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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 613 records · Page 34
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Burst pressure models and validations for thick-walled pipelines containing corrosion defects

Corrosion is one major threat to pipeline integrity. Over the past decades, many corrosion models have been developed for determining the remaining strength of corroded pipelines, including ASME B31.G, Modified B31.G, LPC, PCORRC and their modified models. All these corrosion models are applicable only to large diameter, thin-walled pipelines with a diameter to wall thickness ratio D/t ≥ 20. In practice, many pipelines have a small diameter and thick wall with a D/t ratio < 20, and thus an adequate corrosion model is needed for assessing remaining strength for corroded thick-walled pipelines. This paper briefly reviews the theoretical burst pressure models for defect-free thin and thick-walled pipelines and four representative corrosion assessment models for thin-walled corroded pipelines. On this basis, two modified corrosion models are proposed to thick-walled pipelines in terms of the average shear stress yield theory. To verify the proposed corrosion models, comprehensive validations are performed. Numerical validations include the elastic-plastic finite element analysis to determine burst pressure for pipelines without and with corrosion defects and the model evaluation using a large dataset of available FEA results of burst pressure for machined defects. Experimental validations include a set of burst pressure tests for defect-free thick-walled pipes with different thicknesses and the model evaluation using one large burst dataset for machined defects with flat bottoms and another large dataset for real corrosion defects with curved river bottom profiles. Both numerical and experimental validations show that the proposed corrosion models can more accurately predict the remaining strength for corroded thin and thick-walled pipelines.

Pipeline↗
DOE OSTI2021

CO 2 -selective membranes containing amino acid salts for CO 2 /N 2 separation

In this paper, facilitated transport membranes comprising polyvinylamine (PVAm) as fixed carrier and different amino acid salts (AAS) as mobile carriers were synthesized for post-combustion capture. The AAS carriers were prepared by deprotonating alanine (Ala), lysine (Lys), and proline (Pro) with 2-(1-piperazinyl)ethylamine (PZEA). CO 2 separation performances of the membranes with these AAS carriers were compared, and the AAS effectiveness to facilitate transport of CO 2 was in the order of PZEA-Pro > PZEA-Lys > PZEA-Ala. Here, the membrane comprising 35 wt.% PVAm and 65 wt.% PZEA-Pro at 57 °C rendered a promising CO 2 permeance of 936 GPU and a CO 2 /N 2 mixed gas selectivity of 193. When the PVAm was reduced to 15 wt.%, i.e., its 20 wt.% was replaced by the mobile carrier of PZEA-Sar (sarcosinate), the permeance further improved to 947 GPU with a remarkable CO 2 /N 2 selectivity of 210. Moreover, thermal gravimetric analysis showed a good thermal stability of the membrane, and membrane stability testing also gave stable transport performance. Furthermore, spectroscopic ellipsometry analysis exhibited a uniform membrane selective layer and an excellent agreement on the membrane thickness of ca. 170 nm measured independently by SEM. In addition, the membranes presented in this paper surpassed both the Robeson upper bound and the modified upper bound, indicating a great potential for CO 2 capture.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Finely tuning the microporosity in phosphoric acid doped triptycene-containing polybenzimidazole membranes for highly permselective helium and hydrogen recovery

High-performance polymer membranes with well-defined microporosity and size-sieving ability are especially attractive for helium and hydrogen recovery. Here, in this study, we report novel macromolecular engineering of polybenzimidazole (PBI) membranes that integrate hierarchical triptycene units for high permeability and polyprotic acid doping for size sieving via controllable manipulation of microporous architecture. The triptycene moieties disrupt chain packing and introduce additional configurational free volume, leading to significantly boosted He and H 2 permeabilities compared to previously reported PBI membranes. The acid doping resulted in crosslinked PBI membranes via hydrogen bonding and proton transfer with dramatically enhanced gas selectivities. Via adjusting the H 3 PO 4 -doping level, triptycene-based polybenzimidazole (TPBI) composite membranes (TPBI-(H 3 PO 4 ) x ) exhibit the highest gas selectivities for He enrichment (i.e., α(He/CH 4 ) = 7052 ± 156) and H 2 purification (i.e., α(H 2 /CH 4 ) = 5128 ± 110) among existing polymeric gas separation membranes. Additionally, under mixed-gas conditions at 150 °C, the TPBI-(H 3 PO 4 ) 0.98 membrane displays a H 2 permeability of 46.7 Barrer and a H 2 /CO 2 selectivity of 16, far beyond the Robeson's 2008 upper bound for H 2 /CO 2 separation. The facile and diverse tunability and excellent gas separation performance make TPBI-(H 3 PO 4 ) x membranes highly attractive for helium and hydrogen separation.

42 ENGINEERING↗
DOE OSTI2022

Electrochemical, thermodynamic, and physical properties of tetradecyltrihexylphosphonium ([P 6,6, 6,14 ] + ) and methyl-propyl piperidinium containing ionic liquids and their propylene carbonate solutions

Here, the viscosity, conductivity, electrochemical window and related thermodynamic properties such as excess volume and dynamic viscosity deviation of two phosphonium ionic liquids were measured and calculated for “as-supplied” and dried neat liquids and also v/v mixtures of 99/1, 95/5, 90/10, 75/25, and 50/50 of the ionic liquids with propylene carbonate (PC). Tetradecyltrihexylphosphonium dicyanamide ([P 6,6,6,14 ] + dicyanamide), Cyphos 105, and tetradecyltrihexylphosphonium bis(trifluororomethanesulfonyl)imide (called bistriflimide) ([P 6,6,6,14 ] + bistriflimide), Cyphos 109, ionic liquids were studied. Generally speaking, there were slight differences in the measured properties of the wet and dried IL solutions which were reflected in differences if the calculated properties. The measured and calculated properties were compared with those collected and derived from a piperidinium-based ionic liquid, methyl-propyl piperidinium bistriflimide. Arrhenius plots for both the viscosity and conductivity were linear, with the linearity of the Litovitz plots being slightly higher. The viscosity and conductivity of the phosphonium solutions yielded Walden Plots that differed from Walden plots of piperidinium solutions and other ionic liquid solutions. For the phosphonium based ionic liquids, the ionicity was found to increase with increasing dilution in propylene carbonate. The electrochemical windows of the ionic liquids were determined as a function of the concentration of the ionic liquid present in the solution. The size of the window generally initially decreased and then increased with the addition of PC for the [P 6,6,6,14 ] + dicyanamide ionic liquid increasing from 3.4 V in the 95/5 v/v (volume Cyphos 105) to volume of PC solvent) to 3.7 in the 50/50 dried IL case. The electrochemical windows of the dried liquids were slightly larger 3.5 V for the 95/5 v/v and 4.2 V for the 50/50 v/v Cyphos 105/PC solutions. The electrochemical window was larger and the conductivity was higher for the piperidinium IL solutions, but since the ionicity increases with dilution, the phosphonium based IL solutions may prove favorable for processes such as electrochemical reduction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Microstructure and mechanical properties of high Mn-containing ferritic-martensitic alloys exposed to cyclical thermal treatment

Substantial residual tensile stress tends to accumulate in currently available high-Cr ferritic martensitic steels that are subjected to cyclical heat treatment, which leads to premature brittle fracture. By tailoring the alloy composition, this thermal cycling can be exploited to induce a high number density of nanoprecipitates and phase transformations countering residual tensile stresses. In this work, three new variants of ferritic-martensitic steels have been designed with computational thermodynamics to meet the goals of mitigating residual tensile stresses by lowering martensite start temperatures and of enhancing mechanical strength and irradiation sink strength by increasing the number density of nanoprecipitates. Furthermore, ctenast materials were subjected to cyclical heat treatment. The thermally cycled samples were evaluated with mechanical testing and microstructural analysis to identify the optimal composition in which figures of merit include low residual stress and a high density of nanoscale MX (M = metal, X = C/N) precipitates, leading to high yield strength with reasonable ductility. The noticeably higher density of nanoprecipitates in the optimal alloy favor its higher yield strength, which is supported by the microstructure-derived yield strength calculation and precipitation kinetics simulation.

36 MATERIALS SCIENCE↗
DOE OSTI2022

An overview of cobalt-free, nickel-containing cathodes for Li-ion batteries

The need for high-energy, low-cost batteries is projected to grow dramatically in the next decade due to electrification of the transportation market. Such demands are straining Li-ion supply chains for critical materials including lithium, nickel, and cobalt. Price instability, environment toxicity, and limits in the absolute supply lead to great concern for the continued use of cobalt. Similar to cobalt, the required grade of nickel for batteries, known as Class 1 nickel, has also been declining due to geological scarcity and low incentive prices. Herein, this review summarizes alternative cathode chemistries with no cobalt and reduced nickel content for high-energy Li-ion batteries targeting sustainable growth in the electric vehicle market. Further, the primary challenges associated with each material system are generally classified as being related to four common categories: (1) ion instability during charging, (2) poor electronic conductivity, (3) poor ionic conductivity, and (4) poor thermal stability.

25 ENERGY STORAGE↗
DOE OSTI2024

Superconductivity in CH 4 and BH – 4 containing compounds derived from the high-pressure superhydrides

Inspired by the synthesis of the high-pressure Fm3m LaH 10 superconducting superhydride, systematic density functional theory (DFT) calculations are performed to study ternaries that could be derived from it by replacing two of the hydrogen atoms with boron or carbon and varying the identity of the electropositive element. Though many of the resulting alkali-metal and alkaline-earth MC 2 H 8 phases are predicted to be dynamically stable at mild pressures, their superconducting critical temperatures (T c s) are low because their metallicity results from the filling of an electride-like band. Substitution with a trivalent element leads to phases with substantial metal d- character at the Fermi level whose T c s are typically above 40 K. Here, among the MB 2 H 8 phases examined, KB 2 H 8 , RbB 2 H 8 and CsB 2 H 8 are predicted to be dynamically stable at very mild pressures, and their stability is rationalized by a DFT-Chemical Pressure analysis that elucidates the role of the M atom size. Quantum anharmonic effects strongly affect the properties of KB 2 H 8 , the highest predicted T c compound, near 10 GPa, but molecular dynamics simulations reveal it would decompose below its T c at this pressure. Nonetheless, at ca. 50 GPa KB 2 H 8 is predicted to be thermally stable with a superconducting figure of merit surpassing that of the recently synthesized LaBeH 8 .

36 MATERIALS SCIENCE↗
DOE OSTI2021

Full core LOCA safety analysis for a PWR containing high burnup fuel

For economic reasons, the US nuclear industry is renewing efforts to build a technical basis to extend peak rod average burnup limits above the current regulatory burnup limit of 62 GWd/MTU. The primary driver of these efforts is to economically increase pressurized water reactor (PWR) cycle lengths to 24 months, reduce the number of fresh fuel assemblies, increase time online, thereby reducing number of outages and their associated cost, higher fuel utilization, and possibly reduce core design constraints. In order for US nuclear utilities to leverage these economic efficiencies, the US Nuclear Regulatory Commission (NRC) will likely require nuclear power plants (NPPs) to analyze a number of potential operational occurrences and their potential consequences with each new core design prior to resuming normal operation. Potential operational occurrences can be divided into three primary regimes: (1) normal operation, (2) anticipated operation occurrences (AOOs), and (3) design basis accidents (DBAs). Normal plant operation is an operating regime in which the plant operates within specified operational limits until the end of the cycle, whereas AOOs are events that result in the NPP deviating outside the normal operating regime. A key attribute of an AOO is that the occurrence should be expected. However, by definition, the occurrence of an AOO does not result in significant impact to critical safety functions. The last potential operational occurrence is a DBA. From the fuel performance point-of-view, DBAs can be subdivided into two bounding categories: (1) loss of coolant accidents (LOCAs), and (2) reactivity insertion accidents (RIAs). Unlike AOOs, DBAs may result in fuel rod failure. The NRC imposes fundamental acceptance criteria to minimize radiological consequences to the public and onsite staff. Furthermore, safety criteria are typically linked to the fulfillment of other acceptance criteria related to reactor safety equipment designed to mitigate DBAs.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗