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At least 613 records · Page 34

STS-47 Post Flight Press Conference

The flight crew of the STS-47 Space Shuttle Orbiter Endeavour Cmdr. Robert L. Gibson, Pilot Curtis L. Brown, Payload Cmdr. Mark C. Lee, Mission Specialists, N. Jan Davis, Jay Apt, Mae C. Jemison, and Payload Specialist, Mamoru Mohri, present an overview of their mission. This the 50th Shuttle flight marks the first NASA mission devoted primarily to Japan. Endeavour carries into Earth orbit Spacelab-J (SL-J), a 23-foot long pressurized laboratory built by the European Space Agency specifically for conducting experiments in a shirt-sleeve environment. SL-J contains 43 experiments, 34 provided by Japan, 7 from the United States and 2 joint experiments. Jemison becomes the first African American woman to fly in space and Mohri first Japanese to fly in space. Video footage includes the following: prelaunch and launch activities; various experiments including protein crystal growth, electronic materials, fluids, glasses and ceramics, metals and alloys, and the effects of microgravity on plants and animals; earth views of Japan, Tokyo Harbor, and Hurricane Bonnie; and the re-entry and landing of the orbiter.

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The PMIP4 Contribution to CMIP6 - Part 1: Overview and Over-Arching Analysis Plan

This paper is the first of a series of four GMD (Geoscientific Model Development) papers on the PMIP4-CMIP6 (Paleoclimate Modelling Intercomparison Project - Phase 4 -- Coupled Model Intercomparison Project - Phase 6) experiments. Part 2 (Otto-Bliesner et al., 2017) gives details about the two PMIP4-CMIP6 interglacial experiments, Part 3 (Jungclaus et al., 2017) about the last millennium experiment, and Part 4 (Kageyama et al., 2017) about the Last Glacial Maximum experiment. The mid-Pliocene Warm Period experiment is part of the Pliocene Model Intercomparison Project (PlioMIP) - Phase 2, detailed in Haywood et al. (2016). The goal of the Paleoclimate Modelling Intercomparison Project (PMIP) is to understand the response of the climate system to different climate forcings for documented climatic states very different from the present and historical climates. Through comparison with observations of the environmental impact of these climate changes, or with climate reconstructions based on physical, chemical, or biological records, PMIP also addresses the issue of how well state-of-the-art numerical models simulate climate change. Climate models are usually developed using the present and historical climates as references, but climate projections show that future climates will lie well outside these conditions. Palaeoclimates very different from these reference states therefore provide stringent tests for state-of-the-art models and a way to assess whether their sensitivity to forcings is compatible with palaeoclimatic evidence. Simulations of five different periods have been designed to address the objectives of the sixth phase of the Coupled Model Intercomparison Project (CMIP6): the millennium prior to the industrial epoch (CMIP6 name: past1000); the mid-Holocene, 6000 years ago (midHolocene); the Last Glacial Maximum, 21,000 years ago (lgm); the Last Interglacial, 127,000 years ago (lig127k); and the mid-Pliocene Warm Period, 3.2 million years ago (midPliocene-eoi400). These climatic periods are well documented by palaeoclimatic and palaeoenvironmental records, with climate and environmental changes relevant for the study and projection of future climate changes. This paper describes the motivation for the choice of these periods and the design of the numerical experiments and database requests, with a focus on their novel features compared to the experiments performed in previous phases of PMIP and CMIP. It also outlines the analysis plan that takes advantage of the comparisons of the results across periods and across CMIP6 in collaboration with other MIPs.

climate↗

Haystack Observatory

Among the 32 presently active radio astronomy programs, 15 are spectral line research, 8 involve continuum measurements, 2 are Haystack-Westford short baseline interferometer projects, 5 are VLBI experiments and 2 used the spectrometric receiver with a small horn antenna. Radiometric programs involve the planetary radar, and 2 of these use the Haystack-Westford interferometer to receive the echoes.

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A technique for incorporating the NASA spacelab payload dedicated experiment processor software into the simulation system for the payload crew training complex

The feasibility of some off-the-shelf microprocessors and state-of-art software is assessed (1) as a development system for the principle investigator (pi) in the design of the experiment model, (2) as an example of available technology application for future PI's experiments, (3) as a system capable of being interactive in the PCTC's simulation of the dedicated experiment processor (DEP), preferably by bringing the PI's DEP software directly into the simulation model, (4) as a system having bus compatibility with host VAX simulation computers, (5) as a system readily interfaced with mock-up panels and information displays, and (6) as a functional system for post mission data analysis.

Bremmer, D. A.↗

NCSP Integral Experiments at Sandia in FY21 [Slides]

This presentation provides details regarding integral experiments at Sandia National Laboratory for fiscal year 2021. The experiments discussed are as follows: IER 230: Characterize the Thermal Capabilities of the 7uPCX; IER 304: Temperature Dependent Critical Benchmarks; IER 305: Critical Experiments with UO 2 Rods and Molybdenum Foils; IER 306: Critical Experiments with UO 2 Rods and Rhodium Foils ; IER 441: Epithermal HEX Lattices with SNL 7uPCX Fuel for Testing Nuclear Data; IER 452: Inversion Point of the Isothermal Reactivity Coefficient; and IER 523: Critical Experiments with ACRR UO 2 -BeO Fuel.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Dual-task performance with ideomotor-compatible tasks: is the central processing bottleneck intact, bypassed, or shifted in locus?

The present study examined whether the central bottleneck, assumed to be primarily responsible for the psychological refractory period (PRP) effect, is intact, bypassed, or shifted in locus with ideomotor (IM)-compatible tasks. In 4 experiments, factorial combinations of IM- and non-IM-compatible tasks were used for Task 1 and Task 2. All experiments showed substantial PRP effects, with a strong dependency between Task 1 and Task 2 response times. These findings, along with model-based simulations, indicate that the processing bottleneck was not bypassed, even with two IM-compatible tasks. Nevertheless, systematic changes in the PRP and correspondence effects across experiments suggest that IM compatibility shifted the locus of the bottleneck. The findings favor an engage-bottleneck-later hypothesis, whereby parallelism between tasks occurs deeper into the processing stream for IM- than for non-IM-compatible tasks, without the bottleneck being actually eliminated.

Psychomotor Performance↗

A proposal for reconciling diverse experiments on the superconducting state in Sr 2 RuO 4

A variety of precise experiments have been carried out to establish the character of the superconducting state in Sr 2 RuO 4 . Many of these appear to imply contradictory conclusions concerning the symmetries of this state. Here we propose that these results can be reconciled if we assume that there is a near-degeneracy between a \({d}_{{x}^{2}-{y}^{2}}\) (B 1g in group theory nomenclature) and a \({g}_{xy({x}^{2}-{y}^{2})}\) (A 2g ) superconducting state. From a weak-coupling perspective, such an accidental degeneracy can occur at a point at which a balance between the on-site and nearest-neighbor repulsions triggers a d-wave to g-wave transition.

36 MATERIALS SCIENCE↗

Platform Of Optimal Experiment Management

The platform of optimal experiment management, POEM, powered with automated machine learning to accelerate the discovery of optimal solutions, and automatically guide the design of experiments to be evaluated. POEM currently supports 1) random model explorations for experiment design, 2) sparse grid model explorations with Gaussian Polynomial Chaos surrogate model to accelerate experiment design ,3) time-dependent model sensitivity and uncertainty analysis to identify the importance features for experiment design, 4) model calibrations via Bayesian inference to integrate experiments to improve model performance, and 5) Bayesian optimization for optimal experimental design. In addition, POEM aims to simplify the process of experimental design for users, enabling them to analyze the data with minimal human intervention, and improving the technological output from research activities.

Wang, Congjian [Idaho National Laboratory (INL), I↗

Stratospheric Ozone Intercomparison Campaign (STOIC) 1989: Overview

The NASA Upper Atmosphere Research Program organized a Stratospheric Ozone Intercomparison Campaign (STOIC) held in July-August 1989 at the Table Mountain Facility (TMF) of the Jet Propulsion Laboratory (JPL). The primary instruments participating in this campaign were several that had been developed by NASA for the Network for the Detection of Stratospheric Change: the JPL ozone lidar at TMF, the Goddard Space Flight Center trailer-mounted ozone lidar which was moved to TMF for this comparison, and the Millitech/LaRC microwave radiometer. To assess the performance of these new instruments, a validation/intercomparison campaign was undertaken using established techniques: balloon ozonesondes launched by personnel from the Wallops Flight Facility and from NOAA Geophysical Monitoring for Climate Change (GMCC) (now Climate Monitoring and Diagnostics Laboratory), a NOAA GMCC Dobson spectrophotometer, and a Brewer spectrometer from the Atmospheric Environment Service of Canada, both being used for column as well as Umkehr profile retrievals. All of these instruments were located at TMF and measurements were made as close together in time as possible to minimize atmospheric variability as a factor in the comparisons. Daytime rocket measurements of ozone were made by Wallops Flight Facility personnel using ROCOZ-A instruments launched from San Nicholas Island. The entire campaign was conducted as a blind intercomparison, with the investigators not seeing each others data until all data had been submitted to a referee and archived at the end of the 2-week period (July 20 to August 2, 1989). Satellite data were also obtained from the Stratospheric Aerosol and Gas Experiment (SAGE 2) aboard the Earth Radiation Budget Satellite and the Total Ozone Mapping Spectrometer (TOMS) aboard Nimbus 7. An examination of the data has found excellent agreement among the techniques, especially in the 20- to 40-km range. As expected, there was little atmospheric variability during the intercomparison, allowing for detailed statistical comparisons at a high level of precision. This overview paper summarizes the campaign and provides a 'road map' to subsequent papers in this issue by the individual instrument teams which will present more detailed analysis of the data and conclusions.

Margitan, J. J.↗

Characterization of Mk-IV and EBR-II X441A Metallic Fuel Pins for the THOR-C-2 and THOR-M-TOP-1 Experiments: Results from Post-Transient Neutron Tomography of THOR-C-2 Capsule and Pre-transient Non-Destructive and Destructive Examination of DP 36 and DP 40 (Rev.1)

Current interest in sodium-cooled fast reactor designs, such as TerraPower’s Natrium Reactor, has highlighted the need for advanced-reactor fuel technology development. A Fuel Safety Research and Development (FSRD) program for metallic fast reactor fuels has been created to achieve comprehensive safety testing within the re-commissioned Transient Reactor Test (TREAT) facility at the Idaho National Laboratory. Despite over 60 years of metallic fuel irradiation, uncertainties exist in the performance of the fuel system, particularly under anticipated operational occurrences and severe accident scenarios. Throughout historical testing within the Experimental Breeder Reactor (EBR)-II and the Fast Flux Test Facility, fuel behavior has demonstrated benign response to transient reactor conditions; however, accurate predictions of failure thresholds rely heavily on fuel composition and irradiation history. In advancing the FSRD program, two planned transient heating experiments are at various stages of completion. The Temperature Heat sink Overpower Response (THOR)-C-2, fueled with an unirradiated Mk IV U-10Zr pin, has undergone transient irradiation in TREAT and post-transient three-dimensional neutron tomography. Additionally, pre-transient characterization of test and sibling U-19Pu-10Zr pins for THOR-M-TOP-1 was evaluated by both non-destructive and destructive methods. The test and sibling pins were selected from previously irradiated EBR-II experiment X441A. Both pins underwent visual examination, precise gamma spectrometry, two-dimensional neutron radiography, and element contact profilometry while the sibling pin was additionally subjected to sectioning and optical microscopy. THOR-C-2 radiography captured the fuel and cladding relocation during the intermediate transient at the top and bottom of the THOR capsule, allowing key features to be linked to the pin’s measured thermal response. For THOR M TOP 1, a solid baseline for steady-state behavior has been established. No anomalous features were identified in either the test or sibling pin. Defining characteristics and features were recorded for further comparisons.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Hunga Tonga–Hunga Ha′apai Volcano Impact Model Observation Comparison (HTHH-MOC) project: experiment protocol and model descriptions

The 2022 Hunga volcanic eruption injected a significant amount of water vapor and a moderate amount of sulfur dioxide into the stratosphere, causing observable responses in the climate system. We have developed a model–observation comparison project to investigate the evolution of volcanic water and aerosols and their impacts on atmospheric dynamics, chemistry, and climate, using several state-of-the-art chemistry climate models. The project goals are (1) to evaluate the current chemistry–climate models to quantify their performance in comparison to observations and (2) to understand atmospheric responses in the Earth system after this exceptional event and investigate the potential impacts in the projected future. To achieve these goals, we designed specific experiments for direct comparisons to observations, for example from balloons and the Microwave Limb Sounder satellite instrument. Experiment 1 consists of two sets of free-running ensemble experiments from 2022 to 2031: one with fixed sea-surface temperatures and sea ice and one with coupled ocean. These experiments will help to understand the long-term evolution of water vapor and aerosols; quantify HTHH effects on stratospheric and mesospheric temperatures, dynamics, and transport; understand the impact of dynamic changes on ozone chemistry; quantify the net radiative forcings; and evaluate any surface climate impact. Experiment 2 is a nudged-run experiment from 2022 to 2023 using observed meteorology. To allow participation of more climate models with varying complexities of aerosol simulation, we include two sets of simulations in Experiment 2: Experiment 2a is designed for models with internally generated aerosol, while Experiment 2b is designed for models using prescribed aerosol surface area density. This experiment will help to analyze H 2 O and aerosol evolution, quantify the net radiative forcings, understand the impacts on mid-latitude and polar O 3 chemistry, and allow close comparisons with observations.

Zhu, Yunqian [Univ. of Colorado, Boulder, CO (Unit↗

Creating Frustrated Lewis Pairs in Defective Boron Carbon Nitride for Electrocatalytic Nitrogen Reduction to Ammonia

Abstract The electrocatalytic nitrogen reduction reaction (NRR) on metal‐free catalysts is an attractive alternative to the industrial Haber–Bosch process. However, the state‐of‐the‐art metal‐free electrocatalysts still suffer from low Faraday efficiencies and low ammonia yields. Herein, we present a molecular design strategy to develop a defective boron carbon nitride (BCN) catalyst with the abundant unsaturated B and N atoms as Lewis acid and base sites, which upgrades the catalyst from a single “Lewis acid catalysis” to “frustrated Lewis pairs (FLPs) catalysis.” 14 N 2 / 15 N 2 exchange experiments and density functional theory (DFT) calculations reveal that FLPs can adsorb an N 2 molecule to form a six‐membered ring intermediate, which enables the cleavage of N 2 via a pull–pull effect, thereby significantly reducing the energy barrier to −0.28 eV. Impressively, BCN achieves a high Faraday efficiency of 18.9 %, an ammonia yield of 20.9 μg h −1 mg −1 cat. , and long‐term durability.

Lin, Wenwen↗

Creating Frustrated Lewis Pairs in Defective Boron Carbon Nitride for Electrocatalytic Nitrogen Reduction to Ammonia

Abstract The electrocatalytic nitrogen reduction reaction (NRR) on metal‐free catalysts is an attractive alternative to the industrial Haber–Bosch process. However, the state‐of‐the‐art metal‐free electrocatalysts still suffer from low Faraday efficiencies and low ammonia yields. Herein, we present a molecular design strategy to develop a defective boron carbon nitride (BCN) catalyst with the abundant unsaturated B and N atoms as Lewis acid and base sites, which upgrades the catalyst from a single “Lewis acid catalysis” to “frustrated Lewis pairs (FLPs) catalysis.” 14 N 2 / 15 N 2 exchange experiments and density functional theory (DFT) calculations reveal that FLPs can adsorb an N 2 molecule to form a six‐membered ring intermediate, which enables the cleavage of N 2 via a pull–pull effect, thereby significantly reducing the energy barrier to −0.28 eV. Impressively, BCN achieves a high Faraday efficiency of 18.9 %, an ammonia yield of 20.9 μg h −1 mg −1 cat. , and long‐term durability.

Lin, Wenwen↗

Two-Phase Flow Mechanisms Controlling CO2 Intrusion into Shaly Caprock

Abstract Geologic carbon storage in deep saline aquifers has emerged as a promising technique to mitigate climate change. CO 2 is buoyant at the storage conditions and tends to float over the resident brine jeopardizing long-term containment goals. Therefore, the caprock sealing capacity is of great importance and requires detailed assessment. We perform supercritical CO 2 injection experiments on shaly caprock samples (intact caprock and fault zone) under representative subsurface conditions. We numerically simulate the experiments, satisfactorily reproducing the observed evolution trends. Simulation results highlight the dynamics of CO 2 flow through the specimens with implications to CO 2 leakage risk assessment in field practices. The large injection-induced overpressure drives CO 2 in free phase into the caprock specimens. However, the relative permeability increase following the drainage path is insufficient to provoke an effective advancement of the free-phase CO 2 . As a result, the bulk CO 2 front becomes almost immobile. This implies that the caprock sealing capacity is unlikely to be compromised by a rapid capillary breakthrough and the injected CO 2 does not penetrate deep into the caprock. In the long term, the intrinsically slow molecular diffusion appears to dominate the migration of CO 2 dissolved into brine. Nonetheless, the inherently tortuous nature of shaly caprock further holds back the diffusive flow, favoring safe underground storage of CO 2 over geological time scales.

58 GEOSCIENCES↗

Informing field-scale CO 2 storage simulations with sandbox experiments: The effect of small-scale heterogeneities

Small-scale heterogeneities can significantly affect the fate of the CO 2 plume and trapping during CO 2 migration. We conducted geologic carbon storage field-scale simulations to investigate the impact of small-scale heterogeneities on plume dynamics and trapping performance. Small-scale heterogeneities have been shown to increase the amount of trapped CO 2 during buoyancy-driven flow. The trapped CO 2 saturation is validated by previous sandbox experimental work during buoyancy-driven flow in realistic heterogeneous domains and is implemented through the critical CO 2 saturation parameter (i.e., the first non-zero value in the drainage CO 2 relative permeability curve). Depending on the type and degree of heterogeneity, various critical CO 2 saturation values are exhibited. Furthermore, we investigated the effect of small-scale heterogeneities when multiple capillary pressure models are employed. This study demonstrates that an increase in critical CO 2 saturation reduces the CO 2 plume size and lateral extent, accompanying an increase in residual trapping and a decrease in solubility trapping. Lastly, we show that independent of the capillary pressure model used, an increase in critical saturation leads to similar CO 2 plume dynamics distribution and trapping performance. These results emphasize the importance of quantifying the effect of small-scale heterogeneity as they affect the large-scale behavior of the CO 2 plume.

58 GEOSCIENCES↗

LDEF Materials/Contamination

This pictorial presentation reviews the post-flight analysis results from two type of hardware (tray clamp bolt heads and uhcre flight experiment tray walls) from the Long Duration Exposure Facility (LDEF). It will also discuss flight hardware for one upcoming (Effects of the Space Environment on Materials (ESEM) flight experiment), and two current flight experiments evaluating the performance of materials in space (Passive Optical Sample Assembly (POSA) 1&2 flight experiments. These flight experiments also are concerned with contamination effects which will also be discussed.

Pippin, Gary↗

Tank Pressure Control Experiment: Thermal Phenomena in Microgravity. Video 2 of 4

The report presents the results of the flight experiment Tank Pressure Control Experiment/Thermal Phenomena (TPCE/TP) performed in the microgravity environment of the space shuttle. TPCE/TP, flown on the Space Transportation System STS-52, was a second flight of the Tank Pressure Control Experiment (TPCE). The experiment used Freon 113 at near saturation conditions. The test tank was filled with liquid to about 83 percent by volume. The experiment consisted of 21 tests. Each test generally started with a heating phase to increase the tank pressure and to develop temperature stratification in the fluid, followed by a fluid mixing phase for the tank pressure reduction and fluid temperature equilibration. The heating phase provided pool boiling data from large (relative to bubble sizes) heating surfaces (0.1046 m by 0.0742 m) at low heat fluxes (0.23 to 1.16 kW/m(exp 2)). The system pressure and the bulk liquid subcooling varied from 39 to 78 kPa and 1 to 3 deg C, respectively. The boiling process during the entire heating period, as well a jet-induced mixing process for the first 2 min. of the mixing period, was also recorded on video. Analyses of data from the two flight experiments (TPCE and TPCE/TP) and their comparison with the results obtained in drop tower experiments suggest that as Bond number approaches zero the flow pattern produced by an axial jet and the mixing time can be predicted by the Weber number. This is video 2 of 4.

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