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At least 613 records · Page 34

Modeling Continuous Online Refueling with SCALE 6.3.1 and Serpent-2 in the EIRENE Novel Molten Salt Reactor Design

The Molten Salt Reactor (MSR) is a Generation IV advanced fission reactor design in which the coolant, and in some cases the fuel itself, is in the form of liquid molten alkali-halide salts with a fluoride or chloride ionic base. In liquid-fueled MSRs, reactor refueling may be performed online, where fresh fuel salt is added to the core during operation without the need for shutdown periods. Refueling for these reactor designs is typically modeled using either a batch or continuous refueling approach, both of which can be simulated with the SCALE 6.3.1 and Serpent-2 code systems. However, the specific manner in which they are implemented can vary depending upon the desired rate of refueling, whether the refueling rate is constant or variable, and consideration of salt drainage for systems where the in-core salt volume is kept constant. In a novel MSR fuel cycle concept termed the “Sourdough” fuel cycle, fuel salt is allowed to “grow” within the core, with excess salt either being transferred to an external holding tank to maintain a constant core volume or diverted to an upper plenum within the core to allow for volume growth. In this work, continuous refueling was modeled in a thermal-spectrum, LEU-fueled, small MSR design operating with the Sourdough fuel cycle using the SCALE 6.3.1 and Serpent-2 codes. Two different continuous refueling approaches were simulated, with the performance of each being compared to determine which is most suitable for use with the Sourdough fuel cycle concept.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Interfacial Analysis of Blister Formation in U-10Mo Mini-Plates

A thorough investigation of potential failure mechanisms builds confidence in the performance of monolithic U-10wt%Mo (U-10Mo) fuel plates. The lowenriched uranium (LEU) fuel system is currently undergoing qualification as a high U-density fuel that can be used to convert United States high-performance research reactors from high-enriched uranium (HEU) operation. This will require establishing fuel operational limits such that fission products and a coolable geometry are retained, even during off-normal reactor operation conditions [1]. Such off-normal conditions can subject the fuel plates to temperatures where the internal pressure of precipitated fission gasses result in a permanent deformed, raised area of the cladding, referred to as a blister. These blisters can reduce the local coolability of a fuel plate and can even close coolant channels of a fuel assembly, so blistered plates are considered failed regardless of whether the fuel is truly breached. Historically, a marginto- failure is established through out-of-pile blister threshold testing of irradiated fuel plates. This is accomplished by incrementally heating irradiated fuel plates until blisters are observed. This reveals the temperature threshold that would have resulted in a blister if a plate experienced them at those irradiation conditions [2]. While the blister testing itself reveals the temperatures at which the cladding mechanical integrity was exceeded, a more thorough investigation of the interface evolution in proximity to formed blisters may reveal mechanisms as to the blister formation and retention of fission gases. Previous studies have explored potential underlying mechanisms in historical plates that may have been close to blistering [3]; however, this work is the first exploration of blister tested irradiated plates, fabricated by a commercial vendor—another requirement for qualification of the fuel system [1]. The Mini-plate 1 (MP-1) experiment was the first in a series of irradiation and post-irradiation examination (PIE) campaigns to qualify the U-10Mo monolithic fuel system. It consisted of commercially fabricated 25.4×101.5 mm Al-clad mini-plates with a monolithic U-10Mo foil coated in a Zr diffusion barrier. The primary MP-1 PIE campaign was previously completed. Among the suit of examinations was a blister testing campaign, where plates were incrementally annealed in 25°C increments until blisters were observed or a maximum temperature of 550°C was reached [4]. The previously blistered plates from this campaign were revisited in this work.

25228↗

Advanced Fuels Campaign Execution Plan

The Advanced Fuels Campaign (AFC) Execution Plan details the strategy, mission, scope, and goals—both near-term and long-term—along with the structure and organization of nuclear fuels and materials research, development, and demonstration (RD&D) activities within the Fuel Cycle Technologies (FCT) program. The FCT program, tasked by the U.S. Department of Energy (DOE), employs a science-based approach to advance fuel technologies. This approach integrates theory, experiments, and multi-scale modeling and simulation (M&S) to develop a predictive understanding of fuel fabrication processes and fuel/cladding performance under irradiation, moving beyond traditional empirical methods. The long-term goals of the AFC are guided by the AFC Strategic Plan and align with the DOE Office of Nuclear Energy (NE) Roadmap [1], which outlines a multi-decade vision for demonstrating and qualifying advanced fuel forms to support diverse fuel cycle options. Near-term goals focus on enhancing accident tolerant fuels (ATF) for Light Water Reactors (LWR), a significant challenge that demands balancing immediate objectives with ongoing progress toward advanced reactor missions. Accelerating the traditional fuel qualification process to meet ATF objectives is another critical challenge. A detailed set of 5-year goals, summarized below, has been developed in line with the overarching science-based fuel development approach: • Advanced LWR Fuel Technologies: By 2027, support the development of advanced LWR fuel technologies with improved performance and enhanced accident tolerance. This includes high burnup (HBu), low enriched uranium (LEU)+, coated cladding, and doped fuel, aimed at complementing industry-led significant LWR uprates and plant refurbishments. • Tristructural Isotropic (TRISO) Fuel: Achieve qualification by 2028 and develop improved designs for emerging markets. • Metal Fuel: Achieve qualification by 2028 and develop improved designs for emerging markets. • Molten Salt Fuel: By 2027, deploy a robust program that enables fuel salt qualification technologies needed to support fuel salt research and development (R&D), focusing on emergent needs to derisk fuel salt production and utilization in advanced reactors. • Long-Term ATF: Develop fuel technologies that enable significant power uprates (~50%) in refurbished or new LWRs while optimizing fissile material utilization and waste disposal. The 5-year milestones in the AFC Execution Plan are contingent on an assumed budget. This Execution Plan will be updated annually to reflect actual funding profiles as budget guidance becomes available, ensuring milestones are adjusted accordingly. In summary, the AFC Execution Plan presents a comprehensive strategy to advance nuclear fuel technologies through a science-based approach, addressing both near-term and long-term goals while adapting to funding realities.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

An evolving view of methane metabolism in the Archaea

Methane is a key compound in the global carbon cycle that influences both nutrient cycling and the Earth’s climate. A limited number of microorganisms control the flux of biologically generated methane, including methane-metabolizing archaea that either produce or consume methane. Methanogenic and methanotrophic archaea belonging to the phylum Euryarchaeota share a genetically similar, interrelated pathway for methane metabolism. The key enzyme in this pathway, the methyl-coenzyme M reductase (Mcr) complex, catalyses the last step in methanogenesis and the first step in methanotrophy. Here, the discovery of mcr and divergent mcr-like genes in new euryarchaeotal lineages and novel archaeal phyla challenges long-held views of the evolutionary origin of this metabolism within the Euryarchaeota. Divergent mcr-like genes have recently been shown to oxidize short-chain alkanes, indicating that these complexes have evolved to metabolize substrates other than methane. In this Review, we examine the diversity, metabolism and evolutionary history of mcr-containing archaea in light of these recent discoveries.

54 ENVIRONMENTAL SCIENCES↗

Partial glass isosymmetry transition in multiferroic hexagonal ErMn O 3

Ferroelectric transitions of a hexagonal multiferroic, ErMnO 3 , are studied by x-ray scattering techniques. An isosymmetry transition, similar to that previously observed for YMnO 3 , approximately 300 K below the well-known ferroic transition temperature is investigated. The partial glassy behavior of the isosymmetry transition is identified by appearance of quasi-elastic scattering lines in high-energy-resolution scans. The glassy behavior is further supported by the increased interlayer decorrelation of (√3×√3)R30º ordering below the isosymmetry transition. The transition behavior is considered for possible hidden sluggish modes and two-step phase transitions theoretically predicted for the stacked triangular antiferromagnets. The in-plane azimuthal (orientational) ordering behaviors were also compared to the theoretical predictions. Coherent x-ray speckle measurements show unambiguously that the domain sizes decrease anomalously near both the isosymmetry and ferroic transitions. However, domain boundary fluctuations increase monotonically with an Arrhenius form with an activation energy of 0.54(5) eV through both transitions.

36 MATERIALS SCIENCE↗

Inelastic x-ray scattering measurements of phonon dynamics in URu 2 Si 2

In this paper, we study high-resolution inelastic x-ray scattering measurements of the acoustic phonons of URu 2 Si 2 . At all temperatures, the longitudinal acoustic phonon linewidths are anomalously broad at small wave vectors revealing a previously unknown anharmonicity. The phonon modes do not change significantly upon cooling into the hidden order phase. In addition, our data suggest that the increase in thermal conductivity in the hidden order phase cannot be driven by a change in phonon dispersions or lifetimes. Hence, the phonon contribution to the thermal conductivity is likely much less significant compared to that of the magnetic excitations in the low temperature phase.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Processing of Dilute Mg–Zn–Mn–Ca Alloy/Nb Multilayers by Accumulative Roll Bonding

Recent advancements in the severe plastic deformation process called accumulative roll bonding (ARB) can help to address the long-standing need for manufacturing lightweight, high-strength Mg sheet materials. However, the fabrication of Mg alloy-based laminates via ARB remains a challenge due to the intrinsically poor formability of Mg. Herein, it is shown that Mg-based composite laminates with refined layers can be fabricated via several room-temperature ARB cycles with appropriate intermediate annealing and alloy selection. The final laminates made here consist of equal volume fractions of a dilute Mg–Zn–Mn–Ca alloy phase and a pure Nb phase with fine 150 μm layer thicknesses. Deformation texture evolution in both phases within the composite is analyzed via neutron diffraction measurements taken at different stages in the process. The analysis suggests that the annealing step recrystallizes the Mg-alloy phase. It is also shown that for both phases, the stabilized deformation textures within the composite correspond to the classic stable textures of the individual constituents. Polycrystal texture modeling implies that {10–12} <-1011> extension twinning developed in the Mg alloy during rolling.

36 MATERIALS SCIENCE↗