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At least 613 records · Page 34

Modeling spatial patterns of longleaf pine needle dispersal using long-term data

Abstract Background Predicting patterns of fire behavior and effects in frequent fire forests relies on an understanding of fine-scale spatial patterns of available fuels. Leaf litter is a significant canopy-derived fine fuel in fire-maintained forests. Litter dispersal is dependent on foliage production, stand structure, and wind direction, but the relative importance of these factors is unknown. Results Using a 10-year litterfall dataset collected within eighteen 4-ha longleaf pine ( Pinus palustris Mill.) plots varying in canopy spatial pattern, we compared four spatially explicit models of annual needle litter dispersal: a model based only on basal area, an overstory abundance index (OAI) model, both isotropic and anisotropic litter kernel models, and a null model that assumed no spatial relationship. The best model was the anisotropic model (R 2 = 0.656) that incorporated tree size, location, and prevailing wind direction, followed by the isotropic model (R 2 = 0.612), basal area model (R 2 = 0.488), OAI model (R 2 = 0.416), and the null model (R 2 = 0.08). Conclusions As with previous studies, the predictive capability of the litter models was robust when internally validated with a subset of the original dataset (R 2 = 0.196–0.549); however, the models were less robust when challenged with an independent dataset (R 2 = 0.122–0.319) from novel forest stands. Our model validation underscores the need for rigorous tests with independent, external datasets to confirm the validity of litter dispersal models. These models can be used in the application of prescribed fire to estimate fuel distribution and loading, as well as aid in the fine tuning of fire behavior models to better understand fire outcomes across a range of forest canopy structures.

54 ENVIRONMENTAL SCIENCES↗

Hydrogen Dispersion Modeling for Development of Smart Distributed Monitoring

Studying hydrogen dispersion is crucial for ensuring the safe and effective deployment of hydrogen as an energy carrier. This study presents a comprehensive CFD modeling framework for simulating hydrogen dispersion at a real-world hydrogen production, storage, and utilization facility. Utilizing the Hydrogen Research Facility under the Advanced Research on Integrated Energy Systems (ARIES) at the National Renewable Energy Laboratory's (NREL) Flatirons campus, controlled hydrogen releases at 27 kg-H2/hr were simulated. The model incorporated site-specific atmospheric conditions, including hourly wind speeds and temperatures recorded between 8 AM and 8 PM from October to December 2023. To reduce computational demands, a statistical reduction technique was applied to condense the dataset to 100 representative scenarios, validated by statistical tests for wind speeds and power law coefficients. Simulations were conducted using the Reynolds-Averaged Navier-Stokes equations. Results demonstrated that wind speed substantially influences hydrogen dispersion, with low wind conditions forming concentrated clouds and higher wind speeds stretching the plume. Additionally, clustering analysis informed optimal sensor placement at various elevations with up to 10 sensor locations on each elevation. This framework offers a robust approach for understanding hydrogen behavior in ambient conditions and informing detection strategies.

08 HYDROGEN↗

Modeling the Dispersibility of Single Walled Carbon Nanotubes in Organic Solvents by Quantitative Structure-Activity Relationship Approach

Here, the knowledge of physico-chemical properties of carbon nanotubes, including behavior in organic solvents is very important for design, manufacturing and utilizing of their counterparts with improved properties. In the present study a quantitative structure-activity/property relationship (QSAR/QSPR) approach was applied to predict the dispersibility of single walled carbon nanotubes (SWNTs) in various organic solvents. A number of additive descriptors and quantum-chemical descriptors were calculated and utilized to build QSAR models. The best predictability is shown by a 4-variable model. The model showed statistically good results ( R 2 training = 0.797, Q 2 = 0.665, R 2 test = 0.807), with high internal and external correlation coefficients. Presence of the X0Av descriptor and its negative term suggest that small size solvents have better SWCNTs solubility. Mass weighted descriptor ATS6m also indicates that heavier solvents (and small in size) most probably are better solvents for SWCNTs. The presence of the Dipole Z descriptor indicates that higher polarizability of the solvent molecule increases the solubility. In conclusion, the developed model and contributed descriptors can help to understand the mechanism of the dispersion process and predictorganic solvents that improve the dispersibility of SWNTs.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Dispersion of Boron Nitride Nanotubes by Pluronic Triblock Copolymer in Aqueous Solution

Boron nitride nanotubes (BNNTs) have been of interest for their excellent thermal, electrical, and mechanical properties, and they have a broad spectrum of potential applications, such as in piezoelectric materials, reinforcement of materials, and electrothermal insulation materials. For practical use of BNNTs, it is desirable to disperse them in aqueous solution, which improves convenience of handling. However, it is still difficult to make a homogenous and stable BNNT dispersion in aqueous solution, due to their strong van der Waals interactions and hydrophobic surface. To solve these problems, we used Pluronic P85 and F127, which have both hydrophilic groups and hydrophobic groups. Here, we report the wrapped structure of a Pluronic polymer-BNNT dispersion by using small-angle neutron scattering, UV–Vis spectroscopy, thermogravimetric analysis, and atomic force microscopy.

36 MATERIALS SCIENCE↗

Inferences from the distributions of fast radio burst pulse widths, dispersion measures, and fluences

The widths, dispersion measures (DMs), dispersion indices, and fluences of Fast Radio Bursts (FRBs) impose coupled constraints that all models must satisfy. The non-monotonic dependence of burst widths (after deconvolution of instrumental effects) on DMs excludes the intergalactic medium as the location of scattering that broadens the FRBs in time. Temporal broadening far greater than that of pulsars at similar high Galactic latitudes implies that scattering occurs close to the sources where high densities and strong turbulence or heterogeneity are plausible. FRB energetics are consistent with supergiant pulses from young, fast, high-field pulsars at cosmological distances. The distribution of FRB DMs is: (1) inconsistent with that of expanding clouds (such as SNRs); (2) inconsistent with space-limited source populations (such as the local Supercluster); and (3) consistent with intergalactic dispersion of a homogeneous source population at cosmological distances. Finally, the FRB log N–log S relation also indicates a cosmological distribution aside from the anomalously bright Lorimer burst.

79 ASTRONOMY AND ASTROPHYSICS↗

A stellar velocity dispersion for a strongly lensed, intermediate-mass quiescent galaxy at z = 2.8

Measuring stellar velocity dispersions of quiescent galaxies beyond z∼2 is observationally challenging. Such measurements require near-infrared spectra with a continuum detection of at least moderate signal to noise, often necessitating long integrations. In this paper, we present deep X-Shooter spectroscopy of one of only two known gravitationally lensed massive quiescent galaxies at z>2. This galaxy is quadruply imaged, with the brightest images magnified by a factor of ∼5. The total exposure time of our data is 9.8 hr on-source; however, the magnification, and the slit placement encompassing two images, provides a total equivalent exposure time of 215 hr. From this deep spectrum we measure a redshift of (z{sub spec}=2.756±0.001), making this one of the highest redshift quiescent galaxies that is spectroscopically confirmed. We simultaneously fit both the spectroscopic and photometric data to determine stellar population parameters and conclude that this galaxy is relatively young (560{sub −80}{sup +100} Myr), of intermediate mass (log M{sub ∗}/M{sub ⊙}=10.59{sub −0.05}{sup +0.04}), consistent with low dust content (A{sub V}=0.20{sub −0.20}{sup +0.26}), and has quenched only relatively recently. This recent quenching is confirmed by strong Balmer absorption, particularly Hδ (Hδ{sub A}=6.66{sub −0.92}{sup +0.96}). Remarkably, this proves that at least some intermediate-mass galaxies have already quenched as early as z∼2.8. Additionally, we have measured a velocity dispersion of (σ=187±43 km s{sup −1}), making this the highest-redshift quiescent galaxy with a dispersion measurement. We confirm that this galaxy falls on the same mass fundamental plane (MFP) as galaxies at z = 2.2, consistent with little to no evolution in the MFP up to z = 2.8. Overall this galaxy is proof of the existence of intermediate-mass quenched galaxies in the distant universe, and that lensing is a powerful tool for determining their properties with improved accuracy.

79 ASTRONOMY AND ASTROPHYSICS↗

A Universal Velocity Dispersion Profile for Pressure Supported Systems: Evidence for MONDian Gravity across Seven Orders of Magnitude in Mass

For any MONDian extended theory of gravity where the rotation curves of spiral galaxies are explained through a change in physics rather than the hypothesis of dark matter, a generic dynamical behavior is expected for pressure supported systems: an outer flattening of the velocity dispersion profile occurring at a characteristic radius, where both the amplitude of this flat velocity dispersion and the radius at which it appears are predicted to show distinct scalings with the total mass of the system. By carefully analyzing the dynamics of globular clusters and elliptical galaxies, we are able to significantly extend the astronomical diversity of objects in which MONDian gravity has been tested, from spiral galaxies to the much larger mass range covered by pressure supported systems. We show that a universal projected velocity dispersion profile accurately describes various classes of pressure supported systems, and further, that the expectations of extended gravity are met across seven orders of magnitude in mass. These observed scalings are not expected under dark matter cosmology, and would require particular explanations tuned at the scales of each distinct astrophysical system.

79 ASTRONOMY AND ASTROPHYSICS↗

Dispersive Evolution of Nonlinear Fast Magnetoacoustic Wave Trains

Quasi-periodic rapidly propagating wave trains are frequently observed in extreme ultraviolet observations of the solar corona, or are inferred by the quasi-periodic modulation of radio emission. The dispersive nature of fast magnetohydrodynamic waves in coronal structures provides a robust mechanism to explain the detected quasi-periodic patterns. We perform 2D numerical simulations of impulsively generated wave trains in coronal plasma slabs and investigate how the behavior of the trapped and leaky components depend on the properties of the initial perturbation. For large amplitude compressive perturbations, the geometrical dispersion associated with the waveguide suppresses the nonlinear steepening for the trapped wave train. The wave train formed by the leaky components does not experience dispersion once it leaves the waveguide and so can steepen and form shocks. The mechanism we consider can lead to the formation of multiple shock fronts by a single, large amplitude, impulsive event and so can account for quasi-periodic features observed in radio spectra.

79 ASTRONOMY AND ASTROPHYSICS↗

An analysis of the phase dispersion in the symmetric beam combiner

An astronomical beam combiner combines the two beams of starlight to form white-light fringes. It is desirable that the dispersion of the beam combiner be minimized across the observation wavelength range. We present here an analysis of the phase dispersion from coatings for a symmetric beam combiner. The sensitivity of the dispersion to a slight mismatch in beamsplitter coatings is also studied.

coatings↗

Boric Acid Dispersion of Biofilm (BAD-B)

Biofilms in spacecraft water recycling systems (WRS) can cause crew illness, occlude water lines, and induce corrosion on WRS materials. The treatment of biofilms in spacecraft water systems has historically been limited by a lack of suitable methods to overcome biofilm-associated antimicrobial tolerance (AMT). One way to get around AMT is to induce biofilm dispersion. To address AMT in spacecraft WRS, I evaluated the use of boric acid (BA) as an agent to disperse biofilms formed on common WRS materials, including 316L stainless steel, PFTE Teflon, and Ti6Al4V titanium alloy. Recent studies have shown that BA can be effective at dispersing biofilms of a variety of bacterial species. BA has also been shown to interact synergistically with antibiotics and disinfectants.

microbiology↗

Effects of Oxide Dispersion on Failure Modes in an Additively Manufactured Superalloy

Additive manufacturing opens new paths for introducing oxide particles into superalloys, to potentially provide oxide dispersion strengthening (ODS) at high temperatures. This provides opportunities to study how such dispersions can influence failure modes for a given superalloy, after nearly identical material processing paths. The objective of this study was to compare monotonic failure modes for additively manufactured superalloys with versus without an introduced oxide dispersion. The superalloy for each case was produced by laser powder bed fusion additive manufacturing. Specimens were subsequently given consistent thermal treatment paths and then tested in tensile and creep tests at varied temperatures. Failure modes were then compared. Additively manufactured NiCrAl without ODS had randomly oriented equiaxed grains while this alloy with 0.25 wt% Y 2 O 3 ODS additions had elongated [001] oriented grains in the build direction. Material made without ODS (“No-ODS”) was nearly completely single phase gamma, while ODS additions resulted in gamma, chromium carbide, and Y-Al-Cr oxide phases, with carbide and oxide phases contents estimated at no more than 13 and 1 vol%, respectively. Compared to No-ODS, material made with ODS had higher tensile strengths at room, 760 and 1093 °C. The elongation of ODS material was lower than No-ODS at room temperature, but higher at 760 °C. At 1093 °C ODS material had higher elongation than No-ODS when tested in the build direction, however elongation was lower for ODS material in the transverse direction at 1093 °C. Creep rupture strain, life, and area reduction at 760 and 1093 °C were all much higher for ODS material compared to No-ODS; 760 °C rupture life was nearly 100 times longer for ODS material. The presence of Y in the ODS material significantly improved oxidation resistance.

supperalloys↗

A Robust Processing Approach for Producing Highly Loaded Dispersion Fuels

A robust fabrication method, resulting in higher yields, to produce highly loaded U3Si2-Al dispersion fuels for converting research reactors from a high enriched to a low enriched uranium fuel needs to be developed. To reliably produce a highly loaded dispersion fuel, process changes need to be implemented where the traditional approach has experienced challenges and poor yields. The present work describes the key changes needed. Parts of the work were done with uranium silicide and parts were completed with a representative silicide surrogate. The major deviations from traditional fabrication methods are associated with a refinement in particle size distribution, method for compacting to achieve complex shapes, and welding of the aluminum picture frame used to encapsulate the fuel compact. Methods for rolling and arc melting are also discussed. By using the methods described within, fabricating a highly loaded dispersion fuel that can meet stringent fuel homogeneity and geometry requirements at higher yields and lower costs may be possible.

U3Si2, HFIR, dispersion fuel, Uranium, Research Re↗

Computational Investigation of Fuel Dispersal Phenomena during Large-Break Loss of Coolant Accident in Light-Water Reactors

In the event of cladding rupture, which could occur in light water reactor fuel assemblies during a loss-of-coolant accident (LOCA), fuel particles, along with fission gases, can be expelled into the reactor core from the fractured fuel rod. This expulsion of fragmented fuel particles, referred as fuel dispersal, is the subject of investigation to evaluate the safety implications of increasing fuel burnup in light water reactors, with a specific focus on fuel fragmentation, relocation, and dispersal. Particle trajectories and the resulting mass distribution of the settled particles within the reactor pressure vessel can pose a long-term cooling challenge for the reactor core. The fuel dispersal phenomenon is significantly influenced by the ejection characteristics of the fuel fragments, as well as the size and shape of the cladding rupture and fuel rod depressurization history during LOCA transients. In this study, the transport of fuel particles within a scaled 5 × 5 lattice of a pressurized water reactor rod bundle geometry is modeled through a two-fluid Eulerian framework that treats the gas and solid phases as interpenetrating continua. The required boundary conditions are evaluated from the fuel performance code BISON in a postulated large-break LOCA scenario. The modeling framework considers solid fuel particles as granular matter, interacting with the gaseous dry steam phase and fission gases through the governing interfacial momentum and energy exchange between the gas and solid phases. The simulation results provide the volume fraction of the solids settled on the bottom surface of the fuel bundle, quantifying the deposition within the bundle geometry.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Collective Dispersal Leads to Variance in Fitness and Maintains Offspring Size Variation within Marine Populations

Variance in fitness is well known to influence the outcome of evolution but is rarely considered in the theory of marine reproductive strategies. In coastal environments, turbulent mesoscale eddies can collect larvae into packets, resulting in collective dispersal. Larvae in packets return to the coast or are lost offshore in groups, producing variance in fitness. Using a Markov process to calculate fixation probabilities for competing phenotypes, we examine the evolution of offspring size and spawning duration in species with benthic adults and pelagic offspring. The offspring size that provides mothers with the highest mean fitness also generates the greatest variance in fitness, but pairwise invasion plots show that bet-hedging strategies are not evolutionarily stable; maximizing expected fitness correctly predicts the unique evolutionarily stable strategy. Nonetheless, fixation can take a long time. We find that selection to increase spawning duration as a risk avoidance strategy to reduce the negative impacts of stochastic recruitment success can allow multiple offspring sizes to coexist in a population for extended periods. This has two important consequences for offspring size: (1) coexistence occurs over a broader range of sizes and is longer when spawning duration is longer because longer spawning durations reduce variation in fitness and increase the time to fixation, and (2) longer spawning durations can compensate for having a nonoptimal size and even allow less optimal sizes to reach fixation. Collective dispersal and longer spawning durations could effectively maintain offspring size variation even in the absence of good and bad years or locations. Finally, empirical comparisons of offspring size would therefore not always reflect environment-specific differences in the optimal size.

59 BASIC BIOLOGICAL SCIENCES↗

Chemical Vapor Deposition for Atomically Dispersed and Nitrogen Coordinated Single Metal Site Catalysts

Abstract Atomically dispersed and nitrogen coordinated single metal sites (M‐N‐C, M=Fe, Co, Ni, Mn) are the popular platinum group‐metal (PGM)‐free catalysts for many electrochemical reactions. Traditional wet‐chemistry catalyst synthesis often requires complex procedures with unsatisfied reproducibility and scalability. Here, we report a facile chemical vapor deposition (CVD) strategy to synthesize the promising M‐N‐C catalysts. The deposition of gaseous 2‐methylimidazole onto M‐doped ZnO substrates, followed by an in situ thermal activation, effectively generated single metal sites well dispersed into porous carbon. In particular, an optimal CVD‐derived Fe‐N‐C catalyst exclusively contains atomically dispersed FeN 4 sites with increased Fe loading relative to other catalysts from wet‐chemistry synthesis. The catalyst exhibited outstanding oxygen‐reduction activity in acidic electrolytes, which was further studied in proton‐exchange membrane fuel cells with encouraging performance.

Liu, Shengwen↗

Atomically Dispersed Ni‐N‐C Catalysts for Electrochemical CO 2 Reduction

Abstract The atomic dispersion of nickel in Ni‐N‐C catalysts is key for the selective generation of carbon monoxide through the electrochemical carbon dioxide reduction reaction (CO 2 RR). Herein, the study reports a highly selective, atomically dispersed Ni 1.0% ‐N‐C catalyst with reduced Ni loading compared to previous reports. Extensive materials characterization fails to detect Ni crystalline phases, reveals the highest concentration of atomically dispersed Ni metal, and confirms the presence of the proposed Ni‐N x active site at this reduced loading. The catalyst shows excellent activity and selectivity toward CO generation, with a faradaic efficiency for CO generation (FE CO ) of 97% and partial current density for CO (j co ) of ‐9.0 mA cm −2 at ‐0.9 V in an electrochemical H‐type cell. CO 2 RR activity and selectivity are also studied by rotating disk electrode (RDE) measurements where transport limitations can be suppressed. It is expected that the utility of these Ni‐N‐C catalysts will lie with tandem CO 2 RR reaction schemes to multi‐carbon (C 2+ ) products.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Dispersion relation for hadronic light-by-light scattering: two-pion contributions

In our third paper of a series dedicated to a dispersive treatment of the hadronic light-by-light (HLbL) tensor, we derive a partial-wave formulation for two-pion intermediate states in the HLbL contribution to the anomalous magnetic moment of the muon (g - 2) μ , including a detailed discussion of the unitarity relation for arbitrary partial waves. We show that obtaining a final expression free from unphysical helicity partial waves is a subtle issue, which we thoroughly clarify. As a by-product, we obtain a set of sum rules that could be used to constrain future calculations of γ*γ* → ππ. We validate the formalism extensively using the pion-box contribution, defined by two-pion intermediate states with a pion-pole left-hand cut, and demonstrate how the full known result is reproduced when resumming the partial waves. Using dispersive fits to high-statistics data for the pion vector form factor, we provide an evaluation of the full pion box, a$π-box\atop{μ}$ =-15.9(2) × 10 -11 . As an application of the partial-wave formalism, we present a first calculation of ππ-rescattering effects in HLbL scattering, with γ*γ* → ππ helicity partial waves constructed dispersively using ππ phase shifts derived from the inverse-amplitude method. In this way, the isospin-0 part of our calculation can be interpreted as the contribution of the f0(500) to HLbL scattering in (g - 2) μ . We also argue that the contribution due to charged-pion rescattering implements corrections related to the corresponding pion polarizability and show that these are moderate. Our final result for the sum of pion-box contribution and its S-wave rescattering corrections reads a$π-box\atop{μ}$ + a$ππ, π-pole LHC\atop{μ, J=0}$ = -24(1) × 10 -11 .

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

New Approaches to Study of Thermodynamic Parameters of Oil Disperse Systems

Crude oil and heavy petroleum products are oil disperse systems whose properties depend largely on their thermodynamic state. To determine the thermodynamic parameters and aggregative stability of oil disperse systems, it is proposed to use the inverse gas chromatographic method, which allows calculation of the free surface energy, entropy, and enthalpy of the oil disperse systems from the retention volume.

02 PETROLEUM↗