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At least 613 records · Page 34

Direct Numerical Simulation of Partial Fuel Stratification Assisted Lean Premixed Combustion for Assessment of Hybrid G-Equation/Well-Stirred Reactor Model

Partial fuel stratification (PFS) is a promising fuel injection strategy to stabilize lean premixed combustion in spark-ignition (SI) engines. PFS creates a locally stratified mixture by injecting a fraction of the fuel, just before spark timing, into the engine cylinder containing homogeneous lean fuel/air mixture. Further, this locally stratified mixture, when ignited, results in complex flame structure and propagation modes similar to partially premixed flames and allows for faster and more stable flame propagation than a homogeneous lean mixture. This study focuses on understanding the detailed flame structures associated with PFS-assisted lean premixed combustion. First, a two-dimensional direct numerical simulation (DNS) is performed using detailed fuel chemistry, experimental pressure trace, and realistic initial conditions mapped from a prior engine large-eddy simulation (LES), replicating practical lean SI operating conditions. DNS results suggest that the conventional triple flame structure is prevalent during the initial stage of flame kernel growth. Both premixed and nonpremixed combustion modes are present with the premixed mode contributing dominantly to the total heat release. Detailed analysis further reveals the effects of flame stretch and fuel pyrolysis on flame displacement speed. Based on the DNS findings, the accuracy of a hybrid G-equation/well-stirred reactor (WSR) combustion model is assessed for the PFS-assisted lean operation in the LES context. It is found that the G-equation model qualitatively captures the premixed branches of the triple flame, while the WSR model predicts the nonpremixed branch of the triple flame. Finally, potential needs for improvements to the hybrid G-equation/WSR modeling approach are discussed.

33 ADVANCED PROPULSION SYSTEMS↗

Opportunities and Challenges for Hydrotreating of Catalytic Fast Pyrolysis Oil to Fuels

Catalytic fast pyrolysis (CFP) provides a versatile platform for producing fuels to combat climate change and meet decarbonizing targets. In this contribution, we will discuss the hydroprocessing of CFP oils to a variety of fuels, including sustainable aviation fuel (SAF), diesel, and marine fuel. Both standalone and co-hydroprocessing with petroleum streams will be covered. Hydrotreating CFP oil at temperatures around 400 Degrees Celsius can produce a highly deoxygenated product with oxygen contents below the detection limit. However, the quality of fuel fractions produced has been a problem, manifesting as low octane numbers for the gasoline-range fraction and low cetane numbers for the diesel-range fraction. Incorporating an initial transition zone for hydrogenation during hydrotreating was shown to dramatically increase the diesel fraction cetane number from 24 to 45. A similar approach enabled the production of a cycloalkane-rich SAF fraction meeting key ASTM 4054 guidelines with respect to density, viscosity, heating value, volatility, freeze and flash point. Over 400 hours of hydrotreating for SAF was demonstrated with no signs of catalyst bed fouling, measured by pressure drop over the catalyst bed. Compared to other fuels, marine fuel is unique in that it does not require complete deoxygenation. We investigated the minimum hydrotreating requirements to produce fuel compatible with very low sulfur fuel oil, and the results suggested 30% reduction in hydrotreating costs for this approach. Co-hydroprocessing offers an opportunity to take advantage of refinery infrastructure and economies of scale although the operation is less flexible with respect to operating conditions. Co-hydroprocessing CFP oil with petroleum streams gave efficient deoxygenation at milder conditions (e.g. at temperatures of 320 Degrees Celsius) than required for standalone hydrotreating. Over 90% incorporation of biogenic carbon in the CFP oil was confirmed by carbon-14 analysis. Hydrotreating of CFP oil, whether by standalone or co-processing, can produce a variety of fuel cuts, whose quality can be tailored by changing process conditions. Challenges remain, including long-term catalyst performance and determining CFP oil quality requirements.

09 BIOMASS FUELS↗

Hydrotreating pine-derived catalytic fast pyrolysis oil to jet fuel: Process durability and impact of operating conditions

Hydrotreating woody biomass-derived catalytic fast pyrolysis (CFP) oil to jet fuel has the potential to enhance energy security due to the large abundance of forest and woody resources. CFP oil produced from pine over ZSM-5 was hydrotreated over sulfided NiMo/Al 2 O 3 for 410 h to study the impact of hydrotreating conditions (pressure, temperature, and weight hourly space velocity (WHSV)). The degree of deoxygenation remained high across the tested hydrotreating conditions, and the products contained < 0.01 wt% oxygen. Increasing hydrotreating pressure from 84 to 125 bar enhanced hydrogenation of aromatic rings and the formation of cycloalkanes and increasing the temperature from 385 to 400 degrees C enhanced cracking and the formation of jet-range molecules. Decreasing the weight hourly space velocity from 0.2 to 0.1 g/(g cat h) further enhanced cracking and led to higher gasoline- and lower jet fuel-range fractions. The highest jet fuel fraction (49 wt%) was obtained at 400 degrees C, 125 bar, 0.2 g/(g cat h) WHSV. CFP oils produced from pine over phosphorous-modified ZSM-5 were hydrotreated at this condition for 588 h to investigate the process durability. The hydrogenation performance of the catalyst gradually stabilized in approximately 300 h after which the product composition remained constant. Of the final hydrotreated CFP oil, 53 wt% fell in the jet fuel range with most of the tested fuel properties meeting ASTM D4054 and/or ASTM D7566 specifications. The freeze points were < -50 degrees C vs. guideline of < -40 degrees C and the viscosities at -20 degrees C were 3.8-4.1 mm 2 /s vs guideline of 8 mm 2 /s. Increasing the fraction of cycloalkanes could increase the cetane number and heating value, which did not meet the guidelines.

09 BIOMASS FUELS↗

Field-Emission Properties of Vertically Aligned Carbon Nanotube Cathodes of Varying Geometries

This work characterizes the bulk emission properties of carbon nanotube (CNT) forest cathodes fabricated with various geometries. Geometries explored include dense nanotube forests of varying height grown on 5×5 mm silicon (Si) substrates and discrete, patterned CNT pillars fabricated using UV photolithography. Dense forests heights ranged from 526 μ m to 1.41 mm, with packing fraction for dense forest calculated to be 4e10 nanotubes/cm2 based on an average nanotube separation distance of 100 nm for fixed growth dense forests. Patterned sample micro pillar heights ranged from 47 to 393 μ m with pillar widths on tested samples ranging from 250 to 270 μ m . Properties explored include emission current, turn-on field, and emission current performance over time. A parallel plate electron beam diode with a 100- μ m A-K gap and an automated test apparatus were developed to provide a configurable experiment that provides accurate and repeatable measurements for dc, dc sweep, and timed performance testing. Operating voltages for the voltage sweeps spanned from 0 to −350 V. Furthermore, testing has shown evidence of a hysteresis effect on the emission current tied to the applied field history as well as shifting of the turn-on field magnitude throughout the testing period, suggesting a conditioning effect during use. Three separate emission regions in the I–V curves during sweep testing have also been observed. In the geometric study, dense forests and patterned samples were sweep tested up to a peak applied voltage of −250 V, with the taller samples generally performing better. Currents produced in the geometric study from the dense forest emitters ranged from 36.8 to 572.34 μ A , with current densities ranging from 15 to 2.29 mA/cm2. Currents produced from the patterned micropillar emitters ranged from 39.4 to 317.51 μ A , with current densities ranging from 67 to 3 mA/cm2. DC time testing s...

36 MATERIALS SCIENCE↗

Approach to Startup Inventory for Viable Commercial Power Plant

Summary • FPP realization within the next 10-15 years will require dedicated efforts to improve DIR, burn fraction, fueling efficiency, and/or processing times. • Modest improvements from either the fuel cycle side or plasma physics side should be possible with considered allocation of R&D funding. • Current gaps in particular include blanket extraction at scale, improved efficiency in isotope separation and detritiation, and maximizing DIR efficiency. • Total costs for FPP construction and commissioning depend heavily on site regulation, so decreases in required SI and OI can lead to large decreases in capital outlay. • Some subsystems in the fuel cycle are required from a environmental management perspective but are both energetically expensive and time consuming, particularly water detritiation. • Low inventories but high capital and operational costs mean a centralized water detritiation plant could greatly improve likelihood of deployment of multiple FPPs on the same time scale.

MALONE, COLLIN↗

Auxiliary heating and current drive physics for the ST-E1 fusion power plant

This work describes the physics basis for the proposed auxiliary heating and current drive system on the ST-E1 fusion power plant. The ST-E1 flattop plasma considered here is fully non-inductive with a bootstrap fraction of 0.9 and the remaining current driven by EC waves. Using the recently published physics-based optimization method for EC launchers (Lopez et al 2025 Plasma Phys. Control. Fusion 67 055012), we show that the target flattop ECCD can be achieved with a net efficiency of 52 kA MW −1 using fundamental O-mode (O1) with frequency range 160–200 GHz launched from the low-field side top half of the vacuum vessel (LFS top-launch). From considering two candidate rampup scenarios, we conclude that LFS top-launch O1 ECCD can be equally effective during the early stages of plasma operation, although poloidal steering might be needed. X-mode waves injected from the LFS midplane are also shown to be effective for rampup even when T e < 1 keV. We also present modeling results for the pre-conceptual design of an ICRH system proposed for ST-E1. Using TORIC, we find that an ICRH system aiming for 42–48 MHz and toroidal mode number n φ ~ 10 robustly achieves dominant ion damping via Helium-3 minority heating transitioning to second-harmonic Tritium heating. We then show that such waves can be efficiently generated by a 5-strap traveling-wave antenna (TWA) using the Petra-M code. The TWA has a 40–45 MHz passband within which ~60% of the power entering the TWA is coupled to the plasma with the remaining ~40% of the power being transmitted through the TWA and possibly recirculated; the power reflected back into the transmission lines is negligible. This passband structure persists even when the evanescent distance is increased by a factor of two, or when the magnetic-field angle is increased by 30°, demonstrating inherent load resilience that will be crucial for effective ICRH on ST-E1.

electron cyclotron↗

Summertime Continental Shallow Cumulus Cloud Detection Using GOES-16 Satellite and Ground-Based Stereo Cameras at the DOE ARM Southern Great Plains Site

Summertime continental shallow cumulus clouds (ShCu) are detected using Geostationary Operational Environmental Satellite (GOES)-16 reflectance data, with cross-validation by observations from ground-based stereo cameras at the Department of Energy Atmospheric Radiation Measurement Southern Great Plains site. A ShCu cloudy pixel is identified when the GOES reflectance exceeds the clear-sky surface reflectance by a reflectance detection threshold of ShCu, ΔR. We firstly construct diurnally varying clear-sky surface reflectance maps and then estimate the ΔR. A GOES simulator is designed, projecting the clouds reconstructed by stereo cameras towards the surface along the satellite’s slanted viewing direction. The dynamic ShCu detection threshold ΔR is determined by making the GOES cloud fraction (CF) equal to the CF from the GOES simulator. Although there are temporal variabilities in ΔR, cloud fractions and cloud size distributions can be well reproduced using a constant ΔR value of 0.045. The method presented in this study enables daytime ShCu detection, which is usually falsely reported as clear sky in the GOES-16 cloud mask data product. Using this method, a new ShCu dataset can be generated to bridge the observational gap in detecting ShCu, which may transition into deep precipitating clouds, and to facilitate further studies on ShCu development over heterogenous land surface.

54 ENVIRONMENTAL SCIENCES↗

Cutting the Deployment Costs of Physics-Based MPC in Buildings by Simulation-Based Imitation Learning

It has been shown that model predictive control (MPC) is a promising solution for energy-efficient building operations. However, the deployment of MPC in a large portion of the building stock has not been possible partially because of high installation costs. Every building is unique and requires a tailored MPC solution. The best performing solutions are often based on physics-based modeling, which is, however, computationally expensive and requires dedicated software. A promising direction that tackles this problem is to train a neural network-based optimal control policy to imitate the behavior of physics-based MPC from the simulation data generated offline. The neural networks give control actions that closely approximate those produced by physics-based MPC, but with a fraction of the computational and memory requirements and without the need for licensed software. The main advantage of the proposed approach stems from simple evaluation at execution time, leading to low computational footprints and easy deployment on embedded HW platforms. In the case study, we present the energy savings potential of physics-based MPC applied to an office building in Belgium. We demonstrate how neural network approximators can be used to cut the implementation and maintenance costs of MPC deployment without compromising performance. We also critically assess the presented approach by pointing out the remaining challenges and open research questions.

Drgona, Jan↗

The South Pole Telescope AGN Monitoring Campaign: First Release of SPTpol Bright AGN Light Curves

The South Pole Telescope (SPT) collaboration has recently embarked upon a campaign to monitor the brightness of a sample of active galactic nuclei (AGN), both in real time and in archival SPT data. The original design of the SPT was optimized for observations of the cosmic microwave background (CMB) at arc-minute and larger angular scales, and it has been used for this purpose for nearly twenty years, using three generations of CMB cameras. Recently it has been recognized that data from CMB experiments have the potential to be used for AGN monitoring. In this paper, we present the first public release of data from a full sample of SPT-monitored AGN, comprising 158 AGN light curves and associated data from the SPTpol camera, which was operational from 2012-2016. These light curves were created using observations from the SPTpol 500 deg$^{2}$ survey, in which the instrument was used to scan a 500 deg$^2$ patch of the sky several times per day with detectors sensitive to radiation in bands centered at 90 and 150 GHz. We provide a comprehensive description of the observations, the data processing methods, and the resulting light curve catalog. As an example of analyses that these data enable, we searched for a correlation between variability and spectral index, and we looked for ``bluer-when-brighter'' trends in the sample. Our analysis finds $> 10 σ$ correlation between fractional intrinsic variance and mean spectral index in the sample, but no significant evidence for bluer-when-brighter trends. The datasets from this study can be accessed through the SPT Treasury Record of AGN With Historical Activity and Time-Series or STRAWHAT catalog. This initial data release includes SPTpol light curves at 90 and 150 GHz, focusing on total intensity. In later updates, SPTpol polarization data and new observations from the SPT-3G instrument at 90, 150, and 220 GHz will be included.

Hood, J.C., II [Chicago U., KICP; Chicago U., Astr↗

Study of e+e- → γΦJ/ψ from $\sqrt{s}$ = 4.600 to 4.951 GeV

Using data samples with an integrated luminosity of 6.4 fb -1 collected by the BESIII detector operating at the BEPCII storage ring, the process of e+e- → γΦJ/ψ is studied. The processes of e + e - → Φχc1,c2, χc1,c2 → γJ/ψ are observed with a significance of more than 10σ. The √s-dependent cross section of e + e - → Φχc1,c2 is measured between 4.600 and 4.951 GeV, and evidence of a resonance structure is found for the first time in the Φχc2 process. We also search for the processes of e + e - → γX(4140), γX(4274) and γX(4500) via the γΦJ/ψ final state, but no obvious structures are found. The upper limits on the production cross section times the branching fraction for these processes at the 90% confidence level are reported.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Building Model Calibration: Validation of GridLAB-D Thermal Dynamics Modeling

This report investigates how well GridLAB-D’s house model characterizes the thermal dynamics of buildings given the overpredicted diurnal electric load swing observed in the Distribution System Operation with Transactive (DSO+T) study. This study seeks to validate GridLAB-D’s house model by calibrating it to data from the well-instrumented Pacific Northwest National Laboratory Lab Homes in Richland, WA. The datasets chosen included multiple pre-cooling and pre-heating testing periods where the indoor air temperature was allowed to float over a multi-hour length of time to mimic diurnal behavior. The multi-season calibrations were evaluated by comparing the heating/cooling electric power, indoor air temperature, and the rise/decay time during temperature float periods with Lab Homes data. The default GridLAB-D assumptions for latent load fraction, air heat capacity, mass heat capacity, window-to-wall-ratio, overall envelope conductance (assumed as NORMAL thermal integrity level), and solar heat gain coefficient were compared with the calibrated model to confirm when the default assumptions were adequate and the impact of calibration on the accuracy of modeling the thermal dynamics of homes.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Toward Trustworthy Autonomous Science: A Two-Year Community Roadmap

One year ago, the AISLE roadmap argued that autonomous laboratories operated as isolated islands and proposed a grassroots network organized around five critical dimensions. The field has since moved faster than that roadmap anticipated: multi-agent systems have produced experimentally validated hypotheses, self-driving laboratories have grown more interoperable and orchestrated, reasoning-trained and domain foundation models have raised the capability ceiling, and the Genesis Mission has placed autonomous experimentation at the center of U.S. federal science strategy, with industry emerging as a primary actor. Progress has met a sobering counter-current, including a corrected flagship discovery result, benchmarks showing that agents which rival experts on closed-ended questions still complete only a fraction of open-ended research, and fabricated citations surfacing at leading venues. We read this as the defining tension of the field: producing a candidate discovery is no longer the hard part, but verifying it is, and this asymmetry now limits autonomous science more than raw model capability. Accordingly, we update the roadmap around seven dimensions, revisiting the original five and elevating two former cross-cutting concerns, trust, verification, and reproducibility, and safety, security, and governance, to first-class status. We assess the original milestones (M1 through M14) as achieved, partially achieved, reframed, or open, add four new milestones (M15 through M18) for the elevated dimensions, and scope the path forward to a two-year horizon, with the first year concentrating on interfaces, protocol adoption, and the scaffolding of verification, and the second targeting federation, zero-trust coordination, and governance. Throughout, we position the grassroots network as the interoperability fabric that lets national programs, international initiatives, and commercial platforms connect rather than re-silo.

99 GENERAL AND MISCELLANEOUS↗

Spinel Cu–Mn–Cr Oxide Nanoparticle-Pigmented Solar Selective Coatings Maintaining >94% Efficiency at 750 °C

High-temperature concentrating solar power (CSP) system is capable of harvesting and storing solar energy as heat towards cost-effective dispatchable solar electricity. Solar selective coating is a critical component to boost its efficiency by maximizing solar absorptance and minimizing thermal emittance losses. However, maintaining a high solar-thermal conversion efficiency >90% for long-term operation at ≥750 ºC remains a significant challenge. Herein, we report spray-coated spinel Cu-Mn-Cr oxide nanoparticle-pigmented solar selective coatings on Inconel tube sections maintaining ≥94% efficiency at 750 ºC and ≥92.5% at 800 ºC under 1000x solar concentration after 60 simulated day-night thermal cycles in air, each cycle comprising 12h at 750 ºC/800 ºC and 12h cooling to 25 ºC. The solar spectral selectivity is intrinsic to the band-to-band and d-d transitions of non-stoichiometric spinel Cu-Mn-Cr oxide nanoparticles. Furthermore, this feature offers a large fabrication tolerance in nanoparticle volume fraction and coating thickness, facilitating low-cost and scalable spray-coated high-efficiency solar selective absorbers for high-temperature CSP systems.

14 SOLAR ENERGY↗

Learning to identify semi-visible jets

We train a network to identify jets with fractional dark decay (semi-visible jets) using the pattern of their low-level jet constituents, and explore the nature of the information used by the network by mapping it to a space of jet substructure observables. Semi-visible jets arise from dark matter particles which decay into a mixture of dark sector (invisible) and Standard Model (visible) particles. Such objects are challenging to identify due to the complex nature of jets and the alignment of the momentum imbalance from the dark particles with the jet axis, but such jets do not yet benefit from the construction of dedicated theoretically-motivated jet substructure observables. A deep network operating on jet constituents is used as a probe of the available information and indicates that classification power not captured by current high-level observables arises primarily from low-p T jet constituents.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Reduction of Porosity in Cementitious Waste Forms to Reduce Effective Diffusivity

Although current practices meet regulations for grout waste forms, development of sequestration materials and techniques for contaminants of concern could expand the use of grout waste forms and reduce risk to established processes from future compositional changes. There are contaminants in waste streams that are not permanently and completely sequestered in current grout waste forms under certain conditions. These contaminants include methyl mercury, 129 I, 99 Tc, and nitrate. Each of these species have minor fractions that are not permanently and completely isolated from the environment and therefore potentially contribute to long-term environmental impacts. An approach of interest includes the technique of reducing porosity to result in reduced leachability of all contaminants simultaneously. The current Savannah River Site (SRS) saltstone formulation was used to evaluate the relationship between leachability and porosity reduced waste forms by altering the water-to-binder ratio. Results indicated decreasing the water-to-binder directly reduced porosity and resulted in the waste form’s ability to more effectively immobilize nitrate. This work was funded by the Department of Energy Office of Environmental Management (DOE-EM) Technology Operations Office (TOO) Project # HQ221818.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The Effect of Spark-Plug Heat Dispersal Range and Exhaust Valve Opening Timing on Cold-Start Emissions and Cycle-to-Cycle Variability

The partnership for advancing combustion engines (PACE) is a US Department of Energy consortium involving multiple national laboratories and includes a goal of addressing key efficiency and emission barriers in light-duty engines fueled with a market-representative E10 gasoline. A major pillar of the initiative is the generation of detailed experimental data and modeling capabilities to understand and predict cold-start behavior. Cold-start, as defined by the time between first engine crank and three-way catalyst light-off, is responsible for a large percentage of NOx, unburned hydrocarbon and particulate matter emissions in light-duty engines. Minimizing emissions during cold-start is a trade-off between achieving faster light-off of the three-way catalyst and engine out emissions during that period. In this study, gaseous and soot emissions were measured at a distance representative of the three-way catalyst position downstream of the engine at a 2 bar net indicated mean effective pressure (NIMEP) steady-state operating condition representative of cold-start. The test matrix included sweeps of ignition timing 15 degrees-before to 10 degrees-after top dead center firing (TDCf) across three different spark-plug heat dispersal ranges (HR). Additionally, the effect of varying exhaust valve opening (EVO) timing on combustion stability and emissions was also studied. Results show that the spark plug HR affects the coefficient of variation (COV) of NIMEP under all cold-start conditions, while the impact on emissions was found to be minimal. At very retarded spark timings, colder spark plugs required higher air and fuel flow to maintain the desired 2bar NIMEP load, but the fraction of fuel energy going into the exhaust was found to be similar for all spark plugs. Finally, retarding exhaust valve timings showed a simultaneous reduction in emissions while increasing the fraction of fuel energy being fed into the exhaust. However, engine COV was also observed to increase with retarded exhaust timings.

42 ENGINEERING↗

A control oriented comprehensive degradation model for battery energy storage system life prediction

In order to ensure that stationary battery energy storage systems (BESSs) provide reliable energy buffering, both for power quality and economic purposes, the degradation must be considered. Cell degradation involves various side reactions and is highly dependent on its operating conditions. To accurately track cell degradation and predict its impact on battery behavior, a comprehensive physics-based degradation model based on an electrolyte phase-enhanced single particle (SP) model is developed. Key degradation physics, namely solid electrolyte interphase (SEI) layer formation and growth, Li plating on the graphite anode, and Mn dissolution on cathode of nickel-cobalt-manganese oxide (NMC622) are considered. The model is validated against experimental capacity data. The results reveal that the deposition rate of both SEI layer and Li metal increase as the charge voltage increases. At the cathode side, the solvent oxidation rate determines the Mn dissolution rate. As a result, the volume fraction of NMC622 in the cathode continually decreases at a gradually increasing rate.

25 ENERGY STORAGE↗

Observation of the Y(4230) and a new structure in ${\boldsymbol e^+\boldsymbol e^- \boldsymbol\rightarrow \boldsymbol K^+\boldsymbol K^-\boldsymbol J/\boldsymbol\psi}$

The cross sections of $e^+e^- \rightarrow K^+K^-J/\psi$ at center-of-mass energies from 4.127 to 4.600 GeV are measured based on 15.6 fb -1 data collected with the BESIII detector operating at the BEPCII storage ring. Two resonant structures are observed in the line shape of the cross sections. The mass and width of the first structure are measured to be ($4225.3\pm2.3\pm21.5$) MeV and ($72.9\pm6.1\pm30.8$) MeV, respectively. They are consistent with those of the established $Y(4230)$. The second structure is observed for the first time with a statistical significance greater than 8σ, denoted as $Y(4500)$. Its mass and width are determined to be ($4484.7\pm13.3\pm24.1$) MeV and ($111.1\pm30.1\pm15.2$) MeV, respectively. The first presented uncertainties are statistical and the second ones are systematic. The product of the electronic partial width with the decay branching fraction $\Gamma(Y(4230)\to e^+ e^-) \mathcal{B}(Y(4230) \to K^+ K^- J/\psi)$ is reported.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗