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At least 613 records · Page 34

Orientation Effects in ZnO Films Using Off-Axis Sputtering Deposition

ZnO is a wide-band-gap oxide material and has been used in numerous applications. It is also a good substrate for fabricating GaN-based (a blue laser candidate) devices. Off-axis sputtering technique is one of the best techniques in synthesizing oxide materials because negative ion bombardment and particle kinetic energy is greatly reduced when adatoms condense on substrates. Since the sputtered material from the target arrive on the substrate surface at a 90 deg. configuration, which differs from the normal sputtering geometry, it is expected that the film uniformity and composition distributions will be affected. However, the details of these properties and mechanisms have not been well studied. ZnO films are synthesized on (0001) sapphire and quartz substrates by off-axis sputtering deposition in various oxygen/argon mixture ratios and pressures at different temperatures. Substrates and sputtering sources are placed at three different orientations that are orthogonal to each other. The normal direction of a substrate is parallel to the gravity vector and the other is perpendicular to it. Film thickness profiles at different growth orientations are determined using a profimeter. All films grown at high temperatures have highly textured structures on quartz substrates and epitaxially grow on sapphire substrates. Because of this process, the film surface is very smooth. X-ray diffraction, scanning probe microscopy, and Fourier transfer infrared spectroscopy, and electrical measurements will be used to characterize these films. Detailed results will be discussed in the presentation.

Zhu, Shen↗

Pressure Effect in ZnO Films Using Off-Axis Sputtering Deposition

ZnO films are deposited on (0001) sapphire, (001) Si and quartz substrates using the off-axis reactive magnetron sputtering deposition. Based on film thickness measurements, three transport regions of sputtered particles are observed when films are deposited in the pressure regions of 5 mtorr - 150 mtorr. X-ray diffraction, scanning probes microscopy, and electrical measurements are also used to characterize these films. The full width at half maximum of theta rocking curves for epitaxial films is less than 0.5 deg. In textured films, it rises to several degrees. The epitaxial films deposited at high pressure reveal a flat surface with some hexagonal facets. The density of hexagonal facets decreases when the growth pressure is reduced. The resistivity of these epitaxial films also depends on the growth pressures. A relationship between the pressure effects and film properties are discussed.

Zhu, Shen↗

Femtosecond Pulse Characterization as Applied to One-Dimensional Photonic Band Edge Structures

The ability to control the group velocity and phase of an optical pulse is important to many current active areas of research. Electronically addressable one-dimensional photonic crystals are an attractive candidate to achieve this control. This report details work done toward the characterization of photonic crystals and improvement of the characterization technique. As part of the work, the spectral dependence of the group delay imparted by a GaAs/AlAs photonic crystal was characterized. Also, a first generation an electrically addressable photonic crystal was tested for the ability to electronically control the group delay. The measurement technique, using 100 femtosecond continuum pulses was improved to yield high spectral resolution (1.7 nanometers) and concurrently with high temporal resolution (tens of femtoseconds). Conclusions and recommendations based upon the work done are also presented.

Fork, Richard L.↗

Plasmaspheric Drainage Plumes: Inner-Magnetospheric Coupling from the IMAGE/EUV Perspective

Plasmaspheric drainage plumes appear in the aftermath of periods of enhanced convection/erosion and are interpreted as a near-equatorial signature of the redistribution of thermal plasma along streamlines. Analysis of IMAGE/EUV observations from "FirstLight" through the end of calendar year 2002 reveals that for Kp greater than or equal to 3, there is an 84% probability of observing a plasmaspheric plume in EUV data. We present a statistical analysis of the geomagnetic conditions [Kp, Dst, and solar wind-induced electric field] associated with EUV plume observations. This analysis yields a peak in observational probability when Kp = 4 and Dst = -50 nT. Additionally, EUV pllume observations are associated with a solar wind-induced convection electric field at Earth [Ev, SM] characterized by bi-modal behavior with a positive mode peaked at approximately 4 m V(raised dot) m(sup -1) and a negative model that peaks at -2 mV (raised dot) m(sup -1). Analysis of the time rate of change of the plume-associated Ev, SM indicated that once the mechanism for plume formation is initiated, a slowly changing convection environment is required to allow for sufficient plume development prior to EUV detection.

Adrian, Mark L.↗

Hypervelocity Impact Performance of Open Cell Foam Core Sandwich Panel Structures

Metallic foams are a relatively new class of materials with low density and novel physical, mechanical, thermal, electrical and acoustic properties. Although incompletely characterized, they offer comparable mechanical performance to traditional spacecraft structural materials (i.e. honeycomb sandwich panels) without detrimental through-thickness channeling cells. There are two competing types of metallic foams: open cell and closed cell. Open cell foams are considered the more promising technology due to their lower weight and higher degree of homogeneity. Leading micrometeoroid and orbital debris shields (MMOD) incorporate thin plates separated by a void space (i.e. Whipple shield). Inclusion of intermediate fabric layers, or multiple bumper plates have led to significant performance enhancements, yet these shields require additional non-ballistic mass for installation (fasteners, supports, etc.) that can consume up to 35% of the total shield weight [1]. Structural panels, such as open cell foam core sandwich panels, that are also capable of providing sufficient MMOD protection, represent a significant potential for increased efficiency in hypervelocity impact shielding from a systems perspective through a reduction in required non-ballistic mass. In this paper, the results of an extensive impact test program on aluminum foam core sandwich panels are reported. The effect of pore density, and core thickness on shielding performance have been evaluated over impact velocities ranging from 2.2 - 9.3 km/s at various angles. A number of additional tests on alternate sandwich panel configurations of comparable-weight have also been performed, including aluminum honeycomb sandwich panels (see Figure 1), Nomex honeycomb core sandwich panels, and 3D aluminum honeycomb sandwich panels. A total of 70 hypervelocity impact tests are reported, from which an empirical ballistic limit equation (BLE) has been derived. The BLE is in the standard form suitable for implementation in risk analysis software, and includes the effect of panel thickness, core density, and facesheet material properties. A comparison between the shielding performance of foam core sandwich panel structures and common MMOD shielding configurations is made for both conservative (additional 35% non-ballistic mass) and optimistic (additional mass equal to 30% of bumper mass) considerations. Suggestions to improve the shielding performance of foam core sandwich panels are made, including the use of outer mesh layers, intermediate fabric/composite layers, and varying pore density.

Ryan, Shannon↗

Relativistic Electron Response to the Combined Magnetospheric Impact of a Coronal Mass Ejection Overlapping with a High-Speed Stream: Van Allen Probes Observations

During early November 2013, the magnetosphere experienced concurrent driving by a coronal mass ejection (CME) during an ongoing high-speed stream (HSS) event. The relativistic electron response to these two kinds of drivers, i.e., HSS and CME, is typically different, with the former often leading to a slower buildup of electrons at larger radial distances, while the latter energizing electrons rapidly with flux enhancements occurring closer to the Earth. We present a detailed analysis of the relativistic electron response including radial profiles of phase space density as observed by both Magnetic Electron and Ion Sensor (MagEIS) and Relativistic Electron Proton Telescope instruments on the Van Allen Probes mission. Data from the MagEIS instrument establish the behavior of lower energy (<1 MeV) electrons which span both intermediary and seed populations during electron energization. Measurements characterizing the plasma waves and magnetospheric electric and magnetic fields during this period are obtained by the Electric and Magnetic Field Instrument Suite and Integrated Science instrument on board Van Allen Probes, Search Coil Magnetometer and Flux Gate Magnetometer instruments on board Time History of Events and Macroscale Interactions during Substorms, and the low-altitude Polar-orbiting Operational Environmental Satellites. These observations suggest that during this time period, both radial transport and local in situ processes are involved in the energization of electrons. The energization attributable to radial diffusion is most clearly evident for the lower energy (<1 MeV) electrons, while the effects of in situ energization by interaction of chorus waves are prominent in the higher-energy electrons.

Magnetosphere↗

Edge Wear of the Advanced Electric Propulsion System Pole Covers

This work presents a summary of the first wear test of the 12 kW Advanced Electric Propulsion System (AEPS) focused on characterizing the erosion of the edges and side walls of the thruster pole covers. Testing was performed with the AEPS Engineering Test Unit 2 (ETU-2) thruster and accumulated approximately 325 hours of operation at the 600 V/12 kW condition with the magnetic field strength set to 75% of its nominal value. Thruster performance was invariant throughout the wear test for all thruster throttle conditions and was found to be equal to previous measurements. Contrary to past results, inner front pole cover erosion rates were invariant to magnetic field strength at the 600 V/12 kW condition and no erosion was measured on the outer front pole cover. The erosion profile of the downstream inner front pole cover faces was continuous across the cover indicating no significant change in erosion process at the pole cover edges. Side wall erosion was only detected on the cathode-facing surfaces of the inner front pole cover and was equal in magnitude to the rates measured on the adjacent downstream edges. Taken together, these results suggest that erosion of the pole cover edges and sidewalls is driven by cathode-borne ions and will ultimately not impact AEPS life estimates.

Hall thrusters↗

AGC 4 Graphite Specimen Postirradiation Characterization Plan

This characterization plan describes the thermal, physical, and mechanical measurement techniques that will be used to characterize graphite samples being tested in the fourth Advanced Graphite Creep experiment (AGC-4). Instruments, fixtures, and methods are currently in place for both pre and postirradiation material property measurements of bulk density, thermal diffusivity, coefficient of thermal expansion, elastic modulus, and electrical resistivity. Postirradiation testing procedures used to characterize the samples are described and discussed in the plan. Where they exist, American Society for Testing and Materials (ASTM) International testing standards will apply to the tests. Any departure from ASTM International testing standards or the approved laboratory procedures are documented within this characterization plan. Deviations that occur during testing will be documented in data reports.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Material growth and characterization for solid state devices

Manganese was used as the dopant for p-type InGaAs layers grown on semi-insulating (Fe-doped) and n-type (Sn-doped) InP substrates. Optical, electrical (Hall) and SIMS measurements were used to characterize the layers. Mn-diffusion into the substrate (during the growth of In GaAs) was observed only when Fe-doped substrates were used. Quaternary layers of two compositions corresponding to wavelengths (energy gaps) of approximated 1.52 micrometers were successfully grown at a constant temperature of 640 C and InP was grown in the temperature range of 640 C to 655 C. A study of the effect of pulses on the growth velocity of InP indicated no significant change as long as the average applied current was kept constant. A system for depositing films of Al2O3 by the pyrolysis of aluminum isopropoxide was designed and built. Deposited layers on Si were characterized with an ellipsometer and exhibited indices of refraction between 1.582 and 1.622 for films on the order of 3000 A thick. Undoped and p-type (Mn-doped) InGaAs epitaxial layers were also grown on Fe-doped InP substrates through windows in sputtered SiO2 (3200 A thick) layers.

Stefanakos, E. K.↗

Strong, Nonresonant Radiation Enhances Cis–Trans Photoisomerization of Stilbene in Solution

Previously, it has been demonstrated that external electric fields may be used to exert control over chemical reactivity. In this paper, the impact of a strong, nonresonant IR field (1064 nm) on the photoisomerization of cis-stilbene is investigated in cyclohexane solution. The design of a suitable reaction vessel for characterization of this effect is presented. The electric field supplied by the pulsed, near-IR radiation (ε 1 = 4.5 × 10 7 V/cm) enhances the cis → trans photoisomerization yield at the red edge of the absorption spectrum (wavelengths between 337 and 340 nm). Within the microliter focal volume, up to 75% of all cis-stilbene molecules undergo isomerization to trans-stilbene in the strong electric-field environment, indicating a significant increase relative to the 35% yield of trans-stilbene under field-free conditions. This result correlates with a 1–3% enhancement in the trans-stilbene concentration throughout the bulk solution. Theoretical analysis suggests that the observed change is the result of dynamic Stark shifting of the ground and first excited states, leading to a significant redshift in cis-stilbene’s absorption spectrum. The predicted increase in the absorption cross section in this range of excitation wavelengths is qualitatively consistent with the experimental increase in trans-stilbene production.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Advanced Power Electronics and Electric Machines

The advanced power electronics and electric machines (APEEM) research group at the National Renewable Energy Laboratory (NREL) has developed world-class experimental and modeling capabilities for designing and evaluating efficient and reliable power electronics and electric machines thermal management systems. They also design, fabricate and characterize advanced power electronics packaging, and are developing state-of-health monitoring techniques. These researchers deliver safe, reliable, high performing, power-dense components that allow seamless integration between renewable energy sources, electric transportation, and the grid, helping to make widespread electric vehicle (EV) adoption and greenhouse gas emissions reduction more feasible. This document outlines the group's major capabilities in the areas of power electronics; module development and characterization; thermal modeling and management; thermomechanical reliability analysis of devices, modules, inverters/converters, and electric machines; physics-of-failure-based reliability analysis; and microelectronics. It also overviews the group's state-of-the-art equipment for fluid-based thermal management; thermal measurement & characterization; thermomechanical reliability analysis; micro- and power electronics measurement & characterization; and prototype fabrication, as well as the group's world-class modeling and simulation capabilities.

advanced gate drivers↗

Characterization of dangling bond defects at the crystalline Si/SiO x interface in a polycrystalline Si passivating contact solar cell at room temperature with electrically detected magnetic resonance spectroscopy

Monocrystalline silicon solar cells can achieve photoconversion efficiencies exceeding 26%; however, performance-limiting defects that trap carriers continue to be a challenge. In this work, we have characterized Si solar cells with tunneling SiO x /polycrystalline-Si (poly-Si) passivating contacts (TOPCon) on As-doped Czochralski Si wafers with electrically detected magnetic resonance (EDMR) spectroscopy. We fabricated 2 × 20 mm 2 TOPCon-like mini solar cells with edge passivation alongside larger 4 cm 2 sister cells and obtained similar device characteristics. We performed EDMR spectroscopy at 300 K on two minicells with different degrees of surface passivation based on the recombination parameter, J o , values of 40 and 310 fA/cm2. We optimized the resolution and the signal-to-noise ratio of the EDMR response of the minicells by varying the forward bias voltage and the magnetic field modulation amplitude. We detect two distinct signals with EDMR spectroscopy, an axial-like signal at g = 2.009, 2.0087, and 2.0015, and an isotropic signal at g = 2.0024, which we attribute to Si dangling bonds (P b0 and P b centers) and boron–oxygen related defects, respectively, at or near the c-Si/SiO x interface. The EDMR signals were lower for the cell with a lower value of J o , while the ratio of the two defect populations was very similar. The EDMR signal increases with forward bias but drops to zero at bias voltages >0.5 V, consistent with interface defects within or near the boron-doped emitter depletion region. Our study demonstrates a method to fabricate minicells that can be characterized with EDMR spectroscopy to detect industrially relevant defects in TOPCon cells.

14 SOLAR ENERGY↗

Optical Scattering Characterization for the Glennan Microsystems Microscale Particulate Classifier

Small sensors that are tolerant to mechanically and thermally harsh environments present the possibility for in-situ particle characterization in propulsion, industrial, and planetary science applications. Under a continuing grant from the Glennan Microsystems Initiative to the Microgravity Fluids Physics Branch of the NASA-Glenn Research Center, a Microscale Particle Classifier (MiPAC) instrument is being developed. The MiPAC instrument will be capable of determining the size distribution of airborne particles from about 1 nm to 30 micrometers, and will provide partial information as to the concentration, charge state, shape, and structure of the particles, while being an order of magnitude smaller in size and lighter in weight than presently commercially available instruments. The portion of the instrument that will characterize the nm-range particles will employ electrical mobility techniques and is being developed under a separate grant to Prof. David Pui of the University of Minnesota. The portion of the instrument that will characterize the micrometer-size particles such as dirt, pollens, spores, molds, soot, and combustion aerosols will use light scattering techniques. The development of data analysis techniques to be employed in the light scattering portion of the instrument is covered by this grant.

Lock, James A.↗

Electric Motor Noise for Small Quadcopters: Part I - Acoustic Measurements

There is increased interest in using electric motors to drive propulsors across a range of small air vehicle classes. Applications include both vertical lift and conventional takeoff and landing systems for Small Unmanned Aircraft Systems. Mission profiles call for integrating these systems into urban airspaces exposing populated areas to new noise sources. In addition to the propulsor noise from rotors and propellers, electric motors are expected to contribute to the overall sound levels and possibly human annoyance. This work presents acoustic measurements of electric motors used for small quadcopters to characterize the sound and identify sources with and without a propeller. Free field microphone measurements were used to determine directivity and a phased microphone array was used to identify sound sources. A companion paper (Part II – Source Characteristics and Prediction) compares the far field results with current probe measurements of the signal driving the motor, the structural response of the motor case, and describes prediction methods of electric motor noise.

Aircraft Noise↗

Electric Motor Noise from Small Quadcopters: Part 1 - Acoustic Measurements

There is increased interest in using electric motors to drive propulsors across a range of small air vehicle classes. Applications include both vertical lift and conventional takeoff and landing systems for Small Unmanned Aircraft Systems. Mission profiles call for integrating these systems into urban airspaces exposing populated areas to new noise sources. In addition to the propulsor noise from rotors and propellers, electric motors are expected to contribute to the overall sound levels and possibly human annoyance. This work presents acoustic measurements of electric motors used for small quadcopters to characterize the sound and identify sources with and without a propeller. Free field microphone measurements were used to determine directivity and a phased microphone array was used to identify sound sources. A companion paper (Part II - Source Characteristics and Prediction) compares the far field results with current probe measurements of the signal driving the motor, the structural response of the motor case, and describes prediction methods of electric motor noise.

Electric Propulsion↗

The permanent electric dipole moment of CaOH

The X 2 Sigma(+), A 2Pi, and B 2Sigma(+) states of CaOH are characterized theoretically and experimentally, with a focus on the value of the permanent electric dipole moment (mu). Calculations based on SCF and SDCI studies of CaOH (Bauschlicher et al., 1984 and 1986) give mu values of 0.98, 0.49, and 0.11 D for the X, A, and B states, respectively, in good agreement with experiments in which the pure rotational spectra of these states were not detected. Modified Rittner (1951) and ligand-field models of these states are explored in detail, and the applicability of these results to observational searches for CaOH in circumstellar envelopes is indicated.

Bauschlicher, Charles W., Jr.↗

Study of Electrical Contacts and Devices in Advanced Semiconductors

Research conducted at Tuskegee University concentrates on electrical contacts to GaN films and their characterization with the objective of understanding contact formation and realizing low-resistance metal contacts. Contact properties are known to be strongly related to surface preparation. It appears that the as-received material had a thin oxide film on the surface of the GaN film. Various cleaning treatments were employed in order to render the surface contamination free and removal of the oxide film. Metal films were then deposited by e-beam evaporation. Electrical characteristics of these contacts indicated that the optimal treatment was an organic solvent cleaning followed by etching in buffered oxide solution. Contacts established with Al were observed to be ohmic in nature, whereas Au, Cr, Ti, and Pt exhibit rectifying contacts. Platinum contacts were almost ideal as shown by an ideality factor of 1.02.

Hall, H. P.↗