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At least 613 records · Page 34

All sources NASA NTRS DOE OSTI

NASA NTRS1980

Performance of two-layer thermal barrier systems on directionally solidified Ni-Al-Mo and comparative effects of alloy thermal expansion on system life

A promising two-layer thermal barrier coating system (TBS), Ni-16.4Cr-5.1A1-0.15Y/ZrO2-6.1Y2O3 (all in weight percent), was identified for directionally solidified Ni-Al-Mo (gamma/gamma' alpha). In cyclic furnace tests at 1095 C this system on gamma/gamma' alpha was better than Ni-16. 4Cr-5.1Al-0.15Y/ZrO2-7.8Y2O3 by about 50 percent. In natural gas - oxygen torch rig tests at 1250 C the ZrO2-6.1Y2O3 coating was better than the ZrO2-7.8Y2O3 coating by 95 percent, on MAR-M509 substrates and by 60 percent on gamma/gamma' alpha substrates. Decreasing the coefficient of thermal expansion of the substrate material from 17-18x10 to the -6 power/C (MAR-M200 + Hf and MAR-M509) to 11x10 to the -6 power/C (gamma/gamma' alpha) also resulted in improved TBS life. For example, in natural gas - oxygen torch rig tests at 1250 C, the life of Ni-16.4Cr-5.1Al-0.15Y/ZrO26.1Y2O3 was about 30 percent better on gamma/gamma' alpha than on MAR-M509 substrates. Thus compositional changes in the bond and thermal barrier coatings were shown to have a greater effect on TBS life than does the coefficient of thermal expansion.

Stecura, S.↗

NASA NTRS1980

Improved bond coatings for use with thermal barrier coatings

The potential for improving the durability of thermal barrier coatings (TBC's) being developed for coal derived fuel fired gas turbines was studied. Furnace oxidation behavior of plasma deposited bond coatings was improved by increasing the thickness from 0.010 cm to 0.015 cm and by depositing the coatings at 20 kW with argon 3.5 vol % hydrogen arc gas rather than at 11 kW with argon. The most oxidation resistant plasma deposited bond coatings were Ni-14, 1Cr-13.4Al-0.10Zr, Ni-14.3Cr-14.4Al.0.16Y, and Ni-15.8Cr-12.8Al-0.36Y on B-1900 + Hf and Ni-30.9Cr-11.1Al-0.48Y on MAR-M-509. The oxidation resistant bond coatings improved TBC life when the coatings were deposited on the specimens supported on a nail bed fixture during coating.

Gedwill, M. A.↗

NASA NTRS1979

The erosion/corrosion of small superalloy turbine rotors operating in the effluent of a PFB coal combustor

The operation of a turbine in the effluent of a pressurized fluidized bed (PFB) coal combustor presents serious materials problems. Synergistic erosion/corrosion and deposition/corrosion interactions may favor the growth of erosion-resistant oxides on blade surfaces, but brittle cracking of these oxides may be an important source of damage along heavy particle paths. Integrally cast alloy 713LC and IN792 + Hf superalloy turbine rotors in a single-stage turbine with 6% partial admittance have been operated in the effluent of a PFB coal combustor for up to 164 hr. The rotor erosion pattern exhibits heavy particle separation with severe erosion at the leading edge, pressure side center, and suction side trailing edge at the tip. The erosion distribution pattern gives a spectrum of erosion/oxidation/deposition as a function of blade position. The data suggest that preferential degradation paths may exist even under the targeted lower loadings (less than 20 ppm).

Zellars, G. R.↗

NASA NTRS1980

Noble-gas-rich separates from ordinary chondrites

Acid-resistant residues were prepared by HCl-HF demineralization of three H-type ordinary chondrites: Brownfield 1937 (H3), Dimmitt (H3, 4), and Estacado (H6). These residues were found to contain a large proportion of the planetary-type trapped Ar, Kr, and Xe in the meteorites. The similarity of these acid residues to those from carbonaceous chondrites and LL-type ordinary chondrites suggests that the same phase carries the trapped noble gases in all these diverse meteorite types. Because the H group represents a large fraction of all meteorites, this result indicates that the gas-rich carrier phase is as universal as the trapped noble-gas component itself. When treated with an oxidizing etchant, the acid residues lost almost all their complement of noble gases.

Moniot, R. K.↗

NASA NTRS1980

Polar 5 - An electron accelerator experiment within an aurora. I - Instrumentation and geophysical conditions

A mother-daughter rocket was launched over two auroral structures, which included a 10 keV electron accelerator and a series of diagnostic instruments for monitoring optical and wave effects generated through beam-atmospheric interactions and production of secondary electrons. The instrumentation, the ground and rocket background measurements obtained, and some of the beam effects on various geophysical parameters are presented. Attention is given to the rocket geometry, capacitance probe, particle counters, photometers, and the bremsstrahlung X-ray detector. Observations on the plasma environment, auroral particle precipitation, d.c. electric field, optical emissions, and auroral background HF and VLF emissions are also discussed.

Maehlum, B. N.↗

NASA NTRS1979

Continuous high-power gas lasers

High power gas laser concepts are discussed with emphasis on the role that fluid mechanics has played in their development. Consideration is given to three types of systems: gasdynamic lasers, HF supersonic diffusion lasers, and electric discharge lasers. Flow effects and aerodynamic windows in such lasers are briefly described. Future directions of research are outlined.

Hertzberg, A.↗

NASA NTRS1980

Development of exothermically cast single-crystal Mar-M 247 and derivative alloys

A low-cost, exothermic directional-solidification (DS) process was developed to produce single-crystal (SC) Mar-M 247 high-pressure turbine blades. Stress-rupture data indicated that SC Mar-M 247 provides only marginal improvements in longitudinal strength relative to the columnar grained DS material. Removal of grain boundary strengthening elements (B, C, Zr, Hf) from the Mar-M 247 composition (which are also melting point depressants) permitted the alloy to be solutioned at significantly higher temperatures. An order of magnitude improvement in rupture life relative to SC Mar-M 247 was observed for several derivative alloys at 103.5 MPa (15 KSI) and 1093 C. Rupture lives of the modified SC alloys were significantly affected by both alloy purity and heat treatment. Critical aspects of vacuum induction refining, exothermic casting technology, alloy development and heat treatment, which contributed to this new class of turbine blades, are reviewed

Strangman, T. E.↗

NASA NTRS1980

Radar observations of wave transformations in the vicinity of islands

Remote sensing by ground-based HF radar and airborne synthetic aperture radar and in situ wave measurements performed on March 25, 1977 during the West Coast Experiment have made it possible to form an overall picture of the 7-sec-period wave climate over a 35,000 sq km region off the southern California coast. The picture which emerges from these measurements shows a broad deep-ocean directional distribution arriving from the west and being significantly modified as it travels coastward passing San Clemente and Santa Catalina islands.

Vesecky, J. F.↗

NASA NTRS1979

Low-cost directionally-solidified turbine blades, volume 2

An endothermically heated technology was used to manufacture low cost, directionally solidified, uncooled nickel-alloy blades for the TFE731-3 turbofan engine. The MAR-M 247 and MER-M 100+Hf blades were finish processed through heat treatment, machining, and coating operations prior to 150 hour engine tests consisting of the following sequences: (1) 50 hours of simulated cruise cycling (high fatigue evaluation); (2) 50 hours at the maximum continuous power rating (stress rupture endurance (low cycle fatigue). None of the blades visually showed any detrimental effects from the test. This was verified by post test metallurgical evaluation. The specific fuel consumption was reduced by 2.4% with the uncooled blades.

Dennis, R. E.↗

NASA NTRS1980

Muon spin rotation research program

Data from cyclotron experiments and room temperature studies of dilute iron alloys and iron crystals under strain were analyzed. The Fe(Mo) data indicate that the effect upon the contact hyperfine field in Fe due to the introduction of Mo is considerably less than that expected from pure dilution, and the muon (+) are attracted to the Mo impurity sites. There is a significant change in the interstitial magnetic field with Nb concentration. The Fe(Ti) data, for which precession could clearly be observed early only at 468K and above, show that the Ti impurities are attractive to muon (+), and the magnitude of B(hf) is reduced far beyond the amount expected from pure dilution. Changes in the intersitital magnetic field with the introduction of Cr, W, Ge, and Si are also discussed. When strained to the elastic limit, the interstitial magnetic field in Fe crystals is reduced by 33 gauss, and the relaxation rate of the precession signal increases by 47%.

Stronach, C. E.↗

NASA NTRS1980

Cabin fire simulator lavatory tests

All tests were conducted in the Douglas Cabin Fire Simulator under in-flight ventilation conditions. All tests were allowed to continue for a period of one hour. Data obtained during these tests included: heat flux and temperatures of the lavatory; cabin temperature variations; gas analyses for O2, CO2, CO, HF, HC1, and HCN; respiration and electrocardiogram data on instrumented animal subjects (rats) exposed in the cabin; and color motion pictures. All tests resulted in a survivable cabin condition; however, occupants of the cabin would have been subjected to noxious fumes.

Schutter, K. J.↗

NASA NTRS1980

Internal coating of air-cooled gas turbine blades

Four modified aluminide coatings were developed for IN-792 + Hf alloy using a powder pack method applicable to internal surfaces of air-cooled blades. The coating compositions are Ni-19Al-1Cb, Ni-19Al-3Cb, Ni-17Al-20Cr, and Ni-12Al-20Cr. Cyclic burner rig hot corrosion (900 C) and oxidation (1050 C) tests indicated that Ni-Al-Cb coatings provided better overall resistance than Ni-Al-Cr coatings. Tensile properties of Ni-19Al-1Cb and Ni-12Al-20Cr coated test bars were fully retained at room temperature and 649 C. Stress rupture results exhibited wide scatter around uncoated IN-792 baseline, especially at high stress levels. High cycle fatigue lives of Ni-19Al-1Cb and Ni-12Al-20Cr coated bars (as well as RT-22B coated IN-792) suffered approximately 30 percent decrease at 649 C. Since all test bars were fully heat treated after coating, the effects of coating/processing on IN-792 alloy were not recoverable. Internally coated Ni-19Al-1Cb, Ni-19Al-3Cb, and Ni-12Al-20Cr blades were included in 500-hour endurance engine test and the results were similar to those obtained in burner rig oxidation testing.

Hsu, L. L.↗

NASA NTRS1979

Trends and Techniques for Space Base Electronics

Simulations of various phosphorus and boron diffusions in SOS were completed and a sputtering system, furnaces, and photolithography related equipment were set up. Double layer metal experiments initially utilized wet chemistry techniques. By incorporating ultrasonic etching of the vias, premetal cleaning a modified buffered HF, phosphorus doped vapox, and extended sintering, yields of 98% were obtained using the standard test pattern. A two dimensional modeling program was written for simulating short channel MOSFETs with nonuniform substrate doping. A key simplifying assumption used is that the majority carriers can be represented by a sheet charge at the silicon dioxide silicon interface. Although the program is incomplete, the two dimensional Poisson equation for the potential distribution was achieved. The status of other Z-D MOSFET simulation programs is summarized.

Trotter, J. D.↗

NASA NTRS1980

Development of low-cost directionally-solidified turbine blades

A low-cost directionally solidified (DS) casting of turbine blades of high stress rupture is discussed. The process uses an exothermically heated mold; a newly designed solid blade was cast for the high-pressure turbine of the TFE731-3 turbofan engine. Ni-based alloys Mar-M 247 and Mar-M 200 + Hf were used. The solid DS blade replaced a conventionally cast IN100 component; a 40% cost saving is expected, with a 2.4% reduction in the takeoff specific fuel consumption. The DS Mar-M 247 blade has been selected for production in the TFE731-3B-100, and advanced version of the TFE731-3.

Hoppin, G. S., III↗

NASA NTRS1980

Measurements of the cosmic background radiation

Measurements of the attributes of the 2.7-K microwave background radiation (CBR) are reviewed, with emphasis on the analytic phase of CBR studies. Methods for the direct measurement of the CBR spectrum are discussed; attention is given to receivers, antennas, absolute receiver calibration, atmospheric emission and absorption, the galactic background contribution, the analysis of LF measurements, and recent HF observations of the CBR spectrum. Measurements of the large-angular-scale intensity distribution of the CBR (the most convincing evidence that the radiation is of cosmological origin) are examined, along with limits on the linear polarization of the CBR. A description is given of the NASA-sponsored Cosmic Background Explorer (COBE) satellite mission. The results of the COBE mission will be a set of sky maps showing, in the wave number range from 1 to 10,000 kaysers, the galactic background radiation due to synchrotron emission from galactic cosmic rays, to diffuse thermal emission from H II regions, and to diffuse thermal emission from interstellar and interplanetary dust, as well as a residue consisting of the CBR and whatever other cosmological background might exist.

Weiss, R.↗

NASA NTRS1981

AFGL trace gas compilation - 1980 version

A new edition of the AFGL trace gas compilation is now available. Absorption line parameters of positions, intensities, and half-widths are given for the major bands of thirteen gases covering the spectral region from 0 to 10,000/cm. In addition to updating the original gases (NO, SO2, NO2, and NH3), the molecules HNO3, OH, HF, HCl, HBr, HI, ClO, OCS, and H2CO have been added to the compilation. The sources for the additions and modifications are described.

Rothman, L. S.↗

NASA NTRS1981

Measurement of RF lightning emissions

A lightning radio emission observation laboratory is described. The signals observed and recorded include HF, VHF and UHF radio emissions, optical signature, electric field measurements, and thunder. The objectives of the station, the equipment used, and the recording methods are discussed.

Lott, G. K., Jr.↗

NASA NTRS1982

Cryolite Byproduct in Silicon Production

Process reacts alumina hydrate with HF and NaF from silicon-production process. Cryolite is produced by adding reaction step to process that makes high-purity silicon from fluorosilicic acid. New extended process has been demonstrated in laboratory and could be used in commercial plants.

Bartlett, R. W.↗