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At least 613 records · Page 34

Future Studies of Dihadron Production in SIDIS

Spin asymmetry and cross section measurements in semi-inclusive hadroproduction grant access to a variety of parton distribution and fragmentation functions. Such measurements of dihadron production additionally constrain Dihadron Fragmentation Functions (DiFFs), and the extra degree of freedom from the second hadron facilitates access to some of the parton distribution functions. At CLAS kinematics, subleading-twist parton distributions are accessible in dihadron beam-spin and target-spin asymmetries, and a comparison of semi-inclusive scattering off a proton and a deuteron probes their flavor dependence. The future Electron-Ion Collider (EIC) with a transversely polarized proton will access several transverse-momentum dependent distributions such as Sivers and transversity. On the fragmentation side, numerous DiFFs are accessible, and their partial wave expansion probes correlations between the angular momentum of the fragmenting parton with that of the observed dihadron. Furthermore, different hadron channels probe flavor dependence in fragmentation. Together with CLAS, the EIC as well as CLAS with the proposed 22 GeV accelerator upgrade will cover a broad range of $Q^2$ and $x$, allowing for the study of evolution effects of all of these functions. This presentation will summarize the possibilities of these measurements at CLAS and at future experimental facilities.

Dilks, Christopher↗

The MISR Calibration Program

The Multiangle Imaging SpectroRadiometer (MISR) is currently under development for NASA's Earth Observing System. The instrument consists of nine pushbroom cameras, each with four spectral bands in the visible and near-infrared. The cameras point in different view directions to provide measurements from nadir to highly oblique view angles in the along-track plane. Multiple view-angle observations provide a unique resource for studies of clouds, aerosols, and the surface. MISR is built to challenging radiometric and geometric performance specifications. Radiometric accuracy, for example, must be within +/- 3%/ 1 sigma, and polarization insensitivity must be better than +/- 1 %. An onboard calibrator (OBC) provides monthly updates to the instrument gain coefficients. Spectralon diffuse panels are used within the OBC to provide a uniform target for the cameras to view. The absolute radiometric scale is established both preflight and in orbit through the use of detector standards. During the mission, ground data processing to accomplish radiometric calibration, geometric rectification and registration of the nine view-angle imagery, and geophysical retrievals will proceed in an automated fashion. A global dataset is produced every 9 days. This paper details the preflight characterization of the MISR instrument, the design of the OBC, and the radiance product processing.

Bruegge, Carol J.↗

The Lunar Prospector Mission: Final Results of Trajectory Design, Quasi-Frozen Orbits, Extended Mission Targeting, and Lunar Topography and Potential Models

The National Aeronautics and Space Administration (NASA) selected Lunar Prospector (LP) as one of the discovery missions to conduct solar system exploration science investigations. The mission was NASA's first lunar voyage to investigate key science objectives since Apollo and was launched in January 1998. In keeping with discovery program requirements to reduce total mission cost and utilize new technology, Lunar Prospector's mission design and control will focus on the use of innovative and proven trajectory analysis programs. As part of this effort, the Goddard Space Flight Center and the Ames Research Center became partners in the Lunar Prospector trajectory team to provide the trajectory analysis and orbit determination support. At the end of 1998, Lunar Prospector completed its one-year primary mission at 100-km altitude above the lunar surface. On December 19, 1998, Lunar Prospector entered its extended mission phase. The mission orbit was lowered from 100 km to a mean altitude of 40 km. Due to lunar potential effects, the altitude of Lunar Prospector varied from 25 to 55 km above the mean lunar geoid. After one month at 40 km, the lunar potential model was updated based upon the new tracking data at 40 km. On January 15, 1999, the altitude was lowered again to a mean altitude of 30 km. The spherical altitude varied between 15 km and 45 km above the mean lunar geoid while the topographical altitude varied between 10 km and 50 km. Various means were employed to get accurate lunar surface elevation including Clementine altimetry and LOS analysis. Based upon the best available terrain maps, Lunar Prospector reached actual altitudes of 8 km above lunar mountains in the southern polar region. This extended mission phase of six months will enable LP to obtain science data up to 3 orders of magnitude better than at the mission orbit. At the end of the operations mission, LP was targeted for impact at a chosen location that allowed optical observation of the lunar ejecta as LP ended its mission at 1.6 km/sec. This paper details the trajectory design and orbit determination planning and actual results of the Lunar Prospector nominal and extended mission including maneuver design, eccentricity vs. argument of perigee evolution, topographical altitude estimation, and lunar potential modeling. This paper provides understanding of the quasi-frozen orbit design of the LP mission, the optimization process of lunar orbit targets, the impacts that the selected lunar potential models play, and discusses the feasibility of meeting the mission goals. Observed evolution of the Keplerian orbit elements are compared to the theoretical predictions using the latest lunar potential model available which incorporates the Lunar Prospector Doppler data. Mapping orbit maintenance maneuver design along with results of the actual maneuvers to maintain the orbital requirements are also presented.

Folta, David↗

Solar Sail Trajectories for Solar Polar and Heliopause Missions

Over the last several years, interest in a more vigorous space exploration program has renewed interest in the use of solar sails for the more demanding space missions. Solar sail is eminently suited for some of the higher energy missions since no fuel is consumed and the only criteria is that of the total time required to perform a particular mission. Although solar sail missions to planets and small bodies have been examined previously, and reported in the literature' classes of space missions with no well defined target body have received little attention. These Space Physics missions include some with extremely high energy requirements. Not only are these missions difficult, if not impractical, to accomplish with conventional chemical propulsion spacecraft, but they are also difficult to perform in the near future using projected electric-propulsion systems. Solar sail trajectories for two of the high energy Space Physics missions, a Solar Polar mission and a Heliopause mission, are examined in this paper. The object of the Solar Polar mission is to place 'a payload into a short period orbit around the Sun at a 90 degree inclination to either the ecliptic plane or the equatorial plane of the sun. A forerunner for this type of mission was the Ulysses spacecraft which used a gravity assist of Jupiter to place the spacecraft into a 90 degree inclination orbit around the Sun with a perihelion distance of around .55 AU. The orbital period for the Ulysses mission was around 5 years however, and future Solar Polar missions require many observational passes over the pole of the Sun each year thus implying a significantly shorter orbit period than that for Ulysses.

Sauer, Carl G., Jr.↗

Ultrapotent influenza hemagglutinin fusion inhibitors developed through SuFEx-enabled high-throughput medicinal chemistry

Seasonal and pandemic-associated influenza strains cause highly contagious viral respiratory infections that can lead to severe illness and excess mortality. Here, we report on the optimization of our small-molecule inhibitor F0045(S) targeting the influenza hemagglutinin (HA) stem with our Sulfur-Fluoride Exchange (SuFEx) click chemistry–based high-throughput medicinal chemistry (HTMC) strategy. A combination of SuFEx- and amide-based lead molecule diversification and structure-guided design led to identification and validation of ultrapotent influenza fusion inhibitors with subnanomolar EC 50 cellular antiviral activity against several influenza A group 1 strains. X-ray structures of six of these compounds with HA indicate that the appended moieties occupy additional pockets on the HA surface and increase the binding interaction, where the accumulation of several polar interactions also contributes to the improved affinity. The compounds here represent the most potent HA small-molecule inhibitors to date. Our divergent HTMC platform is therefore a powerful, rapid, and cost-effective approach to develop bioactive chemical probes and drug-like candidates against viral targets.

Science & Technology - Other Topics↗

In-flight radiometry of an airborne multispectral sensor

The in-flight radiometric behavior of the NS001 Landsat Thematic Mapper simulator is being reexamined. The absolute radiometric calibration and polarization sensitivity are being analyzed based on data collected in 1990 and 1991. The NS001 has continuously variable gain settings controlled by the aircraft operator. As such, the of in-flight calibration source, an integrating sphere in the solar reflective spectrum, is the only means for calibrating this instrument. Upgrades to the power supply and monitoring circuitry in 1990 improved the in-flight stability. Preliminary results in-flight calibrations of the NS001 indicate no improvement in radiometric accuracy. Laboratory tests have also shown that the NS001 shows strong sensitivity to the degree of polarization and state of the incoming radiations. Simulation studies for typical in-flight conditions have shown that for the NS001 scanning in the principal plane of the sun over a vegetated target, radiance errors reached +/-10 percent in the 0.45-0.52-micron channel and varied with scan angle.

Markham, Brian L.↗

Performance Testing of a Photocatalytic Oxidation Module for Spacecraft Cabin Atmosphere Revitalization

Photocatalytic oxidation (PCO) is a candidate process technology for use in high volumetric flow rate trace contaminant control applications in sealed environments. The targeted application for PCO as applied to crewed spacecraft life support system architectures is summarized. Technical challenges characteristic of PCO are considered. Performance testing of a breadboard PCO reactor design for mineralizing polar organic compounds in a spacecraft cabin atmosphere is described. Test results are analyzed and compared to results reported in the literature for comparable PCO reactor designs.

Perry, Jay L.↗

An ASME-Compliant Helium-4 Evaporation Refrigerator for the SpinQuest Experiment

This paper presents the design, safety basis, and commissioning results of a 1 K liquid helium-4 (4He) evaporation refrigerator developed for the Fermilab SpinQuest Experiment (E1039). The system represents the first high power helium evaporation refrigerator operated in a fixed target scattering experiment at Fermilab and was engineered to comply with the Fermilab ES&H Manual (FESHM) requirements governing pressure vessels, piping, cryogenic systems, and vacuum vessels. The design is mapped to ASME B31.3 (Process Piping) and the ASME Boiler and Pressure Vessel Code (BPVC) for pressure boundary integrity and overpressure protection, with documented compliance to FESHM Chapters 5031 (Pressure Vessels), 5031.1 (Piping Systems), and 5033 (Vacuum Vessels). This work documents the methodology used to reach compliance and approval for the 4He evaporation refrigerator at Fermilab which the field lacks. Design considerations specific to the high radiation target-cave environment including remotely located instrumentation approximately 20 m from the cryostat are summarized, together with the relief-system sizing methodology used to accommodate transient heat loads from dynamic nuclear polarization microwaves and the high-intensity proton beam. Commissioning data from July 2024 confirms that the system satisfies all thermal performance and safety objectives.

Roberts, Jordan D. [Virginia U.]↗

TRIDENT Drill Validation at Mars and Lunar Analog Field Sites

Drilling on Earth is typically a human-intensive activity. Drilling on other planets is further complicated by the lack of prior local field surveys of their target area, hence blindly drilling into uncertain target rocks. Field conditions on the Moon or Mars are also different than for shallow drilling on Earth: lower temperatures and pressures, less power available, low masses (hence less weight-on-bit). Given the cost of transport from Earth, no drilling muds or working fluids are likely to be available to carry away cuttings. And impact-gardened regolith and dust vary mechanically and texturally from most terrestrial soils. The Regolith and Ice Drill for Exploration of New Terrains (TRIDENT) is a rotary-percussive 1m-class drill from Honeybee Robotics. It is low-power (rotary and percussive actuators are 200 W each) and lightweight (<20 kg) with the maximum weight on bit limited to 200 N. TRIDENT has been manifested for the Volatiles Investigating Polar Exploration Rover (VIPER) and PRIME-1 lunar south pole missions in 2024, has previously been field tested at a hot, dry analog site in the Atacama Desert, and in lunar conditions in thermal vacuum chamber tests. TRIDENT was also part of the 2019 Icebreaker Mars Discovery proposal, as well as in the Mars Life Explorer concept. During ARADS tests, drill control and fault recovery automation software enabled hands-off operations of a rover-mounted TRIDENT drill. TRIDENT Drill Analog Site Validation: Past TRIDENT tests in thermal vacuum (TVAC) chambers targeted containers of manufactured lunar simulants with added volatiles. 2022 TRIDENT ambient testing at NASA Ames drilled into cemented lunar simulant materials. Low cuttings-permeability led to cuttings buildup, and drill choking and binding was observed. The Atacama analog site in ARADS had desiccated unconsolidated sediments that did not challenge the TRIDENT design. However, lunar polar regolith is expected to be diverse and heterogeneous with varying clast sizes, with abundant impactites and perhaps subsurface ice deposits. Neither the simulants nor Atacama testing had completely covered the TRIDENT-targeted field characteristics, motivating further analog tests prior to the planned lunar missions. To gain more insight into the behavior of the TRIDENT hardware in diverse impactites and subsurface ice, and to verify the software automation in that environment, in August 2023 TRIDENT was brought to Haughton Crater, a field analog site in the Canadian Arctic. In September 2023 the same drill was brought to the Bishop Tuff in southern California to verify whether drilling binding behaviors previously seen in lunar simulant testing would be observed in naturally occurring fine-grained massive layers. The ~22 Ma Haughton Crater impact structure is located at 75 ̊22’ N, 89 ̊41’ W, on northwestern Devon Island, Nunavut, Canada. Numerous deposits of pale-grey crater-fill polymictic impact-melt breccia are found within the crater with a typical thickness reaching ~125 m or greater and covering ~60 km -2 . An approximately 600m-thick permafrost layer is also present with ice typically found within 0.5-0.6m of the surface. The volcanic tableland north of Bishop, CA exposes densely welded tuff laid down during the eruption that created the Long Valley Caldera at approximately 0.76 Ma. Extensional faults and the Owens River gorge expose cross-sections across the plateau. The area is viewed as an analog site for Mars features believed to be of pyroclastic origin. Results: Haughton Crater.Drilling tests were conducted 8-13 August 2023 at a previously undisturbed area separated 5-10 m from past years’ Drill Hill test sites (75.4208, -089.7613). In six days, TRIDENT drilled 8 holes to nearly 1 m depth each, totaling 7.80 m. The active layer/ice boundary was at ~67 cm depth, with a total of approximately 2.4 m drilled into ice or ice-cemented impact breccia. During drilling, five drill fault states were observed and successfully recovered. Holes 23-1, 4 and 7 were drilled under manual control, using Honeybee’s Thorax user interface. Holes 23-5, 6, and 8 were drilled with the Ames IBexec automated drilling control software. TRIDENT was observed to have little difficulty in the thawed uncemented impact breccia above the active layer boundary, but required percussion to make slower headway in the ice-cemented breccia. In Hole 23-7 (Fig.1), drilling slowed down in a massive unit just above the active-layer boundary (perhaps a large rock extending into the ice-cementation?), with only 7cm progress made in 27 minutes of high auger torque and constant percussion, leading to a choking fault and then a binding fault. A similar pattern had been observed in TRIDENT Rio Tinto test data from 2017 [6] as well as in the 2022laboratory tests.Bishop Tuff.A team from NASA Ames and the US Geological Survey deployed the same TRIDENT drill to Bishop Sites 1B and 1C (37.4203, -118.4289; 37.4265, -118.4215) on 13-16 September 2023, on the Bishop Tuff plateau. A third drill site was used 17-18 September 2023(37.4598, -118.3667) in an abandoned pumice mine. Four holes (totaling 2.5m depth) were drilled into the fine-grained, meters-thick tuff units at Sites 1B and 1C, and a further two boreholes (totaling 1.98m depth) were made at the pumice site. Drill behavior in the tuff below 10 cm depth was similar to that seen at 65-74 cm depth in Haughton Hole 23-7 (Fig. 1) and that seen in the 2022 lab simulant drilling. Drill safety torque limits were exceeded multiple times resulting in drill stops downhole. These freezes then required external added torques (with a pipe wrench) to resume rotation, to unstick the drill for withdrawal. To prevent this choking and binding behavior we found that more-frequent cuttings removal was necessary, e.g., reducing the “drill bite” size from the nominal 10 cm to 2 cm per bite --bringing the auger up to the surface more frequently, as seen in Bishop Site 1C Hole 2 (Fig.2). This permitted slow progress without drill binding and without external interventions. Conversely, TRIDENT drilling in the more porous pumice target material showed no cuttings buildup issue, and single bites as large as 40 cm were demonstrated. Discussion: We observed that TRIDENT easily penetrated unconsolidated heterogeneous soils (both above the active layer boundary at Haughton and previously in the Atacama). Cemented or consolidated targets that were cuttings-permeable (icy impact breccia, pumice) required more energy applied and percussion. However, in non-cuttings-permeable targets (welded microporous tuff, cemented simulants, boulder) TRIDENT was observed to be prone to excessive cuttings accumulation leading to choking/binding faults and stalling. The wedge cutting bit, used by TRIDENT in field tests and in its flight versions, pulverizes the target rock and creates fine cuttings that ideally are transported up the auger spirals for removal. In porous, fractured or vesicular target materials (such as at the Bishop pumice site) a significant portion of the cuttings are pushed aside, but for non-fractured, microporous targets the cuttings remain in the borehole and accumulate. Rock powder is relatively incompressible as a working fluid at only 100-200N downward force (TRIDENT limits) and hence eventual drilling progress slows or stops. Our recommended strategy for improving TRIDENT cuttings removal in massive target units with low cuttings-permeability is to reduce TRIDENT bite sizes when encountering these units, from 10cm to as little as 1-2cm, to effectively bail the accumulating cuttings. This approach was demonstrated to reduce choking and allowed slow progress to continue in cuttings-impermeable microporous target units (viz. the Bishop tuff in our September 2023 tests or cemented simulants in 2022 ambient tests).

robotic drilling↗

A ligand discovery toolbox for the WWE domain family of human E3 ligases

The WWE domain is a relatively under-researched domain found in twelve human proteins and characterized by a conserved tryptophan-tryptophan-glutamate (WWE) sequence motif. Six of these WWE domain-containing proteins also contain domains with E3 ubiquitin ligase activity. The general recognition of poly-ADP-ribosylated substrates by WWE domains suggests a potential avenue for development of Proteolysis-Targeting Chimeras (PROTACs). Here, we present novel crystal structures of the HUWE1, TRIP12, and DTX1 WWE domains in complex with PAR building blocks and their analogs, thus enabling a comprehensive analysis of the PAR binding site structural diversity. Furthermore, we introduce a versatile toolbox of biophysical and biochemical assays for the discovery and characterization of novel WWE domain binders, including fluorescence polarization-based PAR binding and displacement assays, 15 N-NMR-based binding affinity assays and 19 F-NMR-based competition assays. Through these assays, we have characterized the binding of monomeric iso -ADP-ribose ( iso -ADPr) and its nucleotide analogs with the aforementioned WWE proteins. Finally, we have utilized the assay toolbox to screen a small molecule fragment library leading to the successful discovery of novel ligands targeting the HUWE1 WWE domain.

59 BASIC BIOLOGICAL SCIENCES↗

Flue Gas CO 2 Capture via Electrochemically Mediated Amine Regeneration: Desorption Unit Design and Analysis

We analyzed the performance of an electrochemical desorption unit to be implemented in an electrochemically mediated amine regeneration (EMAR) process, which separates CO 2 and regenerates the amine upon modulation of a targeted species that complexes with the amine molecules. Using a simplified one-dimensional boundary layer model, we combined the kinetic expressions of the faradaic reactions with mass transfer effects to analyze the polarization behavior of the flow cell. Mass transfer limitations become dominant at high current densities, leading to increases in energy consumption. An understanding of scaling laws with key parameters, such as the Sherwood number, is required to achieve high power operation with minimal mass transfer losses. Because the EMAR chemistry is sensitive to temperature, heat distribution in the unit is also examined. Our results indicate that the desorption performance increases with addition of a high-temperature heat source. Additionally, incorporation of membrane crossover suggests energy losses because of diffusion and migration of active species. Furthermore, these findings inform on scaling laws for at-scale desorber design and provide a model for scaling up the EMAR system for larger scale operations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Photoproduction of the Λ(1520) hyperon with a 9 GeV photon beam at GlueX

The GlueX experiment is located at the Thomas Jefferson National Accelerator Facility (JLab) in Newport News, VA, USA. It features a hermetic 4π detector with excellent tracking and calorimetry capabilities. Its 9 GeV linearly polarized photon beam is produced from the 12 GeV electron beam, delivered by JLab’s Continuous Electron Beam Accelerator Facility (CEBAF), via bremsstrahlung on a thin diamond and is incident on a LH2 target. GlueX recently finished its first data taking period and published first results. The main goal of GlueX is to measure gluonic excitations of mesons. These so-called hybrid or exotic mesons are predicted by Quantum Chromodynamics (QCD) but haven’t been experimentally confirmed yet. They can have quantum numbers not accessible by ordinary quark-antiquark pairs which helps in identifying them using partial wave analysis techniques. The search for exotic mesons requires a very good understanding of photoproduction processes in a wide range of final states, one of them being pK + K - which contains many meson and baryon reactions. The Λ(1520) is a prominent hyperon resonance in this final state and is the subject of this presentation. This talk will give an introduction to the GlueX experiment and show preliminary results for the photoproduction of the Λ(1520) hyperon. The measurement of important observables like the photon beam asymmetry and spin-density matrix elements will be discussed and an outlook to possible measurements of further hyperon states in the pK + K - final state will be given.

Pauli, Peter↗

Light front synchronization and rest frame densities of the proton: Electromagnetic densities

We clarify the physical origin and meaning of the two-dimensional relativistic densities of the light front formalism. The densities are shown to originate entirely from the use of light front time instead of instant form time, which physically corresponds to using an alternative synchronization convention. This is shown by using tilted light front coordinates, which consist of light front time and ordinary spatial coordinates, and which are also used to show that the obtained densities describe a system at rest rather than at infinite momentum. These coordinates allow all four components of the electromagnetic current density to be given clear physical meanings. We explicate the formalism for spin-half targets, obtaining charge and current densities of the proton and neutron using empirical form factor parametrizations, as well as up and down quark densities and currents. Angular modulations in the densities of transversely polarized states are explained as originating from redshifts and blueshifts due to quarks moving in different longitudinal directions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Using interfaces to: create strongly-coupled magnetic-ferroelectrics

Starting at the level of electrons and atoms our long-term goal is to rationally design complex oxide heterostructures and interface-materials with targeted emergent behaviors. This is not a matter of simply optimizing material parameters, but rather begins with understanding a mechanism to control the interplay between the diverse microscopic degrees of freedom prevalent in complex oxides in order to create targeted macroscopic phenomena and ends with the design of new material realizations. These realizations are in turn created with atomic-layer precision, structurally assessed to see that they are the intended realization, and finally their relevant properties are measured. During this program we have developed the scientific ideas necessary to apply this materials-by-design paradigm to the creation of materials offering electrical control of magnetism. At the heart of our approach lies a partnership between theory, synthesis, and characterization. These are the areas of expertise of the three co-PIs, who have worked closely together since their arrival at Cornell. During this project bold ideas on where to put the atoms to provide electrical control of magnetism were met with the latest methods of synthesis science and electron microscopy in an attempt create targeted new multiferroics. Our work applying this materials-by-design methodology to multiferroics has enjoyed multiple successes. The Co-PIs have invented new mechanisms for multiferroics, which provide strong coupling between polarization and magnetism, and reduced them to practice. Specifically, we pioneered multiferroics based on spin-phonon coupling, rotation-driven multiferroicity, and novel geometric multiferroics. Importantly, the latter two of these mechanisms enable the deterministic switching of magnetism by an applied electric field, which is key to the application of multiferroics to future device technologies. Most recently, we performed detailed theoretical analysis on a system involving the combination of magnetoelectric and colossal magnetoresistance behaviors and predict that electrical control of a metal-insulator transition is possible in appropriately strained SmBaMn2O6. The research enabled by this grant led to 63 publications in leading refereed journals including Nature, Nature Materials, Physical Review Letters, and Advanced Materials demonstrating a materials-by-design paradigm to the creation of materials offering electrical control of magnetism.

36 MATERIALS SCIENCE↗

Radar investigation of asteroids and planetary satellites

Radar reconnaissance of near-Earth asteroids, mainbelt asteroids, the Galilean satellites, the Martian satellites, and large Saturnian satellites, using the Arecibo 13-cm and the Goldstone 3.5-cm systems is discussed. Measurements of echo strength, polarization, delay/Doppler distribution of echo power provide information about dimensions, spin vector, large-scale topography, cm-to-m-scale morphology, and surface bulk density. The observations also yield refined estimates of target orbital elements.

Ostro, Steven J.↗

NICER X-ray Observations of Seven Nearby Rotation-powered Millisecond Pulsars

The Neutron star Interior Composition Explorer observed several rotation-powered millisecond pulsars (MSPs) to search for or confirm the presence of X-ray pulsations. When broad and sine-like, these pulsations may indicate thermal emission from hot polar caps at the magnetic poles on the neutron star surface. We report confident detections (≥4.7σ after background filtering) of X-ray pulsations for five of the seven pulsars in our target sample: PSR J0614−3329, PSR J0636+5129, PSR J0751+1807, PSR J1012+5307, and PSR J2241−5236, while PSR J1552+5437 and PSR J1744−1134 remain undetected. Of those, only PSR J0751+1807 and PSR J1012+5307 had pulsations previously detected at the 1.7σ and almost 3σ confidence levels, respectively, in XMM-Newton data. All detected sources exhibit broad sine-like pulses, which are indicative of surface thermal radiation. As such, these MSPs are promising targets for future X-ray observations aimed at constraining the neutron star mass–radius relation and the dense matter equation of state using detailed pulse profile modeling. Furthermore, we find that three of the detected MSPs exhibit a significant phase offset between their X-ray and radio pulses.

Sebastien Guillot↗

Triplet Photosensitized para -Hydrogen Induced Polarization

Despite its enormous utility in structural characterization, nuclear magnetic resonance (NMR) spectroscopy is inherently limited by low spin polarization. One method to address the low polarization is para-hydrogen (p-H 2 ) induced polarization (PHIP) which uses the singlet spin isomer of H 2 to generate disparate nuclear spin populations to amplify the associated NMR signals. PHIP often relies on thermal catalysis or, more infrequently, UV-activated catalytic hydrogenation. Light-activated hydrogenation enables direct and timed control over the hyperpolarization of target substrates, critical for identifying short-lived intermediates. Here, we use an established Ir(III) triplet photosensitizer (PS) to visible light sensitize the triplet ligand-field states in the d6-transition metal dihydride Ru(CO)(PPh 3 ) 3 (H) 2 (1). Excitation inside a 9.4 T NMR spectrometer with the PS and a 420 nm blue LED, under 3 atm of p-H 2 , successfully photosensitized hyperpolarization in 1 and in a range of unsaturated substrates at and below room temperature, up to 1630-fold. In otherwise identical experimental conditions without light activation, no polarization was realized in 1 or the substrates evaluated. We believe triplet-sensitized PHIP (Trip- PHIP) represents a facile experimental means for probing triplet sensitized light activation in transition metal catalysts possessing low-lying triplet ligand-field states, providing mechanistic insight of potentially tremendous value in chemical catalysis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Laser-driven quasi-static B-fields for magnetized high-energy-density experiments

We present measurements of magnetic fields generated in laser-driven coil targets irradiated by laser pulses of nanosecond duration, 1.053 μm wavelength, 500 J energy, and ∼1015 W/cm2 intensity, at the LULI2000 facility. Using two perpendicular probing axes, proton deflectometry is used to characterize the coil current and static charge at different times. Results reveal various deflection features that can be unambiguously linked to a looping quasi-steady current of well-understood polarity or to a static charging of the coil surface. Measured currents are broadly consistent with predictions from a laser-driven diode-current source and lumped circuit model, supporting the quasi-steady assessment of the discharges. Peak magnetic fields of ∼50 T at the center of 500-μm-diameter coils, obtained at the moderate laser intensity, open up the use of such laser-driven coil targets at facilities worldwide to study numerous phenomena in magnetized high-energy-density plasmas, and its potential applications.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗