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At least 613 records · Page 34

The biostratigraphy and paleogeography of Maastrichtian inoceramids

The global distribution of Maastrichtian inoceramids is now known in enough detail that the patterns of disappearance can be used to place first-order constraints on paleoceanographic changes that may have occurred during that age. The Inoceramidae is an excellent group to focus on in a study of Maastrichtian events for the following reasons: (1) they were globally distributed in the early Maastrichtian; (2) they did not survive the age (i.e., they undergo change during the interval); and (3) they have left a rich microfossil and macrofossil record. Some inoceramids grew to be very large; however, even the largest often passively disaggregated and are preserved as hundreds of millions of characteristic, columnar, polygonal prisms of calcite approximately 100 microns across. This taphonomic process has greatly increased the inoceramid fossil record and provides a means of objectively estimating changes in their standing population. In addition, because these prisms commonly occur in Deep Sea Drilling Project (DSDP) and Ocean Drilling Program (ODP) cores, it is relatively easy to generate a truly global database. The existing macrofossil record of inoceramids has less temporal and spacial resolution but greater taxonomic resolution than the microfossil record. In concert the microfossil and macrofossil records of inoceramids demonstrate that important changes occurred during the Maastrichtian. These changes are distinct from the KT boundary catastrophe but are part of the larger KT transition.

Macleod, K. G.↗

Ocean-atmospheric linkages

This chapter focuses on the role of the ocean in the global carbon cycle on the time scale of decades to centuries. The input rate of CO2 to the atmosphere due to fossil fuel burning and deforestation has continued to increase over the last century. To balance the global carbon budget, a sink is required whose magnitude is changing on similar time scales. We have sought to identify aspects of the ocean system that are capable of responding on decadal time scales, to examine our present ability to model such changes, and to pinpoint ways in which this ability could be improved. Many other important aspects of the ocean's role in global change are not addressed, including the importance of oceanic heat transport and thermal inertia to the climate system, biogeochemical cycling of elements other than carbon, and the importance of the ocean as a source or sink of trace gases.

Rintoul, Stephen R.↗

Insight to Global Change: EOS/SAR Mission

This video presentation describes the methods and instrumentation used to help in determining future climate changes on Earth and explains the benefits of experimentation with synthetic aperture radar (SAR). It also gives a better understanding of the burning of fossil fuels, deterioration of the biosphere and deforestation of the rain forest which causes the greenhouse effect.

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Interstellar grains in primitive meteorites - Diamond, silicon carbide, and graphite

Primitive meteorites contain a few parts per million (ppm) of pristine interstellar grains that provide information on nuclear and chemical processes in stars. Their interstellar origin is proven by highly anomalous isotopic ratios, varying more than 1000-fold for elements such as C and N. Most grains isolated thus far are stable only under highly reducing conditions (C/O greater than 1), and apparently are 'stardust' formed in stellar atmospheres. Microdiamonds, of median size about 10 A, are most abundant (about 400-1800 ppm) but least understood. They contain anomalous noble gases including Xe-HL, which shows the signature of the r- and p-processes. Silicon carbide, of grain size 0.2-10 microns and abundance about 6 ppm, shows the signature of the s-process and apparently comes mainly from red giant carbon (AGB) stars of 1-3 solar masses. Some grains appear to be not less than 10 exp 9 a older than the solar system. Graphite spherules of grain size 0.8-7 microns and abundance less than 2 ppm contain highly anomalous C and noble gases, as well as large amounts of fossil Mg-26 from the decay of extinct Al-26. They seem to come from at least three sources, probably AGB stars, novae, and Wolf-Rayet stars.

Anders, Edward↗

Sources and distribution of NO(x) in the upper troposphere at northern midlatitudes

A simple quasi 2-D model is used to study the zonal distribution of NO(x). The model includes vertical transport in form of eddy diffusion and deep convection, zonal transport by a vertically uniform wind, and a simplified chemistry of NO, NO2 and HNO3. The NO(x) sources considered are surface emissions (mostly from the combustion of fossil fuel), lightning, aircraft emissions, and downward transport from the stratosphere. The model is applied to the latitude band of 40 deg N to 50 deg N during the month of June; the contributions to the zonal NO(x) distribution from the individual sources and transport processes are investigated. The model predicted NO(x) concentration in the upper troposphere is dominated by air lofted from the polluted planetary boundary layer over the large industrial areas of Eastern North America and Europe. Aircraft emissions are also important and contribute on average 30 percent. Stratospheric input is minor about 10 percent, less even than that by lightning. The model provides a clear indication of intercontinental transport of NO(x) and HNO3 in the upper troposphere. Comparison of the modelled NO profiles over the Western Atlantic with those measured during STRATOZ 3 in 1984 shows good agreement at all altitudes.

Rohrer, Franz↗

Our Mission to Planet Earth: A guide to teaching Earth system science

Volcanic eruptions, hurricanes, floods, and El Nino are naturally occurring events over which humans have no control. But can human activities cause additional environmental change? Can scientists predict the global impacts of increased levels of pollutants in the atmosphere? Will the planet warm because increased levels of greenhouse gases, produced by the burning of fossil fuels, trap heat and prevent it from being radiated back into space? Will the polar ice cap melt, causing massive coastal flooding? Have humans initiated wholesale climatic change? These are difficult questions, with grave implications. Predicting global change and understanding the relationships among earth's components have increased in priority for the nation. The National Aeronautics and Space Administration (NASA), along with many other government agencies, has initiated long-term studies of earth's atmosphere, oceans, and land masses using observations from satellite, balloon, and aircraft-borne instruments. NASA calls its research program Mission to Planet Earth. Because NASA can place scientific instruments far above earth's surface, the program allows scientists to explore earth's components and their interactions on a global scale.

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Absolute proper motions to B approximately 22.5: Evidence for kimematical substructure in halo field stars

Radial velocities have been obtained for six of nine stars identified on the basis of similar distances and common, extreme transverse velocities in the proper motion survey of Majewski (1992) as a candidate halo moving group at the north Galactic pole. These radial velocities correspond to velocities perpendicular to the Galactic plane which span the range -48 +/- 21 to -128 +/- 9 km/sec (but a smaller range, -48 +/- 21 to -86 +/- 19 km/sec, when only our own measurements are considered), significantly different than the expected distribution, with mean 0 km/sec, for a random sample of either halo or thick disk stars. The probability of picking such a set of radial velocities at random is less than 1%. Thus the radial velocity data support the hypothesis that these stars constitute part of a halo moving group or star stream at a distance of approximately 4-5 kpc above the Galactic plane. If real, this moving group is evidence for halo phase space substructure which may be the fossil remains of a destroyed globular cluster, Galactic satellite, or Searle & Zinn (1978) 'fragment.'

Majewski, Steven R.↗

Exobiological exploration of Mars

Of all the other planets in the solar system, Mars remains the most promising for further elucidating concepts about chemical evolution and the origin of life. Strategies were developed to pursue three exobiological objectives for Mars exploration: determining the abundance and distribution of the biogenic elements and organic compounds, detecting evidence of an ancient biota on Mars, and determining whether indigenous organisms exist anywhere on the planet. The three strategies are quite similar and, in fact, share the same sequence of phases. In the first phase, each requires global reconnaissance and remote sensing by orbiters to select sites of interest for detailed in situ analyses. In the second phase, lander missions are conducted to characterize the chemical and physical properties of the selected sites. The third phase involves conducting 'critical' experiments at sites whose properties make them particularly attractive for exobiology. These critical experiments would include, for example, identification of organics, detection of fossils, and detection of extant life. The fourth phase is the detailed analysis of samples returned from these sites in Earth-based laboratories to confirm and extend previous discoveries. Finally, in the fifth phase, human exploration is needed to establish the geological settings for the earlier findings or to discover and explore sites that are not accessible to robotic spacecraft.

Klein, H. P.↗

Site selection for Mars exobiology

The selection of sites on Mars that have a high priority for exobiological research is fundamental for planning future exploration. The most immediate need is to identify targets for high resolution orbital imaging during the Mars Observer and Mars '94/'96 missions that can be used to refined site priorities for surface exploration. We present an objective approach to site selection whereby individual sites are selected and scored, based on the presence of key geological features which indicate high priority environments. Prime sites are those that show evidence for the prolonged activity of liquid water and which have sedimentary deposits that are likely to have accumulated in environments favorable for life. High priority areas include fluvio-lacustrine (stream-fed lake systems), springs, and periglacial environments. Sites where mineralization may have occurred in the presence of organisms (e.g. springs) are given high priority in the search for a fossil record on Mars. A systematic review of Viking data for 83 sites in the Mars Landing Site Catalog (MLSC) resulted in the selection of 13 as being of exobiological interest. The descriptions of these sites were expanded to address exobiological concerns. An additional five sites were identified for inclusion in the second edition of the MLSC. We plan to broaden our site selection activities to include a systematic global reconnaissance of Mars using Viking data, and will continue to refine site priorities for exobiological research based on data from future missions in order to define strategies for surface exploration.

Farmer, J.↗

Applicability of PM3 to transphosphorylation reaction path: Toward designing a minimal ribozyme

A growing body of evidence shows that RNA can catalyze many of the reactions necessary both for replication of genetic material and the possible transition into the modern protein-based world. However, contemporary ribozymes are too large to have self-assembled from a prebiotic oligonucleotide pool. Still, it is likely that the major features of the earliest ribozymes have been preserved as molecular fossils in the catalytic RNA of today. Therefore, the search for a minimal ribozyme has been aimed at finding the necessary structural features of a modern ribozyme (Beaudry and Joyce, 1990). Both a three-dimensional model and quantum chemical calculations are required to quantitatively determine the effects of structural features of the ribozyme on the reaction it catalyzes. Using this model, quantum chemical calculations must be performed to determine quantitatively the effects of structural features on catalysis. Previous studies of the reaction path have been conducted at the ab initio level, but these methods are limited to small models due to enormous computational requirements. Semiempirical methods have been applied to large systems in the past; however, the accuracy of these methods depends largely on a simple model of the ribozyme-catalyzed reaction, or hydrolysis of phosphoric acid. We find that the results are qualitatively similar to ab initio results using large basis sets. Therefore, PM3 is suitable for studying the reaction path of the ribozyme-catalyzed reaction.

Manchester, John I.↗

X-ray investigations of the hot ISM

At energies less than one keV, the intensity of the galactic x-ray background dominates that of the extragalactic background in almost every direction on the sky. Below 1/4 keV, the galactic x-ray background has a galactic stellar component, but the dominant emitter seems to be hot interstellar matter. The origin of the general 3/4 keV x-ray background remains uncertain, but one component must also be the contribution from hot interstellar matter. An overview is given of recent x-ray investigations of the hot interstellar medium using data from the ROSAT X-ray Telescope/Position-Sensitive Proportional Counter (XRT/PSPC) instrument. Several prominent features in the low energy x-ray background that are interpreted as fossil supernova remnants are discussed.

Sanders, W. T.↗

Scaling craters in carbonates: Electron paramagnetic resonance analysis of shock damage

Carbonate samples from the 8.9-Mt nuclear (near-surface explosion) crater, OAK, and a terrestrial impact crater, Meteor Crater, were analyzed for shock damage using electron paramagnetic resonance (EPR). Samples from below the OAK apparent crater floor were obtained from six boreholes, as well as ejecta recovered from the crater floor. The degree of shock damage in the carbonate material was assessed by comparing the sample spectra to the spectra of Solenhofen and Kaibab limestone, which had been skocked to known pressures. Analysis of the OAK Crater borehole samples has identified a thin zone of allocthonous highly shocked (10-13 GPa) carbonate material underneath the apparent crater floor. This approx. 5- to 15-m-thick zone occurs at a maximum depth of approx. 125 m below current seafloor at the borehole, sited at the initial position of the OAK explosive, and decreases in depth towards the apparent crater edge. Because this zone of allocthonous shocked rock delineates deformed rock below, and a breccia of mobilized sand and collapse debris above, it appears to outline the transient crater. The transient crater volume inferred in this way is found to by 3.2 +/- 0.2 times 10(exp 6)cu m, which is in good agreement with a volume of 5.3 times 10(exp 6)cu m inferred from gravity scaling of laboratory experiments. A layer of highly shocked material is also found near the surface outside the crater. The latter material could represent a fallout ejecta layer. The ejecta boulders recovered from the present crater floor experienced a range of shock pressures from approx. 0 to 15 GPa with the more heavily shocked samples all occurring between radii of 360 and approx. 600 m. Moreover, the fossil content, lithology and Sr isotopic composition all demonstrate that the initial position of the bulk of the heavily shocked rock ejecta sampled was originally near surface rock at initial depths in the 32 to 45-m depth (below sea level) range. The EPR technique is also sensitive to prehistoric shock damage. This is demonstrated by our study of shocked Kaibab limestone from the 49,000-year-old Meteor (Barringer) Crater Arizona.

Polanskey, Carol A.↗

Biogenic and anthropogenic trace gases in the atmosphere

This paper illustrates the importance of biogenic and anthropogenic trace gases for the global environment and for the climate system. The paper briefly reviews the currently available estimates of sources and strengths of the biogenic and anthropogenic gases on the global scale. One of the major concerns for the global environment is the rapid increase in the concentration of long-lived trace gases such as CO2, CH4, N2O and the chlorofluorocarbons. The trend in the carbon dioxide concentration, as a result of fossil-fuel burning, is of the order of 0.4 percent per year, and this trend is related to the CO2 uptake by the ocean and by terrestrial ecosystems, which are likely to be modified if the planet warms up in the forthcoming decades. The concentrations of methane and nitrous oxide are increasing by 0.9 and 0.25 percent per year, respectively. In the case of the most widely used chlorofluorocarbons, trends as large as 10 percent per year or more are being measured.

Brasseur, G. P.↗

Hydrophobic Catalysts For Removal Of NOx From Flue Gases

Improved catalysts for removal of nitrogen oxides (NO and NO2) from combustion flue gases formulated as composites of vanadium pentoxide in carbon molecular sieves. Promotes highly efficient selective catalytic reduction of NOx at relatively low temperatures while not being adversely affected by presence of water vapor and sulfur oxide gases in flue gas. Apparatus utilizing catalyst of this type easily integrated into exhaust stream of power plant to remove nitrogen oxides, generated in combustion of fossil fuels and contribute to formation of acid rain and photochemical smog.

Sharma, Pramod K.↗

An Exobiological Strategy for Mars Exploration

The idea of searching for evidence of life on Mars may strike some as far-fetched, even fanciful. But there is a compelling logic to such a quest, as well as an equally compelling excitement. Early environments were apparently sufficiently similar on Mars and Earth, and life arose so rapidly on Earth once conditions became clement, that emergence of life on both planets at that time is scarcely less plausible than emergence on only one. Furthermore, although a fossil on Mars might seem at first like a proverbial needle in a haystack, experience on Earth tell us that if we know where to look, finding evidence of ancient life is not particularly difficult, especially when one considers that such evidence can be relatively widely disseminated in the form of chemical or isotopic signatures. The key is to recognize that the search for ancient life on Mars will involve a logically designed sequence of missions, each of which will focus on defining ever more closely where and how biosignatures may be found. Although one can never rule out a chance discovery, this quest should not be approached as one that will yield to a single, expeditious mission. (In fact, the proposed strategy lends itself particularly well to the use of a series of relatively small, inexpensive spacecraft, rather than a single flagship-class mission). The search for life on Mars will take time and commitment, but the reward could be a discovery of inestimable importance, not just to science, but to humanity as a whole.

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Search for Past Life on Mars: Possible Relict Biogenic Activity in Martian Meteorite ALH84001

Fresh fracture surfaces of the martian meteorite ALH84001 contain abundant polycyclic aromatic hydrocarbons (PAHs). These fresh fracture surfaces also display carbonate globules. Contamination studies suggest the PAHs are indigenous to the meteorite. High resolution scanning and transmission electron microscopy study of surface textures and internal structures of selected carbonate globules show that the globules contain fine-grained, secondary phases of single-domain magnetite and Fe-monosulfides. The carbonate globules are similar in texture and size to some terrestrial bacterially induced carbonate precipitates. Although inorganic formation is possible, formation of the globules by biogenic processes could explain many of the observed features including the PAHs. The PAHs, the carbonate globules, and their associated secondary mineral phases and textures could thus be fossil remains of a past martian biota.

McKay, David S.↗

Conference on Early Mars: Geologic and Hydrologic Evolution, Physical and Chemical Environments, and the Implications for Life

Topics considered include: Geology alteration and life in an extreme environment; developing a chemical code to identify magnetic biominerals; effect of impacts on early Martin geologic evolution; spectroscopic identification of minerals in Hematite-bearing soils and sediments; exopaleontology and the search for a Fossil record on Mars; geochemical evolution of the crust of Mars; geological evolution of the early earth;solar-wind-induced erosion of the Mars atmosphere. Also included geological evolution of the crust of Mars.

Clifford, S. M.↗

Destination Mars: An Astronaut's Perspective

The recent discovery of possible fossilized life forms within a Martian meteorite has rekindled interest in human exploration of the planet. While the global scientific community must carefully study this physical evidence as well as await the results of 4 space probes to Mars in the coming years, others are looking ahead to the next logical step of sending humans to the planet. Such a feat, while a tremendous scientific undertaking, is nearly within the grasp of current technology. The travel distance involved and the harsh Martian environment itself impose great challenges to human physiology as well as to spacecraft design. Mission planners face challenges from the long-duration microgravity environment, complex life-support systems, interplanetary radiation, and the psychological stressors involved in such an endeavor.

Parazynski, Scott↗