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At least 613 records · Page 34

Sulfur and Metal Fertilization of the Lower Continental Crust

Mantle-derived melts and metasomatic fluids are considered to be important in the transport and distribution of trace elements in the subcontinental lithospheric mantle. However, the mechanisms that facilitate sulfur and metal transfer from the upper mantle into the lower continental crust are poorly constrained. This study addresses this knowledge gap by examining a series of sulfide- and hydrous mineral-rich alkaline mafic-ultramafic pipes that intruded the lower continental crust of the Ivrea-Verbano Zone in the Italian Western Alps. The pipes are relatively small (<300 m diameter) and primarily composed of a matrix of subhedral to anhedral amphibole (pargasite), phlogopite and orthopyroxene that enclose sub-centimeter-sized grains of olivine. The 1 to 5 m wide rim portions of the pipes locally contain significant blebby and disseminated Fe-Ni-Cu-PGE sulfide mineralization.Stratigraphic relationships, mineral chemistry, geochemical modeling and phase equilibria suggest that the pipes represent open-ended conduits within a large magmatic plumbing system. The earliest formed pipe rocks were olivine-rich cumulates that reacted with hydrous melts to produce orthopyroxene, amphibole and phlogopite.Sulfides precipitated as immiscible liquid droplets that were retained within a matrix of silicate crystals and scavenged metals from the percolating hydrous melt. New high-precision chemical abrasion TIMS-UPb dating of zircons from one of the pipes indicates that these pipes were emplaced at 249.1+/-0.2 Ma, following partial melting of lithospheric mantle pods that were metasomatized during the Eo-Variscan oceanic to continental subduction (approx. 420-310 Ma). The thermal energy required to generate partial melting of the metasomatized mantle was most likely derived from crustal extension, lithospheric decompression and subsequent asthenospheric rise during the orogenic collapse of the Variscan belt (<300 Ma). Unlike previous models, outcomes from this study suggest a significant temporal gap between the occurrence of mantle metasomatism, subsequent partial melting and emplacement of the pipes.We argue that this multi-stage process is a very effective mechanism to fertilize the commonly dry and refractory lower continental crust in metals and volatiles. During the four-dimensional evolution of the thermo-tectonic architecture of any given terrain, metals and volatiles stored in the lower continental crust may become available as sources for subsequent ore-forming processes, thus enhancing the prospectivity of continental block margins for a wide range of mineral systems.

Marek Locmelis↗

Operations and Results from the 200 Gbps TBIRD Laser Communication Mission

Since launch in May 2022, the TeraByte Infrared Delivery (TBIRD) mission has successfully demonstrated 200 Gbps laser communications from a 6U CubeSat and has transferred up to 4.8 terabytes (TB) in a pass from low Earth orbit to ground. To our knowledge, this is the fastest downlink ever achieved from space. To support the narrow downlink beam needed for high rate communications, the payload provides pointing feedback to the host spacecraft to precisely track the ground station throughout the 5-minute pass. The space and ground terminals utilize fiber-coupled coherent transceivers in conjunction with an automatic repeat request (ARQ) system to guarantee error-free communication through an atmospheric fading channel. This paper presents an overview of the link operations and mission results to date, as well as implications for future missions with high rate lasercom.

TBIRD↗

The role of substrate on stabilizing new phases of two-dimensional tin

In this work, we investigate the role of substrates in determining the morphologies and electronic structures of two-dimensional (2D) Sn. Here, we use Ir(111) and 2D hexagonal boron nitride (h-BN) predeposited on Ir(111) as substrates. The latter contains Moiré patterns with varying binding strength between h-BN and metal. Using scanning tunneling microscopy and first-principles calculations, we reveal the distinct morphologies of 2D Sn on different substrates. Of particular interest, we discover a new √7 × √7 Sn phase, originating from the local charge transfer with metal beneath the “decoupling” h-BN monolayer at the strongly interacting Moiré region. To the best of our knowledge, this work demonstrates, for the first time via combined experimental and theoretical approach, that new 2D Sn phases can be achieved using Moiré patterns on h-BN/metal. This finding should be instrumental in the development of 2D-based topological materials.

36 MATERIALS SCIENCE↗

SPECTROSCOPY OF THE INNER COMPANION OF THE PULSAR PSR J0337+1715

The hierarchical triple system PSR J0337+1715 offers an unprecedented laboratory to study secular evolution of interacting systems and to explore the complicated mass-transfer history that forms millisecond pulsars and helium-core white dwarfs. The latter in particular, however, requires knowledge of the properties of the individual components of the system. Here we present precise optical spectroscopy of the inner companion in the PSR J0337+1715 system. We confirm it as a hot, low-gravity DA white dwarf with T {sub eff} = 15, 800 ± 100 K and log{sub 10}(g) = 5.82 ± 0.05. We also measure an inner mass ratio of 0.1364 ± 0.0015, entirely consistent with that inferred from pulsar timing, and a systemic radial velocity of 29.7 ± 0.3 km s{sup –1}. Combined with the mass (0.19751 M {sub ☉}) determined from pulsar timing, our measurement of the surface gravity implies a radius of 0.091 ± 0.005 R {sub ☉}; combined further with the effective temperature and extinction, the photometry implies a distance of 1300 ± 80 pc. The high temperature of the companion is somewhat puzzling: with current models, it likely requires a recent period of unstable hydrogen burning, and suggests a surprisingly short lifetime for objects at this phase in their evolution. We discuss the implications of these measurements in the context of understanding the PSR J0337+1715 system, as well as of low-mass white dwarfs in general.

79 ASTRONOMY AND ASTROPHYSICS↗

RefSoil+: a Reference Database for Genes and Traits of Soil Plasmids

Plasmids harbor transferable genes that contribute to the functional repertoire of microbial communities, yet their contributions to metagenomes are often overlooked. Environmental plasmids have the potential to spread antibiotic resistance to clinical microbial strains. In soils, high microbiome diversity and high variability in plasmid characteristics present a challenge for studying plasmids. To improve the understanding of soil plasmids, we present RefSoil+, a database containing plasmid sequences from 922 soil microorganisms. Soil plasmids were larger than other described plasmids, which is a trait associated with plasmid mobility. There was a weak relationship between chromosome size and plasmid size and no relationship between chromosome size and plasmid number, suggesting that these genomic traits are independent in soil. We used RefSoil+ to inform the distributions of antibiotic resistance genes among soil microorganisms compared to those among nonsoil microorganisms. Soil-associated plasmids, but not chromosomes, had fewer antibiotic resistance genes than other microorganisms. These data suggest that soils may offer limited opportunity for plasmid-mediated transfer of described antibiotic resistance genes. RefSoil+ can serve as a reference for the diversity, composition, and host associations of plasmid-borne functional genes in soil, a utility that will be enhanced as the database expands. Our study improves the understanding of soil plasmids and provides a resource for assessing the dynamics of the genes that they carry, especially genes conferring antibiotic resistances.Soil-associated plasmids have the potential to transfer antibiotic resistance genes from environmental to clinical microbial strains, which is a public health concern. A specific resource is needed to aggregate the knowledge of soil plasmid characteristics so that the content, host associations, and dynamics of antibiotic resistance genes can be assessed and then tracked between the environment and the clinic. Here, we present RefSoil+, a database of soil-associated plasmids. RefSoil+ presents a contemporary snapshot of antibiotic resistance genes in soil that can serve as a reference as novel plasmids and transferred antibiotic resistances are discovered. Our study broadens our understanding of plasmids in soil and provides a community resource of important plasmid-associated genes, including antibiotic resistance genes.

59 BASIC BIOLOGICAL SCIENCES↗

Flow instabilities in helical-coil steam generators for small modular reactors: A review

Here, this study covers the research and discoveries in two-phase flow-boiling instabilities available in the literature—specifically for a helical-coil steam generator (HCSG), including experimental findings, theoretical research, computational models, and system code analyses—supporting research and development of representative small modular reactors (SMRs). Like other new and advanced reactor systems, water-cooled SMRs require experimental data from both integral and separate thermal-hydraulics test facilities for the verification and validation (V&V) of the computational models and computer codes in order to design and obtain regulatory approval. The complex dynamics of two-phase flow-boiling instabilities includes flow regimes physics phenomena, flow-channel geometries, heat-transfer behavior, and interactions among the solid–liquid-gas within the system boundary, all of which are pivotal for understanding the design and operational challenges of SMRs. This study focuses on identifying the relevant knowledge gaps on boiling instabilities—specifically for a HCSG—and provides insights about future research direction optimizing the transport of thermal energy, mass-flow rates, and boundary conditions that ensure the adequate heat-transfer performance, operational stability, and safety associated with SMR systems.

20 FOSSIL-FUELED POWER PLANTS↗

Integration of the fundamental knowledge on solvent-packing interactions into the multiscale framework for column scale design and optimization

The interfacial area, also known as the effective mass transfer area, is a key factor for determining the mass transfer for carbon dioxide (CO 2 ) capture via the chemical absorption process in a packed column, and thus the overall capture efficiency of the packed column. Most of the widely used empirical and semi-empirical models for interfacial area were derived indirectly through absorption mass transfer with simplifications based on fast chemical kinetics. This report presents the comprehensive unique multiscale approach to develop a surrogate model for effective mass transfer area in structured packed columns that accounts local hydrodynamics as well as variation in physical properties, and changes in solid surface characteristics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Electroactive biofilms: how microbial electron transfer enables bioelectrochemical applications

Abstract Microbial biofilms are ubiquitous. In marine and freshwater ecosystems, microbe–mineral interactions sustain biogeochemical cycles, while biofilms found on plants and animals can range from pathogens to commensals. Moreover, biofouling and biocorrosion represent significant challenges to industry. Bioprocessing is an opportunity to take advantage of biofilms and harness their utility as a chassis for biocommodity production. Electrochemical bioreactors have numerous potential applications, including wastewater treatment and commodity production. The literature examining these applications has demonstrated that the cell–surface interface is vital to facilitating these processes. Therefore, it is necessary to understand the state of knowledge regarding biofilms’ role in bioprocessing. This mini-review discusses bacterial biofilm formation, cell–surface redox interactions, and the role of microbial electron transfer in bioprocesses. It also highlights some current goals and challenges with respect to microbe-mediated bioprocessing and future perspectives.

59 BASIC BIOLOGICAL SCIENCES↗

Nuclear Data Sheets for A=212

Spectroscopic data for all nuclei with mass number A=212 have been evaluated and the corresponding level schemes from radioactive decay and reaction studies are presented. Highlights from this evaluation include the first observation of 212 Hg by 2010Al24 and the first measurement of the ground state half-life by 2012Be28and 2016Ca25. The first measurement of the β - decay of 212 Tl populating excited states in 2 12 Pb has been per-formed by 2014Mo02. Knowledge of excited levels and their half-lives in 212 Po has been significantly extended in the transfer reaction studies of 2010As01, 2010As03 and 2016Ko03, 2017Ko38. A new (9 - )isomer which α decays in 212 At was observed by 2007Ku30. The level scheme of 212 Rn was significantly extended through the(HI,xnγ) reaction studies of 2009Dr12 and 2008Dr01. New levels in 212 Ra were identified in a transfer reaction experiment by 2018Pa04. Finally, the α decay of both the ground state and an isomer in 216 U populating 212 Thwas reported for the first time by 2015Ma37 and 2015De22

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Computational Design of New Magnesium Electrolytes with Improved Properties

Here, we use computational design to examine 15 new electrolyte salt anions by performing chemical variations and mutations on the bis(trifluoromethane)sulfonamide (TFSI) anion. On the basis of our calculations, we propose two new anions as potential candidates for magnesium energy-storage systems, which are evolved from TFSI with the substitution of sulfur atoms in TFSI and the modification of functional groups. The applicability of these new anion salts is examined through comprehensive calculations using both first-principles as well as benchmarked classical molecular dynamics. We elucidate the important properties of these anions, including the electrochemical stability window, chemical decomposition, preferred solvation structure, diffusion coefficient, and other dynamical properties for 15 rationally designed molecules. Two of the designed anions are discovered to successfully avoid the vulnerability of TFSI during ion-pair charge-transfer reactions while retaining comparable or better performance of other properties. As such, our work provides, to our knowledge, the first theoretically designed electrolyte salt for contemporary multivalent batteries and provides guidance for the synthesis and testing of novel liquid electrochemical systems.

25 ENERGY STORAGE↗

Open quantum system violates generalized Pauli constraints on quantum device

Abstract The Pauli exclusion principle governs the fundamental structure and function of fermionic systems from molecules to materials. Nonetheless, when such a fermionic system is in a pure state, it is subject to additional restrictions known as the generalized Pauli constraints (GPCs). Here we verify experimentally the violation of the GPCs for an open quantum system using data from a superconducting-qubit quantum computer. We prepare states of systems with three-to-seven qubits directly on the quantum device and measure the one-fermion reduced density matrix (1-RDM) from which we can test the GPCs. We find that the GPCs of the 1-RDM are sufficiently sensitive to detect the openness of the 3-to-7 qubit systems in the presence of a single-qubit environment. Results confirm experimentally that the openness of a many-fermion quantum system can be decoded from only a knowledge of the 1-RDM with potential applications from quantum computing and sensing to noise-assisted energy transfer.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Hard x-ray methods for studying the structure of amorphous thin films and bulk glassy oxides

High-energy photon diffraction minimizes many of the corrections associated with laboratory x-ray diffractometers, and enables structure factor measurements to be made over a wide range of momentum transfers. The method edges us closer toward an ideal experiment, in which coordination numbers can be extracted without knowledge of the sample density. Three case studies are presented that demonstrate new hard x-ray methods for studying the structure of glassy and amorphous materials. First, the methodology and analysis of high-energy grazing incidence on thin films is discussed for the case of amorphous In 2 O 3 . Additionally, the connectivity of irregular InO 6 polyhedra are shown to exist in face-, edge- and corner-shared configurations in the approximate ratio of 1:2:3. Secondly, the technique of high-energy small and wide angle scattering has been carried out on laser heated and aerodynamically levitated samples of silica-rich barium silicate (20BaO:80SiO 2 ), from the single phase melt at 1500 C-o to the phase separated glass at room temperature. Based on Ba-O coordination numbers of 6 to 7, it is argued that the although the potential of Ba is ionic, it is weak enough to cause the liquid-liquid immiscibility to become metastable. Lastly, high-energy small and wide angle scattering has also been applied to high water content (up to 12 wt.%) samples of hydrous SiO 2 glass quenched from 1500 C-o at 4 GPa. An increase of Si 1 O 2 correlations at 4.3 angstrom is found to be consistent with an increase in the population of three-membered SiO 4 rings at the expense of larger rings.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Information transfer as a framework for optimized phase imaging

In order to efficiently image a non-absorbing sample (a phase object), dedicated phase contrast optics are required. Typically, these optics are designed with the assumption that the sample is weakly scattering, implying a linear relation between a sample’s phase and its transmission function. In the strongly scattering, nonlinear case, the standard optics are ineffective, and the transfer functions used to characterize them are uninformative. We use the Fisher information (FI) to assess the efficiency of various phase imaging schemes and to calculate an information transfer function (ITF). We show that a generalized version of Zernike phase contrast is efficient given sufficient prior knowledge of the sample. We show that with no prior knowledge, a random sensing measurement yields a significant fraction of the available information. Finally, we introduce a generalized approach to common path interferometry that can be optimized to prioritize sensitivity to particular sample features. Each of these measurements can be performed using Fourier lenses and phase masks.

Koppell, Stewart↗

Hydromagnetic waves at low latitudes - A symposium review from the fifth IAGA assembly

The aim of the symposium was to bring together investigators with interests in low latitude hydromagnetic waves in order to review the present state of knowledge in this area of magnetospheric physics. Of particular importance is the means by which wave energy is transferred to low latitudes to produce geomagnetic pulsations on the ground. The group of contributed papers reviewed shows that definitive experiments are underway and new theories capable of providing resonant wave energy at low latitudes are being developed. Particular topics covered by the review include solar wind control, wave spectra, array studies of wave parameters, storm time waves, and global wave resonance theory involving the coupling of compressional and transverse waves in the magnetosphere.

Fraser, B. J.↗

NASA/DOD Aerospace Knowledge Diffusion Research Project. Paper 5: Aerospace librarians and technical information specialists as information intermediaries: A report of phase 2 activities of the NASA/DOD Aerospace Knowledge Diffusion Research Project

The flow of U.S. government-funded and foreign scientific and technical information (STI) through libraries and related facilities to users in government and industry is examined, summarizing preliminary results of Phase 2 of the NASA/DOD Aerospace Knowledge Diffusion Research Project (NAKDRP). The design and objectives of NAKDRP are reviewed; the NAKDRP model of STI transfer among producers, STI intermediaries, surrogates (technical report repositories or clearinghouses), and users is explained and illustrated with diagrams; and particular attention is given to the organization and operation of aerospace libraries. In a survey of North American libraries it was found that 25-30 percent of libraries regularly receive technical reports from ESA and the UK; the corresponding figures for Germany and for France, Sweden, and Japan are 18 and 5 percent, respectively. Also included is a series of bar graphs showing the librarians' assessments of the quality and use of NASA Technical Reports.

Pinelli, Thomas E.↗

Mission and system optimization of nuclear electric propulsion vehicles for lunar and Mars missions

The detailed mission and system optimization of low thrust electric propulsion missions is a complex, iterative process involving interaction between orbital mechanics and system performance. Through the use of appropriate approximations, initial system optimization and analysis can be performed for a range of missions. The intent of these calculations is to provide system and mission designers with simple methods to assess system design without requiring access or detailed knowledge of numerical calculus of variations optimizations codes and methods. Approximations for the mission/system optimization of Earth orbital transfer and Mars mission have been derived. Analyses include the variation of thruster efficiency with specific impulse. Optimum specific impulse, payload fraction, and power/payload ratios are calculated. The accuracy of these methods is tested and found to be reasonable for initial scoping studies. Results of optimization for Space Exploration Initiative lunar cargo and Mars missions are presented for a range of power system and thruster options.

Gilland, James H.↗

Scientific issues and potential remote-sensing requirements for plant biochemical content

Application of developments in imaging spectrometry to the study of terrestrial ecosystems, which began in 1983, demonstrate the potential to estimate lignin and nitrogen concentrations of plant canopies by remote-sensing techniques. Estimation of these parameters from the first principles of radiative transfer and the interactions of light with plant materials is not presently possible, principally because of lack of knowledge about internal leaf scattering and specific absorption involving biochemical compounds. From the perspective of remote-sensing instrumentation, sensors are needed to support derivative imaging spectroscopy. Biochemical absorption features tend to occur in functional groupings throughout the 1100- to 2500-nm region. Derivative spectroscopy improves the information associated with the weaker, narrower absorption features of biochemical absorption that are superimposed on the strong absolute variations due to foliar biomass, pigments, and leaf water content of plant canopies. Preliminary sensor specifications call for 8-nm bandwidths at 2-nm centers in four spectral regions (about 400 bands total) and a signal-to-noise performance of at least 1000:1 for 20 percent albedo targets in the 2000-nm region.

Peterson, David L.↗

Towards a Multisensor Approach to Improve on Current TRMM Retrievals of Clouds and Precipitation

The Tropical Rainfall Measuring Mission (TRMM) was designed to measure tropical rainfall and its variation from a low inclination orbiting satellite. The TRMM payload was carefully chosen to overcome a number of limitations of past satellite observing systems. This payload is predicated on the combination of active and passive observations from the TRMM Precipitation Radar (PR) and TRMM Microwave Imager (TMI) and Visible and Infrared Scanner (VIRS). Our research over the past three years has been devoted to the challenge of developing the most effective way of combining complementary information from these sensors to provide the most consistent estimate of precipitation. We have approached this problem from three directions. The first was to carry out preliminary analysis of passive microwave and infrared data from the TMI and VIRS instruments to understand the character of clear and cloudy skies in the basis defined by polarization and brightness temperature differences. Using this information as a foundation, the properties of two retrieval algorithms were analyzed, one for retrieving ice clouds from VIRS that was developed in parallel with this project and the other for rainfall from the TMI. Finally, the knowledge gleaned from each of these studies, coupled with ancillary data from NWP models and a broadband radiative transfer model, was used to create and algorithm for synthesizing the principal components of the Earth's energy budget from the basic building blocks of the atmosphere, gases, clouds, and precipitation. Principal results from each of these areas of research and their role in the TRMM and climate communities are summarized.

Stephens, Graeme L.↗