitor.

Richard M Wilson↗