SEARCH · Engineering Papers

Results for “INFRARED SPECTRA”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 613 records · Page 34

All sources NASA NTRS DOE OSTI

NASA NTRS1974

The hard start phenomena in hypergolic engines. Volume 3: Physical and combustion characteristics of engine residuals

An investigation was conducted to determine the cause of starting problems in the hypergolic rocket engines of the Apollo reaction control (RCS) engines. The scope of the investigation was as follows: (1) to establish that chemical reactions occurred during the preignition and post combustion periods, (2) to identify the chemical species of the products of preignition and post combustion reaction, and (3) to determine the explosive nature of the identified species. The methods used in identifying the chemical products are described species. The infrared spectra, X-ray spectra, and other signatures of the compounds are presented. The physical and explosion characteristics of various hypergolic agents are reported.

Miron, Y.↗

NASA NTRS1975

A practical multi-spectrum Hadamard Transform Spectrometer

A Hadamard Transform Spectrometer (HTS) which simultaneously obtains fifteen infrared spectra, each having 255 spectral elements was constructed. Spectra are obtained essentially in real time through use of a minicomputer with 8K words of memory and a CRT display. This permits operation of the instrument in the field.

Tai, M. H.↗

NASA NTRS1974

Techniques for carrying out radiative transfer calculations for the Martian atmospheric dust

A description is given of the modification of a theory on the reflectance of particulate media so as to apply it to analysis of the infrared spectra obtained by the IRIS instrument on Mariner 9. With the aid of this theory and the optical constants of muscovite mica, quartz, andesite, anorthosite, diopside pyroxenite, and dunite, modeling calculations were made to refine previous estimates of the mineralogical composition of the Martian dust particles. These calculations suggest that a feldspar rich mixture is a very likely composition for the dust particles. The optical constants used for anorthosite and diopside pyroxenite were derived during this program from reflectance measurements. Those for the mica were derived from literature reflectance data. Finally, a computer program was written to invert the measured radiance data so as to obtain the absorption coefficient spectrum which should then be independent of the temperature profile and gaseous component effects.

Aronson, J. R.↗

NASA NTRS1975

The spectral energy distribution of NGC 1275

An analysis of absolute spectral energy distributions of interstellar gas for a galaxy (NGC 1275) is presented. Infrared spectra data shows heavy reddening. It is proposed that the interstellar gas may be ionized by shock waves or by nonthermal or stellar radiation. It is suggested, that high velocity, emission-line knots are H2 regions in a Perseus cluster galaxy or intergalactic gas cloud seen in projection against NGC 1275.

Shields, G. A.↗

NASA NTRS1974

The spectrum of Mars in the region 1800-3200 per cm

During the 1971 opposition of Mars, new infrared spectra covering the region 1800-3200 per cm were taken at a resolution of 0.095 per cm using a Connes'-type Fourier spectrometer on a 2.7 m telescope. No new trace constituents have, as yet, been found in the spectra, but several previously unobserved combination of isotopic bands of CO2 are visible. It has also been found possible to fit fairly well defined kinetic temperatures and Bond albedos to the data. The kinetic temperatures have been determined by a new technique. It is found that the albedo at 33 deg phase, which was determined a few days after the onset of the great dust storm of 1971, was significantly higher than for the clear atmosphere. The explanation for this phenomenon must await detailed radiative transfer calculations for a dust-laden atmosphere.

Beer, R.↗

NASA NTRS1974

Surfaces and interfaces of glass and ceramics; Proceedings of the International Symposium on Special Topics in Ceramics, Alfred University, Alfred, N.Y., August 27-29, 1973

The characterization of surfaces and interfaces is considered along with the infrared spectra of several N-containing compounds absorbed on montmorillonites, applications of surface characterization techniques to glasses, the observation of electronic spectra in glass and ceramic surfaces, a method for determining the preferred orientation of crystallites normal to a surface, and the friction and wear behavior of glasses and ceramics. Attention is given to the wear behavior of cast surface composites, an experimental investigation of the dynamic and thermal characteristics of the ceramic stock removal process, a dynamic elastic model of ceramic stock removal, and the structure and properties of solid surfaces. Individual items are announced in this issue.

Frechette, V. D.↗

NASA NTRS1975

On the presence of phyllosilicate minerals in the interstellar grains

The composition of the interstellar silicate dust is investigated. Condensation or alteration of silicate grains at temperatures of a few hundred degrees, in the presence of H2O, would result in hydrous or phyllosilicates, the silicate type most abundant in the type I carbonaceous chondrites. Infrared spectra of small particles (about 0.1 microns) of the high temperature condensates, olivine and pyroxene, at 300 K and 4 K do not give a good match to the interstellar absorption band near 9.8 microns. Laboratory spectra of several phyllosilicates give better agreement as does the spectrum of a carbonaceous chondrite. We propose that the silicates in the interstellar grains are predominantly phyllosilicates and suggest additional spectral tests for this hypothesis.

Zaikowski, A.↗

NASA NTRS1975

Cyclic octatomic sulfur - A possible infrared and visible chromophore in the clouds of Jupiter

Near-ultraviolet light is known to be an effective agent for the photoproduction of a variety of organic molecules from simulated primitive Earth and contemporary Jovian environments. The study discusses the infrared spectrum of a brown polymeric material produced under simulated Jovian conditions and its comparison with recent high-altitude infrared spectra of Jupiter. It is shown that this polymeric material is composed mainly of cyclic octatomic sulfur, even though a range of complex organic compounds is also present. The polymeric sulfur, produced from the ultraviolet photolysis of hydrogen sulfide, displays its strongest band at 465 reciprocal centimeters. This is in fair agreement with the frequency of the unidentified Jovian absorber recently reported by Houck et al. (1975). Polymeric octatomic sulfur may thus be an important constituent of Jovian clouds.

Khare, B. N.↗

NASA NTRS1975

Far Infrared Spectroscopy of H II Regions

The far infrared spectra of H II regions are investigated. A liquid helium cooled grating spectrometer designed to make observations from the NASA Lear Jet is described along with tests of the instrument. The observing procedure on the Lear Jet telescope is described and the method of data analysis is discussed. Results are presented from a search for the (O III) 88.16 micron line. An upper limit on the emission in this line is obtained and line detection is described. Results are compared to theoretical predictions, and future applications of fine structure line observations are discussed. Coarse resolution results are given along with calibration problems. The spectra obtained are compared to models for dust emission.

Ward, D. B.↗

NASA NTRS1975

The Skylab concentrated atmospheric radiation project

The author has identified the following significant results. Comparison of several existing infrared radiative transfer models under somewhat controlled conditions and with atmospheric observations of Skylab's S191 and S192 radiometers illustrated that the models tend to over-compute atmospheric attenuation in the window region of the atmospheric infrared spectra.

Kuhn, P. M.↗

NASA NTRS1977

Identification of 180 million years old, probably unchanged melanine

The comparison of the infrared spectra of recent sepia melanine and of the content of the ink sac of fossilized cuttlefish indicates that the 180 million years old substance is unchanged melanine. Both substances behave identically on heating. Other procedures for identification of melanine are surveyed critically.

Beyermann, K.↗

NASA NTRS1977

Environmental change pattern in central Japan as revealed by LANDSAT data

The author has identified the following significant results. A patched cirrus reported by weather stations was hardly recognizable by the eye in LANDSAT MSS data of a three year time lapse. The cloud cover affected radiance values significantly in band 4, while its effect was minimal in bands 6 and 7 (near infrared spectra). The cross correlation coefficient analysis between the two images indicated that the highest value obtained in central Japan was 0.963 for the area where little change occurred in land use over the three period. An analysis of land use in Nagoya showed little change in the metropolitan area while a fairly large change occurred in the northern periphery of the city where large scale housing projects are located.

Maruyasu, T.↗

NASA NTRS1976

Infrared characterized spacecraft contaminants and related compounds

Infrared spectra (% transmittance plotted vs wavelength/wavenumber) of a large number of lubricant and sealant oils and greases, insulating tapes, and solvents likely to contaminate the internal or external environment of spacecraft are reproduced. Accompanying introductory remarks characterize the nomenclature and properties or uses of the materials whose spectra are reproduced, and offer information on the techniques and equipment used in taking the spectra.

Gross, F. C.↗

NASA NTRS1977

Observations and interpretation of the infrared spectrum of HD 44179

Infrared spectra of HD 44179 have been obtained for the 3040-, 1150-, and 890-kayser emission features. The strengths of the features put constraints on the possible constituents of the materials responsible for each emission feature. The 3040-kayser feature can be due to emission either from a solid (if it arises from a different region than the 890-kayser feature) or from a gas-phase molecule. The 8-13-micron spectrum is fitted with a simple model employing carbonates plus a dielectric in emission and silicates in absorption. It is suggested that amorphous carbon is the dielectric responsible for the featureless underlying continuum.

Bregman, J. D.↗

NASA NTRS1977

Observation of preplanetary disks around MWC 349 and LKH-alpha 101

Infrared spectra of three highly reddened emission-line objects (MWC 349, MWC 297, and LKH-alpha 101) have been obtained from both aircraft and ground-based observatories. These spectra show bright emission lines which are consistent with recombination in an H II region. Additional optical data for MWC 349 yield a model which consists of a central O6.5 star with circumstellar disk seen face-on, a surrounding H II region, and circumstellar dust. The parameters of the disk are discussed in terms of the viscous dissipation model of Lynden-Bell and Pringle (1974). The observations are in excellent agreement with the predictions of the model and represent the first substantial case for a newly formed star with a preplanetary disk.

Thompson, R. I.↗

NASA NTRS1978

Traction and lubricant film temperature as related to the glass transition temperature and solidification

Does a traction fluid have to be a glass or solid under operating conditions. Infrared spectra on dynamic EHD contacts of several types of fluid were used to determine the surface and oil-film temperatures. Polarized spectral runs were made to study molecular alignment. Static glass transition pressures at appropriate temperatures were between 0.1 and 2.0 GPa, with the traction fluid showing the highest. In the EHD contact region, the traction fluid showed both the highest film temperatures as well as the greatest degree of molecular alignment. A plot of the difference between the film and surface temperatures vs shear rate resulted in a master plot valid for all the fluids. From this work, the authors propose a model of 'fluid' traction, where friction between parallel rough molecules provides the traction.

Lauer, J. L.↗

NASA NTRS1979

ATMOS Spacelab 1 science investigation

Existing infrared spectra from high speed interferometer balloon flights were analyzed and experimental analysis techniques applicable to similar data from the ATMOS experiment (Spacelab 3) were investigated. Specific techniques under investigation included line-by-line simulation of the spectra to aid in the identification of absorbing gases, simultaneous retrieval of pressure and temperature profiles using carefully chosen pairs of CO2 absorption lines, and the use of these pressures and temperatures in the retrieval of gas concentration profiles for many absorbing species. A search for a new absorption features was also carried out, and special attention was given to identification of absorbing gases in spectral bandpass regions to be measured by the halogen occultation experiment.

Park, J. H.↗

NASA NTRS1978

Absorption bands in the spectrum of Io

Near-infrared spectra of Io in the region from 2.8 to 4.2 microns are reported which show distinct absorption features, the most notable at 4.1 microns. Frozen volatiles or atmospheric gases cannot account for these absorptions, nor do they resemble those seen in common silicate rocks. Several candidate substances, most notably nitrate and carbonate salts, show absorption features in this spectral region; the deepest band in the spectrum may be a nitrate absorption. The satellite surface is shown to be anhydrous, as indicated by the absence of the 3-micron bound water band.

Cruikshank, D. P.↗